SCIENTIFIC ABSTRACT I.G. CHEKRYGIN - I.A. CHEKULAYEVA
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Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R000308310019-6
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RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
June 12, 2000
Sequence Number:
19
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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MMERT, Vladimir Adamovicb; "gHEKRYIGIINI Ivan Gavrilovich- SHWOV,
Aleksey Tirnofeyevich; red.; ST OV, V.M. P
Voy~
red. izd-va; WESMA, G.D., tekhn. red,.
[Road-buildirg rachinry; a manual for tractor operators)
Dorozbno-stroitelInys mashir3y; posobie traktoristu. Moskvaj,
Naucbno-tekbn. izd-vo Ve-va, avtomobillnogo transp. i shosseirqkh
dorog RSFSR, 1960. 17.4 p. (Road machinery) (MIRA 15:3)
VAVILOV,, Mikhail Aleksandrovich- CHMUGIb" I.G. red.; DONSMA,
G.D., teklm, red. -n.~
[Booklet for a dump-truck driver] Famiatka, shoferu. avtomobilia-
samoovala. MosImp Naucbno-tekbn. izd-vo, M-Ya avtomobillnogo
transporta, i shosseirykh dorog RSFSRq 1961. 50 p. (MIRA 15-3)
(DuM trucks-Safety measures)
k GIN, Ivan Gayrilovich; FILIN, A.G., red.; DONSKAYA, G.D., tekhn.
[Manual for the automobile lubricator] Pooobi* smaschiko, awtomobilei.
Moskva, Wanobno-tekbas-isd-To N-va avtonobillmogo transp. i sbos-
seizWkh dorog RSM9 1961. 62 p. (MIU 14:7)
(Autmobiles.-Imbrication)
MNERT, Vlzdimir Adamovich; C.M=LQjX,-j3La ~Gavr~ilovich; SHMMOV, Aleksey
Timofeyevich; SMANOV., V.Yj,,, red.; GANTUSHIN, A.I.,, red. lzd-val
MALIKOVAj N.V.$, tekhn, red.
[Road machipery: bandbook for the tractor driver) Dorozhno-
strolUlliWe mashiW; posobie mashinista traktorov. Izd.2., iopr.
i dop. Moskvap Avtotransizdatf 1962. 234 p. (MIU 15:6)
(Road machinery)
CHEKRYGI ygA,,Gq-yrilovich; BARANOV, A.Ya., red.; GALAKTIONOVA,
- - - -, - 1-1 -
Ye.N., tekhn.
[Safety measures in the maintenance and repair of motor
vehicles] Tekhnika bezopasnosti pri tekhnicheskom obslu-
zhivanii i remonte aytomobilei. Izd.5, ispr. Moskva,
Avtotransizdat, 1963. 71 p. (MIRA 16:10)
(Motor vehicles-Maintenance and repair)
,CHEK,'aQIN Ivan Gavrilovich; FILIE', red.
--,I- ~:-- . . ;
Diandbook for the greaser, of motor vehicles] Posobie
srqazchilcu avtomobi-:,-. Iz-d.2., isp. i dop. Moskva,
Izd-,.ro "Transport.,' 1964. 76 p. (MIRA 17:8)
CHEKRIGIN, Ivan Gavrilovich;,FILIN, A.G.,, red.
[Safety measures in operating motortrucks] Tekhnika bez-
opasnostl pri, ekspluata-tsii gruzovykh avtoi!.abilei. Mlo-
sivap Transport, 1965. 31 P. (MIRA 18:8)
CE3KRYGIffq 5.1.
-maintenance of elgnallug, central control,
d= e=pwuQ- Vii
&;A block systems.' Avtom, telez., I evias 1 2 uo,7:43 JI 158.
(NDA 2116)
L Ismestitell moballailm Deballtserskoy distantsli signallsatell I
;:T;S,l Monetskoy dorodo' ,
.(Railroads-Sigialing-Block system)
CHEMYGIN, S.I.
- ~ *
Pub~lic ~spp "etors are at work. Avttom., telem. i sviazl 8 no.8:
20-21 Aa t64. (,MU 17:10)
1. Starshiy elektronekhanik2 rulcovoditell soveta obshchestvennyl,.h
inspolctorov, po bezopasnosti dvizheniya poyezdov Deballtsevskoy
distantsii Donetskoy dorcgib
PINaKAXAP R.M.1 BADETAS A.S.0 ;WPHTEINg P.De; ROGLIKv S.M*,- ARIOZON9
P.T&.; XOPSUEN014 LN*j VASINAp I*N*; CHIMMERA. N.I.:
-9 Z.Ya.; IMOOMSKAYA,
Treatment of patients vith tubermaous meningitis without
subaraebuoid administration of antibacterial prepamtions~
Probl.tub. 38 to.lt6O-67 160. (KMA 13210)
MA6LYY, P*S.v lmj~~1,5 CIFE'9UGINA-,-- P-- irmb.
Infbiance of additives on the degree of concrete waterproofness.
Shakht, strol, 9 noelOsI5 0 165. (MIRA.180)
I.-Shaklitoprokhodahaskoye upravlaniya No.1 trest-L Krivbasehakhtoprokhodka.
CIIEKSTF,Ry G.Ya. p inzh.
Davice, for automatic reversion of c=ent in a degreasing bath.
Trakto i sallkhozmashe 33 no.6-.44,46 Je 063. (MIRA 16:7)
l..Nauchno-issledovateltakiy institut tekhnologii traktornogo i
sellskokhozyaystvennogo mashinostroyeniYELO
(Machinery-Cleaning)
L 3078~-6 EWP(k)/EWT(d)/EW'P(ii)AWP(h)/T-2/FWP(I)/EWP(W)/r,,WP(V)
ACC NR:' -AP6022100 SOURCE CODE: UR/013.4/66/
IJP(c) -EM
AUTHOR: Gallporin, M. I. (Enginser); CheLa~v, A. V (Engineer)
ORG: 'none
TITIB: Transport b~ water of odd-shaped, heavy working. rotors of powrful radial-
AX3A1 VWUMUMMS
SOUItCE: Energonashinostrayeniye, no, 2, 1966, 45
TOPIC TAGS: inland Waterwa transportation, transportation equipment, crane
turbine rotor
A14TRACT: The experience of shipping two large,, heavy turbine rotors from
Leningrad to Krasnoyarsk on the Yenisey River showed that the loading'.
shipping an& unloading presented no insurmountable problems. The material
was loaded at Leningrad vdth a 350-ton crane,k-~and shipped during July And
early August to the destination. The jRWEe-st probleris were created by
locks on the Belomorsk-Baltic canal vhich were too small to admit the trans-'
,port barge plus tugs,, requiring the barge to be pushed into the locks vith
usage.of only one tug. The methods used to fasten the heavy.rotore down-in.]
the barge proved satisfactory, even under storm conditions-. / fi'PRJS
SUB CODE: 13 / SUEH DATE: none / ORIG REF: 001
UDC:
TPRASENKO, A.,, gvardii gene-sil.-mayor meditsinskoy sl--,Zhby v otstavke;
CHEKULAYEV G.. Polkovnik meditalnekoy aluzhl7j v otstavke
Reaults of the treatment of pation'to with neglected cancer in
the Leningrad District Military Hospital with preiArations
recommended by biochemist A.T. Kachugin. Vop. onk. 9 no.6:
116-120 063, (MIR-4 17:8)
1. Byvshiy nachallnik Voyenno-meditsinskogo otdola Leningrad-
skogo voyennogo okruga (for Tarasenko). 2. Byvshiy glavw
terapeyt Lenir4gradskogo voye=ogo okruga (for Chek-ulayev).
CHEWLAYEV, G. N.
Col. Med. Service, Chair Pbysieml Therapy Mil. Med. Acad. Ra. W, M. Kirov,
Ieningrad, -c.1948-.
Medicine.
"Rematcpoiesis with Cancerous Metastasis in the Bone Marrow," Klin. Med.,
26, No. 1, 1948.
CIEDUMEV, G . N.
Chekulayev, G. N. - "Leuco - and erythropause in ulcer disease of ti~-e stmach and
duodenum, 11 ' Sbornik trudov (Voyen.-med. akad. ima. Kirova), Vol. X-LIII, 1949, p. 148-69,
Bibliog: p. 161-62, 169
SO: U-4355, 14 August 53, (Letopis 'Zhurnal Inykh Statey, No. 15, 1949.)
TUTXV, G.N.
Content of ascorbic acid in bone narrow and peripheral blood
in patients with peptic ulcer. Ilin.sed., Hookys, no.4:86 Ap 150.
(CUM 19:3)
1. Of the First Department of Faculty Therapy (Head of Department
Active Member of the Academy of Medical Sciences USSR Prof. M.I.
Arinkin, Lieutenant-General Medical Corps, deceased), Medi-
cal Academy Intni S.M.Kirov, Leningrad.
C#eKO4,9V,FiJ- CA).
ITANOV. V.A: SAPROXHIN. M.I:CRIKULUNT. G.N.
Modifications In peripheral blood and bons narrow
tion. FIsol-sh-SSSR 36 no.5:594-599 SePt-Oct 50.
following exer-
(CIML 20:4)
1. Staff of the First faculty Therapeutic Clinic and the PtWsI-
cal, Aucation Department of the M111ta:7 Medical Academy Iseul
S.M. 11rov.
CEESKUL&UT, G.F.
Cytodiagnosis of lymphogranulomatosis in exudates. Ilin.med.,
Moskva 29 no.4:60-63 Apr 1951. (CIXL 20:9)
1. Of the Pirst Paculty Therapeutic Clinic (Head of Staff-
-Prof. V*A. Boyer, Colonel, Medical Corps,
CRWZjITEV. G. N.
Association of leukemias and malignant neoplasms. Ilin. med.,
Moskva 30 no.4.-85 Apr 1952, (CLWL 22:2)
1. Leningrade
I
CHEMLAYLT. G. N.
% -~
ftthrolaukenta (Orythroleukomyelosts). Klin. ned,, Moskva
30 no.4:86 Apr 19.52. (OLML 22.62)
1, Leningrad@
-- MMULAYLT, G-N.. kand.med.uauk (louingrnd)
A came of lead poisoning at home. 11inmed. 37 no,2;154-156
Ja 159. Ma POISCIMPGI (KIRA 12:3)
cam* reports (Rus))
CHREUIAM, G.S... starshly uaucbnyy sotrudnik.
W-K~
Indices of cbannel bottom stability In Irrigation systems. Top.
g1dr. no. 1: 61-73 155. (KM 9:12) ~
(Irrigation canals and flows)
.0
r
CHEMMA M-7 9 1.
--, '-.1 -.1 , t
Urgent matter, Pr&f,,..tekb, obr, 21 no,7s4 JI 164. (KM 2.72 2-1)
CHEh'ULAYEV 11.
Encouraging results* Avt.trarap. 43 no.11:13-14 N 165.
(MIRA 18:12)
1. Direktor avtokolonny-No.1103 Lenpromtransa.
SOV/124-58-1-816
Translation from.- Referativnyy zhurnal, Mekhanika, 1958, Nr 1, p 106 (USSR)
AUTHOR- Chekulayev N. M.
TITLE: On the Distribution of the Air and the Material to Be Dried in an
Air-type Spray Dryer (K voprosu o raspredelenii vozdukha i
sushimogo material& v vozdushnykh raspylyayushchikh sushilkakh)
PERIODICAL: Tr. Vologodsk. molochn. in-ta, 1956, Nr 14, pp 329-339
ABSTRACT: Bibliographic entry
Card 1/1
CMKULAYEV, 4k0-1-&-"4 lrh*y] nytj &4- ITANOTA, N.M., red.; SOKOWYA. I.A.,
takhn.red,
[Nvaporation and evaporating apparatus In the dairy industry)
Typarlyanle I vypernys imotmuovki v molochnol prowqmblennosti.
Kookwa. Pishchapromisdat, 1959. 70~p.
(KIRA 14:2)
(Dairy Industry-14pipmnt and mipplies)
(fteporating applianoes)
.CHEOLAYEV. P.G., gornyy Insh.
Rig with a sinker rock drill in the "XayraktinBkIyO open-Dit
mine. Gor.shur. no.9:72 5 160. (MIECA 13-9)
1. Krasnoyarskly institut tevetnykh metallov.
(Karaganda Province--Strip mining)
(Rock drills)
PANGHEV, S.S., prof.; PASHKOV, A.D., gornyy inzhener; DUSEV, V.I., gornyy
inzhener: CHEKULAYEV, P.G., gornyy inzhener
Comparative evaluation of rock breaking by detonations of charges
in vertical and inclined holes. Vzryv. delo no.47/4:52-63 061.
(MIRA 15:2)
1. Institut tsvetnykh metallov imeni M.I.Ralinina.
(Blasting) (Boring)
MoTiRY-A, 14.A_y CHUVILIN, A..H.. imll.; FEsNov., B.,
., irz".".
CHRULAuv - - , inzh.; Sojrz-T;TT G.A., inz,,.
~ I
Testing a new bortrg bit for slrRer hamrner.,. Gor. zhur.
no.9:51-52 S 165, (MMA 18:9)
I. Vse,3o)-uznyy nauchno-jssjedOvL,-ejiskj.y institut tverdykh
splavav" mo~-k-ra. 6
C-t-IEKUL
SMMI37, S-V-; MMOVIMAYA. A.I.; CHWULAM. P.I.
- MMMMN---W--
Operating practice of GM finishing factories. Toket,prom,14
no*32,.35-37 ]D'34~ (KM 8: 2)
(Textile finight1w
L fi /VI
3MUMU, S.V.; MROVMYA, A.I.; CMMUUTZV,~..
Operating experience of finishing plants of the German People's Re-
public. Tekst.prom. 14 no. 9:29-32 S 154. (ML" 7:11)
(Germany, Mastern-Textile finishing) (Textile finishing-
GermatW, Iketern)
120) SOV/1-35-59-9-12/23
AUTHORS Veret-LAk, L. D. and Chekulayev, V. E ., Engineers
TITLE: Diesel Locomotive TE-1 0 With Unifr m-ne Body of Nelded
Construction
PMIODIC.AL: Svarochnoye proizvodstvo, 1959, Nr 9, pp 33-35 (USSR)
ABSTRY-OT: The authors present a report on the construction of a
new type of diesel locomotive (TE-10). This diesel
locomotive is constructed by the Khar'1rov Transport
Machine BiAlding Plant imeni Malyshev. It has 3000 hp
and will be used on the railway system. In comparison
with other Soviet diesel locomotives (TE-3. TE-2 TE-1),
the weight per horse power is low (46 kg/hp). TL uni-
frame body (Fig 1) is a compound welded construction.
Its weight is 17 tons, length of -the body: 17.5 m,
width: 3.1 m and height: 3.1 m. The speciality of this
welded cors truction is that the body and frame coTs ti-
tute one part, and every element carries a certain part
of the total load. The uniframe body consists of: 1)
body-frame (Fig 2); 2) two cabins for the engineer
Card 1/2 (Fig 3); 3) two side walls; 4) cover on the cooler and
SOV/135-59-9-12/23
Diesel Locomotive TE-10 With Uniframe Body of Welded Construction
5) cover on the engine. All joints were done by semi-
automatic welding with electrodes type E42 and R50.
Tests have shown that all stresses were irithin the er-
missible limits and were -not higher than 1400 kg/cm .
The sagging in the middle part of the body amounts to
30 mm. 'There are 6 photographs.
ASSOCIATION: KharIkovskiy zavnd transport'nogo mashinostroyeniya
imeni Malysheva (Khar'kov Transport Machine Building
Plant imeni Malyshev)
Card 2/2
3/389/62/000/063/019/021
9194/9436
AUTHORS: Aliyeva, P.Z., Chekulayev, VOP
TITLE: Special construe lonalfeatures, of resistance
thermometers
SOURCE: USSR. Komitet standartov, m*r.i lzm*rit*l*nykh
priborov. Trudy institutov Komiteta. no. 63(123).
Moscow, 1962. Issledov&niya v oblasti teplovykh i
temperaturnykh izmereniy. gl8-224
TEXT: The development of platinum resistance thermometers for
accurate measurement of temperature in reviewed briefly and
accepted methods of making such thermometers are described.
In the VNIIM it was particularly required that the resistance of
the thermometers should be very close :to that of the reference
standard and. so an to make it easy to adjust their resistance,
the coiled wires were cut in two, wound into the grooves of the
supporting frame and jolned at the tip where the adjustment could
1)e made. In this way the resistances were adjusted to within
+ 0.1% of the nominal value. To improve heat tranarov condltLona
'i;etween the sensitive elements and the surrounding medium, noot of
the thermometers were filled with helium containing about 10% oxygme ,
Card 1/2
S/589/62/000/063/019/021
Special constructional features ... E194/E436
For experimental purposes two thermometers wore filled with pure
helium and four with dry air whilst two were left unfilled and
unsealed. Stability tests are described for about 20 resistance
thermometers made from high purity platinum wire, and it is
concluded that the heat treatment procedure is most important.
Resistance thermometers which are filled with air stabilise
quickly at 500*C, but prolonged heat treatment is required to
stabilise thermometers filled with helium. This agrees with
results obtained in the British National Physical Lab'oratory.
It was also found that thermometers made of platinum with a
temperature coefficient of resistance equal to or greater than
3.926 x lo-3 (degress)-l are more stable than those with the
temperature coefficient of 3.923 x lo-3 (degrees)-l. The data
obtained indicate that the new thermometers are very-stable.
There are 4 tables.
ASSOCIATION: VNIXM
SUBMITTED: March 18, 1961
Card 2/2
AWEVA, F. Z.1- CMMULArNV, V. P.
Equipient for, the reproduction or the boiling point of water.
Trudy inst. Tom. stud,, mr i im prib. no.51:35-40 Ift.
(MIU 16: 1)
1. VoescrumW nauabno-inaledovatel'okLy inatitut metrolael.
is. D.
(Boiling points)
ALIYEVA, F.Z.; CHEKUIAIEV, V.P.
Structural characteristics of resistance thermometers. Trudy inst.
Kom.stand., mer timprib. no,63.218--224 162. (14M 15:8)
1. Vaesoyuznyy nauchno-issledovatellakiy institut metrologii
imeni D.I.*ndeleyeva.
(Thermometers)
clilymayu, V.P.
- -------
Water bailer. Ilov. nauch.-issl. rab. po metr. VIIIIII no.3:1-2
16/, (MIRA 18:2)
Z-HERMURSKIY, B., -kand.takhn.nw, ; MARAKIN, N., inzh.; CHMULAYEV, Me., im"h.
Use of high-mcment hydraulic drive for the turning mechanism of
gantry crane upper structures, Rech. transp. 20 no.12:1D.Z3 D
161. (14IRA 14:12)
(Cranes, derrickup etc,-Hydraulic drive)
CHEKULAYEV, Ye.F., lnzh. f,
I
Hydrostatic drive ~or the displacement mechanism of a bridge
orane. Mashinostroanis no.4&46 Jl-Ag 164. (III-RA 117glo"
ZAKHARYUTA, Vyacheslav Pavlovich, starshly predovavatell; SIMONENKO, Igor'
BoriBovich, kand. fiziko-matem. nauk; ~,HEKU~AYEVA -'eksandra Afanaslyevna
mladshaya, nauchnaya sotrudnitsa; YUDOVICH, fiziko-
matem. ispolrWaushchiy obyazannosti dotsenta
Capacitance of a round disc on a dielectric layer; for a case of thick
layer. Izv. vys. ucheb. zav.; elaktromekh. 8 no.5s487-494 165.
(KRA 18:7)
1. Kafedra matematichaskogo analiza Rostovskogo-na-Donu gosudarstvennogo
universiteta.
sna,d,-NA reffiedllftittl of vinyl edws d otbalimismises-
aid N. A. CwrAtrIll- 17-1 "ad-
(1) in N 6 111- Ill U11 Ill* 1-1tv 64 It
chAttlinlinvial4s.1m; in th, I"r-litt' taf K( Ill vat'll-2tia."
ur Intrills. uhile A11,111. Ill IW;. K Nall 44 1 aivt-% tfll,~ fill.
Ilvaling I unalm 40,116 per-ular k If% JIM 411% all tile
jure-,tacc ald 10% X011 (AAAd, gave 10-12% viltyl drriv.
mW nuwb tar; uithout KOJI in C411s, only tar fortn"I.
The ben yi" were obtaismi ben 72 It. I w- treat-I writh
2.8 g. K wW the willn. dihi. mith UP flat. Call. aml hwme,l
12 lars. at 1244-W in a rxtatsuat steel Autowttv strawlea If,
atilt C,II,: saveM d. 1-11TV 01-:01001,C11,N11.
I"', M..'a I". IIA 16'. k1? 1:. 01,111S.
ticat,il with dii. ll.,iO, it yivhl, AM, dimn. of the hight-r-
,".i,i"g I"., io", gave I "", """' "' *,I ", U. **
CIIM,11,01,N/101: CH, It. -Ii, 1 4*11. 1:. li,1401:0,
Altai Ifth 14 115 115'. NJ," 1 -11,11.42. 1','
1,111112. 111"411 tile at."111411Y ill pall I,v .111
~
t,us j,4,d. tn. !45-6% 41- fanim t., NI. K4-441.6
& 9 . . s 0
Jf 14
c vi C- K t I ~-- I, Y -EV /,' ) -.-q
SHOSTAKOVSKIY.', H.P.; CIPXULATWA, I.A.: GERS S YN. N.A.
Synthesis and transformations of vinyl others of ethanolanines. 11.
.Synthesis of amino acetals, Bull. Acad. Sci.-U.S.S.R.. Div. Chem. Sci.
154, 185-92 [114gle translation],
(CA 47 no-19:9911 '53)
CHEKuLM,A, A.
Moethyl
_T__ :9111-i" r U
A. Chekulac !-and M Gershteln. -A a
S.S.R.. "St. Org. AIItM.-..YSaIexy. Urr. Soedinenir,
Sbernik 2~ 16-17(1952); cf. C-4. 43, 6159C.-Into a pre-
-cooled autoclave was charged 16.4 g. MeCH(OCHBIQo
as- VAI I OCJIiCH2CI and .50 ml. liq. NIL: the mixt. was heated 8
hrs. at 140-50* (110 atm. max. pressure) and filter6d after
cooling, release of NIT. pressure and washing th with
E40. Distn. gave 47% 'XCII(OCIIM'.')O&'M"VH,'
LVA~ CL,,-J~ b,,71-C,-.1~.75-41',d:aO.gl23.n*,?1.4-940. Similarlyfrom.
NfeCH(OCH3CHhfe,)OCHCH.Cl%vc& obtained: -VeCff-
(OCfftCHMe2)OCHiCHi2VHx. ba Ea49. du O.WW. sy
1.4.046: tHeCII(OC11,CHVe,)OC]f-tilA,.,VH, b,. IM-15 .
Ldw 0.9210i n.0 TAM; and (AfebI(OCIIjCHMe,)OCH._
CfrihN, bo 210--20'. d-a 0.9322, ?JV 1.4380. Among the
by-prMu-ts in prepn. of the iso-Pt- deriv. there were found.
W d
OrrCH(OC MCOOCIItCH-VH~ b. 147 , 0.9m.
W 1.4.300. and DfeC;I(OCjI_UeI)OCH.,' CHJ V. b. 195-050,
d--. 0.13397, P:2~0, 1.4340, in 29% and 8.5,j',yid&. resp..
Ift-iting for 10 brq. or longer increases the A d of the niono-
NIT, deriv. to over 46%. while lowering the proportion of
N11. to 4 =16~ to I mole of chloro dt3iv. raiies the iield of
thesecondary tti~lne to 40%. G. M. Kwlapoff
Vinyl 2,g4 LAu*md, A
I= t~ , Akast. Aduk'T.S.S.Ry
nil
hist. Org. Kilim., Sininy Org.Sordiurnii, Sboritik 2, 33-1
(1952); cf. C.A. 3N, 1301.-To 72 g.'IIOCII.-C1I-NIlj iris
slowly addeit'!JS g. K mid the ptothict in 150 lid. C1114 %Yns
placrd into nit autocliive; C!Ilt xN:t% added to 1.1-16 atm.
and tile mixt. was heated to 120-40' 1 -6 lirs.; ;tf ter LOOlillg 0
to 20-410' the CsH2 pressum was. agalit rrstot&I and lwating
TePested usitil the caW. nuil. is consuilled. Dism. gave
85% )IjAICHIC11:01111:CH, crudr. 1). 1 IDL-20'. whielt was Af
tre " I"' 'a In tile cold and irdistd. viv-1-fitig t1w purc j C, '51
Olewi."`!~7 bill, n',T, 1.439O.'d., 1.90)8 (Mc).1--
The autoclave intist not hate silly Cu Imot., ill mder that
ixplosians be averted. C.. M Kosolipoo
n f yi ethers a ethanol-
R~a iThReithia6imilter of Ope double bond of xi~__
7- anli s. kqv-
of ethanolamines. t _,J~c and 1. A.
_41121neviii. Mwest. !~d. Wau
1 N4-uk_Mr, 308-73; cf. C.A. 47, 1505e, 9911 g.-Passage
of ethylene oxide into 75 g. MiNH in 250 ml. 1110 over 4.5.
It". at rj-10* gave, after addn. of 60-70 g., 60% EhNC11t-
MOM. b. n'S 1.4412, d,. 0.8838. This with
10% ROK In CjTj vras heated in an ELutoclave undet
atin. CIFI, Initial pressure to 1411-50', yielding 9
El,NCHvCfftOC1f:C11i (1), b. 155-7% n',? 1.4.13Z'Mo
0.8306. Without CsHa the -yield drops to 83-5%, while
KOI1 as catalyst gave a 0% yield, and much tar. Ilydro.
gentition of the product over Raticy Ni. gave EhNCIACITi-
;E._1l_1Q'O_4N_~Ag2N_11_,.At 2-0*, _mono-Ag aspaR_aFc7~M__aM--
stirbs more than :3 NH~. but no definite compti. coul(I be
isolated: at U* and -18* it forms the letraN11. complex,
CjII,04NAg.4NII,. To prep. it successfully, II must be
very fintly divided (by adding its ale- soln.). for the granular
p It. formed by- digestion of H2NCH(CO:Ag)C[ljCO2Ag
VII) in hot arl. aspartic axid giv" variable and uncertain rc-
suits. At 20* and 0*, 111 form C4H6O4NAgi.3NH3 and,
at - 18*, C.H.O.NAg,.4NUz (cf. Bruh! and Levi, tio source
cited). At 20*, Ag glutarnate absorbs more than 3NIla,
but no definite compd. could be isolated; at -18* the
tetra-Mirs complex, C&HsO&NAg.4NH3. is formed. At 20*,
mono-Ag glutatiflonste absorbs more than Mill. but no
tIrfinite cointid. was isolated; at 0' and -18* the tetra-N11',
complex, C,.Ilj.OsNjSAg.4KH2. is formed. At 20*, di-Ag
sCluttithlotiate forms the tetra-Mls complex, CleHlsO*N,-
SAgIANIll, and at 0* and -18* the hexa-Mrx complem,
CtolIikOsMxSAgj.GN14,. At 201, D-MesCHCH(MHOC03A9
absorbs more than-21111. 'but does not give a definite cam-
plex; at 0* and -18*. it Forms the,:ri-Mls complex, C411to-
O#NA9.3NiJj. At 20*, 0', and -18*,~ the Ag deriv. of
saccharin rot-tits the fri-Nfri compkx, C71140.SNAg.31,1143.
These results parallel those obtained by Ley for Cu. complexes
Z. Elektrochem, 10, 0.54(1904); C-A. 3, 10151. In coil-
tloction. with the clu-Iier work of U-M. the expts. leall to
I
certain general conclusions. For the i41, grotip to be co-
Irn-damit.-A uith Ag. it muiE Ili- iv; (!I,, It, I-
pa~itiwl' is incoallibAv, awl ill Ow
t1tv 1c. r4nittlillate k lvialivvly 'lu;W. A
factor, of mitior icaltIence, Is Ow sh(-ujifli 'if Ow ;tv'H; 11 Wit
sturic (JOIctwim! Ow sallic, [Ill- Ill,- ~Icid'
tile greater is tile touleticy for div NI)o poiti, v.,iwdm,l'r
with Ag.
'EVA,
C,%iE,K U
c
F. shoo
M.-J; Baturv~
1. A. Chominva, and A
4pll); Maveej#: Ztliu*o lost (kg.
-scl. uss'It" Moscow). .. 1w0. AQ. Sauk, S.S.S , -
c
Kkim. Al c
-UNk A110. AW. 84j.. U.S.S
Iwo. t3to
421(n),,
Sci- I059,4SIAI?n#I.AriLnd4tjaa), &WbD; d
CA.- 4 813(1). 1
7898b;; Th,
t.Prevlo"y rep 6
in wted vbyl etherp 01 et=
1'44'16'01 :
~'am a and its analop isplay the Purnan chsnLcte.,htks of.
Hbofi cis- -the chem. lbutness of mne wmpds.
4,
in this group 12 aser'ibed,to H banding, Thereglonoftill-I I ,
fuse JtA 7
Inan Ones at BM-Mlem.-I lududes the o_H__0*
OCH: Cl
well 4 X7-11-0 bonds. The following Raman spectra
~:are rtpozted:- CH9:CHOCH,
CHINHI, IRMO)
W3 0
_2 -824f 91 1 P,
0
oh 710(2). 821(6b 4 9-w- i), 9MR 4), 2 1287(1),
91
11*2) 32 2 Ib]
1493
W2 11*150 6
1384 2 '14C 14)
02"), 2M OC
1) 321150) 11 1 p,
if Hb
N110C 1~ 24 4 03
IM
660M. 745(01 NMX:
0:_
lpaffl
jfto: �3
9k72 3 1001(2). 1M3),
lulj7(2 , 1102 2
j3h 1*3(311322(1~0 6.1.3
' ___ (1).
-WO) 1389 413CIII), Mal. I
a 4
I HOCA-,"fitil,
824(1), ~ 3W,
B(b
50 1 b f
qlo~ III Ob)
7
). OW2b). 0).2R
97 3). 901(a ill
1 0
1), 1 132410, 1 0
?
18) 1b 2Z18b)), 1WX2) 16 1
I VE, et, 11
16
21M( 0'), 29
4 Mffi' io
so
'~74. rAI
48 40). 3W 4b Phi4k
CRIO
J'2). 178(.1).214(2). b
=3 2). 248(2 i 41
1414
67
StO 619(4",, 0,
852
U
10
5.1
01%14
1 1
1 0).10)11 0), 1 1
-_!_
486
X10) 1619(l) _(1), 2ftXO),
0 1039 2876(
J), iiwm, ~;Oloj, SaaX
(4 t"
71
1 1). BS~
,~~%)JQ. =? 4874(8
1OLO 173(2b), MIMI
W 10 07
MK b). 1460 ~ IM(lb), 2707 Sb
3
SIM, 3113187(3),, ZM9(2),.,'
lb),
(no
'VM
69
1,^." P--d tr~qrmatlons of vinL) g~bo of ethanol-
anilue.. J. The vinyl - eth 2-(ChpheIIyIRmla0)-
ath". IA-ChCk4kPv3 a
-18; d. C-4.
49, 15489i; so. IftI.-MAting 11hjNH with ethylene oxide
to an autoclave too 2", gave W5%0 PhINCHICHWH
R bo 183-V, dio 1.121, nV 1.6210. This (73 g.), 8 g,.
X salt.200ml.C4%,and 14-16 atin. CHI gave. after 3 hm
1801, 74.5% PIhNCIhCIIj0CII:CIh, h. 158-9*. nV
1.69W,dml-0M.: lit dioxnue soln. the yield reaches 81.6%;
the use of KOH: mitalyst gave 52-66.5% yields in CJ14.
The ether hydrolytes with 2% HISO, at 95' to Aell and 1.
Hydrogenation of I over Itancy Nj save PA.XCII. C10M,
b. IS&-9% Irl." 1.5920, dis Lom. I Ph%NCHCH%0CH:Clf.
(8.7 g.) and 7.2 g. I treated with I drop coned. UCI, and
kept 4 furs. after the-exothennic reaction yielded 62,5%
Ate CFI(O CH.M.NPA02 (11), N 2&9-4'. sW L0185, dm-
1.1175. Similarly the Vinyl ether with BuOR gave MCCH.;
(Ollu~ and U, as well as a wide fraction of materials which
deibompd. during distri., yielding BuOCH.-Clit and 1. A
similar reaction with MeOll gave 11 and MeCH(OWN, as
well as dmmpn. products, including 1. FeCh (5% in Bu-
OR) polymerizes PhiNCH*CH*OCHCll2 to 29% of a
viscous dut liquid. radl. wt. about 6W; coned, 11CI gives'
about 31% polymer, mol. wt. 4-V-W, (:NCMeXNX
polymerizes the.viuyl ether to a yellow oa. mol. wt. 475. in!
A13ary low yield after 100 los. at 60'. G..m. K.
AUTWHS: Shostakovskiv, M. F., and Chekulayeva., I* A, 62-`~.-r-L/22.
TIft: Synthesis and Conversions of Vinyl Ethers of Ethanolamines. Part 8.
ViTW1 Ethers of Beta-Mimethylamino)Ethanol and Beta-(2,5-Dichloro-
pherWlardno) Ethan o 1 (Sintez i prevrashchaniya vinilovykh efirov
etanolaminov, Soooshchenive 8. Vinilovye Wiry beta- (dine tiland no)
etanolai beta-(2,5-dikhlorfenilamino)etamia)
MtIODICALs Izvestiya Akademii Nauk SSSR, Otdeleniye Mimicheskikh Nauk,, 1957,
No. 1. pp. 75-79 (U.S.S.R.)
ABSTRACT: The authors synthesized vinyl ethers of beta-(dimsthylamino) arxi beta-
(2,5-dichlorophenulamino) ethanol and studied sore conversions of these
ethers, The relation betveen the nature of the amino-group and the
reactivity of the vinyl etbqr is explained. It uas established that
virql others having the primary or secondary amino group are inert
toward ion conversions, The substitution of the hydrogens of the
CIA 1/3 amino group with alIql groups and especially with pherVl radicals
SyTrbhesis and Gonversions of Vinyl Ethers of Ethanclamines. Part 8
leads to a higher reactivit-. of the virW1 ether. Vinyl ether of
beta-(dimetbylamIno)ethano1 is perfectly identical in its character-
istics to virql ether of beta-(diethylamino) ethanol; wben subjected
to reaction with alcohols if florms: acetals: CH2 - CHOCH2CH2N(CH3)2+
HOCH202N(~H3)2 --]P CH3CH[OCTI~CHACH3)2I 2-
Virql ether of beta-(2,5-dichlarophanylamino) ethanol is identical
to the vinyl ether of beta-(phenylaminv) ethanol; thanks to its
gmater hydrogen aDbUity in the presence of nitrogen and traces
of concentrated hydrochloric acid, the vinyl ether easily submits
to certain conversions (see formulas on bottom of page 75).
Cad 2/3 Table. There are 8 references, of which 6 are Slavic
i$-
--c K ulay~f Vo-, J- 'A
AUTHORS: Shostf&kovshiy, E. F. , Chek-ala.,
,reva, 1. 1. 62-2-12/28
TITLE: Synthesis and Conversions of the Vinyl Ethers of Ethanol-
-Amines (Sintez i prevra-shchen-1ya vinilovykh efirov etanol-
aminov). RepoTt 9: Quat-ernary Azmoniwa Salts of the Vinyl
Ethers of Ethanol Amines (Soobshch~nlye 9. Chet-verichnyye
ammoniyevyye soli vin-i-lovylch ofirov etanolaminov).
PERIODICAL: Izvestiya U4 SSSR Otdeleni~eKhimicheskikh Nauk., 1958, Nr 2,
pp. 204-209 (USSR).
A13STRACT: The investigation of the properties of the interaction pro-
ducts of the above-mentioned vinyl ethers with all;yl halides
is a natural continuation of the investigation of the reactiv-
ity of the do-able bond of" the vinyl ethers of ethanol azines.
This bond depends an the nature of the ai,.iino Croup and in..
creases with the replac:ement o:C free hydrogens by alkyl- and
phenyl-radicals. The iinfluence of the amino group can be ex-
cluded by means of addition compound of the alkyl halides to
the nitrogen of the vinyl ethers of ethanol amines. In the in-
vestiGation the authors used the vinrl ether of,4-(diethyl-
amino)-ethano'L, the vinyl ether ofg-(diphenylannino)-ethanol
Card 1/2 and the trivinyl ether of triethanol anine. Quaternary
Synthesis and Conversions of the Vinyl Ethers of Ethanol- 52-2-12/28
-Amines. Report 9: Q-aaternary Aminon-Dan 3alts of the. Vinyl
Ethers of Ethanol Amines.
ammonium salts of /3 - (di ethyl ami no) - ethanol, of the Vinyl
ether of and some derivatives of
it (with CH 31 02HJ a~'d Cf'-'q5 Br) were obtained. The authors in-
vestiCated some sowrersions of the quaternary smracnium salts
of the vinyl ether of (~-(d--Ietl:.,-la:-.iio)-etl-iano."L (Vdrolysis,
polymerization, interaction with alcchol3 and organic acids).
The authors examinel the interaction of the trivinyl ether of
triethanol-amine and the vinyl ether of P-(diphenylamino)-
-ethanol with methyl i.Ddide and athyl Dromide. There are 1
table and 5 references, 5 of whioh are Slavic.
ASSOCIATION: Institute for OrCanic. Chemistry AN USSR imeni N.D. Zelinsk--iY
(Institut organiche3koy k1hi0ii inieni N.D. Zelinslcoco Alkademii
nauk SSSR).
SUBMITTED: September 28, 1956
AVAILABLE: Library of Congress
Card 2/2 1. ViTWI others of ethanol-amines-Synthesis 2. Quaternar7
ammonium salts
AUTHORS: Shostakovskiy, M. F., Chekulayeva, 1. A. 307/62-58-6-33/37
Kondratlyeva, L. V.
TITLE: Letter to the Zditor (Pis'ma redaktoru)
PERIODICAL4 Izvestiya kkademil nauk SSSR, Otdeleniye khimicheskikh nauk,
1958, Nr 6, pp. 794 - 794 (USSR)
ABSTRACT: Recently increased interest has been displayed by research
workers in the chemistry of diacetylene. In the course of the
present report the authors describe some of the peculiar features
of the interaction between diacet lene and some aminoalcohols.
It was shown that P-(qiethylamino~ethanol enters into reaction
with diacetylene.(contrary to non-substituted alkyl esters)
without a catalyzer. On this occasion 1-(P-diethylamino)ethoxy-
butene-in-3 (19raula I) with 80-90% yield is formed. Ethinylvinyl
ester combines with the 2.molecule of P-(diethylamino)ethanol
under more rigorous conditions. This causes the formation of:
Di-(P-diethyliminoethoxy)buthadien-193 with 55-6VIo yield:
Card 1/2 (C2H5)2 HCH2CH2OR 41(C2H5)2 XCH2CH 20CH'CH_CH'CHOCH2CH2N(C2H5)2'
Letter to the Editor SOY/62-58-6-33/37
In the case of buthyl, alcohol the following acetal was obtained:
CH 3 -C a C - CH(OC 4H9) OCH2CH2N(C 2H 02. The structure of the
compounds obtained was ascertained by means of hYdrOlYsis and
spectral analysis.
ASSOCIATION: Institut organicheakoy khimil im. N.D. Zelinskogo Akademii nauk
SSSR (Institute of Organic Chemistry imeni N.D.Zelinskiy) AS USSR)
SUBMITTED: April 16, 1958
1. Acetylenes-Cheideal reactions . 2. Amino alcohols-Chemical
reactions 3. sp6etrographic analysis-Applications 4. Cyclic
compounds-HydrolyAls
Card 2/2
50) SOV/62-59-1-21/38
AUTHORS: Shostakovskiy, M. F., Chekulayeva, I. A.
TITLE: Synthesis and Transformations of Vinyl Ethers of Ethanol Amines
(Sintez i prevrashcheniya vinilovykh efirov etanolaminov).Com-
munication lo. Free-radical Polymerization and Copolymerization
of Trivinyl, Ether of Triethanol Amine(Soobshcheniye 1O.Svobod-
noradikallnaya poliinerizatsiya i sopolimerizatsiya trivinilovogo
efira trietanolamina)
PERIODICAL: Izvestiya JLkademii nauk SSSR. Otaeleniye khimicheskikh nauk,
1959, Nr 1, pp 130 - 133 (USSR)
ABSTRACT: In the present paper the authors investigated the polymerization
of trivinyl ethers of triethanol amine (CH 2-CHOCH2CH2)3 W and
its copolymerization with methyl methacrylate under the influence
of benzoyl peroxide and dinitrile of the azoisobutyric acid an"'
determined some laws governing this reaction. The results of
the investigations are given (Tables 1 and 2). It was found that
the polymerization of the respective vinyl ether and its oopoly-
merization with methyl methacrylate are not initiated by benzoyl
peroxide. The polymerization and copolymerization of trivinyl
ethers of triethanol amine with methyl, methacrylate was carried
Card 1/2 out in the presence of dinitrile of azobutyrie acid. It was
Synthesis and Transformations of Vinyl Ethers of Ethanol SOV/62-59-1-21/38
Amines. Communication 10. Free-radical Polymerization and Copolymerization
of Trivinyl Ether of Triethanol Amine
stated that primarily threaldimenuional products are produced
therein. Polymers and copolymers were hydrolized with sulfuric
acid of 2% at 200. The authors found that they contain free'
vinyl groups. The products of hydrolysis possess also a three-
dimensional structure. The results of the hydrolysis are pre-
sented in table 3. There are I figure, 3 tables and 7 Soviet
references.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk
SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy of
the Academy of Sciences, USSR)
SUBMITTED: April 18, 1957
Card 2/2
5(3) sov/162-59-1-22/3'.'
AUTHORS: Shostakovskiy, M. P., Gladyshevskaya~ V. Aoq
TITLE- Synthesis and Transformations of Vinyl Ethers of Ethanol
Amines (Sintez i prevrashcheniya vinilovykh efirov etanol-
aminov) Communication 11. Some Features of Copolymeriza-
tion of Vinyl Ethers of the P-Aminoethanol and Methyl Esters
of Methacrylic Acid (Soobshcheniye 11. Ob osobennostyakh
sopolimerizatsii*vinilovogo efira P-aminoetanola i metilo-
vogo efira metakrilovoy kisloty)
PERIODICAL- Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,,
1959, Nr 1, pp 13d - 139 (USSR)
ABSTRACT: Since the dinitrile of the azoinobutyric acid, unlike bcn?iyl
peroxide, includes not only methyl methacrylate but also
the vinyl ether of P-aminoethanol in the polymerization
(Ref 2) the authors investigated the copolymerization of
these substances under the effect of dinitrile of the azo-
isobutyric acid. It was shown that the interaction of the
components mentioned is complicated. Apparently three -
Card 1/3 compounds participate in the copolymerization: vinyl ether
Synthesis and Transformations of Vinyl Ethers-of Ethanol soV/62-59-1-22/-Zr
.j
Amines. Communication TT. Some Features of Copolymerization of Vinyl
Ethers of the P-Aminoethanol and ]-Aethyl Esters of Methacrylic Acid
of P-aminoethanol, methyl methacrylate and the product
of their interaction, 1. e. the methyl ester of 0-(0-
vinyl oxy-ethyl) aminoisobutyric acid. The latter is for~~.~
according to the equation
CH2=CHOCH2 CTMH 2+CH2-C(CH 3)COOCH3
_+ CH2=CHOCH 2 CH2NHCH2CH(CH3)COOC113 durinC the reaction
so that its concentration in the system remains unknown.
The participation of the three components in the copoly-
merization leads to the formation of 2 fractions of the
copolymer for each ratio of the initial monomers (Table
The process investigated is complicated by the fact that
besides copolymerization and addition also condensation
takes place. This is a result of the fact that besides
multiple bonds also other functional groups of the initial
components participate in the reaction, Tihich leads to
the formation of copolymers with three-dimensional structure.
In addition, the polymerization of i-zietlVl ester of 0-(0-
Card 2/3 vinyl oxy-ethyl)aminoisobutyric acid and its copolymeriza-
Synthesis and Transformations of Vinyl Ethers of Ethanol SOY/62-59-1-22/76
Amines. Communication 11. Some Features of Copolymerization of Vinyl Ethers
of the P-Aminoethanol and Methyl Eaters of Methacrylic Acid
tion with methyl methacrylate under the influence of di-
nitrile of azoisobutyric acid (Table 3) were carried out.
There are 3 tables and 6 references, 2 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D. Ze-
linskiy of the Academy of Sciences, USSM)
SUBMITTED: May 6, 1957
Card 3/~
50) SOV162-59-9-36140
AUTHORS: Shostakovskiyq X, Fog Chekulayeva, I* As, Konaratlyeva, L.V.
TITLE: Interaction Between Diaoetylene and Amines
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 9, p 1690 (USSR)
ABSTRACT: The authors report an addition of amines and diamines to
diacetylene, by means of which various nitrogen containing
unsaturated compounds were also obtained in good yields without
use of a catalyst. Hitherto, compounds of this kind were mentioned
once only in patent publications (Ref 2), for the synthesis of
which catalysts'were-applied. Primary amines form
N-alkyldiamino-1,4(-193)-butadione-lo3 (Yield 80%) with diaoetylenee
Secondary amines form W,X-dialkylamino-l-buten-l-ine-3 (Yield 60%)
with diacetylenee By addition of a second molecule of amine,
these compounds give 1,4-diaminobutadienes. Diacetylenes can also
add diamines, giving compounds of various structures according to
reaotior. conditions* The structures of these compounds were
card 1/2
Int.eraction Between Diacetylene and Amines SOV162-59-9-36140
confirmed by means of hydrolysis, diene synthesis, and
spectroscopy. There are~2 references, 1 of which is Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N.D. Zelinskogo Akademii nauk
SSSR (Institute of Organic Chemistry imeni N.D. Zelinskiy of the
Academy of Sciences, USSR)
SUBMITTED: June 6, 1959
157 a 00, 2
q
AMMORS:
TITLZ:
PIRIODICAL:
67038
Shostakovskil#_N. P., Bogdanovap A-. V.9 BOV/153-2-5-23/31
Synthesis of Now lonomers on the Basis of A2e~len;~and
Diacetylen*
Isvestiya vysehikh uchebnykh zavedeniy. Khimiya i khimicheakaya
tekhnologiyaq 1959, Vol 2, Hr 5, PP 769 - 775 (USSR)
ABSTRLOT: From acetylene and diacetylene, as well as from compounds con-
taining a mobile hydrogen, monomers (ether and thioethor) with
a vinyl-ethyl-vinyl- and a diene group can be obtained. The com-
pounds with mobile hydrogen si-jin particular: alcohols of various
structure, amino alcohols, mercaptanes, phenols, silanols, etc.
According to the method of A. Ye. Favorskiy and 1. P. Shostakov-
skiy different types of vinyl compounds with a total formula
CH -09-XR can be obtained where X = O,NpS,Sip and R is an alkyl,
2
aromatiog hydroaromatic, or othe'r radical (Ref 1). The most in-
teresting among the recently obtained unsaturated compounds on
acetylene basis, is the vinyl-ether of the amino alcohols
(Refs 5p6). They say be used as initial raw materials for several
Card 113 nitrogen-containint macromolecular products including some with
67038
BInthesis of Now Konomere on the Basis of Acetylene SOV/153-2-5!-23/31
and Disoetylens,
Card 2/3
a three-dimensional structure (to be used as ion-oxohangwre-
sing)'. it-P'reaent.discetylone booomes.-Anteresting because It say
servo " a starting raw material for various synthoseag, and be-
cause it has both-&.soi*ntifio and a practical significance. In
the laboratory for vinyl compounds of the Institute in which
the authars,work,.the hitherto neglected chemistry of the di-~
acetyl*nQ* concerning the interaction with compounds containing
mobile hydrogen has beensyst,osiatically.studied. By the reaction
of diacetyleno with alcohols-(Rof 8.) and aeroaptanes (Rof 10)
(constants of the reaction products. in ?a'ble 14 as well as with
amino al9ohole (Ref 10), org&uic,compounds with a oimpl*T*.ther
(also containing nitrogen)and with a thio-ether-gro in the
aonjugated,eyaUs ofthe double and triple linkagenuti) can-be
obtained. Additional ly, butadi*ne-a-other (II), a,6-di-thio-
other (III) and mixed a,6-thio-other are obtained.-The synthesis
method of.tho,l-alkoxy-butadiones-1,3 on the diacotylone and the
alcohol basis makeg possible the production of several repre-
sentatives of this class which contain alkyl- and cyclic r&di-
calm (Ref 16). The alcohols react with diacetylene under the in-
fluenoe of alkali and on heating. In this reactiong elfhyl-vinyl-
67038
SY%thstit Of low Sonomoro on the Basin of Acetylene SOT/t53-2-5-23131
and Diacetylene
other (I) And &**tale of butin-2.k-&14(see Scheme) are formed.
The reaction of the diacetylene with neroaptanee occurs gradual-
ly. Unlike the reaction with alcohols, the 2-aereaptane molecule
'Adds itself to the threefold linkage and di-thio-alkyl (or
phenyl) of the butadiene-10 is forizadjSchame). The, qonpounds..pro-
duced are highly reactive* The authors recommended a now method
of synthesis for the I-alkoxy-butadione-193 based on partial
hydration of the ethyl-vinyl-ether (Table 4). Tables 29395,
and 6 list the constants of additional products synthesized.
Finally, they-established-the conditions of the synthesis of
vinyl other of ethanol aminenYof various structures, and ex-
amined their properties. There are 6 tables and 18 references,
13 of which aretSoviet.
ASSOCIATION: Institut organicheskoy khimii AN SSBR is. 1. D. Zelinekogo
(Institute of Organic Chemistry of the Academy of Scian"s.
USSR ineni. N. D. Z91japkiy)
Card 3/3
5.361o
77353
sov/79-30-1-14/78
AUTHORS: Shostakovskiy, M. F., C Kondratlyeva,
L. V.
TITLE: Reaction of Butadiyne With Amino Alcohols and Amines.
I. Synthesis and Conversions of 1-(/3-Diethylamino)_
ethoxybut-l-en-3-yne
PERIODICAL: Zhurnal obshchey Ichimii, 1960, Vol 30, Nr 1, pp
75-81 (USSR)
ABSTRACT: Reaction of butadiyne witA(diethylamino)-ethanol
at room temperature withou catalyst yields (80-90%~
1 - (13 -die thylamino) -ethoxybut -1 -en-3 -yne (I), bp 99
(11 mm), n 20 1.4832. When compound I is hydrolyzed
D
with 10% H2S04 it yields 1,3,5-triacetylbenzene (yield
8o%), mp 162-1630. Reaction of compound I with aliphatic
alcohols under rigorous conditions (boiling under vacuum
Card 1/7 (10 mm) for 6 fir in the presence of' catalyst, potassium
Reaction of Butadiyne With Amino Alcohols 77353
and Amines. I. Synthesis and Conversions SOV/79-30-1-14//"(-8
of 1-( R-Dethylamino)-ethoxybut-l-en-3-yne
ethoxide) yields, along witli the acetals of but-1-yn-
4-al,also addition products of one molecule of alcohol
to a molecule of ethylvinyl ether. These addition
products have both a diene and an allene structure.
Thus, reaction of I 3-(dieth,,iamii-,o)-ethanol-.yJLelds
with / .7
(55-60%) di-( /?-diethylam'lnoetlioxy)-biAta-~1,3-diene (II),
bp 1510 (4 mm), n 20 1.4819. Compound II can also contain
D
some 1,4-di-(/3-diethylamii-loethoxy)-buta-1,3-diene (IIa).
CH~=C-CH--CHOCH2ICH2N(C,H 5)2
1
UUH2 CH2N(C2H5)2 (11)
(C2H 5)2 NCH2CH2OCH-CH-CH=CHOCH2 CH2N(C2H5)2 (IIa)
Reaction of I with butanol yielded (-1,0-60%) the acetal
of but-1-yn-4-al (III), bp 138-14o0 (10 mm), n 20 1.4542,
Card 2/ 7 D
Reaction of Butadiyne With Amino Alcohols 77353
and Amines. I. Synthesis and Conversions SOV/79-30-1-114/T8
of 1-(/3-Diethylamino)-ethoxybut-l-en-3,-yne
containing an admixturea product with an allene
structure. The yield of butoxy-(/3-diethylamino)-
etho,xybuta-1,3-diene (IV), bp 153-1550 (7 mm), 11 20
D
1.4570, in this case, was
CH',C-=CCH /OC H9.
\OCH 2CH2N(C,;)H5)2
(III)
only 10-25%.
H9C4OCH=CH-Cli---CHOCH2 CN2N(C2H5)2
(IV)
During the reaction of ethyl vinyl ether with alcohols
there occurs, evidently, not only the isomerization that
causes migration of the triple bond, but acetylene-allene-
dienic isomerization of reaction products as well, which
leads to the formation of di-allcoxybuta-1,3-dienes.
Card 3/-j
Reaction of Butadiyne With Amino Alcohols 773153
and Amines. I. Synthesis and Conversions SOV/~9-30-1-i4/78
of 1-(/t3-Diethylamino)-ethoxybut-l-en-3-yne
OR
HCEC-CH=CHOCI-I CH N(C H HOR-411CEC-CA-113 C14
\OCH 2CH2N(C2B5)2
OR CH3 CMC-CH(OR)OCH2 CH2 N(C2H 5)9
%=C=C!L-CH /
OCH CH N(C H Hj=C(OR)CIT-11~CHOCH CH N(C H
2 2 2 5)2 0 2 2 2 5)2
R=C0 9 and CH2CH 2N(C2 Ii 5)2
When the reaction of I w-Ith /3-(di-e-L",iyiarii-i-ic,)-e'L-hanoi
is extended from 0 to 22 hr the addit4on product of 'wo
Card 4/7 molecules of amino alcohol with one molecule of eth~rl
0
Reaction of Butadiyne With Amino Alcohols
and Amines. I. Synthesis and Conversions
of 1-(//3-Diethylamino)-ethoxybut-l-en-3-yne
Card 5/7
77353
SOV/~9-30-1-14/78
vinyl ether is obtained. The structure of this comuound
is V or Va (based on spectral analysis) and its physical
constants are: bp 178-1790, n20 i.46oS.
D
CHI,-C-CH2CH CH CHN(C If
eL 10 2 - 2 5)2]2
L2 CH2N(C2H 5)2
M
CH3C=CH-CH IOCH2CH2N(C2H5)212
1
UUh2 Uki 2N(C 2H5)2
(Va)
Reaction of T with ethylinercaptan at 70-800 for 6 hr
yielded (60-70%) ethylmercapto-( P-diethylaminoethoxy)-
Reaction of Butadiyne With Amino Alcohols 77353
and Amineo. 1, Synthes1s and Converslons SOV/79-30-1-14/78
of 1-(R-Diethylamino)-ethoxybut-l-en-3-yiie
-buta-1,3-diene (VI) or (VIa), bp 1520 (7 1-nm), 1-1 20
D
1,5290, The attempt to prepare compound VI by parallel
synthesis from 1-ethylmereaptobut-l-en-3-yne and 1-
butoxybut-l-en-3-yne failed. Only di-( ?-dieti-lylamino-
ethoxy)-buta-1,3-diene (H) was obtaine;. The formation
of II in this case can be explained by disproportiona-
tion of bu,toxy-($-diethylamiiioethoxy)-buta-1,3-diene
(IV) Into symmet ic dialkoxybuta-1,3-dienes.
2CIMC-CH-CHOC H + 2HOCH CH N(C H 2r~=C-CH=CHGC H
4 9 2 2 2 5)~~ 1 .4 9
OCH2CH2N(C 2H5)]2
(II) + CHg=C(OC4H 9)CH=:CHOC4 H9
(IV)
Card 6/~
Reaction of Butadiyne With Amino Alcohols 77353
and Amines. I. Synthesis and Conversions SOV/79-30-1-i4/"(8
of 1-(,/3-Diethylamino)-ethoxybut-l-en-3-yne
ASSOCIATION:
SUBMITTED:
The authors wish to thank B. V. Lopatin for spectral
analysis of the prepared compounds. There are 11
references, 5 Soviet, 5 German, I U.S. The U.S.
reference is: Copenhaver, J. W., Bigelon.. M. H.,
Acetylene and Carbon Monoxide Chemistry, 305 (!949).
Institute of Organic Chemistry of the Academy of
Sciences, USSR (Institut ora,,.aniches1-*,oy khimii Akademii
nauk SSSR)
October 15, 1958
Card 7/7
8h866
S/079/60/030/010/002/030
/A AMO B0O1/BO75
AUTHORS: Shostakovskiy, M. F., Chekulayeva, I. A., and Kondrat'-
yeva, L. V.
TITLE: Reaction of Diacetylene~with Amino Alcohols and Amines.
II. Synthesis of N-Alkyldiamino-1,4-butadienes-1,3 and
N,N-Dialkylamino-l-buten-l-ines-3
PERIODICAL: Zhurnal obahchey khimii, 196o, Vol. 30, No. 10,
pp. 3179-3183
TEXT: The authors had shown in Ref. 4 that the reactions of diacetylene
with aliphatic amines and P-(dialkylamino) ethanols start at room tem-
perature and proceed exothermically without a catalyst. This paDer gives
a detailed description of these reactions in which the nature of the ini
tial amine plays an essential part. Thus, primary amines react with
diacetylene to form N-alkyldiamino-1,4-butadienes-1,3 (1) (80% yield)
according to the following formula:
2RNH2 + CH=-C-CmCH ---* RNHCH-CH-CH-CHNHR (I) (I a): R - n-C4Hq;
Card 1/3
8L 866
Reaction of Diacetylene With Amino Alcohols S/079/60/030/010/002/030
and Amines. II. Synthesis of N-Alkyldiamino- B001/B075
1,4-butadienes-1,3 and N,N-Dialkylamino-l-
buten-l-ines-3
(I b): n-C 5H11 ; (I v): iso-C 5nil *Secondary amines react under analogdbs
conditions, forming N,N-dialkylamino-l-buten-l-ines-.3 (H) (60% yield)
according to the following formula:
R2NH + CH~C-C=CH R2NCH=CH-C=-CH (II) (II a): R = C2H5;
(II b): n-C4H9; (II v): n- C5H11 . The addition of the amines to com-
pound (iI) requires harder conditions. The diene structure of the reaction
products was proved by spectral analysis and by diene synthesis with
ethyl vinyl sulfone. The structure of the products obtained by reacting
diacetylene with secondary amines was proved by hydrolysis. The synthe-
sized products are unstable liquids which are only stable when kept in
sealed ampoules between -50 0 and -700. Dienes (I) and (III) absorb car-
bon dioxide from the air and form solid, stable carbonates. The spectral
analysis carried out by B. V. Lopatin confirmed the presence of t6
group - C.'00 in the dienes obtain-eT.--There are 1 table and 6 references:
-0-
3 Soviet, 2 German, and 1 US.
Card 2/3
84866
Reaction of Diacetylene With Amino Alcohols_ S/079/60/030/010/002/Q30
and Amines. II. Synthesis of N-Alkyldiamino BOO1/BO75
1,4-butadienes-1,3 and N,N-Dialkylamino-l-buten-
1-ines-3
ASSOCIATION: Institut organicheskoy khimii Akademii nauk SSSR
(Institute of Organio'Chemistry of the Academy of Sciences
ussRT-
SUBMITTED: August 4, 1959
Ik
v
Card 3/3
0
5. S 41 b
#. 1, W
AUTHORS:
TITLE:
PERIODICAL:
84667
2ZO5
S/q2o/60/135/001/020/030
301.6/BO67
Shostakovskiy, M. F., Corresponding Member AS USSR,
,Chekula eva. I. A.., Kondratlyeva, L. V., and Lopatin, B.V.
i_
Structure and Some Properties of the Products of Interac-
tion Between Diacetylene-and Alkyl Amines
Doklady Akademii na S(IR, I
uk S 196o, vol. 135, No. l,pp-101-104
TEXT: In studying the reaction of diacetylene with primary ands secondary
alkyl amines (Ref. 1) the authors observed that the N-alkyl-diamino-194-
butadienes-10 and the N,N-dialkyl-amino-l-butenines-3, respectively, are
the main products. The authors succeeded in isolating the geometric iso-
mers of N,N-diethyl-amino-l-buten-l-ine-3 (I and II) from the reaction f
0 x
diacetylene with diethyl amine. The chemical transformations the data
of spectral analysis prove that I and II have cis- and trans-structures,
respectively. On heating, isomer I passes over into II. The UV spectrum
of II is more intensive than that of 1. In the IR spectrum of 1, no ab-
sorption bands were observed in the range of from 800 to 1000 cm-1, 'in
the IR speitrum of II, however, an intensive absorption band is observed
at 945 cm- which is characteristic of a trans-configuration (Table 1).
Card 1/4
84667
Structure and Some Properties of the Products S/02 60/135/001/020/030
of Interaction Between Diacetylene and B016%o67
Alkyl Amines
Furthermore, an intensive absorption band is observed in the spectrum of
substance I at 692 cm-1 which is interpreted as the CH-vibrational de-
formation of the isomer. In spectrum 11, no corresponding band exists in
this region. The IR spectra of the isomers I and II were taken on a spec-
trophotometer of the type UR-10. The pictures showed that the bands of
the double bond are split into two components. The intensities of the
components are not equal. Substance I and II may only be geometrical
or place isomers:(C2H 5)2NCH'CR_CvzCH and CH2=CN(C2H5)2-C=CH. In the
range 685-895 cm-1 and 3075-3095 cm -1 of the IR spectrum of both substan-
ceB, no absorption bands are observed which are characteristic of a
terminal double bond. This confirms the cis-trans isomerism. On the basis
of the investigation of products of the addition of amines (III), alcohols
(IV), and mercaptans (V) to I and JI, the place isomerism. seems to be
excluded (see Scheme). In the reaction of n-amyl amine with the isomers
I and 11, 1,4-amino-substituted butadienes (III) were
formed under analogous conditions which
Card 2/4
84667
Structure and Some Properties of the ProduotsS/02o/6o/135/001/020/030
of Interaction Between Diacetylene and B016/Bo67
Alkyl Amines
had the same physico-chemical constants, formed the same picrates, and
also had similar IR spectra. The IR spectra of products of the addition
of butyl alcohol (IV) and ethyl mercaptan (V) to I had no absorption bands
corresponding to the terminal double bond. This excludes the presence of
this bond in the initial isomers. Hence, the addition with the formation
of I is the most essential point in the reaction of diacetylene with di-
ethyl amine. This agrees with the results obtained by the ion reaction of
the thiols with diacetylene,which is stereospecific and proceeds according
to the method of the "trans-addition" rule. N-butyl-diamino-1,4-blitadiene-
1,3 (VI) with cis-cis configuration of the substituents with respect to
the double bonds is the main product resulting from the reaction of di-
acetylene with n-butyl amine. The structure of VI was confirmed by a-diene
synthesis and by data of spectrial analysis. IR spectra of butadiene VI
in a polar and a non-polar solvent showed that the position of the ab-
sorption bands of >C-N and >C-CC=N (1684 cm-1 in the IR spectrum) was also present
Card 3/4
84667
Structure and Some Properties of the ProductsS/020/60/135/001/020/030
of Interaction Between Diacetylene and B016/Bo67
Alkyl Amines
in a second substance which was formed in a small amount in the reaction
of diacetylene with n-butyl amine. This substance will be further investi-
gated. There are I figure, 3 tables, and 3 references: 2 Soviet and I US.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR
(Institut6of Organic Chemistry imeni N. D. Zelinskiy
of the Academy of Sciences, USSR)
STJBMITTED: july lo, 196o
Card 4/4
SHOSTAKOVSKIY, M.F.; KHOMUTOV, A.M.; CHEEULAYEVA, I.A.; EFONUTIOVA, N.M.
Syntbesis and polymerization of dW)yl tartrate. Izv.AN SSSR,
Otd.khim.nauk no.11:2075-20?7 N 161. (KRA 14:11)
1. Institut organicheskoy kbimii im. N.D.Zelinskogo AN SSSR. i,
(Tartaric acid) (Polymerization)
CHEMIAMA, LA.; SHOSTAKMKIX; M&F.,- GIADISHEVSKAYA, V.A.; LIPOVICH, I.V.
Synthesis and transformtiom of vinyl etbanolami others.- Part 13:
Copolymerization of som vinyl othanolami ethers with mothacrylatA.
Vynokom,,soed* 3 n*96:901-9D7 Jo 161. (MM 14:6)
Is Jmt:Ltut organichemkoy kh'miJ :Uwzd N.D.Zeliwkogoo
(Sthanol) (10thacry3ic acid) (Polymerization)
SHOSTAKOVSKIIS X.F.; LASKORINI B.N.; NIKULISKiTA, G.M.; CHEKUIAXEVA, I.A.;
IOAMIANI,, P.G.
Swpewion polynalsation of the trivinyl sUor of triothe lanime
Synthesis of a now anLon, exchanger. Vy8okoa.wmd. 3 no.6:908-9.u
lo 161* (MM 14:6)
1, Iwtitut organicheskoy 'rhim" imid ND*Zoliwkogo AN SUR.
(Ethanol) (Ztba") (polywrization) (Ion exchanger resins)
I N
AUTHORS;
29522
S/062/61/000/011/009/012
B103/B147
Shostakovskiy, M. F., Khomutov, A. M., Chekula~-,,eva, . A., and
Khomutova' N. M.
TITLE: Synthesis and polymerization of diallyl tartrate
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 11, 1961, 2075 ~-- 2077
TEXT: Synthesis and polymerization of diallyl tartrate (DAT) were studied.
This was done to clarify the effect of its structure on the course of -
polymerization as well as the polymer roperties, in the case where DAT
contains further functional groups (OH5. The synthesis was effected by
ester;ification of tartaric acid with allyl alcohol in the presence of
hydroquinone and sulfuric acid at 700C in benzene solution. In order to
:establish the polymerization conditions of DAT, different uantities of
the folloving initiators 'were used: (a) benzoyl peroxide (B'Z 0 and (b)
2
azoisobutyric acid dinitrile, the temperature (60, 95, and 125 C) as well
as the re-~ition time (5 - 21 hr) beina varied. It has been found that
Card 110'Zi
29522
S/062/61/000/011/009/012
SYnthesis and polymerization... B103/B147
either linear (I) or tridimensional (II) polymors aro formed in difforent
quanUtative proportions dependinr on the iouction couditionc:
--CH,-CH-CH,-CIi- -CII, I-CH;-CH-
(1) 0 v 0
(11)
L
C=O C=O O,
-=o
6
6
HO-CH HO-CH HO-
HO-
I
& CH
HO
C
HO-C
HO-
H -
HO-
H
I I
LO C=O =U F-=LP
I I
I I
0 0 0 0
C
&. H, J, H,
I
CH
& Cli
,=
cHj=
Card 2/#
29522
3 /0 6 2/ .5 ? A) o. C) /o i012
Syn*thesis and polymerl-zntion !1 1() 5 /11
Table I shows the effect of Bz,u", as --in,-tiator on the Polymprizataon of-' DAT
The polymers have a predominantly cross-linked structure in the presence
of 4-5 - 6~; 0f BZ202; Increase of temperature and heating time have the
following effects,- with 6~c of Bz 2021 DAT is practically no" polymerized
within 5 hr at 6ooC, whereas a solid and insoluble polymer is formed at
950C (yield 57%),. Such a polymer forms at 600C only after heating for 21
hr, Polymerization with of Bz202 at !250C for 18 hr gave the best
results: 98~- of a solid transparent polymer which cannot be charged by
static electricity.' Its heat resistance is 294 0C (b) is inferior to
Bz202 as initiator. At 95 0Cv its use yields only rl,~o' of viscous polymer
within 18 hr, DAT is less active in Polymerization than fumaric and
maleic esters, This might be due to the OH groups contained in DAT. There
are 2 tables and 6 references: 4 Soviet and 2 non-Soviet The references
to English-language publications read as follows: Tsurac Araki. Hiroko
Jida. Repts Govt. Chem, Ind, Research Inst. Tokyo..
Abstrs,. 47, 10889 (1953). ~1, 95 ('q'~2~; Chem,
Card 3/01,
29522
S/06 6110001011,100910112
Synthesis and polymerization.... B103Y3147
ASSOCIATION; Institut organicheskoy khimii im, N, D, Zelinskogo Akademii
nauk SSSR (institute of Organic Chemistry imeni 1q D,
Zeiinskiy of the Academy of Sciences USSR)
SUFMITTED: June 12, ';961
Table 1. Polymerizat Ion of dially-. tartrate with different quantities of
L
Bz202 at 050C within 5 hr.
Legend- (1) Bz 0 conten,; 0,-b,; (2) fractionated quantity c:f polymers i-;
2 2 v I I g
(3) polymer yield, (4) t3tal; 0) tridimensional; (6' ---near; (7)
quantity of nc,npo-tymer-Izerl monomer, %; (6) content of 'tEirtar-,c a~--id in the
tridimensional polymer, 5~; (9) real; (10) th"oretical
Card 4/0 Z/
GASTILOVICH9 Ye,A,; SHIGORINO D.N.; GRACHEVA, Ye.F.; CHEKUIAYEVA,
SHOSTAKOVSKIY, M.F. ---
Investigating the nature of the complexes and derivatives of
acetylene by the method of infrared absorpti=4~spectra, Opt.i,
spektr. 10 no,5:595-599 W 161. 1 (MM 14:8)
. (Acetylene-Spectra)
SHOSTAKOVSKIT, M.F.; CHEKULAMA, I.A.; KONDRATIYEVA, L.V.
Reactions of diacetylene vith amin alcohols and Amin-9. Part 2:
Synthesis of N-alkyl-19-4-diamino-l,,3-butadiencoB and N.,N-dialkyl-
amizio-1-buten-3-7neso ZhuroobAh'-. 30 no*10:3175~-3183 0, 164
(KM 3-4:4)
1. Institut organicheMm.V Irkinji AN SSSR.
(Butadiene) (Butempe)
SHOSTAKOVSKIY, M.F.; CHEKULAYEVA, I.A.; MIGALKINA, E.V.
Vinyl ethers of ethanolamines in diene synthesis. Report No.1:
Interaction of vinyl ethers of A -(dialkylamino)-ethanols and
monoethanolamine with cyclopenthdiene. Izv. AN SSSR Otd.khim.nauk
no.1:152-155 Ja 162. (MIRA 15:1)
1. Institut organicheskoy khimii im. N.D.Zelinskogo M SSSR.
(Ethanol) (Ethers) (Cyclopentadiene)
b S/02Y62/146/002/011/C11;
B101 B144
A UT I n--, - Shoctakovskiy, Y.. P. , Corrosponding Member' AS, USSR,
Chekulayeva, I. A., Kondratlyeva, L. V.
TIM: Reactivity of cthiny~ vinyl compounds containing nitrogen
F I V'D1 Akademiy6 nauk 33S'R. ' Doklady, v. 146, ro. 2, 19062, 376-379
T-"'X The ~:ffttct of nitroeen z;Ltoms on the hydrolyzability of triple bonds
in compounds With the general strqrtijre RNC11=CH-CaC11 was studied. - In
1',,N-uliaiett,yl-ziinir,0-1-butene-1-yne-3 and the corre spondinC diethyl compound,
the H 2 0 adrition takes place without a catalyst even -at room ~empera'ture.
The corresponding N,N-dialkyl vinyl ketones R NCP=CH-CO-CH, are formed.
2
The pre--,ence of carbonyl',--roups c .onju;~-ated --Aith the double bond was z~roved
by IR spectra, and the structure was confirmed by a color reaction TO-1
methyl ketone. The corresponding dibutYl and dipentyl compounds hydrolyze
ziore sl-owly. Dialkyl-aminobutenines react with water, alip-hatic F-lcoholE,
and amines under less sevPre conditions than ~-dialkyl aminoethoxy
butenines. 1-(g-diethylamino)-ethoxy butene-1-yne-3 did not hydrolyza at
Card 1/12
S/020/62/11,f! 1002101111013
Reactivity of ethinyl ... B1 01 /D1 4'4
room tempk!raturo. Bio.-Ynthe~,Is is attributed to the action of biocatalysts
and to the formation of similar compounds reacting under nild conditions.
There is 1 fiGuro.
k3SOCIATI07!; Institut oreanicheskoy khimii im. N. D. Zelinskogo Akadr-iiiii
nauk SSSR (Iristitute of Organic Chemistry imdni 1". D.
Zalinskiy ofthe Actidemy of Sciencer, USSR)
SUF.'ITT-'.D: May 25, 1962
Card ZA61~