SCIENTIFIC ABSTRACT K.V. CHIBISOV - K.V. CHIBISOV

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• Collection: Scientific Abstracts
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• Document Creation Date: December 30, 2016
• Document Release Date: June 19, 2000
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

K~V~
6
idsm/ Physics - Spetrophoto0etry
CWA 1/1, Pub. 43 - 28/62.
Tit IBM010ya, spectr7Ophotciistric method for the study of the chemical
sensitization.of photo emulsions
Par Lodical IIzvi AN SSSR Sbr .. fix.~ 32/~ ~-6894W Nov-Doe 1954
AbarLract IA -dif f erentUl; P'pedvroph Otometric methododeveloped by Ye. A, Kirillov was
utilized for the Arst- time for Us study of centers formed during chemicalj,
reduction and sensitization processes of silver bromide emulsions. The
sensitizzation wis: accomplished by immersion of the layer in a hydrazine solu-
tion, The effeots of sensitization and aging were determined spectrophoto-
metrically and then covpRred photographically for the purpose of determining
the light sensitivity of the emulsions, Results obtained are briefl'y des-
cribed, One MR-rafereace (1951). Graph.
lwtitution *.The I. I. Machraov-State.Univeraityp Physics Instep Odessa
Submitted

rff /J'o 1001-
'-:'USSR/Chemistry - Physical. chemistry
Card 1/1 ~Pub. 22 - 27AS
AuthDrs KirMov, E. A.; Broun,, Zh. L.; and Chibisov K. V., Memb.Corres. of Pd1 SSSR
Title Study of the chemicalsensitization of photo emulsions. Effect of the re-
ducing agent,
:.Peri;bdical Dok. ANsSSR 98/~, 427-430, Sep 23., 1954
Abstract t Reduction sensitization experiments by treating a Liprnann AgBr emulsion in
the fom of layers applied on glass slides,, with a hydrazine (N2H4 * H250 4)
s6lution, are described. 'The absorption spoctrum of the emulsion layer,
treated in a hydrazine sollution., was measured and the results are shown'in
graph. It was found, on the basis of spectrophotometric measurements, that
the physical essence of sensitization with hydrazine, consists in the. fca"na-
tion of silver centers which increase in number ani size during increase in
concentration of the solution. Three USSR references (1948-1953). Graphs.
lnotittAibn-, The 1-. 1-. Mechnikov:State-University.. PhYoica Institute, Odessa
J, May.6j, 1954:

A of Itho Qh~inlcaj simuilization of is lihrjt(j-
cintilrilwi, Tho uffeas of cf)mpounds Aith k4blIt,
SAftli. P, A. L, Ortit'il, awl. K. V, 01:1liviv
ljjqtL~ I!lljv,. Aikllt~v 'Ituff, it, .
102, 1 15111,112(111174t); ell. C. 1. 41), U-91"k, - W
'I'liv tole A I 11"'l'! S ili tile., ClIvIll. t4 photfl-
Ila, by the ~:mw-
Ill't 1e j ii thors lo invuhl 4:.1 t, ".0 ilk.-
I i'm i4a 3l- ( C. I - 49, 12i);Mlij 1, Thi n Jj 'ver, id Lipp-
iimwi AgOr umilslon wit, triatttj for I inin. "t 2411 will]
, , -1 allolt, 1.
l;ijll.i. if Ellizillwa Cmitt'. 0,*-- x 10-1 and 0.3 It) I
all"I Wj plic)l(l.
:0)II11111"'m ill . r1ftiml 'ilwi-IN FeWfoll %%
grtlihilt propurtit,s inijival" tl.i~ Immitilm of flell, 1'elivity
c., aturs in alk. ximiLr Iti,prolierlius to tliosl; fritilled.
Wn the'l-lillonuna tinulsion was tmitcd with
b) W
thiourc-A -it iii omii pll~ in "inwrted" silecLirum of finc
wil:Jurc was oliu-bif-J, ijulit-Ating a titstructiou of the
prim.try o-weri. NVith a thillurva cuarn. .4.0.3 X Ill I
llstlight
6,1'. wi(Il 0.3 Y I it. I l"Illk-ji. it 114, -1))W.1 to 4111illl 11, '~iltlv
w.,ulliptimin -aw S*1f9l;t*Ntl*d If- Nfit0lell'.
couctptiun (4 paAstive holu tmpA as coutributitit tit
fight ~.+Mtlvity illivaus law NUtchell, C-4. 48, WK h,1. Ag
"inters formed in the nonmt imillsion are fDrined doriul;
tile iiAitir.1 ripening principally inside the equats and act
astlicamplorbof the "poehlyebobs" and ol the Br Atoms.
Relatively large amorphic Ag centers, located principally
on the wirface. are the acceptors of the photolelectron3.
While bi4b_kiMs Ucenbirsare
their functiow. T'he rok of 8 compils. (wW of MHO con-
flists In the aceckration of the Chem. ripening at The cost of -
auluicrewd conen; of at. As centers. W. M. Sternbexit
--- -------

CHIBISOF, X.Y,
. I-M-00-0
"Principles of the thes,37 of photogrqftie proosissesol* 2 *d. UoK.
Utushev mA V.-I.Shoberster. Astleved by Ir Chibleov. ZhUrerAuche
1 prIk1. f ot. i kin. 1. no,1:77-78 Ja4 15;.' (MMA 9: 10)
(Photographic ohmIstry)(Utushcv, U.N.) (Shoberatev.V. 1.)

C1111315c"V V
Category : USSR/()pt..JCF. p~ j,'g,q
Ab a Jour ; Ref MmT: - 2;-;.~IkA, A- j., 19F7 N, ~-6581
Author : Brour... 2.1h..t., kz* I.Jjev, Yc?,.A., C."Ilbisov, K.V.
last Rbcysics I'Yjq_L th-~
Title Spect.-~.-DIA1,+i :'r
~'.r C-temical SeAsitizatioa of Photographic
Bmulsiz~s.
_Mft.
Orig Pub Zh. nauch, i f-,tc tc , 1956, 1, No 2, 98- 0
Abstract Chemic9l vas vit'h 19yers of Lipman emx1sion, first
K-1.1
pracpsa~ai I:-.- a zt-'I-atlom f:7f ti:z chloride, thiourea, or thioZinmnine
at 20P f--~~ Wz~r,,tE:s., Afte~~ the laye:r, was washed axLd dried, the ab-
SOX-fftj~._ Sp-:;~Ijtt'M VaS jalt'S ft &4ubie monochromatdr I-ram the ratio
to tLe !%YF-Z' fl~ thz-, t7v'%')--80-0 mu regicn, with irme-rvals of 2.5--5
mu (usirg th~~ mtethcl), To Istermine. the photographic action of these
soluticc-S., tlk:~ comIA-W"Is wrsrs exWsc-_I a,-A developed in a glycin developer. The
light Se-FLeltivity- %-n,s.dete~imtned from the threshold (using the Ecler-Hecht wedge).
It was fztFibIl.sh-A that vh.~-n th.= I_nye~~ -?f Idpwa emmlsion is treated vith re-
ducers b.
Ti t= chl_cTl.de) -r vi,th compounds with labile sulphur (thiourea
or thyozj_-..,aao:-_ 8.-UmI-Lcf~_me:djum) Ir- ceitai- concentrations, me observes a
flne with the structure rzoduced by photochem-
ice.1ly-dy"....--a &V_irv~or cx by v8cuim spattering of silver. An analogous
I

CHIBISOV, K.V.
ftftwafi~~~
Defense of dissertations. Zhur.nauch. I prikl. fot. i kin. 1 no.3:236
H.v-Je 056. (Color photography) (MIRA 9:9)

i
CHIBISOV. N.V.
ODoeweents on the history of the Invention of photography;
corresponde%ce of J.N. Nispes, J.M. Daguerre. and others'
("Trudy* ol the Archives of the AcadmW of Sciences of the
U.S.S.R., no. 7). Reviewed by K.T. Chlbisaw. Zhur. nauch.
i prikl. fot. I kin. I io.4:317-318 JI-Ag 156. (MM 9- 10)
(Phetagrapbr-History) (Nlepc*. J.1.) (Deguerre. J.9.)

-Eon= I
imqmpm
7=t !P;v7

"Inroat4tatlans o! the rktu f
K It, 11 4 4. "~ ~
-rk' Will 41

amorphous Parlicles incANI.WS the

CJUBISOV, I.V.
Q-0mm"iPmalk
Swmmari of the work of the International Conference on Scientific
Photograpby, Zhur. nauch. i priid,, fot.1 kin. 2 no,1:65-68 J&-F
'57. (Cologne-Photography-Congresses) (HLU 100)

ITSSR/General Problems. Methodology. History. Scientific A
Institutions and.Conforences. Instriaction.
Ques-It.-Jons Concerning Bibliography and Scien-
tific Documentation.
Abs Jour Ref Zhur-Khimiya, No 3, 1958, 6813
Author K. V. Chibisov
Inst
Title ',.-'Io*-nk of Soviet :.'cientists in 'L:',phere of ;.Nicory
of 111-iotoi3raphic IRmulsions
Orig Zh. nauclm.* i prikl. foto-r. i kinematorr.,
10j'57: 2., No 5, 3?2-389
Abstract- Review (covering 40 years) of most imDortant
works. BiblioGra-phy with 116 titles.
Card 1/1

CHIBISOV, K.T.
. a mm"
The nature of p1hotographic sensitivity. eip, nauch. fot, v01, 3:5-)8
157. NURA 10:6)
(Photographic sensitometry)

CHIBISOF K -
~-
Photography qs a method of research In science and technology.
Sav.foto 17 no.1:3-6 Ja 157. WU 10:7)
l..Chlen-korrespondent Abadvell sank SM.
(Photogrephy-6ddentific applications)

041BISOV, K.., . ,
1-mmummm I - 4~ . .
Summary of the work.of the International Conference on Scientific
Photography. Say. fate 17 ne.4:60-62 Ap 157. Mu lo:6)
(C41agne--Photography-.Convolsax,)

AUTHOR: Chibisov, K. V., Corresponding Member AS USSR 3o-2-25/49
TITLE: Conference on Scientific and Applied Ph,tography
(Konferentsiya po nauchnoy i prikladnoy fotoGrafii)
PERIODICAL: Vestnik Akademii Nauk SSSR, 1958, ITIr 2, pp 9o-91
(USSR)
ABSTRACT: Called by the Hungarian Society for Optics and Motion
Picture this conference took place in Budapest from September
11 to September 14, 1957.12 reports were made by Hungarian
and 14 by foreign specialists. The participants visited an
exhibition of photographic cameras and of photographic
material of Hungarian origin, as well as the production of
motion picture films photographic films and photographic
paper. This conference dealt with problems of the nature of
light-sensitive photographic films, the photographic activity
of gelatine and its synthetic substitutes, sensitizers and
others. Questions of emulsion technology, of colour photo-
Graphy, of the developing process and of photographic
sensitometry. The conference decided to establiah a regular
Card 1/2 exchange of publicationsand systematic meetings of

Conference on Scientific and Applied Photography 3o-2-25/49
specialists of the people's republics. Moreover, such
conferences should be held at least once a year.
AVAILABLEi Library of Congress
1. Conferences-Photograp)W-Budapest 2. Photography-Hungary
3. Photography-Equipment- 4. Films-Applications
Card 2/2

CHIBISOV -- -
Conference on scientific and applied photography In Budapest and
the phntographic and cinematographic industry of Hungary. Zhur.
nauch. I prikl. fot. I kin. 3 no-1:73-75 Ja-F 158. (MIRA 11:21'
(bidapost--Photography--Gongre~Bes)
(Rungary-Photography) (Hungary-Ginematographr)

SOV 77-3-4-23/23
AUTHORs Chibisov, K V * Bogomolov, K.S.
TITLEs The Stat of Photographic Science and Industry in Japan (So-
stoyaniy: fotograficheskoy nauki i promyshlennosti v Yaponii)
PERIODICALt Zhurnal nauchnoy i prikladnoy fotografii i kinematografii, 1958#
Vol 3, Nr 4P pp 314-320 (USSR)
ABSTRkCT: The authors review the vArious spheres of activity in theoretic-
al photography and in t%e photographic industry in Japan. There
are 2 photos and 3 tables.
1. Photography--Japan 2. Photography--Theory
Card 1/1
uscomm-Dc-
.556o6

CHDISOV. I.V.
-.
4OPI_ Present-day lnterprotati0n� of the formation of photographic
sensitivity. Ahluenauk I prom. 3 noo5:556-567 .)6.
Nzn 3LI: n)
1. Chlenpkorrespondent AN SSSR-
(Photographic emulsions)

Present Opinions in the Field of the Photographic 71',-27-3-2/7
Emulsion Theory
geneity of the defects of admixtures,as well as of the
uniformity of chemical sensibility (as a reduction pro.
cess) (see diagram 6 and 7).. The author investigated the
actions on the spectral sensitivity to light of the pri=
mary centres, the changes of concentration by means of
chemical maturing. For this purpose the distribution of
sensitivity within the range J~ = 400-800 MJL at non-
sensitized emulsions (at various moments of the second
maturing) was investigated by means of spectral sensime=
try, For the dttermination of the joint binding between
S79 Smso and SKk6,,-sensitivity the change of these
quantities since the second maturing was compared (see
diagram 6). It strikes in this comparison that the in=
crease of sensitivity (SX%5O) since the second maturing
to the maximum considerably la-a behind the increase
U
of the integral. sensitivity (s-j. in this connection
the increase of the lon,; wave ,,.cnsjtivity is
,ard 2/3 of the same order as with SV.. Tlherc!fore, it. if-, -,jsu!~Ied

-Present Opinions in the Field of the Photographic 74-27-3-2/7
Emulsion Theory
that chemical maturing is more effective than the long
wave or integral sensitivity. 1.1oreover, the author
describes the bromine iodine containing emulsions on
which occasion he finds that the iodine ions equally act
on the integral and "blue" sensitivity which increases
their value to the maximum. The dependence of the sensi.
tivity on the content of silver iodide in the emulsions
is illustrated in diagram 7, and the lanciform phenomena
of the increase of sensitivity after the addition of
hydrazine sulfate to the emulsion on diagram 8. Also the
reciprocal bindings between the own and the added de.
fects of the emulsion crystals are of interest. It was
found that there is always an interaction between the
own and the added defects of the emulsion crystals.
Finally the case of the hidden shoping in chemically
non sensitized micro crystals is discussed: this pro=
cess takes place in two stages.
There are 9 figures, 2 tables,and 56 references, 31 of
-.rn Soviet..
1. Photographic emulsion---Theory

CHIBISOV, K.Y.; BOGWOLOV, K.S., Imud. khim. nauk
...............
wwwow'"~ Fourtb symposium on photographic sensitivity. Test. 0 SSSR 28
no. 6:95-4 Ja 058. - (14MI 11:7)
1. Chlon-korrespondent AN SSSR(for Chibisov).
(Tokyo--Photograp'nic emulsions--Congresses)

AUTHORS: Karpova, A. L., Mikhaylova, A. A., SOV/2o-121-1-37/55
Chibisov, Corresponding Member, Academy of Sciences, USSR
TITLE: On the Photographic Activity of Gelatin (0 fotograficheskoy
aktivnosti zhelatiny)
PERIODICAL: Doklady kkademii nauk SSSR, 1958, Vol- 121, Nr 1,
PP. 133 - 135 (USSR)
ABSTRACT: The authors tried to remove the admixtures from gelatin by means
of adsorbers and to separate them by means of an electro-
dialysis with the aim to investigate the influence of these
admixtures on the chemical "ripening". Various adsorbers
exhibit a selective action and only some resins with ion ex-
change were suited for a practically complete removal of all
active admixtures. By this the different gelatin samples
were given the same properties and turned into slowly acting
gelatin. Also electrodialysis removes the active admixtures
and renders gelatin inert. If a five-chamber device is applied
the admixtures can be separated in the form of an anodic
and a cathodic fraction by electrodialysis. The substances
of the cathode fraction do not directly interact with the silver
Card 1/3 ions. The compounds with unstable sulfur, the reducing agents,

On the Photographic Activity of Gelatin SOV/2o-121-1-37/55
and the complex forming substances of the first kind,
however, turn into the anode fraction. According to photo-
graphic investigations, the solution of the cathode fraction
slows the ripening down while the anode fraction accelerates
it. The photographic effect of the gelatin during ripening
is realized by its two components: The macro-component, i.e.
the albumins of the gelatin, exhibits a protective effect and acts
reducingly; the micro-components control the velocity of
the chemical ripening. There are 3 figures, 2 tables, and 3
referenceaq ' which are Soviet.
ASSOCIATION: Vsesoyuznyy nauchno-issledovatellskiy kinofotoinstitut
(All-Union Scientific Research Institute of Photography and
Cinematography)
SUBMITTED: March 18, 1958
Card 2/3

On the Photographic Activity of Gelatin SOV/2o-121-1-37/55
1. Photographic emulBions--Separation 2. Photographic emulsions--Chemical reactions
3. Photographic emulsions--Properties 4. Adeorbents--Performance
Card 3/3

23( SOV/77-4-3-4/16
AUTHORS: Karpova, A.L., Mikhaylova, A.A., Chibisov, K.V.
TITLE: On the Photographic Activity of Gelatine
II. An Increase in the Kinetic Activity of Gelatine
PERIODICAL: Zhurnal nauchnoy i prikladnoy fotografii i kinemato-
gratii, 1959, Vol 4, Nr 3, pp 183-192 (USSR)
ABSTRACT: This is a study of the effect of sodium thiosulfate
on -the second ripening process of gelatine solutions,
shown on the example of three different galatine com-
ponents. On the basis of experimentally obtained data,
the authors deduced a general equation, expressing
with it the deDendence of the rate of second ripening
on -the quantity of natural and added accelerators.
Parallel to these experiments,'.the authors studied
the effect of other sulfurous sensitizers and also
of bromine (silver) ion concentration. Different
quantitites of sodium thiosulfate and the solid phase
Card 1/7 separated from the colloid of the first ripening pro-

SOY/77-4-3-4/16
On the Photographic Activity of Gelatins. II. An'Increase in the
Kinetic Activity of Gelatins
cess were added to solutions of gelatine with different
activity coefficients. The solid phase contained 3
mol. % AgJ in addition to AgBr. The authors started
from the assumption that in the stage of chemical
ripening sodium thiosulfate acts only as a complex-
forming substance, causing acceleration of chemical
ripening. The added quantity A', therefore, was added
to the quantity A of natural accelerators in the ge-
latine. These data, in connection with the quantity
B of' natural retarders, served as the basis for the
calculation of the activity coefficient (K = A + A'
13 ) -P
Table 1 demonstrates the results obtained. It con-
tains in addition the values r, (time reauired to reach
the maximum light sensitivity) and ro (r. = k%). The
values r were calculated with the aid of the curves of
Card 2/7 change in light sensitivity for each concentration of

SOV/77-4-3-4/16
On the Photographic Activity of Gelatine. II. An Increase in the
Kinetic- Activity of Gelatine
Na2l'3203introduced into the emulsion. This calcu-
lation was carried out., to demonstrate the subor-
dination.of the values to the already found
/-reference 2 7 linear dependence between the acti-
7ity coeffici'6nt and the rate of chemical ripening
and, consequently, to confirm the assumed role of
Na2S2O3 in this process, The results confirm this
assumption, showing that Na2S2O 3 behaves like those
natural complex-forming components, which have most
affinity to the silver ions. The obtained values are
chELracterized by two prominent features: 1) A strict
dependence of 'ro on the conditions of emulsion syn-
thesis, and 2) fluctuations of the individual values
of this magnitude within parallel experiments. This
Card shows that Tv (time required to reach the maximum

SOV/77-4-3-4/16
On the Photographic Activity of Gelatine. II. An Increase in the
Kinetic Activity of Gelatine
light sensitivity, if k=l) is a very sensitive magni-
tude indicative of the observation of constancy of
the established synthesis conditions. On the basis
of their experiments, which confirmed the role of
Na 2S203 as accelerator during the ripening process,
the authors enlarged the previously obtained formula
To - A& by adding At to the numerator of the ac-
tivity coefficient. The equation (in its final form:
A'. ro B I - A), on the basis of the dependency
P7r( see graph 1, which represents this depen-
enc~ f3r the three series of experiments in table 1),
mak'6~ it possible to determine the content of acce-
lerators and retarders in gelatine. In order to cla-
Card 4/7 rify the role of sodium thiosulfate, the authors

SOV/77-4-3-4/16
On the Photographic Activity of Gelatine. II. An Increase in
the Kinetic Activity of Gelatine
considered it suitable to compare its effect on che-
mical ripening with the effect of other compounds
with an unstable sulphur component. A study of the
effect of thiourea, sodium tetrathionate and tri-
thionate and potassium rodanide revealed that, with
the exception of thiourea, these compounds are not
subject to the general equation (graphs 2-4). They
showed a retarding effect on the ripening process.
Finally, the authors studied the effect of pAg (pBr)
on the kinetics of chemical ripeninS. Graph 5 shows
curves (based on previously described experimental
data), which represent the dependence of the rate of
ripening on pAg for bromine and bromo-iodine emul-
sions. The curves (table 4) show the complicated
character of this dependency. A further factor is the
instability of the maximum light sensitivity (section
Card 5/7 2 of graph 5), which can be reached at various values

S011/77-4-3-4/16
On the Photographic Activity of Gelatine. II. An Increase in
the Kinetic Activity of Gelatine
of pAg. Optimum pAg can be assumed in the case, -,-.,hen
the maximum light sensitivity has been reached. The
strong effect of the nature of the Selatine component
on this phenomenon however has to be taken into con-
sideration. This factor also plays a role in the de-
pendence of the change of maximum sensitivity on pAg.
The last section is a theoretical generalization of
the results. Table 4 is a synopsis of the effects
exercised by the various substances on the rate of
ripening, the maximum of light sensitivity and the
fog phenomenon. The latter is considered in connec-
tion with the maxima of light sensitivity. The authors
mention the Soviet scientist V.A.Bekunov /-reference
7-7, who proved the linear dependence (pAg, 1 There
to
Card 6/? are 5 tables, 5 graphs and 8 references, 6 of which are

SOV/77-4-3-4/10"
On the Photographic Activity of Gelatine. II. An Increase in
the Kinetic Activity of Gelatine
Soviet and 2 Englinh.
ASSOCIATION: Vsesoyuznyy nauchno-issledovatellskiy kinofotoin-
stitut (NIKFI) (All-Union Scientific Research In-
stitute for Motion Pictures and Photography (NIKFI))
SUBMITTED: 22 August, 1957
Card 7/7

23(
AUTHOR: Chibisov, K.V.
SOV/77-4-3-14/16
TITLE: Great Jubilee. The Seventy-Fifth Birthday of Pro-
fessor Ye.A. Kirillov
PERIODICAL: Zhurnal nauchnoy i prikladnoy fotografii i kinemato-
grafii, 1959, Vol 4, Nr 3, pp 237-238 (USSR)-
ABSTRACT: This is a review of the scientific, pedagogical and
organizational work of Professor Yelpidifor Anempo-
distovich Kirillov, written on occasion of his 75th
birthday. Since 1921 the scientist has been a pro-
fessor at Odesskiy gosudarstvennyy universitet (Odessa
State University), where he holds the chair of experi-
mental physics in the physico-mathematical department.
There is 1 photograph.
Card 1/1

SOV/20-126-5-30/69
On the Spectral Properties of Optically Non-sensitized Photographic Emulsions
ripening of the emulsion for different *X, with the kinetic
curves of the total light sensitivity (Figs 2,3). The fine
structure of the absorption spectra indicates that the crystal-
lization of silver bromide is in the first ripening accompanied
by the formation of impurities consisting of silver nuclei.
The latter have an immediate effect upon the total sensitivity
as well as the sensitivity to blue light. The sensitivity to
long-wave light increases only slowly during the time for
ripening and is not determined by the amount of AgJ, which in-
creases only the concentration of the primary nuclei (silver
nuclei) and the total sensitivity and the sensitivity to blue
light. According to Mitchell (Ref 7) the following is assumed:
The sensitivity to long-wave light is caused by a kind of co-
agulation of the nuclei to larger units. The concentration of
these units remains inconsiderable compared with that of the
primary nuclei. Experiments made by Ye. P. Kramaley (Ref 8)
show that silver may occur in the emulsion also in atomic or
molecular state apart from the colloidally disperse form. This
is assumed for the primary nuclei (I) which, therefore, con-
Card 2/3 sist of A92 , are in equilibrium with AgBr, and are adsorbed in

BOV/20-126-5-3o/69
On the Spectral Properties of Optically Non-sensitized Photographic Emulsions
the lattice defects of the microorystalo. They cause the total
and blue light sensitivity. The secondary nuclei (II) - the
units - determine the sensitivity to long-wave light and repre-
sent the sublatent nuclei. The third kind are the catalytic
developmental nuolbi (III). They consist of amorphous silver
particles with a high energy potential. They are fcrmed during
the capture of photo electrons by the positively charged sub-
latent nuclei (II). The transformation (I) - (II) - (III) takes
place in the course of ripening of the emulsion as well as under
the action of light. These impurity nuclei take part in the
formation of the latent image. There are 3 figures and 13 ref-
erences, 7 of which are Soviet.
ASSOCIATION: Vsesoyuznyy nauchno-issledovatellskiy kinofotoinstitut (All-
Union Scientific Research Institute of Cinematography and Pho-
tography).Institut fiziki Odesskogo gosudarstvennogo universitets,
im. I. I. Mechnikova (Physics Institute of Odessa State Uni-
versity imeni 1. 1. Mechnikov)
SUBMITTED: April 1, 1959
Card 3/3

A
PH= I Wa ZOWMTION SOV/4159
Akademiya nauk SSM. Komisaiya po naacbnoy fotografil i kinematografti
Uspekbi nauchnoy fotografii, tom 7: Prirods fotograficheskoy ebuvstvitellnosti.
lzgotovlezdye galoidoserebryanykh fotogrefichaskikh sloyev.
Opticheakays sensibilizatmiya igipersensibiUzatsiya. Khimiko-fotografi-
cheakaya obrabotka avetochuvatvitelInylb sloyev (Nature of Photographic Sensi-
tivity. Preparation of Haloid-Bilver Photographic Layers&Optlcal Sensitizing
and Hyper-%%naitizing. Chemical-Photographie Treatment of Photo-gensitive
Uyers) Moscow.. 1960. 260 p. Errata slip inserte&, 1.,800 copies printed.
Editorial Board: K.V. Chibisov (Reap. Ed.) Corresponding Member, Academy of
Sciences USSR.. V.I. Sbeberotov (Deputy Reap, Rd.) Candidate of Chemical
Sciences, Docent, Yu. N. Gorokhovskiy, Doctor of Chemical Sciences,, Professor,,
G,A, Istomin) Doctor of Technical Sciences, Professor, and I.I. levkoyev.,
Candidate of Chemical Sciences; Rd. of Publishing House: K.I. Warkhilevich;
Tech. Ed.: GA. Siskina,
PWWR: This collection of articles is add seed to those working in theoretical
and applied photography and cinematography, and to researchers in the chemistry
Card 1/T

nature of Photographic Sensitivity (Cont.) SOV/4159
Sheberstov.. V.I. Aging an& Stabilization Processes of Photographic
layers 25
Solavlyev.. S.M.,, and V.A. Dwitriyeva. Aging of Photographic R'sall ions
and Quantity of Illumination During Exposure 50
Vendrcvskiy.. K.V. Effect of Preparation and Processing Conditions of
Photographic layers on Deviation ft= the Law of Interchange 57
Poshkovskiy, Th. Sh. Zffect of Chemical Sensitization on the Sensitivity
of Photographic Emulsions at Low Mvnination Intensities 77
I.P.., Yu. A. Krakau., and P.T. Sidarenkova. Role of
Thiocyanogen Ions in the Chemical Sensitization of Photographic E-11 I
With Gold 87
Novikovj, I.A,j, and N,S, Gafurvvm. Investigation of Effect of Sodium
Thiosulfate on the Photographic Properties of Ma3l ions Sensitized With
Gold 96
card 3A

Natwe of Photographic Sensitivity (Conte) WV/4159
Novikov., I,A. Change in the Dispersion of Small Grain ffmasions in
the Cheideal Aging Process 103
Kirillov., N.L., Yu. G. Chikishev., &L-1 V.L. Ze3.ikmn, Continuous
Processes in the Synthesis of Photographic Emulsions 108
7.elikman, V.L.,v and Ye. Be Ecmdratlyeva. Gelatin Concentration in
the First Aging 3.15
Levi., S.M. Modern Concepts of Gelatin Structure
Zimkin., Ye. A.., and 8.1. Paronik. Albuminous Type Admixtures
320
in Photographic Gelatin 134
Levi, 8,M. Modern Concepts of the Rheologic Properties of Gelatin
Solutions and Photographic E-1 ions 137
Uvarova., V.M,., and V.A. MalItseva, Search for Ways of Improving the
Structural Medhirnical. Propierties of Photographic Layers for Nuclear
Research 150
Card 4/7

Natare of Photographic Sensitivity (Cont.) SOV/415,
Ze3ikm!Ln.. V.L., Hetkods of Tenn' Photographic Mallsions 161
Levi,. S,N.,, Effect of Wetting Agents in MUttwes and DUr4ag
.~Jttlayer Coeul-tg 170
Rodicheva,p Elementary Composition of ftclear Photographic
Roll ions 178
II. OPr= ~IMZATIM AND 91 ITMATM
Borin, A.V. 1mvestigation of Concentration Effect Daring Optical
Sensitization of Photographic RwOsions 183
Pokrawskaya, Xj, Investigation of Interaction of lbroeyanines With
Silver Ions in Solution 191
Solarlyev, S.M, Hypersensitization, of Infracbromatie Loyers 201
Card 5A

Nature of Pbotograpbic Sensitivity (Cont.) SOV/4159
and. X.X, Parfenovs. Methods of Increasing the Stabi3ity
of Hyperseusitized Infrachromtic Film 210
in. cma= 33G OF LMK WSITM LAME
Bukin I
.0 ft. 1. (Deceaaed), Iuvestigation of Ta6cal ITfects in Developmut
ancl Their Effect on the Quality of Moving Picture 219
Kirillov,, N.I., A,X, Toytsekhovskaya., and N. Ye. Kirillova. Investi-
gation of the Stabi3ity of Coomraial Bleaching Solutions Used in
WIVI Processes 230
Kirillov, N.I., k.M. VoytsekhavakVa.. and N. Ye. Kirillars.
Utilization of Varicus Fi3dng Solutions in NW1 Processes 236
Kirillov, N.I.p AX Voytsekbovskqa., and X, Ye, Kirillcra.
Investigation of Thermostatic Aging of a Color Picture on a
*21tilayer Film Treated in Varicw Processes 240
Card 617

. Nature of Photographic Sensitivity (Cant.) SOV/4159
. Arnolld., To, 8, Problem of the Prodevelopant of Nmlt:Llayer
Color Negatives 2)!6
LlUfftbehlw, G.D.,, and S.A. 5hiptsyn. Problem of Btorqp of
Developers 253
AVAILAWA: Library of Congress
CIO& 7/7 JA/lab/ma
lo-2k-6o

KARPOVA, A.L.; CHIBISOV, K.T.
Additional reflections on the nature of the photographic activity
of golatin. Zhur.naucb.t prikl.fotA kin. 5 no.4:301-308
Jl-Ag 160. (MIRA 13:8)
(Gelatin) (Photographic emulsions)

CRIBISOV, Ia.
Chemical sensitizing in the ripening of the photogrpphic
emulsion. Zhur.nauch.i prikl.fot.i kin. 5 no.1:65-74 '60.
(wu 13:5)
(Photog?aphio emulsion)

23(0)
AUTHOR: Chibisov, X.V , Corresponding S/030/60/000/01/025/o67
-X*W16r4Tf-t?1~"*6ademy of Sciences B015/B008
USSR
TITLE: Collo2uium on Scientific Photography
PERIODICAL, Vestnik Akademii nauk SSSR, 1960, Nr 1, pp 72-73 (USSR)
ABSTRACT: The Colloquium was hold at Li4ge, Belgium, from September
14 to 19, 1959, and had been convened by Li4ge University.
The program of the Colloquium consisted of 3 comprehensive
problems: factors and the character of photographic sensitive-
ness; optical sensitivenessi essential photographic processes.
The following reports were given on behalf of the Soviet
scientists: V.A. Bekunov reported on the influence of gelatin
on the kinetics of chemical maturingi X.V. Chibisov reported
on the character of chemical sensit'Lieness; 1.1. Levkoyev,
E.B. Lifshits and S.V. Natanson reported on the light
r.-boorption and the sensitizing action of the cyanogen dyes
in dependence on their structure; S.V. Natanson characterized
the adsorption of optical sensitizers on silver-halideal
Card 1/2 A.B. Terenin and I.A. Akimov analyzed the optical sensitiza-

1- I."
Intermtional Colloquium on Scientific Photograpby. Zhure .-L-)
usuohA prikl.fot.i kin. 5 no,3:234-238 MY-Je 160.
(KIRA 13:7)
(PbotograpIV-Scientific applications)

I- CHIBTSDV, K.V. .1-1
Nature and formation of photographic sensitivity (Leased on the
Mitchell theory). Usp.rmch.fot- 7 13-24 16o. (MM 13:7)
(Photoebasistry)

LIVITSYAYA, R.A.: BROUN, Zh.L.,,','CgjBISOV, X.V.
Transformation of the additive centers during accelerated aging
of photographic emalsions. Zhur.nauch. i prikl.fot i kin- 5 no-5:
361-363 S-0 160o (MIRA 13:12)
1, Institat fisiki Odesakogo universitsta Imeni I.I.Mochnikova i
Kafed.ra uchabnoy i nauchnoy fotografii i kinematografii Mookovskogo
gosudarstyennogo universitsta.
(Photographic emulsions)

QLHPkSOVf K.V.
Ways of increasing the effective sensitivitX in pboto&raphy* Zhur.
nauch. i prikl. fot*i kin. 6 no.1:67-74 Ja--y 161* (MIRA 34:3)
(Photograr,hy-Research)

CHIBISOV,, X*V.;_SMC-WIC, L.,[translatorj
Photographic sensibility. Kem-ind 10 no.4zSuppl.F- 52-53 Ap 161.
1. Akademija nauka SSS, Moskva (for Chibisov),,

MELINICHUK, L. P.; BROUN, Zh. L.; CHIBISOV, K. V.
Localization of the topochemical reaction during the rapid aging of
photographic emulsions. Zhur.nauch.i prIkLfbt. i kin. 6 no.4:301-
304 JI-Ag 161. (MIRA 14:11)
1. Inatitut fiziki Odeaskogo universitats. imeni I. I. Mechnilkova i
Kafedra uchabnoy i nauchnoy fotografii i Pinematografii Moskovskogo
universitata.
(Photographic emulsions)

GMWVSKIY, Yevsey Mikhay1ovidh-,,--AWIBIPOT. K.T., otv. red.; PRO-
KOF'YZYA. N.B., red. izd-va; V=6V-A-.-Y--T--, tekhn. red.
(From silent to panorsiato motion ple'tureal Ot nemogo kino
k ponoramnomu. Moskva, Izd-VO A)wa. nauk SSSR, 1961. 147 p,
(MIRA 14:5)
1. Chlen-korrespondent AN SSSR (for Chibieov)
(Notion pictures)

VALyUSO Nikolay Adamovichl CgBISOV K.Vof' otv. rod.; GUS'KOV, G.G.,
red, izd-va; MAWIl YO.V-o t0 . red.
(StereoscopylSteroookopiia. Moskva, lzd-vo Aktd. nauk SSSR,
1962. 376 p. (MIRA 15:U)
-~44'912 -
1. Chlen-korrespondent Akademii nauk SSSR (for Chibisov).
(stereoscopy)

CIII-DISOVY K.T.
atructnre of the impurity absorption spectrum of silver
halidee. Zhur.nauch.i prikl.foto i kine 7 no-3-226-P-28 $62.
(HIRA 15;6)
(Silver halides ... Sp-,Ara)

V.
CIBISOV,j.V.;-SANDOIJC, Dranka [tranalatorl
Metbods of-luor,eaming effective mewitiveross.iA photograPhir-
oyotems. Isidja uAndustriji 2,2 no.2:6o-63 f62.

CHIBISOV, K. V.
[Basic problems of the chemistry of photographic emulBionB]
Oenovy problemy khimil fotograficheskikh emullaii. MosIm..
Izd-vo Mosk. univ. NIKFI, 1962. 121 p. (MIRA 16:4)
1. Chlen-korrespondent Akademii nauk SSSR (for ChibIsov).
(Photographic emulsions)

_5D JD 0
EWT(Q)~LNT(m)/BDS AEM_/A
ACCESSION NRs AP3001659 3/0077/63/008/003/0174/0184
AUTHORt --Kraush, L. Yap-1 Ly*s9nko,'L.,P I Chibisays K2_ V,
TITLE: Investigation of substructure in silveiybromide nicrocrystals
...........
SO~RCEs Zhurnal nauchnoy i prikladnoy fotografii,i kirA-matografiis, no. 39 1963v
174-184,, vol- 8
TOPIC TAGSs photolysis, polyhedric substructure,, silver bromide., electron stage
ionic stageo crystal lattice, microcrystal- i.
ABSTRACT: The model microcrystale up to 50 Micron in size used in this investi-i
.gation were obtained by spontaneous evaporation of a saturated silver bromide
solution in 15% armwnia. In order to bring out their substructure these c stals
X7
.were etched by exposure to ammonia vapors., to a 1% solution of sodium thiosulfa~e,.
:or to dilute methol-hydroquinone solutiqn, taking care to permit the etching to
!affect only the surface of the crtstals artial breakup, without causin,
for their p g
;dissolution, The crystals were exposed to daylight, as well as irradiated with:
a
quartz mercury lamp. It was found that the spots of the crystals which were
qfected by such treatment were those where some defects of the lattice structure
'Card 1
J

!L
185ih-63
Ids AP30016 9
1.ud already existed, presumably formed during the growth of the crystals, Micro-
ir7stals were generally more affected than large crystalse Gaseous ammonia, as
-.fell as photolysial, was capable of separating well-shaped tablets into separate
parts. These observations ate in accord with the already known fact that in
'photolysis of silver bromide crystals the deposition of free silver takes place
jalong the boundaries of the polyhedral structureo Orige art, hass 6 pictures*
AMOCIATION: Kafedra uchebngy i nauchnoy fotografii i kinematografii Moskovskiy
gosudarstvennogo universitati (Chair of Instructive and Scientific Photography
and Cinematography, Moscow State Univers
SUB14ITTkZ2 15bec'61 ACQs l2Jun63 ENCLs 00
I SUB CODEs CH NO REP SDVs 001 OTHM, 021
Card 2/2

BROUN, Zh.L.; CRIBLSOVp ]~.V.
Comparison study of the chemical and physical developing. Zbw.
nauch.i prikl.fot.i kin. 8 no.1:59-61 Ja-Feb. 163.
(KMA 16:2)
1. Nauchno-issledovatel'skly Institut fisiki Odeaskogo
universitsts, i kafedra uchebnoy i nauchney fotografii
i kiriematogr&fii MoskOTakogo gosudarstvennogo imiversiteta.
(Photography-Developing and devlopers)
it

BEWLZ,, V.M..-, CHIBISOV X,V
Relationship between.the luminescent " piptographic prop-
erties of emulsion 1hyers. Miur.nauch. i prI4.fot. i kin.
8 no.5:334-337 &-0 163. (MMA 16:9)

CSIBISZOVI K.W. [CHIBISOV)-K.V.)p dr. (Moszkva); FOLSTER, Alfred, dr.
- [trans3.ator.']'-
Topograph:.'eal properties of chemical sensitization of
photograph.'c emulsions. Kep hang 9 no.6:161-163 D 163.

L
S/020J63/149/062/ 3 028
BM/B186
AUTHOR6:., ''Brount Zh. L.' -'Kirillovo Yes A, t sukitiv_' ~V- 9
Corresponding.Hember-AS USSR
_TME: The discrete character of the extrinsic spectral ph6to-
sensitivity of photographic emulsions
56
PERIODICAL: Akademiya-4-1.pguk.;1.5SSR1. Dokladyt v. 149# no. 2t 1963, 353-3
TEXT: The extrinsic spectral,~botosensltivity of photegraphic emulsions
was studied by the differential method which determines.the relative
sensitivity to1ight- 31 8 t/S,.% - H,-%,O/H4,t. S is the spectral
Aw
_-photoeensit-ivity--and--H__ the-monochromat4v:- radiation- energy-which- gives
rise to- a-Pertain --- the. light Sensitivity) -durjmg-F____--
-the grgund-state ofthe,-O~ul6ion
.(0) and,in a definite instant (t) of
0 hemi oal- - s on sit izati-on f-- respe ct tirely*---The -- aut hors - stud i ed: a -Li P'pmann
waver bromide: emulsi aen iti d:with gold chloride, and normal
0 a Be
chemically ripened emulsions. The. curves of the extrinsic spectral
photosensitivity iDf the Lippmam -emulsion showed: selective bands with
coincident maxima'at a:different.dogree of sensitization; during
Card

!ACCESSION z--- AP4013973 S/0077/64/009/001/0038/0046
4XTHORS. Broun, 21. L.; Varshavert B. G.; Mellnichnukl L. P.; Chibisov, X, V.
iTlIM: Interaction investigations between spectral sensitivity and admixture
I
!spectral absorption of photographic emulsions
SOURCE: Zhurnal nsuohnoy i prikladnoy fotografii i kinematografii, v. go no..1,
1964t.38-46
ITOPIC TAGS: spectral sensitivityq photographic emulsion, silver bromide, admixture
center, gold sensitizer, discrete bands
:ABSTRACT: The possible existence of a discrete character in the spectral sensi-
Itivity of an optically unsensitized photographic emulsion has been studied. First,
Ithe magnitude of relative spectral eensitivit;r SIA - HA ~Hp,,t (HN - enerry of
Imonochromatic radiation) is calorlated for various values ofp, and, secondly# a
Isilver bromide Lieppman emulsion is used to observe carefully the thin structure of
'the admixture center speotrap using the differential method with a gold sensitizer.
'The spectrosensitometer ISP-73 is used to determine S.,%,- in the wave-length interval
1420-7('0 m
It is shown that the admixture spectral sensitivity is distributed in

!ACCESSION NR: AP4013973
Idiscreto bands both in the limits of fundamental 0sorption of silver halogenide and'
lin the long wave-length region, with a spectral position corresponding To thin
Istructured bands of the admixture spectra. A discussion is given on the role playe&
by these-centers on the emulsion layer under the action of light. "The authors are
~Srateful to Professor Ye. A. Kirillov for evaluating this-work." Orig. art. hast
_;6 figures and 2 tables.
:ASSOCIATION; Odesskiy gosudarstvenny*y universitet im. I..I. Meohnikova (Odessa
~State University); Vseopya=04~y nauchno-iseledovatellskiy kinofotoinotitui; (NMI)
011-Union Scientifio.Researoh Notion Picture Institute)
;SUBMITTED. 13Hov62 DATE 16q't i4re~64 ENCL: 00
~ISUB CODE: PG NO REP SOY&* 017 OTMM a 0~3
'6rd

BELOUSf V.
Luminescence studies of the role played by admixed silver centers
in the photolysis of silver halides. DokI. AN SSSR 156 no. 1:
121-124 My 164. (MMI 17:5)
1. Odtaskoye vyssheye inzhenornoye morskoye uchilishche i
Moskovskiy gosudarst,.renny)- .miversitet im. M. V. Lomono3ova.
2. Chlen-korrespondent AN SSSR (for Chibisov).

CHIBIS-OVP- KI.V, 1.
:Introductory address delivered at the l3th Conference an the Scientific
Applications of Photograpby. Usp.nauch.fot. lOz5.-6 164.
(MIRA l7t1O)

PYPIVITSKAYA, A.B.; MLINICHUK, L.P.; BROUR, Zh.L.; CHIBISOV, K.V.
-. ............... . .........
Evolution of additives' centers
ripening and accelerated aging
Par' 1: Changes in the spectral
ripening and accelerated aging.
kin. 9 no.5:321-327 S-0 164.
during the process of after-
of photographic emulsions.
absorption during chemical
Zhur. nauch. i prikl. fot. i
(11411RA 17: 110)
1. Odesakiy gosudarstvennyy universitet iraeni Mechnikova.

,; KALIMANS011, ES.
CHJBJ~OV, ZV I
Effect of surface additive centers on the deep light sensitivitY
of photographic emulsions. Zhur. nauch. i prikl. fot. i kin. 1.0
no.4:292-294 JI-Ag 165. (PIMA 18:7)
1. Vsesoniznyy nauchno-issledoratel. I ski y kinofotoinstf-tut (111iKiPI).

BRWN, Zh,L,; KIRILLOV, Ye.A. [deceased]; C~t~kJLSO
--Y& K. ~.,
Comparative study of the chemical ripening and photolysis of
photographic emulsions. Dokl. AN SSSR 161 no.3-.624-626 Mr 165.
(KRA MO
1. Chlen-korrespondent AN SSSR (for Chibisov).

KIRILLOVY YO.A. (del-ea:,iad3,- GOL"DENDFRG, A.D.:: hT.33TFROVSKAYA, Y&.A.,-
CHIBISOV.--K.V4.
AbBorption features of collo!dal solutions and dT-j layers of
certain organic dv.es. Pokl. AN SSSR 161 no.6-.113711-131-74 Ap f65.
(MIRA 180)
1. Nauchnc-Is3ledovatellskiy institut fiziki Odesskogo gosudarstven-
nogo universlt~eta im. I.I.Machnikova. 2. Chlerkormspondent AN
SSSR (for Chibisovi

ACC NR-, AV7010713 SOURCE CODE:' UR/0020/66/170/005/1121/1123
AUTHOR; Broun' Zh. L.; Chibisov 11, (Corresponding I-Amber AN SSSR)
P V
ORG: none
TITLE: Nature of centers of the latent Image and latent fog
SOURCE: AN SSSR. Dokladyv V. 170, no. 5, 1966, 1121-1123
TOPIC TAGS: STET image, photographic cmulsion, optic density, spectrophotometry,
photographic densitonater / SSF-4 spectrophotometer, IIS-12 spectrometer
SUB CODE: 14,20
ABSTRACT: The authors studied the differences between the' fomation and pro-
perties of centers of latent fog and the latent image. The study is based
-on an investigation of the kinetics of chemical aging and photolysis from
data of 1".rect observations which were compared with the pattern of the dc-
veloped fog and image. Since the differential method for measuring optical
-densities at various moments of aging and photolysis was used for direct ob-.
.servation, information was obtained not only on the quantity of free silver
formed, but also on its degree of dispersion since the latter affects the
covering power. The study of chemical aging was based on a normal iodobro-
mide emulsion with specimens taken after various periods (up to 128 hours).
gelatin sAution (1:20) and the optical den
The specimens were diluted in a
Card 1/2 UDC:_ 535.34

ACC NR: AP7010713
sities of the dry layers were measured (after desensitization in pinacryptol
yellow) on an S.5F-4 spectrophotometer at 710 mP with respect to zero aging.
These same layers were developed (Metol hydroquinone developer, 1:5) and
measured at the same wavelength. The phqtolytic study was based an a silver
bromide Lippmann emulsion Ox concentration). The emulsion layers were ex-
p,.)sc:d to the light of a mercury.lamp and darkening was measured with re-
spect to'the initial layer on Ye. A. Kirillov's unit at 710 mij and on the
IKS-12 spectrome*ter at 926 mv. The layers were then developed (Metol hydro-:
quinone developer, 1:20) and measured'on a photoelectric densitometer. The
resultant curves for aging (latent fog) and photolysis show pronounced per-
iodicity. The periodic nature of these curves is retained on curves for the
developed fog while development of the exposed layers results in an ordinary
characteristic curve. Analysis of the experimental data shows that centers
,of latent fog have no cat.Uytic activity in the useful aging region (up to
), while the centers of the latent image, which accumulate rapidly dur-
max
ing exposure, show high activity. This is the fundamental feature of a
photographic emulsion responsible for selective development and the possi-
~magp!;
bility of producing an
.Ori g. art. hast I figuro.
fJFRS: 40,3--i71