SCIENTIFIC ABSTRACT G.I. DERKACH - K.N. DERKACH

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• Collection: Scientific Abstracts
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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

AUTHORS;
TIME.
PERIODICAL:
2 Z 1 0,
84882.
S/079 150/030/1310/023/030
BOO1YBo66
Derkach- G. I. and Kirsanov, A. V.
Polymerization of N-Diaroxy-phosphinyl Arene Amidin
Zhurnal obshchey khimii, 1960, Vol. 30, No. 10,
pp. 3397 - 3401
TEXT: The amidines ArC[-NPO(OArl)2]NH2 synthesized by the authors in a
previous work are quickly and quantitatively polymerized by strong
mineral acids to give colorless, crystalline products without basic
properties (Table 1), According to their ultimate analysis and molecul&r
,ght, they are trimers of the 11--diaroxy-phosphinyl arene amidines.
wei
Polymerization takes place readily and with small quantities of strong V
mineral acids, as well as with formic and ac.etic anid; benzoic acid is
ineffective. If the amidine hydrochlorides &re exposed to air, they are
quaatitatively converted into trimers after some days, which is not the
case in dry air, not even after several months. Polymerization, procpeds
smoothly when boilinE their salts in 961/1fa ethanol and, dissolving them in
Card 113

81,881
Polymerization of N-Diaroxy-phospliinyl 8/079/60/030/01D/023/030
Arene Amidine B000066
concentrated sulfuric acid. The trimers of N-diaroxy-F-hosphinyl arene
amidines greatly differ in their properties from the initial monomers:
They melt at considerably higher temperatureEl, are insoluble in most
organic solvents (contrary to the monomers), and are riot changed when
treated with dilute acids and alkali lyes, not even by short boiling.
Polymerization is usually caused by the unsaturated state of "he mole
cule. Thus, a double bond --ausing trimerizat-ion is bound to exast in the
molecules of N-diaroxy-phosphinyl arene amidines, i-e., between the
carbon atom and one of the nitrogen atoms. It can thus be illustrated
only by the two tautomeric forms
NE - H~ N --.- 11.
ArC 0 ArC 0
N - P(OArt)2 NH -- f(OAr!)2
M (II)
For this work,some N-diaroxy-phoophinyl arene amidines hitilerto unknown
were synthesized by the previous method (Table 2). There are 2 tables
~ ---1 --5 /7

84881
Polymerization of N-Diaroxy-phosphinyl S/079 60/03o/biO/023/030
Aiene Kmidine BOOlYBO66
and 5 :^eferences: 3 Soviet and 2 Gorman..
ASSOCIATION: Institut organichenkoy khimii Akademii nauk
Ukrainskoy SSR (Institute of Organic Chemist:ry of the
Academy of Science3 Ukrainskays SSR)
SUBMITTED: November 9, 1959
f, a ~A A /:;

DERKACH. DREGVALI, Vo KIRSANOV, A.V.
D-ichlorophosphazi~-it-ary.Iiiu3Xorayliminobenmoyls. ZhuroobAhim* 30
nci.10:3402-3407 6.~.
,- "~ 161. (MMA 1434)
L Inatitut organichookoy khimii All UkraJzskoy SSR.
(Phoophazo compowuls)

FROTSENKO, L.D.; CH9 G.I.; KIRSJLNOV,, A.V.
Bistriethylenetriamidophoophfizo derivatives of dibaoic acids
and diethylenediamides of bio-li--diethylenediamidophospliimylimino-
carboxylic acids. Zhur.obekhim. 31 DO-10:3433-3436 0 161.
(MMA 14:10)
1. Institut organichaskoy khImii AN Ukrainskoy SSR i Mrrainskiy
nauchno-issledovatel'skiy saaUtarno-khimicheskiy institut.
(Acids, Organic) (Phosphazo compounds)

KROPACREVA, A,.A.;,DERKACH, G.I.; KIRSANOV, A.V.
N, Kf, NR-Triethylenetriamidophoupliazo Compounds and N'. IP, Nt"-
trietlWlezt~-N-diamidophosphiny3Areimmidiaes, Zhur.ob.khIm. 31 ,
L
no. 5:3.60246% Yjv 161. OMU 1410,)
le Institut orgaLnicheakoy khimii Akademii nauk Ukrainakoy SSR.
(Pho5pbazo compounds) (Amidines)

-DERKACH,--O.I.j SHOKOL, Y.A.; KIRSANOVj, A.V.
NI-di:aroxyphciophinyl-N2(N3-qr.vlthioctirbaminyl) arenamidines
ENI-aryi-N2- lq3* iyl -' royl),thioureal. 2,bur.
diaroxyphosphb iminoa
ob.kh:lm. 31 no..792275-2282 Jl 161. (kW 14:7)
i
1. Institut organichesko'y kIdmii AN Ukrainakoy $SR.
(lirea) (Amidines)

DMYACH, G.I.; DREGVALI, G.F.; KIRSAWOV, AS.
Triaryloxy I)hosphazo-N-Arylsvlfonyliminobenzoyls_and R-!
cliarylox-yphosphinyl-NI-arylsu:LfonylWnzamidines. Zhur.ob.khim,
31 no.7:2385-2390 Jl 161. (MIRA 3-4:7)
1. Institut organichesko7 khimii AN Ukrainskoy SSR.
(Phosphorus organic compounds) (Benzamidines)

DMACH, G.I.; KRUMENT-11RIKHODIKO, V.V.; KULSANOV, AS.
11-diaminaphosphiny'laroy2amides. Zhur.ob.khim. 31 no.7:2391-23016
il 161. (KRA 14:7)
I, Institut organicheakoy khimii AN Ukrainskoy SSR.
(Phosphinic amide)

DFAIUCH G I - GUBNITSKAYA, Ye.S.; KIRSANOV, A.V.
-- tt~~-
Triphenylphospbazoaro~lsj, H-diphanylphosF,hinylphanylarvl ketimines..
and N-diarylphosphinylaroyl amides. Zhur. ob. khim. 31 no. 11:3679-
3684 N 161, (KMA 14:11)
1. Institut organicheskoy khimii AN Ukrainskoy SSR.
(Phosphorus organic compounds)

DEMCH, G.I.; GUBITITSKAYA, Ye.S.; KIRSAVOV, A.V.
TrianilidophosphazDaroyls and N-dianilidciphosphinyl-NO-al-11-
arenamidines. Zhur. ob. khIm. 31 no. 1.1:3746-3750 N 161.
(14IRA 14: 11)
1. Institut organicheskay khiTnii AN Ukridmakoy SSR.
(Phosphazo compounda) (Amidinefs)

DERUCHp G.I.-, DREGVAL', G.F.; KIRWOVp AN.
Trianilidophosphazo-N-tu7lsulfonylaminobenzoyle andN'-Iianilidophos-
phinyl-NI-arylaulfon,ylbenzamidines. Zhur. ob. khim. 32 no.1:154-159
Ja 162. (MIRk 15:2)
1. Institut organicheskoy khimii AN Ukrainsko SSR
(Phosphorus organic compoundsT

I
DERMACH G.1 - S40KOL, V.A.; 3AMARAY, L.I.; KTJWCV, A.V.
=-~~ I J
Now method of preparing triohlorophosphaw.)acyls. Zhur. ob. khim.
32 no.2tl59-160 Ja 162. (MIRA 15-~)
1. Institut organichookoy kbimii AN Ukrainskoy SSR.
(Phoophazo compmado)

SHOKOLp V.A.; DERKAGH, G. I. - KIIWOV, A.V.
Phonyldl:ohloro- and diph(~nylahlorophosl)h&2o-dichloro-and
trichloroacetyls and their derivatives. Zhur'. ob. khim. 32 no.l:
166-171 Ja 162. (MIRA 15:2)
1. Institut organicheskoy kbimii M Ukrainskoy SSR.
(Phosphazo compounds)

DERUGH) 0.1;; LEPESA, A.M4; KIRWOV, AN.
Alk7l eaters of N-dialkocyphospllinyl.,Iminocarboxylic acids.
Zhur. ob, khim, 32 no,1:17:L-174 Ja '62. (MJM 3-5:2)
1. Institut organichaskoy khimii AN Ukrainskoy SSR.
(Phosphinic acid)

-'-:;'NOV
.. A I A.V., [Kirsanov, O.V.] akademik; LEFESA, A.M.; DERKACK, G.I.
a
(Derkach, H.I.1
Et ers of monoanilides of aroylamidophosphoric acids. Dop. All
URSR no.3:384-386 162. (MIRA 15:5)
1. Institut organicheskoy khimii AN USSR. 2. AN USSR (for
Kirsanov).
(Phosphoramidic acid) (Ethers)

DERKACH, G.I.; GUBNITSKAYA, Ye.S.; SHOKOL, V.A.; KIRSANOV, A.V.
Triaroxyphosphazoacyls. Part 2. Zhw-.ob.Ichim. 32 no.4t1201-
1207 Ap '62. (MIRA 15-4)
1. Institut organicheskoy kh:Lmii AN Mcrainskoy SSR.
(Phosphorus organic compounds) (Esters)

KROPACHEVI, A.A.;__DERKACR,,-G.I.-~--ZHURAVLEVA, L.P.; SAZDKOV, N.V.;
KIRSANOVt A.V.
N-diethylonedimidophosphonyl-M-arylurea. Zhur.obAhim, 32
no,5t1540-1542 My 162. (MM 15:5)
(Urea)

DEWCH,, G.I.; GUBNITSKAyk, YG-S-; SHOKOL, V.A.; KIRS.41?OV, A.V.
Phenyldictiloro-., dipherqleUoro-,, and triphenylphoElphazo acyls.
Zhur.ob.lddin. 32 no.6-.1874-1878 Je 162. (14IRA 15:6)
1. Institut organicheskoy Irbimii'Akademii nauk Ma-ainskoy SSR.
(Phospbazo compo=ds)

',,j-4--J)0IZVA G.F.; KIRSANOV, A.V.
DERKACIII. G LS
Derivatives of phosphorylated amidines. Zhur.ob.l:him. 32 no.6:2878-
1882. Jo 162. (MMA 15:6)
1. Institut organichealcoy khimii Akademii nauk Ul=ainsko SSR.
(Amidine) (Phosphorus organic campounM

DERKACH, G.I.; MMARAY, L.I.
Reaction of antimony pentochloride with alkyl esters of iminocarboxylic
acids* Zhur.ob.khime 32 no.6:205;8 Je 162. (MIRA 15:6)
1. Institut organicheakoy Iddidi Akademii nauk Ukrainskoy SSR.
(Antimony chlorides) (Esters)

DERKACHJ, G.I.; SMARAY, L.I.; SHOKOL, V..A.
lli~ --
Trichloropho .,.--0 acyls. Zhursiobekhim, 32 noo6:2059 Je 162,
(MRA 15-.6)
1. Institut organicheskc~~U.Akademii nauk Ukrainskoy SSR.
(Phosphazo compounds)

KIRSANOV, A.V.
Phosphorylated amicUnes. RunobAhim. 32 no.7.2254-2256 JI 262.
MRA 15:7)
I. Iwt1tut organtcheskoy,khimli Ali USSR.
(AmMines) (Phoophorous acid)

DERUCH, 0.1.
N-dicblorophoqphirq1ixide chlorides of carboxylic acid.
zi~~lulicatlwl of
4A,
u,)I, by Fa-.:,,z!r Acad, lcl,,
C011OCtion of comllet~- owwi-Ii LwosimL-md At the

___pKaWHT-C..L4 ZHURAVLEVA, L.P.; KIRSANOV, A.V.
N-dichlorophotiphinyl-NI-aryl-C-c'hloroformamidines. Zhur.ob.khim
32 no.)s879-4)81 Mr 162. (MA 15:3~
1. Institut organicheakoy khImii AN Ukrainskoy SSR.
(Formamidins) (Phosphinic chloride)

DEMCH G.1 ; LEFESA, A.M.1 III&SANOVp A.V.
Derivatives of monowdlides of aroylamidopboapboric acide. 2hur.-
ob.kWz. 32 no.8.2600-2606 Ag 162, (MIRA 15:9)
1. Institit organiehoskoy-khinii AN Mcrainakcry SSR.
(Phosphorwddia aoid)

DERY-PiCII G.I. ; TI
.9 ~ROTSEMKC) L.D.; Z7!UIU-,VLEVI,, L.P.; JURS.-`IXTY A.V.
N-di ethyle nediamidopliosphinyl-N I --athylone-TVI -arylguani dines.
Zhur.ob.khim. 32 no.9:2992-2994 S 162. (MM 15:9)
1, Institut organicheskoy Ichimii AN UkrSS11.
(Guanidine) (Phosphonylation)

EK'RKACH G I - DREIGTALI, G.F.; KIRSANOV, A.V.
5-d.tchlorophosphin.vl-Nld..-chloroben2ala.renamidines. Zliiw.ob.khim.
32 no.9:3OD2.-3007 S 162. KMA 15:9)
1, Institut organicheako khimii AN UkrSSR.-
(Benzamidine~ (Phosphorus orpMo compowids)
ir. ~

DERKACH, G.I.
Heterocyclic*system containing phospbo---uq and nitrogen.
Zhur.ob.kh:Lm. 32 no.9:3107 S 162. KTRA 15~9)
1. Institut organipheskoy khimii AN Ukr.';SR.
(Heterocyclic compounds)
(Phosphorus organic compounds) (Nitrogen compounds)

MUCH G I. - SAMAMY.1 L. I.; SIMPANEX, A..").; KIRSANOV, A. V.
Alkyl esters of phosphamocarbonic acid. Zhur.obkhim.
32 no4ll:3759-3761 N 162. MRA 15:3-1)
1, Institut crganicheglto~ )dlimii All Ukr3SR.
(Phosphazo comwunds)
(Carbonic acid)

- MRUCH), G.I.; S.U%RAY, L.I.; IC[RSMIOV,, A.V.
Reaction of Jininoesters with phosphorus pentachloride.
Zhursob.khim. 32 no.11:3761-3764 W 162. (MIRA 15:11)
1. Institut organi-chaskoy lehimii AN UkrSSR.
(Esters)
(Phosphorus chloride)

DERKAGH,. Qrigo#y Illarionovich- SERDYUK O.P., red.; TURBANOVA,
p 9
N.A. , -bekhn, red.
[Chemical protection of pliuits] Khimicheskaia zasbohita
rastenii. Kiev, Izd-vo AN Ukr.SSR,, 1963. 99 p.
(MIRA 1618)
(Insecticides) (Herbicides)

BERNACHP G.I.; S90KOL, V.A.; GUBNITSKkYA, Ye.S.
Aryldichlorophosphasoacyls andtheir derivatives, Zbttr.ob.
kUr. 33 no.2s!553-557 F 163. (MIRA 1632)
1. Inatitut organicheakoy khijinii AN Ula%SSR.
(Phosphorus organio compounds)

DERKACH~ G.I.; GUBNITSKAYk, Ye.S.; SAMARAY, L.I.; SHOKOL, V.IL.
Diaroxy,chloro.. and triaroVphospha*&eyls. Zhur.ob.khim. 33
no.2t557.-562 11 163. (Mk 16:2)
(Phosphorus organic compounds)

DFJMCB., G.I.; FEDORUIA, G.K.; GIIBNITBKAYA, YO.S.
Phenyldialkyl- and Styry1dialkylphosphazo acyle. Zhur.ob,khiM.
33 no.3:1017--1019 Mr 163. (MIRA 16:3) ..- -
1. Institut organicheakoy khimij AN UkrSSR.
(Phosphorus organic compounds)

I
DERKACH, G.1 - NARBUT A.V.; KIRSANOV, A.W,
10
P .0
Reaction of phosphorus pentachloride with aryl i"aBj Zhur.
Ob. kbim. 33 no-5:1584-1587 My 163. (MIRA 60--
1. Institut organiebeskoy khimii AN UkrSSR.
(Phomphorus chlorides) (Uma)

DERKACHJ, G. 1. ; SAMIJUY, L. I.
Derivatives of isocyanatophotphoric acid. Zhur. ob. khiw-. 33
no.5.*1587-1591 YT 163. (MDU 16:6)
1. Institut organlohookoy khimii AN Mrr.WR.
(Phosphoric acid) (Isoaywiic acid)

SHOKOL, V.A.; DIMKACH, G.I.; KISILENKO, A.A.
Ultraviolet and infrared spectra of diesters of acylthioamidophosphoric
and acylamidophosphoric acids and their derivatives. Zhur. ob.
khim- 33r no.8t2660-2667 Ag 163. (MIRA 16:11)
1. Institut organicheakoy khimii AN UkrSSR.

DMACH, G.I.; GUBNITSKAYA, Ye.S.; SHOKOL, V.A.; KISILENKO, A.A.
.- I . -i .
Infrared spectra of trichlorophosphazoacyls and their derivatives.
Zhur.ob.khim. 34 no.1:82-88 ja 164. (MIRA 17:3)
1. Institut organicheskoy khinii AN UkrSSR.

DEPTA H G I.; GUBMITSKAYA, Ye.s.
Reaction of aroyl azidas with phosphites and.,pboaphines. Zhur.ob.khim.
34 no.2:604.-609 F 164. . (MA 17:3)
1. Institut orgaricheskoy 'khimii AN UkrSSR.

~~LAM8-6 :EWTW/,9PJrW/ZWPQ)' Pc.~
4 4 RM
JS/0O79/64/034/ODB/28l2/2812
MON NR: Ap5w26,26
~AUTHOR: Kirsanov, A. V.; Dej*tach, G. 1. Idp~M~aNb I*
__==~"77777-:,
TITIX: Derivatives of N-pho*phorylated iminocarbonic acids
SOURCE: Miurnal -obstichey khimii, V. 34, pko.18, 1964, 2812
TOPIC TAGS: phosphoric acid, formic acid., chlorinated. organic cow-mund, chloride,
ester, carbonic acid
Abstract: Dichlorides of N-phosphorylatod iminocarbonic acids, syRthesized
by-chlorinatior, of acids, react
vigoroosly with alco'holates, phenolates,. and amines. forming the corres-
ponding diestevs and- diamides of,!,I-phospliortoitninoc:arbonic acid. Isocyanates
of dialkylphosphoric acids are obtained with anhydrous formic acid, The
.action of phosphorus pentachloride on di.ithlorides of N-alkylphoaphonoiminc.-
carbonic acids produces 'i-*-,)iclilorophoup~,onoininoptios,gene. Orig. art. has 3 form-
ulas and 1 table.
ASSOCIATION: Institut organicheskoy Ichiudi Ukraini5koy Akademii nauk (Institute
of Organic Chemistry, Ukrai
Man Acadevy _qi:SD_ce,s)
Card 1/2

DERY-ACE, G.J.; KISILENIKO, A.A.
Infrared spectra of isocyanophosphoric acid derivatives. Zhur.
ob. khim. 34 no.9:3060-3063 S 164.
(MIRK' 17: 1.1)
1. Institut organicheskoy khi.mii AN UkrSSR.

IVANOVA, Zh.M.; DERKACH, G.l.; KIRSU,,'OVA, N.A.
Derivatives of N-acylisothiocyanates~ Zhur. ob. khim. 34 n0,.10;
3516-3518 0 164. (MIRA 17:11)
1. Institut organicheskoy khimii A14 UkrSSR.

DERKIA ',gcr 4 x ZFXUROVA, IrJ.ria Nikolayevna;
KIRSANOV, A:I&R-s-a-Mdr~aslll7evich; SHEVGMKO. Vs-rinmin
Isaakovic:h; 87'-18MP'K- k1la Stanislavolmt POKROVSM-Aj-,f-
Z.S.
[Phosphazo compnunds] Ifoofazosoedir-oniia. Kiev,, Naukoya
dwaka, 1965. 283 po (14jqA 18-8)

DERKACH, G.I. (Derkach, H-71.1
Ninth Mendeleev Congress. Dop. AHI URSR nD.8:1206-11111 165.
(141 RA 18:8)

S,IVARAYY 'I ~; BONDAR 1, 1Y.A.; DEBRACH, G.T
Reaction of oarboxyllo acid amidines with oxhlyl chlo:ldn~
Zhur. org. khlm. 1 na.lli2004-2008 N 165. Wlpj~ 18~ 12)
1, Jnstitut organichesk(:~v kbJn-di AN UkrSSR. Stibmittee.
Jaruary 18, 1965,

!i
. IVAROVA, Zh. M.; ICIRSA140VA, N.A.; DM-KAGH, G.I.
Derivatives of N6acy,1:Wnoo&rbcnic acid chlorides* ZUir6 orge
khim. 1 no. 12r2186-219T. D 165 (min 192T)
Is Thetitut organicheskoy khimii All TJkr=, Submitted December
2% 1-1964o

5:1 1-20-14-4
.L6 MP
4 1,
..SC
W5191 UP 033/0370332705
ORGv. iql 6 Lga. AN UkrSSR (~mfttut organicheakpy Wdzdi'ANUkr9,M):-
tferivttives of.tAdx1m*hoq&azofXwroaoy3ji
SOMM 2mrftl obsbahey kbindi, Va. 35, Do, 3, 1;~5p'1532,-534
.~--TOPIC TACS: organic ato compomA, phoophome cUoride amide, f luord nctiA organic
~.eompound hydrolysis, oblorinatAod organic con
pound. esUr
ABSV.ACTi Reaction of phosphoms pentachlorlde "with'am-fUs- of 0
and. p-fluorobenzolo-acide proceeded according to the.phosphazo
:reaction scheme, produoin&the oorresponding trichlorophosphazo-
;fluorotenzoyls.---Th6se*are low melting orystalline substancest with,
Johemical pro~pertles.dlose to those of trichlorophosphazo'benzoyls. I
Subsequent hydrolysis of the trichlorophosphazof luorobenzoyla
-~iyleldOd dichlorld6s of fluio:robeiazovlamidophosphorILo acids and the
..:free fl,uorobenzoylanildophcis]?hor:Lo acids. Reaction of the dichlo-
:rides of fluorobenzoylamidophos!horic acids with alcohols and
sodium phenolate produced the corresponding diesters cf f luoroben-
zoylamidophosphorio aoids., Diphenyl esters of fluoroaroyliLmido-
~phosphorlo aoids,Are also produced In good yield by the action of
iphenol on triobloroph6s-
phetzofluoroaroyls,__tq~lowed by hydrolysis
water or with 2N., sodium hydroxide,;, Orige art. h":.!; I tal"O' LJ-PR�7
M Mh OD4
;SUB CME 1 0? MM]AM., AWAM&
Card ~ 1h ~4
MCI. W)AIR42 rjkO,

SAMARAY) L.I.; DERKACH, G.I.
Phosphorylated derivatives of oxalic acid amides. Zhur. ob. khim.
35 no.4:755 Ap 165. (M114 18: 5)
1. Institut organichoskiy khimii AN tlkrSSR.

ALEKSAN-KJN,, M.M.; SAMARAY, L.I.; DFRKACH, G.I.
Study of the thermal decomposition of' ethyl ester of
trichlorophosphazoearbonic acid by means of 018. Zbur.
ob. khim. 35 no.5t923-925 My 165. (MIRA 18:6)
1. Institut organicheskoy khimli AN Ukx,-"-SR i Institut fizicheskoy
khImil AN UkrSSR.

D-VR.KACFR G.T.; NARBUT, A.V.
Derivatives of plio--phadiazacyclobutaiione. Zhur. ob. khim. 35
izo.5s932 My 165, (M-7PA 18g6e)
1. Institut organiaheskoy khimil AN UkrSSR.

DERKACB,,G.T-.; MOTTLO, M.V.
-1 -------I- ---
Derivatives of tetraazadirhosphacycloootatetraene. ",hur. ob.
khim. 35 no.631001-1005 j" 165. (KRA lg,,,6)
1. Institut orgarlcbe~kVy- kh-'.ndi AN UkzESR.

DERY,.',C,H, 0.41.-, NkRBITT A,,V*
-- - -----. I I
AryltmideB of phosphazooarbonic anidgi. Zhur. cb. khirr.. 35
no.6:1006-1008 Ja 165. (YERA 18.-6)
1. Institut organichesko7- kbimii All INrSSR.

DERFJi(Tiy G.T.; -,UBNI"Kl-..YA, Ye.S.; SHOKOL, V,,A.
Derivatives of acylamidoarylphogrihon-'~- anids. Zhur. ob. khim.
35 no.6.-1014-1018 Js 165. (MIPA 18t6)
1. Institut organicheskoy khirdl- AN lfkrSSR.

DERKACH, G.J.; RUDAVSKly, V.P.
N-phosphorylated trichloroacetamidine derivatives. Zhur. ob.
khini. 35 no.7:1202-1206 Jl 165. (MIRA 18:8)
1. InFtitut organicheskoy khiridd AN [JkrSSR.

7- 7, V", i
Cos ~j 1 c-

DERKACHS G.I., SLYUSSAREPIKOf Ye.,.; LIBM0, B.U.; LIPTUCA, M.
D:Lf.soc,yanates and d.-II-4-soth-locyanates of alkylphosphonfc acids.
Zhur. ob. kh.Lm. 35 no.10:1881-1882 0 165. (WJU 18:10)
2. Institut organieheskoy khllmil AN UhrSSR.

M 256D9-66 EWT(M)/EWP(J) RM
ACC NRt AP6016o9 SOURCE GODE: UR/0079/65/035/012/220C)/2204
AUTHOR: Derkach, G. I.; Rudavskiy, V. P.
ORG: Irstitute of Orizanic Cheminti-Y. AN UkrSSR ~Institut organicheskoy. khJmdi
AN UkrSSRT----
TITIE: Phosphorylated derivatives of the amideu of dichloroacetic and alpha,
alpha-dichloroproprionic acids
SOURCE: Zhurnal obshchey khimiis 1r, 35, no. 3.2, 19.65, 2200-2204
TOPIC TPGS,. chlorinated organic,compound, carboxylic acid, phosphorus chloride,
hydrolysis, acetic acid, acetone, nonmetallic organic derivative, carboxylic acid
chloride, organic amide
-~osphorus
ABSTRACT: The amides of the ab6ve Acids react with P
pentachloride to fom tr1ohlbrophosphamoarbaoylsi
CH CC1 CONH PC1 -4 2HC1 cH Cal CON
3 2
3. 2 2 5 34
The hydrolysis of-trichloropliosphazodichloroacetyls and alpha,beta-''
-dichloroproprionyl with anh4jrdrous acetic acid or water In acetone.
results In d1ohloracetyl- and alpha,beta-diehloropropionylamldo-
phosphorio aVids. The corresponding diesters of diamides of the
acids'.are obtained by the action of alcoholso.phenolso thiophenolso--,
:or amines on ihe dlohlbrid*es-of these a(Ads.
Card 1/2- UDC: 546-185 547-29

L 25609-.66
ACC Ms
AP6o16699
e
'Th acid chloride of N-d iohloropho sph6ny3. im ino- alpha, alpha-d ichlo=--''
.proprlonio aoid.-is obtained by treating phosphorus pentaohloride
.With e~i-p",h"a"-,-*a,-lp*ha-dichloroprop:rionylamidolfhosphorto acid dio'hlorld:e,
,Twenty-four derivatives of oliloroproprionylamidophosphoria aoids.
RCOMOX2, where R CH COI and X equals various groups,,were
3 - 2
'obtained and characterized,,, Twenty-three derivatives of diohloro
iaoetylamidophosphorio.a6id, CHM CONHPOX,,I- were obtained and
characterized. Orig, art. has: 2 ta7bles,
SUB CODE: 07 SUM DATEs. 25DeC64 ORIG IIEF,. 004 oTH - RU -00:L
Corel 2/2 rV

`~~604~-66 ZWT(l)/ZWT(M)/EWP(J) WW/RO/RM
ACC NRi SOURCM CODE: UR/0079/65/035/012/2220/2222
AP6016704
AUTHOR; Derkac;hj Go Iq Slyuvarenko,, Ye. 1. S I
=Or anic Chemistry, AN UltrSSR (Inatitut organichesoy. AN Ukr H)
ORG: Institute .4mli
-Y,
TITLE: Mixed diesters og urethaneph s )ric acids
SOURCE., Zhur~al obohchey khimii,-Y, 35, no. 12,, 19,15m 2220-2222
TOPIC TAGS: insecticide, organic phvsphorue compound, ester phosphoric acid,
vacuum disti1lation, organic isocyanate compound.
ABSTRACT: Certain diesters of urethanephosphorle acids with identi'
cal substituents on the phosphorus atom poisess strong InsecticidaITP
The dimethyl ester.of methylurethanephosphorle acid (K4-20-,,%','
30) and the dimethyl ester*of,iLisopropyltire*thanephosphorle acid
(avenin) are effeotive systemio Insecticides against the garden
beet -weevil. In contrast to other organophosphorus.inseoticides
they do not.possess the properties of oholinesterase Inhibitors
:and are absolutely harmless to warm-blooded animals.
to
The mixed diesters of urethanephosphorle. acids were unknown UP
this time. The diesters of urethanejphosphor1o, acids with Identi-.~!.,.!
,oal'substituents on the phosphorus atozare readily obtained by
.the reaction of alcoholates or absolute alcohols and the acid,:
'diohlorides of urethanephosphoric.aoids,
!To obtain the diestere of urethanephosphorio aoids'with different
substituents. on the..:phosphorus atom*, the reaction between the aoid'.
Card 1/2 UDC: 547.269318-

..25%604-
ACC NRa
wowa
'~'diohio'rlaes and'aldohols, Is conducted -in the presenos ot tri-*
ethylamine In two statest
OH R1tOH
ROCOIRHPbCL2 *-* ROCON11PO(ORI)CL ROCONHPO(OR (011i
02H ) N
02HP 3N
5 3
I*A*total of 18 mixed diesters viere obtained and oharaoterized in-
c
loluding those derived-from the higher c ) aloohols.
6 10
iThe mixed.diesters of urethandphosphorio aolds upon being disti I
-i
in a vaouiim (7-10 mm) eleave off quantitatively the aloohols a
bare eonvirted-Into the diesters of isooyanatophosphorld aoids
(R,00)(ROO)PONHCOOR ROH (R11.0) (RIO)PONCO.
N
The diesters of isoeyanatophosphorlo aold resot v i ro g o i i a Ii t h%`-1j'7,-'
!aromatio amines tolorm N_phosphono,-N'.-ar~lureas-
tRIO) (R' to) PONCO -;!E-N1-11k '~k'rNHOOM)CI (OR (OR
Orig. art. has: 2tables. LJPRS)
SUB CODE: 07 SUBM DATE! 18AM5 ~;ORIG REFi 003
Card 2/2

L 29276-66 -F-WP(J)/eNT(M)/T RM
--~GURCN
UWBI Ult/UUYV/b.5/Ui-,)/uL)o/-L4w/.Lwt.LI
'ACC NRs AP6019322
AWHORt Shokoll, V,. A.; Derlmah, G. Is
ORGs Institute of Organic ChOmistrY 1W UkrSSR (Tnetitut orgardahaskay kbird'i
AN UkrSMY
TITLEt Pialkyl eaters of acylal-d-dophoispharic aoids
SOURCE: 2birnal obahchey Widi, v. ro 8 11,63v 1468-14,71
TOPIC TAGS i phosphate aster, organic i*rnthatic process, aloohol
ABSTRACT: By ihteractVi8 -trf0h:Lorophdiiphazoacyls or diehlorides
of aeylamidophosphorlo. aoids with ikloohols in benzene solutions
;.~n the presenee of triethylaminov dialkyl esters of acylamidophos-
4phorio aoids RCONHPO(OAlk)g (1) weire prepared. The following new
oompounds of this type were synthesized by these methods:
-I (R--CH Cl, Alk--Me); 1(11-mCH $ AllctmEt); I I:R=CH C19 Alk = iso-Pr);
2 2C' 2
I (R--Ccl Alk=iso-Pr);;.-I (H--P111, Alk =* iso-11r); I (R-Ph, Alk = hexyl);
3
11 (HuPhs Lk=heptyl); I (R--Phv Alk sm ootyl);. I (R=Ph, Alk =nonyl);
-I (R--Phq Alk=deoyl),, I (R=p-M%Hj~j, Alk = hoxyl); I (R-P-ClC640
-Alk hepty.1); I (R_.=-_p-!C1C6H4q Alk optyl); I (R--p-ClC(,Hj
Card 1/2 UDC: 546.325:547.2613.18-

1.0 L 2Q"A-AA --

L 46585-66 EWT(m)/EWP(j) RM
ACC NR: AP6025534 SOURCE CODE: UR/6O--7916q06/60-170-0-Tf/6C-
AUTHOR: Dorkach. G. I.; Kolotilo. M. V.
ORG: Inst =tUte of Organic Cho m-st7p AN UkrSM (Institut organichoskoy khimii AN U1
TWIE-t 11-phosphoi7lated alkyl- and arylariadines
CR: Zhurnal obnhchey Idiinii, v. 36, no. 1, 1966, 82-84
TOPIC TAGS: Cheracal r*-action, solvent, amido, phosphorus compound, picric acid,
]Vdrocliloric acid, trio-Uiylarrino
AMT.VXT: N-Dialkvlr)hosphono&lkvlamidinostland N-dialkvlphosphonoarylamidiries
c,nd alkyl chlorides are formed in the reaction of N-chloroalkylamidinosq.-,nd
The roaction is very violent
.1-chloroaryleunidinos with trialkyl phosphites.
in the absence of a solvent and therefore is conducted in benzeno or other.
ti-Dia:Lkylphosphonoal-kylamidinos aro also prepared by the reaction of dialkjrl
chlorophosphates with amidines in the presence of trio-Uiylamilios, but tn
20-30% lowor yields. N-Chloro-Nlarylalkylamidines and N-chloro-Nf-arylaryl-
&Tddines react with trialkyl phosphites to form the corrosponding N-dialkyl-
phosphono-ill-arylallcyl(aryl)amJ.dinas. 7ho phosphor,riated amidines synthesized-
are very weak bases, giving no salt with picric and hydrochloric acids. In
.4e reaction of N-aryl-NI-chloroarylamidines with ta-iphanylphosphine,
phosphonium salts are formed, which *give 19-aryltriplienylphosphazoiminoaroyls
under the action of triothylamine. Origi arte has: 3. table'. fj-FRS-. 35,~qff
3 CO- 003
07 / SUM DATS: 0111ar65 / ORIG REF:
hS MC! ".1894~7.298.5

ACC NR; AP 22805 SOURCE CODE: UR/O()79/66/036/002/0322/0326
AUTHOR: Derkach. G. Marbut A. V.
ORG: 1nqf1tujT-6'of C~~~try, N Ula-SSR (Institut organicheskoy khimii AN-3
UkrSSR)
TITLE': N-dichloropbosphonyl-Nt-alk 14~chloroforaamidinesland their ,ae'ri'V'itives
L
SOURCE: Zhurnal obshchey khimii, v. 13)-,n~-. -2, f9ZT,-*~-22-326
T
i
POPICC TAGS: organic phosphorus compound, nonmetallic organ c derivative, aminep
chemical'8ynthesis, hydrolysis, phosphorus chloride
LBSTRACT:- Alkyluroas react with phosphorua pentachloride to form 11-dichloro.
I)hosphonyl-NI-alkyl.-C-chlorofomamidinoo. Under the action of phanols
(alcohols), waines, and phonyl magnesium bromido upon N-dichlorophosphonyl.
11-alkyl-C-chloroforTia.midines. the follcadlig products are formed-. N-diaryl
I:diallcyl)phosphono-111-alkyl-0-aryl(alkyl)isoureas, N-diamidophosphonyl-Nl-
4akyl-NI-aryl%'alkyl)gunnidines, and N-diplienylphosphonyl-Ri-mothyl-
benzamidine, respectively. In the reaction of triisopropyl phosphite and
triphenylphosphine with the azide of met1kylearbamic acid. the methyluddes
of the corresponding phosphatocarbonici acids are, formed. Hethylamines of
trialkovphosphazoicarbonio acids are reactUy hyd"Iyzed tmder the action of
atmospheric moisture to N-dialkylphosphonc)-NI-mathylureas. The authors thank
A. V. KirEanov for help and advice in thi13 work. Orig. art. has: 1 figure
and 1 table. [JPRS1
SUB CODE: 07 SUBM DATE: 01jan64 / ORIG RU: 003

__L_3~790-66 EWT(m)/EWP(j) WW111Y,
7 i~R __.O_Td~~1675 , &ODE' UR/0079/56/036/oWF41~1W7 -
ACC SOURCE 0
XrLHOR: Dgrkach. G. I.; Uptuea N. I.
1~ 5'
ORG: Instituto of Organic Chomistry, Ali UkrSSR (Institut organicheskoy khimii
(AIN U]wSS,Z)
TrUil. Derivatives of N-Phosphorylated iminocarbomrlic acids
SOURC3- Zhurnal obshchey 1(hizaii, ve 36, no* 3, 1.966, 461-IP67
TOPIC TAGS: nonmotallic organic derivative, organic phosphorus compound, carbWlio
acid chlorido, chorideal ss~mthesis, imine coqxund, hydrolysis, formic acid
ABSTRUICT: X-Phosphonoimiri"oc~wbox~lic'icid 'dichlarides wers' prepared by the
-chlorination of isothiocyanates of dialkyl.. and diaryl-phosphoric acids.
Dichlorides of N-phosphonoiminocarboxylic acids reaLet with sodium alcoholates.
-phenolates, marcaptides, and thiophenolates, as -ovll as aliphatic and
aromatic amines to yield diesters, dithioesters, and diamides of N-phosphono.
iminocarboxylic acids. In the reaction of N-phosphomiminocarboxylic acid
dichlorides with two moles of an aromatic amdne, N-phosphono-NI-aryl-C-chloro-1
formamidines are formed, which react with triethy-lamine to give N-phosphono- I
NO-arylcarbodiimides. Hydrolysis of R-diiLI)Wlphcosphono-NI-ar7learbodiimides
yields N-phosphono-NI-arylureas. The action of p1iosphorus pentachloride on
N-dialkylp4osphonoiminocarboxyUc acid dicUloridets produces N-dichloro-
Card

L
ACC NRt AP6021675
phosphonyliminophosgene. Djesteri 'of iiOMmat"honhoric acidLre praj~ared
-by formolysis of N-phosphonAminocarbw7lic acid dichlorides vith wkydrous
ono -ani'din i'N-phosphono.
formic acid. Hydrolysis of N-phosph es*(~iijiiared *h~om'
NI-aryl-C-chloroformamidines and aininesf,731 dilute acid solutions results in
the formation of dialkyl phosphates pnd guanidines. N_Phosphonoiminocarbo~ylic::
acid dichloride react vigorously with potassium salts of diesters of
dithiophosphorio acids, but only diesters of iscomatophosphorloacid could
be isolated from the reaction producto. Origg grte has: 1-table. J_PRST
SUB CODE: 07 / SUM DATEt 18Jan63 ORIG on 009 / OTH REF: 003
Card 2/2

04
L
A-CC
AP1000744 SOURCE CODEI UR/0079/66/036/005/0930/0937
',SII0KoL,,V. A., MOLYAVIM, L. I.., jPjjWHj 0. 1., Institute of Organic Chemistryl-.,
AcadpanW of Sciences Ukrainian 6GWft_"I_ 3D
Reaction-of Compounds of Trivaient Phosphorus with N-Chloramddes of
Acids. I. interaction of Phoiaphitee and Tr!p~~jphosphi with N-Moro-fi-
I Moscowt ZhurnnI shchey Khimii, Vol 36., iio 5) 1966? pp 930-937
.Ab s.tract:.In the reaction of N-chlo'ro-N.-methylarylsulfamides with trialkyl-
or alkyldiarylphosphiteso there is an Arbuzov rearrangement, forming diesters
'of N-alkylamida..ihosphoric acids. The diesters are colorless viscous liquids
or low-melting trystalline substances, which yield N-alkylarylsulfamides when
boiledivith aqueous alcohol solutions of hydrochloric acid. Triphenylphosphine,
reacting.with H-chloro-N-methylarylsulfamides, gives N-methylarylsulfonylrmido-
tri~henylphosphonium chlorides. They are all readily hydrolyzed by atmospheric
moisture or under the action of water or alcohol, yielding complex compounds
d .triphenylphosphineIoxide with N-methylarylsulfanddes ArSo2N(CH3)H ... OP(C6H5)3'l;
When the phosphonJu salts are heated to 90-12000 they split off an alkyl halidep,
yielding triphenylphosphazosulfonylar_%rls. The infrared spectra of the com
poundA
Orig. art. has: 1 figure and 4 tables. [JPRS-. 37,023)
TOPIC TAGST irganic amide, organic sulfur compound!, organic phosphorus compound
I'M CODE-..-*07',/ SUBM DATE: 19Apr65 / ORIG REF: Oil. / OTH REFt 005
rnVA
10,

ACC NRt AIC)027772 Monograph URI
Derkach Gri ori Illari Zhmurova. Irinq Ni Kircancyp Aleksandr
VM11y;vich; Shevche 0t Veniamin Isaakovich; Ght panek, Alla Stemislavoyns,
lLospha~o qompounds (Fo3fazosoyedineniya) Kiev, Izd-vo, "Naukava dtunka.," l965. 283 P-
illus., biblio'-.-'- (At head of title: Ikkademiya nauk.Ukrainskoy SSR.__ Institut
organicheekoy khimij) 2000 copies printed.
TOPIC TAGS: organic phosphorus compound, nitrogen compoundp organic azo compound
PURPOSE AND COVERAGE: The introduction contains a review of recent research in the
field and a discussion of the problems connected with inconsistencies in terminology.
The nomenclature employed is that first proposed by A. Mikhaelin. The book deals
P
with data on the chemistry of phosphazo compounds, published in the scientific press
up to 1 January 190~, and presents lists of the phospbazo compounds that are known
at the present time. It in intended for scientistap industrial workers) teachers,
and students interested in modern progress In organic chemistry, especially those
working in the field of phosphor-organic compounds. Each chapter deals with a dif-
ferent class of compounds, for which the authors give the method of preparatioup the
chiemical properties, a list of compounds; wid-an appropriate bibliograpbye
T4DLE OF CONTENTS [abridged];
1. Introduction 9
Ch. 2. FhosphazoBulfonyls - - 16
Ch. 3- Fhoophazoearbacyls - - 79
Card

ACC NRt AN5027772
Ch. It. Phosphazo derivatives of phosphoric acid - 19f
Ch. 5. Phosphazahydrocarboxis - - 177
Ch. 6. Phosphazohydrides - - 225
Ch. 7. Phosphazoamides - 23.5
Ch. 6. Phosphazinca - 238
Ch. 9. Phosphazides - 258
Ch. -10. Phosphazo compounda of various types 263
Ch. 3.1. On the nature of the nit-rogen-phosphorus bond in phosphazo compouude - 265
BUD CODE: 07/ SM DATE: IOApr65/ OUG REF: 222/ Onl REF: 31,9

0=1 VV0079166/0:16/008/1437/1"1
I1mrTi5i 0. 1*; Iblotilo, M. V. - 7
Owl; 9 ItLutq Ot Organic Chemistgre AN UkrSSR, Kiev (Dwtitut organicheakoy
1, 1601M AN; UkrSSR)
,"ATM. Derivatives of cyl
I'MWEt' Zhurnal obahchey khimil v. 369 no. 89 19669 1437-1"1
IMIW- TAGS: phosphorus chloridev aminog organic phosphorus compound
N-ChloroaMw2axidines react with triaryl phosph1tC3 t foxil
""Ainophosphonium salts, which when treated with triothyLvaine adily split
'ftli- hythfogen chloride and aro converted to triaroac~~Wt oalkoyls. In
coatrastr to the analogous triaroxyphosphazoiudnoaroyls, triaroxyphosphazoinino-
AMcovIs do not split out phenol and are stable to hydrolysis. N-chloro-
armamidines react analogous3y with diphaWlchlorophosphite,, phenyldichloro-
phtWphite, pheny1difluorophosphite, and phosphorus trichloride, forming the
4ar"panding phosphonium naltaj which are readily hydro2yzed by atmospheric
14tare. Reaction of the phoophonius salts with. triothylanine led to resinifil
"idm; their reaction with pytidine yielded pyridine bydrochloride and the
.~*vTe1qMding dipb==WcUoro-s-pbonowoioblaro-,pboncuydifluoro-, and
tMcb1orophof!phazaiuinmw diphenootychloro
1/2

...11 IIhOO-67
T-A4~d- ~k'-AAPP'7003656
pbwcocydichloro-, and trichlorophosphazoininoaMle by atmospheric moisture
~yie2ded N-diphanylphosphonoarenamidiness N-phoncoWehlivophosphomylarenai;idiness
..'md']K-dichloroi)hosphonylarensaidiW, Mpogtivel Partial aci4ol"u-pf
*Kchlorophosphazoininoaroyls with ac6il~ acid yielded both N-dichlorophosphoijyj.;
6w~dincs and N-wnochlorownohYdraNYPhosPhoriylareimmidines. The reaction
-of diphenoxychlorophosphazoiiminobantOYI 4th trietlW111mine yielded 2,2,6.,6-
utraphenazy-4,,6-diPherwl-l,,3,t5p7-t-etraaua-2,,6-diphoel?ha-l..3,,5,7-cyolooeta-I
'J t6trafte. &-Phenyl-NI-ohloroarenamidines react vith tr~l phoophitea to form -f
saltia,, wbich Awn. reacted with tri9tIWIaKLU9 giTO trL&rw7phOSphaZo-'
Irlindnoar
OVIS* TbO latter are very unstable *wJ are hy*WlxW at,
latwepherio, M"U"JO N-diwiph"Ipbono-N I -OM --.J,
-::,Gxlgo art@ hass 2 t~bI*s*,;:LJPWs '380,97'
-SW C=s 07 4MM DAIMI..
lb

*7CC i'14R: A1'7003657
SOURCE CODE: UR/007 9/66 /036 100311442 /144-4
AU7KOR: Shekel,
V. A.; 141khaylyuchenko, N. K.; Derkach~ G.
0.'~G; ~titute of Organic Chemistry, AN McrSSR (Institu-E7-rCan-ichaskoy khimii
o
AN Uk.rSSR)
TIME-: Reaction of compounds with trivalent phosphorus with n-chloramidos
of acids. !I. Reaction of phosphitas with n-chloro-n-alkylurethans
SOURCE: Zhurnal obshchey Idiiiiiii,v. 36, no. 8, i~-6-0--'-f44~--i-4-44--
TOPIC TAGS: organic phosphorus compound, IR spectrum, ester, orZani~::
synthetic process
NT-cliloro-i~~-a3lcyl-aret'narc-.s rE:ac-z,----i'Uh triall-Y1 2:'R~-~Lh4taslto r o n-.,
,10STRACT: r, 1T, C,'-
dia-E-Yi esters of N-alkyliwethanophosphoric --cids. Tllao rcactior, is ana-106-ous
to Iu-'hat of N-chloro-N-alkylarylsulf ~,,Udos with triz.11-yi p'ljosphites, s Id*l ed
.a U";
earlier by the authors. The dialkyl estc7rs of LN,-al'I-VYI-,Lire~uharophosphoric acids,
are colorless free-floving liquids, rc-adily soluble in ,:aterz --nd --ost orzanic
solvents. Eloven diesters were sn, thesized (4.an for. Vine firs-~ tim-o) and
charactcrizod. Their 'infrared.si)ectm wero s,tudied. Orig. art. has: 1 table.
r 0
L-J?RS: . 38,97.1
SUB CODE: 07 / SUBM DATE: 10ju165 ORIG REF: 004 OTH REF: 002
Card 1/1 jb UDC! 5-q7
e_q

3 __4 4
ACC NR. AP66i89_Ol__ SOURCE CODE'j- UR/0079/66/0 6/008/1442ji 4_.
AUTHORt Shokol, V. A.; Mikhaylyuchenko, N. K.;.Derkac_h_,,.R,,_I.
ORG: Xnstitute of Organic Chemistry. Ac.~demy of Sciencea)UkrSSR
(Insifiiuit organiches oy khimii Akademii nauk UkrSSR)
TITLE: Reactions of compounds of trivalent phosphoru,q with N-chloro-
amides. Il. Reactions of phosphites with N-chloro-N-iilkylurethanes
SOURCE: Zhurnal obahchey Ithimii, v. 36, no. 8, 1966, 1442-1444
TOPIC TAGSt insec icide, alkylphosphonocarbamic acid este 0
ABSTIRAM N-'dhloro-N-alky:Lurathanes react with trialkyl yhoeyhitealto
form the corresponding estiars:
ROCON(RI)CI + (R'rO).,P ---.* jR0C0N(J1')P(0R")3J4C1_
ROCON(JIVO(01112 + 11"C"
Without solvent the reaction is very vigorous, therefore, it is con-
ducted in benzene solution with boiling. The diestera of H-alkylRhoa
phonocarbanic acid are a fective insecticidea~and at the same time t
are harmless to human& and animals* The Initial N-chloro-N-alkylure-
thans were obtained by chlorination of N-alkylurethanvoor by methylat
1 1 It tin

ACC NRi APbUZUYUI
of N-chlorourethanse with dimethyl sulfate:
HOCONIIR' ROCON(RI)CII
.ROCONHCL
Couposition and properties of th* diestoral-are gjv4Q Ig, the table,
Orige art* haso I tables JW.A. 501

Table 1. Diesteirs at 11-alkylphosphasocarbasic licids R0C0W(K')r0(0A")2
.
a bp (p In 00) or "e Found Led
Clis CH, Cup 93-44-11.5) 1.2"4 1.4366 40.40 40.71 Ifi.q2 c'u"Nosp 15.71
CBS CBS
.IV
C 4
64
10-48(t.5)
J.JMD
1.4310
50.08
49.23
13.15
C711"No,p
13.76
C11, C "S f1se-CIN, a 75-7s(0-4) 1.1050 1.4299 $9.17 59.18 12.3t C'112*N0#p 13.24
CH, C'2H8 clill U 94-116 (0.41 t1a 1.4X13 54.61 54.67 13.19 r,11,'N0,p 12.0s
CBS C911, to-Cliff 50 90-91(0.3) 1.073D 1.42R5 64.12 93.90 11.63 ruli'mop 11.59.
1:3,18 Cos Cou 50 11-7210.4) 1.2150 1.4K3 45.27 45.33 14.33 C'11"No'p 14.01
qRS cu, qNs 43 83-4-4 (0.5) 1.1310 1.4301 54.93 54.51'. 13,23 c:SHpN0'p 13.95,
clus co, too-con, 55 91-82jM) Lom 1.42" 63.8t 63-00 It-51 C'"'N0'p 11.62-
Joe-CjHl CBS CBS 57 114-115(3) 1.1&57 1. 43no 49.99 49.16 13.68 CFHNNDSP 13.71
imvx~H' cu, cWs UP 01--" (1. 5) 1.1041 1.4422 fiv. 14 $0.111 13A C,11,110,p 12.24
0011~31 coo 906-csur to lot-Itelf.5) LOW 1"12" U.65 88,43 11.04 CjtH#,M0&P 11.0.1
SUB CODES 07P(o/SUBM.DATZI 1OJu165/ ORIG RE.Ft 008/. 0TH REPS 004

ACC NR. AP6031382 SOURCE CODE: UR/0079/66/0.'16/009/1636/1639
AUTHOR: Shokol, V. A.; Golik, G. A.; Libman, B. Ya.; Derkach, G. I.
ORG:' Institute of Organic Chemistry, Academy of SciencesUkrSSR (Institut
organicheskoy khimii Akademii nauk UkrSSR)
TITLE: Monoalkylamides of alkyl methylphosphonates
SOURCE: Zhurnal obshchey khimii, v. 36, no. 9, 1966, 1636-1639
o P 6 1 C Ahnj DE,
*TOPIC TAGS: insecticide, ==-alky - etl.31 Fh'-F!'4-'=tQ
40 3 J_7 ,I
r AI(J,L,' fe /W/o
.ABSTRACr: In a search for new insecticides'. a series of monoalkyl-amides
of alkyl methylphosphonates was obtained by the reaction of
methylphosphonic acid chloride with primary amines in the presence
of triethy;amine in an ether solution at room temperature: j
~14-p (OR)CI CBSP(0)(0R)N5R'
(C63AW
Composition and properties of the amides are given in th.e.table.
UDC: 547.26'

F-A-C-C--N-R,-,060-31382- W"I 1.
T MonoWAylamides of &Lkyl ~ethy'lphoxphmuit"
-cjj,p(O)(ojk)NHR,
Card 21.
CH3
CH3
CH3
CH3
c2HS
C2HS
CPS
C2HS
iSO-C3H7
iSO -C3H7
iso-c3H7
iSO-CJH7
JL* lyield, % lbp (p, =t) I I
CH3 37 "72-730 (0.02) 1.1288 1.4423
C21ts a, 58 78-79 (0.02) 1.0779 1.4402
na"3H, a;. 42 81-83.(0.021) 1.0402 1.4373
a.-CdHs a. 36 95-96 (,M) 1.0192 1.4424
CH3 6. 82 (69) 86-88 (0.5) 1.0835 1.4390
C2HS 6. 72 91-93(0.4) 1.0482 1.4372
SaG-C3H7 6. 78 (62) 66-67 (0.03) 0.9995 1.4347
B.-c4Hg** a. 54 (it) 100-101 (0.1) 0.9971 1.4400
CH, 6, 81 (5i) 73-75 (0.06) 1.0372 1 .4350
CIHF, 6, 79 69-7t (0.03) t.0109 1.4338
nao-C2H7 6. 6-3 85-87 (0.07) 0.9863 t.43i8
H.-C4Hp s, 54 (0) 138-139 76
(11) 1 0.9712 1,43

ACC NR:.AP60313,q-^,
found calc.,
.28.89 29.0
.33.54
38. U
42.92
33.32
37.92
43.08
47..39
.38.03
A2.53
47M
33.65
38.3G
42.98
33.G5
38.36
42.08
47.60
38.36
42.98
47.60
52.13 1 52.22
Card 3/4
found, % Iformula I calculated
N H.43
C1130 22.53.
CH,O RO. 65
C1130 18.74
N 10.21
N 9. 22;
P 20.53
p 18.59
N 7.5~
N 9.34
N 8.43
N - 7 99;
P 17:34
N 7.28;
P 16.04
C'11ION0,P
CiIIIIN02?
CHliNO::P
COH,GNO,
.,P
C,H,,.NO,P
CjjHjjNO.jP
CsIIIONOIP
C7HISNOll'
CsH,.NO,ll
C,H,sNO211
CH,,Ndll
CaHION0,11
N H.38
C1130 22.59
CII,O 20.S3
CH30 18-79
N 10'.22
N 9.27;
P 20.49
P 18.75
N 7.81
N 9.27
N 8.48
N 8.01;
P - 17.28
N 7.25;
p t6.05

These amides have strong insecticidal properties but are very
toxic to domestic animals. Monoalkylamides of alkyl methyphos-
phonates react with tert-butyl hypochlorite to form N-c.hloro-N-
alkylamides of alkyl methylphosphonates. The reaction takes
place in chloroform at 20-30*C. [WA-50; CBE No. 12]
I-SUB, C-ODE:06.071 SUBM DATE: 17Jul65/ ORIC REF: 003/ '0TH REP: 014/
r-'I";I LL/ZL

ACC NRI AP6031383
SOURCE CODE. UR/0079/66/036/009/1639/1642
AUTHOR: Slyusarenko, Ye. I.
ORP: Institute of Organic Chemistry, Academy of Sciences,UkrSSR (Institut organichezko~
khii.-,ii Akademii nauk UkrSSR)
TITLE: Derivatives of diesters of isocyanatophosphoric acid
SOURCE: Zhurnal obshchey-khimii, v. 36, no. 9, 1966, 1639-1642
TOPIC TAGS; ester, dichloride, phenol, organic isocyanate compound, phosphoric acid,
,che:-.,ical reaction, urea compound
P.BSTRAcr: Depending on tlie'reactant"raitio, . d.i- and triphenols react with
j dichlorides .and diesters of isocyanatophosphoric acid to form
mono-, di-, or trio-phosphonourethans.-
GI,PONCO
-* CGBG_.(OCON11POC1j).
C'H'_.(OH)0-1(R0),P0NE0. CjH,.jOCON11PO(OR),j.
1JDC: 547.26'118

X~C NR: AP6031383
Diesteils of isocyanatophosphoric acid react similarly with 2,2-di-
-dihydroxydiphenylpropane:
p
(CH,),C(C,H4011)j+ 2(RO)2PONCO (cjj3)2c(CI"40.CONUPO(OR.):111i
With p-hydroxybenzoic ac3fd and p-aminobenzoic acid diesters of
isocyanatophosphoric acid react similarly to phenols and
aromatic amines:
Card 2/5
L-
-~-,Hocji,COOH-n-HOOCC 61140C ONHPO(OfI)I
(RO)IpONCO ..H,NC,H.X
--p n_xC,I14NIICONIIpO(OR)3
X =cooH. 50,10S., COOGH,.

ACC NR: AP6031383
With ','chlorophos" diesters of isocyana.tophosphoric acid react
by the same mechanism as with alcohols:
(CII3O)2P(O)rII(OII)CC13 21-01."'TLO. (cilio)~P(O)CIIJOCON111'0(OR)21CIC13
The reaction of isocyanatophosphoric acid dichloride with
hexamethyl-disilazane takes place in ether solution at tempexa-
tures below 25*C:
[(("113)3S'I&N"+CIIPON(:O ((CII3)3SJj2NCONIIPOCIj
Card.--3/

ACC NRt AP6031383
The phosphorylated urethans 'and urea hydrolyze in the presence
?f HU with cleavage of the N-P bond:
ROCONIIPO(on,), -11.10 iIOGONH,+ (R,O)ZPOOII
HCI
RINIICON11PO(OR*)2 -1-0~ nNIICONH, + (R,C)2POOII
CO'MPO'Sition and*properties 'of the isoe*y'anatophosphoric acid
derivatives are given in the table: [WA-50;. CBE No. 121
it, -A

ACC NR- AP60"i-i'Z13,
,.Table 1. Derivatives of isocyanatophosphoric acid
Ca-

ompound
yfridl
I
r-Pd
rormult, u-
C 1
I:t.d

If Orn,ocnit it Poi nc iw, 93 Its-fir 1I.M tj.94 qH"MO.I.
OC11140CAIP411polocly, 93 118-110 11.60. 11.41 C^'-fo'?
11.10. 11.26 C.""N.O.1" 11.81
IV r'11JOCOMBPO(Oc".y. PC 134-133 13.15, 13,03 1700.001 f3.44
V C4 11,10COM If Po(oc'ur I "1' 1`4 - 11.31. 11.44 C'11~"'O.F' U'll
Tj 4.6-(11 OAR ISOCON it Pol OCIIIII 104-1011 11-41. 1143 C,R,,ND,P 11.17
Ytt (Cillilc
rlt(.OCONttpo(octt,ll. too-M WMI 11.44 r,'110.00, 11.41
yl 11 i
2.4.6.q 1.10CO)IMP01001.41. t41-143 fS.10, 15.33 C.11".4,0"I" 14.04
Ix q",Ococ.K Iwllcatilimocly~ 44 100-013 IAL AAI c0lulso.1, It."
x qii,OCOCH..~iicott"po(oc$N,-,.II 141 151-1s] 8.81. 1.12 1.31
At mooec'st'"Hcom"Polocilil, 64 Ijil-jell wit. 0.14 10.14
Ali HOOCCAOCON"POEOCH311 $7 - mm. 10.63 C'.""MO'P 10.71
Atli no ocqll.oco N IIPOIOC,H r Iwh w - 4.51. 8.10 CIM."Oll' 3.97
x1v cCj.CHIOCON"PO(OC1J3hlPO(OCHsh 03 38-40 13-41- 15-4$ C11111CONPI 95.14
~ff CCliCHIOCOMBPOIOCHrix%IPO(OCHs6 84 - 13.3-L 13.31 CO.M.80.1'. 13.33
xyl N11,11o'c'11,1411CORMPoloc".). 1114-11111 1.31. I-4j CA.M.0.1's 1.58
XVII P.l4H.SoAH,NHCoNIIpo(or'H'k*4 iso-112 &.,A sm m,,P-mors 1.25
XTIII i(CM."911.11COMM"Of ~32.scx 22.31 C'11"Ct'"Argl. Q n.97
i SUB CODE: OT/ SUBM DATE: 12Ju165/ ORIG REF-- 002/
Card 5/5

ACC NR: AP7011820 SOURCE CODEt UV0079/66,036/012,2215/2217-
AUTHOR: Derkach, G. I.; Gubnitskayaj Ye. S.; Kolotilo, M. Vo; Matyusha, A. G.
ORG: Institute of Organic Chemistry, Academy of Sciences Ukrainian SSR
(Institut organicheskoY khimil AN UkrSSR)
TITLE: Reaction of isocyanatophosphites with alkyl halidesv N-chloro
compounds, and azides
SOURCEt Zhurnal obshchoy kh1mli, v. 36, no. 12, 1966, 2215-2217
TOrIC TAGS& organic Isocyanate compound, azideq chlorinated organic
compound, organic azine compound
SUB CODE: 07
ABSTRACT: The alkyl esters of isocyanato- and diisocyanatophosphorous acids react.
readily with alkyl halides, N-chloroamines, acid N-chloroamides, and N-chloro-
iminoesters with an Arbuzov rearrangement, forming derivatives of isocyanato-
phosphonic (1) or amidophosphoric acids (II). The compounda EtP0("YC0)(0Et)'
:~M-o 2"C04COPP(NCOMS02 (liquid), and m-O0C6H4CONHPO(OEt) 'KHCONHPh were syn-
-thesized in this manner. The interaction of N-chloroamidines witb isocyanates of
trivalent P led to phosphatriazIneep of which
Ca,d 1/2 UDCt 50

ACC NRj AP7011820
N
PhC \ IIN-\\
P(D)OBt PhC P(m),
and (liquid)
HN NH N PIK
G C
0 0
were prepared. Alkyl azides, aryl azides, and azides of carboxylic, phosphoric,
and sulfo acids reacted vith phosuborous acid isocyanates vith the formation of
4socyanatophoophazo compounds: -Rj~ + R9 P(NCO) N2 + RN=PR' (NCO) (.III),
n 3-n n 3-n
R9 = AlkO, ArO, AlkS, ArS, NR2 ; n = 11 2
'Compounds I-III reacted readily vith alcohol&,, pbenols, amines, or other compounds
icontaining active H or metal atoms, forming the corresponding phosphorylated '
urethanes or ureas. The constitution of the P isocyanates and their derivatives
ivas est~blisbed on the banie of IR spectra, chouical reactions,, and analytical
data. Orig. a'rts hass 3 fonsulas and I table, r_j, 1151 40,3LIJ
Lip
card 2/2

PASHCHENK0, V.Ya.; SISETSKIY, A.G.[SisotstlWi A 11.]; SMM12,10 G.S
[S;yzonsmko, II.S.); DASSETMICY, Ya.R.jD;;hkerjch, IA.R.J;
KOVALICHAK, G.I.LKovallchak, H.1.1; KOVAL', F.T., red.;
121PIYAKEMICII, I.P.[Krypliakewch, I.P.I. red.; CHUGAYOV,V.P.
(Chubaiov, V.P.], red.; DERKACH I -red.,- BURKATOVSYMA, TS.
(Burkatovslka, TSI, teklE. red.
(Condition of Lvov xmi-kers, 1917-1939]Stanovyshche trudia-
shclvlth LI-rova, 1917-1939; dokumenty ta materialy. Liviv,
IUWzhkovo-;:hurnallne vyd-vo, 1961. 4.43 p. (MDIA 15: 11)
1. Uk--aine. ArkhiN-noye upravloniye.
(Lvov-Labor and laboring classes)

RABINOVICH., B.D.; Prinimali uchastiyer VDZENtKOVSKIY, V.I.; PPKA.CH, ~jq
XOCPIINA, L.V.; POLOVKO, Ye.T.; SHILO, V.P.
Investigating the performance of a vibratory screening machine.
Trudy W~rNIISP no.5.-21-33 159. (MM 16:11)

PASHUK, Andrey Iosipo,,1ch[Paszuk,, Ai)I,DERKACH, Ivan Stepanovich
[Derkacz, I.]
(Lvov; concise illustrated guidebook] L!viv; korotkyi iliu-
strovanyi putivnyk. Llviv, Knyzhkovo-zhurnallne vyd-vo, 1961.
1
170 p. (.MIRA 16:6)
(Lvov--Guidebooks)

PASHUK., A.I.; DERKACH, I.S.
[Lvov; concise illustratee ruidebook] Korot.kvi Iliustro-
varyi putivnyk. Llvivp Knyzhkovo-zhurnallne vyd-vo,
1963. 173 P. (MM 18:5)

PASHU-N, Andrey losifovich; DIRYLACH
.............
LLvov; a brief Mustratod guidebook] Llv; 'v;
strovanyi putivnyk. Llviv, Llviv-Oke
,.,yd-vo, 1962. 173 p.

DERNXH~ K.F., inzh.; MOZ,"!.-..BI, GJ. inzh.; 1MVIBEM., V.D.., insh.
Idning and ore-dressing eqwipment made by the Yasinavatka Mach-inery
Plant. Gor. zhur. no.)-.0-66 Hr 162. (141M. 15~7)
1. Yasinovatskiy mauhinostrolteVnyy zaLvod.
Yasinovatka-Mining machinery)
asinovatlm-Ore :h-essing-Equipmnt and supplies)
R

5-0 0
AUTHOR: Derkach, R. N.
4h254
S/035/62/000/012/oi7/064
AOO1/A101
TITLE: Photographic and photoelectric polarimetry of the Moon through
light filters
PERIODICAL: Referativnyy zhurnal, Astronomiya I Geodeziya, no. 12, 1962, 65-66,
abstract 12A478 ("Uch. zap. Kharlkovsk. un-t", 1962, v. 122, "Tr.
Astron. observ.", v. 14, 79 - 85)*
TEXT: The author presents polarimetrie studies of some areas of the lunar
surface in red, yellow, green, blue and integrated light. Lunar pol'arimetric
studies were performed by means of the 8" refractor of the Khar'kov Astronomical
observatory by the photographic and electrophotometric methods. Maxima polariza-
tion degree for all measured lunar ax,eas Ic observed In blue light. It has been
established, on the basis of results of elect,-opolarimetric studies, that majori-
ty of details have minimum polarization degree with the yellow filter, and mi-
nority - with the green one. There are 9 referencos.
From author's summary
[Abstracter's note: Complete translation]
Card 1/1

6015215 SOURCE CODE: UR/0269165/000/012/00181001'9
AUTHOR: Dudinov, V. N.; Derkach, K. N
TITLE: Preliminary measurements of the degree of polarization made with an
automatic electric polarimeter
SOURCE: Ref. zh. Astronomiya, Abs. 12.51.156
REF SOURCE: Vestn. -,Khar1kovsk. un-ta, 1965, no. 4, ser. astron., vyp. 1, 65-70
T013IC TAGS: moon polarization, electric polarimeter, phatomultiplier
N-/
ABSTRACT: A new model of an automatic electronic.R!21ar meter produced at the
Astronomical Observatory of Khar1kov Universit is described. The instrument has
a revolving polaroid behind which a photomultiplier is placed. Measurement of
polarization actually consists of measuring the amplitude of the variable component
of the photocurrent. Amplification is made by direct current. The d-c amplifier is
enclosed in a negative feedback which stabilizes the amplification. It is noted that
the mean square of error is 176 of the measured polarization value. When measuring
Card 1/2 ILJDC: 522. 617

L 45221-66
ACC NRt AR6015215
polarization for 1--~-216 at low phases, the mean square error remains of the same
order, because in this case the brightness of details increases considerably. The
tables show results of polarization measurements of details of the Moon during two
phases. [Translation of abstract] 7-\ [VA
SUB CODE: 02,20,091 SUBM DATE: none/
hs
- ) n