SCIENTIFIC ABSTRACT BOGDANOVA, N.M. - BOGDANOVA, A.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000205910008-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 9, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

BOGDA,NOTA, N.M.
Unusual stop-type gully Morb-bash") forms In the Piedmont plain
of saathwastern lopet Degh. Isy. AN Twk. SSR no.1:108-111 '57.
(XIM
1o:4)
t"
Z
1. Institut geografil Akadexii nauk SM.
(ZDpet Dagh-Brovion)

BOGDAMVA, N. M.
-
Relief of the Kara Kum Canal region. Izv.AN Turk.SSR. no.2.*
56-63 '57. (MLRA 10:5)
1. Institut geografti Akademii nauk SSSR.
(Kara Kum Canal ragion-Phyaical geography)

BOGDANOVA, K. M.
Origin and age of the Noshed sand mmeeif in southwestern Turkmeniae
Trudy last. geog. 80s6DR82 160. (KM 13:8)
(Mashed meeif-Geology)

-- BOGDANOVA, N. X.
Old terrace-deltas in northern Afghan rivers In the southeastern
Kara XUm- Trudy Inst. geog. 80:83-86 16o. (xm i3ts)
(Zara Kum-Terraces (Geologr))

PIOTRJOTMY, Vladimir Tladimlrovioh; PODCBXDOT~ N.S.. prof., retesuzont;
BOGONOLOTj L,J61 dotseutp ressenzeuti GILLAR# S,Tu*q dcktor geograf,
nauk, retsenzent; BLAGOTOLIN, N.S,,, ?A~ahVy sotradnik, retsensent;
BWD iNOVAJLK,,- nauebw notrudnik, reteenzentl DOSKACH, A.G.,
nauc-huyy notradnik, retsenzent; ZHIVAGO, A.T., nauchnyy sotrudnik,
retsenzent; RARISKAX, Te.Ta,, nauohnyy motrudulk, reteenzent; HIKOLATIT,
N.I,, prof,, reteenzents, DOBROVOLISKIT, V.V., doteent, reteenzent;
VOSKRESINSKIT, S.S., red,; SHAMOVA, T,Ag redpizd-va; PREYS, ZMeq
tekhn,red,
[Geomorphology and fundamentals of geology] Geomorfqlogiia o oanovami
geologii,, Riga, Xzd-To goodes,lit-rr. 1961, 283 N
MRA i4t 12'
1.3~,ehallnik.otdela goomorfologit Institute. gecgrgfil AN SSSR ifor OtIler).
2 Otdel Peomorfologii Institute. geografft AT SSW (for Blagovolin. agda-
U;va, Dookach, Zhivago, Rantsman).
(Geomorphology) (Geology)

I BMABOVA, N.H.
Special features of the geomorphological structure of Eambil
(southeastep Turkmenistan) in connection with the stratigrzphy
of 4e Qaat+rnax7 formation. Izv, Ali SSSR. Ber*geog. no.6t6o-
66 16-D t62.~ (KEM 15912)
lo Institut geografii AV SSSR.
(Narabil Upland-Goomorphology)

.4~2DANOVA, N.P., insh.
Mechanization of fabric laying on the cutting-out tnble. Leg.
prom.17 no.9:43-46 5 '57. (MIRA 10:12)
(Clothing industry--Equipment nnd supplies)

11 71
- -,
"Effect of Fo~ on thn 7,,.9r lative 7.1alance of t- .'.ctivs- ur'oca.1,
-li I--- . -
Cand Sci, ~!ain Gt~ophysical ObserwAor.,-, !-~f,3.
(RZhFiz, 1,,~54)
SO; Sir, 01132, 2~) "ar 55

BOGDANOVA, M. P.
"Enerimental Investigation of the Influence of Fog on the Radiational
Balance of an Active Surface".
Trudy Gl. geofiz. obsery., No 46, pp 80-86, 1955
An experimental investigation of the radiational effect of fog in
an adiabatic chamber of the Main Geophysical Observatory (volume 110
cubic meters, height 9 meters, diameter 4 meters). Compared are the ra
radiational losses from a layer of ice at the bottom of the chamber
without. fog and for the case of fog. At a height of 4 meters from the
surface of1he ice a Yanisbevskiy effective pyranometer was placed with
cylindrical cap for protection from radiation of the shamber wall.
The author compare d the experimental values of effective radiation and
values computed according to the formulas of K. S. Shifrin (ibid,, No 27,
1951; No 46, 1955), and found the results satisfactory (RZhGeol, o 9, 1955)
SO: Sum No 812, 6 Feb 1956

BOG--14NOVA, N. P.
"Precalculation of the Temperature of the Soil's Surface in the Pres-
ence of Fog".
Trudy Gl. geofiz. obsea., No 46, PP 87-89, 1955.
An equation for the calculation of nighttime lowering of the tem-
perature of the soil's surface in the presence of fog whIch influences
the effective radiation is proposed. The atthor gives an example of
calcualtion for one case in Koltushi, but without any indication of
the date. (RZhGeol, No 10, 1955)
SO: Sum No 884, 9 Apr 1956

36-71-6/16
AUTHOR: Bogdanove, N. P.
TITLE: The Theory of Nonzonal Distribution of Moisture in the
Atmosphere During the Cold Time of the Year (Teoriya
nezonallnogo raspredeleniya vlazhnosti v atmosfere dlya
kholodnogo vremeni goda)
PERIODICAL: Trudy Glavnoy geOflZiChe8koy ob8ervatorii
1957, Nr 71, pp. 94-102 (USSR)
ABSTRACT: The author develops a quantitative theory regarding the
transfer of moisture, a factor of considerable practical 81gnif-
icance bearing on the amount of precipitation. Assuming a uni-
form zonal distribution of moisture distorted by meridional
irruptions, the basic equation for transfer may be solved by
the method of consecutive approximations. Using substitutions
or transformations depending on different limiting conditions,
it is possible to arrive at separate solutions for land and
ocean surfaces within a latitudinal belt divided into four
areas: the Pacifte, North American, the Atlantic and Eurasian.
By application (Z the turbulent-exchange principle, i.e., the
vertical velocitv of the wind and its latitudinal component, a
.practical solution for distribution of vapor on the surface of
Card 1/12

16-71-6/16
The Theory of Nonzonal DIBtribution of Moisture in the (Cont.)
earth is developed. To provide a better solution for some occa-
sions the merldional transfer of moisture Is also considered.
One case, for lat. 50* N. indicated that Moisture decreased in
moving from the ocean to the contintent,a well-known fact.
Other systems of differential equations led to graphic presen-
tations of the distribution of moisture under variable verti-
cal velocities of the wind. The distribution is considerably
affected by the last-mentioned factor and which should not be
omitted In calculations. There are 5 figures, and 3 references
of which 2 are USSR.
1VAIUBLE: Library of Congress
Card 2/2

PHASE I BOOK EXPLOITATION SOV/2547
3(7)
Leningrad. Glavnaya geofizicheskayspbservatoriya
Voprooyd1namicheskoy meteorologii (Problems in Dynamic Mete6rology)
Leningrad, Gidrmeteoizdat, 1959- 91 P- (Series: Its Trudy, vyp. 81)
Errata slip inserted. 1,200 copies. printed.
Sponsoring Agency; Glavnoye upravleniye gidrometeorologicheskoy sluzhby
pri Sovete Ministrov SSSR.
Ed. (Title page): M.I. Yudin, Doctor of Physical and Mathematical Sciences
and M.Ye. 6hve*, Doctor of Physical and Mathematical Sciences;.Ed.
(inside book)- L.P-. Zhdanova; Tech. Ed*: O.G. UsAlmirov.
17JRPOSE: This issue of the Geophysical Institute's Transactions is intended for
scientific. workers and specialists in dynamic and synoptic meteorology.
COVERAGE: This collection of articles treats problems in dynamic meteorology.
The articles'. for the most part, disc~xss computation methods of forecasting
meteorologic elements. Closely related to this is a study aimed at determining
C'a,rd 1-/-32

Problems in Dynamic Meteorology.
SOV/2547
vertical velocities according io aircraft vibration data. No personalities
are mentioned. References acccoppany each article.
TABLE OF CON=S-.
Shvets,, M.Ye. The Problem of Advance Ccmputatiou of the Field of Relative
Humidity 3
Bogd_anam,_D[,,P.,.and M.Ye. Shvets. Determining the Lower Boundary of
In-iramass Stratus Clouds 13
Yudin, M.I.,.N.I. Yakovleva, L.V. Rukhovets., L.S. Orlova,, and P.A. Selltser.
The Problem of Cyclone Evolution 2_0
Pyatygina, K.V.~, and M.A. Yemel'yanova. Results of Advance Computation
of the Displacement of Near Surface Cyclone Centers 34
Dubov, A.S., T.G. "seva, and Z.S. Rakova. Ccmpamtive Analysis of
Sme*.of -the Simplest Methods of Numerical Forecasting 46
Gandins L'*So and T, Do'lod. Methods for Integrating the Vortitity Equation
Along an Isobaric Surface~ 53
Card 2/3

Problems in Dynamic Meteorology SOV/2547
Gandin, L.S., and T.A. Alimova. The Problem of Stabilizing the SmootJjed-iut
Currents Used in Graphoanalytical Forecasting Methods 58.
Pyatygina, K.V. Fom"' for-Advance Computation of Upper-Air Bweic
Center Displacements 64
Dubovp A.S. The Pro~lem of' Detwnlnlng Vertical Wind Velocities ircm
Aircraft Accelerogra~h Data
73
Zavarina, M.V. Detennininig the-Critical Values of Richard on's
Ntmber as an Index CAterion of Increased Ataos~heric Turbulence 85
AVAILABLE: Libraxy of,C69ress
Yx/gmP
10-28-59

b
PHASE I BOOK E(PLOITATION SOV/4174
SOV/2-S-99
Leaingrado Glevnaya ge6rizicheskaya observatoriya
Voprosy chislennogo Srognoza i teorii k3lmata (Problems in Numerical Weather
Forecadting and Climatology). Leningrad, Gidrometeoizdat, 1959- 129 P-
(Series.: Its. Trudy, vyp. 99) -Errata s3ip inserted. 1,000 copies printed.
Additional Sponsoring Agency: USSR. Glavnoye uprevleniye gidrmeteo--ologicheskoy
sluzhby.
Edo.: M.Ye. Shvets, Doctor of Physics andMathem ties, and M.I. Yudin, Doctor of
Physics and Mathematics; Ed. (Inside book): T.V. Ushakova; Tech. Ed.: N.V.
Volkov.
PURPOSE: The publication is intended for specialists in the field or dynamic
"and synoptic meteorology and cLimatology,, as well as for graduate students in
these fields,
COVERAGE: This is a collection of 3.1 articles published as No. 99 of the Trans-
actions of the Main Geophysical Observatory imeni. A.I. Voyeykov and dealing
Card 1~

Problems in Numerical Weather (cont.) SOV/4174
with new methods of numerical analysis prognosis* Individual articles are con-
cerned vith contiguous problems of climatologyt temperatlare anomalies in the
atmosphere, effect of the heat of condensation on pressure changesp numerical
prognosis of.the pressure pattern affected by orographic factore,and the hydro-
dynamic theory of frontal cyclogenesis, References accappany each article.
TABLE OF CONTENTS:
Rakipova, L.R. Formation of the Mean Monthly Anmalies of Atmospheric
Temperature 3
Kagan, R.L. Calculating the Effect of the Condensation Heat Flow and of
the Stratosphere on Change in the Pressure Pattern 15
Bdgdanovd N.F* Approximative Evaluation of the Effect-of Heat Released
nMi;; on the Change in Pressure Pattern Near the Ground 37
Du~ Sin-yuan's More Precise System of Calculating the Irregularities of
the Earth's Surface in'Numerical Methods of Forecasting 43
Card 2/3

Pr6blems in Numerical Weather (Cont.) SOV/4174
Gandin., L.S. Numerical Methods of Map Analysis 48
Gandin, L.S, The Problem of Optimum Interpolation 67
Gandin, L.S.,, and Ye. le Bagrova. The Structure of the Height Pattern
for a Surface at 500 Millibars 77
Du Sin-yu='* Spatial Problem in the Numerical Forecast of a Baric
Field.Ta3dng into Account the Influence of High Plateaus 93
Dd Sin-yuaul' a Problem of the Hydrodynamic Theory of Frontal Cyclogenesis 105
Arrago, L.R. Vertical Currents in the Atmosphere over a-Thermally Non-
uniform Surface 112
Shvets., M.Ye... and R.L. Kagan. Problem of Calculating Vertical
Velocity in the Atmosphere 123
AVAIIABLE: Library of Congress
jp,/Qdv/gmp
Cexd 3/3 9-8-6D

!:.P.
Stv.-J~drj.- the
36(.
- ., -iri,,. o.' 4LI.'-' -xroit-~---n e--t o-"
L-vrin - f: 1 --I . ~ I - -~, I-', .Trl e- ~ G ',(- , 0. 1.1-4: It 1 -1.-"
L . i
(,.!" - 1,',: 1'.
(,~ ~, tt~ crol C,)

BOGDANOVAJ, N.P.; TYR EVJP A.H.-
Relation of veather and climatic characteristics with the radiational
temperature of the underlying surfice, Trudy GGO no.109:38-52 161,
(MM 146)
(Solar radiation)

C-
TSYGANOV, V. A. ; ZHMVA, R. A. ; BOpANOVA N. P. ; NAMESTNIKOVA, V. P.
"A new species of the streptomycete 2732/3, producing an antibiotic pigment."
report submitted for Antibiotics Cong, Prague, 15-19 jun 64.
Cent Antibiotic Inst, Leningrad.

-BDGUM"P*l KOVALEVA, L.Ae; SHENIN, Tu.P.; SOTOVIYEV, S.N.: TSYGANOV, V.A.j
ZHUK(YVA, R.A.1 NAMRSTNIKOVA, V.P.
Violacein, a new antibiotic. Mikrobiologiia 34 no.4t623-626 Jl-AR
165. (MIRA :L9 t 10)
1. Uningrads)dy naucbno-issjs~dovatellskiy institut antibiotikov.

BOGDAU'S1,~..; KONEV, Yu.Ye.; SANNIKOV, W.A.; SOr,OV?n,-V, S.N.;
SOKOLOV., D.V.; TSYGANOV., V.P.
IdantifJoation of the antibiotic 1160 pmWeed by actino-
myeates from the Actinomyces grizeus group. Antibiotiki 2-0
no.3:195-201 Mr 165. (IMIRA 18 10)
1. Leningradskiy nauchnc,--Lg sled ova tel I sk iy inatit-ii-1. antl-
biatikov.

TSTGANOVp V.A.; K07-4EV,, Yu,'Teq; FURSENKO, m,v,; 1OFINA, E.I.; ALIBERT,, H.H.j
KJSTAFOVA, N.N.; VENKOVA,, I.B.; SOIDVITEV.. S.N.; MALYSHKINAO M,A.;
BOGDANOVA N.P.; KOTENKO, T.V.; FILIPPOVA, A.I.
.--4--. P,
Isolation and characteristics of actinomycetes producing the
antibiotic trichomycin. Antibiotiki 9 no-4:291-296 Ap 164.
(MIRA 19:1)
1. Leningradakiy nauchno-isaledovatellskiy institut antibiotikov.

POPOVAp Ye.G.; MUnp M.Yaq BO*NOVAp N.S.; PERSHINg G.N.
Qwternau amonium salt derivativea of alkylaminoalk-ylamides of
10-undeconoic aoid. Had. prom. SOR 14 no.12t3-9 D 160.
, (MM 1.3;12)
1. Vaesqj=yy nauchno-issladovatellskiy Irchimi o-f"tsevtieheekiy
institut J~iani S. Ordzhonikidze.
(UNDECONOIC ACID)

25o49
S/064/61/000/007/001/005
B124/B206
AUTHORSt Boguslavskiy, I. M., Vollfkovich, S. I*, Kazakova, S. B.,
Bogdanova, N. S.
TITLEs Production of hydrogen fluoride from silicon tetrafluoride
PERIODICAL: Khimicheskaya promyshlennost', no. 7, 1961, 6 - 8
TEXT3 During the production of superphosphate fertilizers by decomposition
of apatite and phosphorites with sulfuric acid, about 45% of the fluorine
present in the ore escapes in the form of SiF 4' together with the waste
gases. HF can be produced from SiF by the process studied and proposed in
this paper, without great capital i4vestment for the raw material produc-
tion. Production cost of HP is also greatly reduced due1o complete utiliza-
tion of SiF 4 for the production of HF and high-quality SiO 2* The process
consists of two main stagess production of solid ammonium fluoride and
-bifluoride from SiF 4-containing gases and decomposition of ammonium
fluoride and -bifluoride by means of sulfuric acid, by which EF and
(NH 4)2 so4are obtained. The main reactions of the first stage ares
Card 1/6

25r4
C
S 0 4/61/000/007/001/005
Production of hydrogen ... B124/B206
SiF4 + 2NH4F (h-H 4)2SiF6 (1); (NH4)2SiF6 + 4NH3+ 2H2o - 6NH4F + Si02
(2); 2KH4F NH4F-HF + NH3 (3).. SiF 4 is absorbed by a recycled NH 4P
solutionj reaction (1) takes place in the absorption apparatus. The
(NH 4)2 SiF6solution obtained is led from the absorption apparatus for
neutralization with ammonia, which is carried out under continuous cooling
of the NH4F solution formed. The precipitated SiO 2 is filtered off and
rinsed with water. The greater part of the mother liquor is led to the
evaporator, and the rest in the form of a 10-12% solution to the absorption
of Sip 4* The NH 4F solution is evaporated to a salt concentration of
94-95%, reaction (3) taking place. The ratio between ammonium fluoride
and -bifluoride in the evaporated solution depends on the boiling point of
the solution. Table 1 shows data on the evaporation of NH 4F at various
temperatures and pressureal practically no fluorine is present in the con-
densate at 14700, and the sum of the salts in the solution reaches 98% in
this case. The solution solidifies at about 1000C. The solid NH 4F-Hp
- NH4F salt mixture with a total fluorine content of 60% represents an
Card 216

25049
S/06 61/000/007/001/005
Production of hydrogen... B124 B2o6
intermediate product in the production of HF. The second stage of the
process can be characterized by the reactionst NH 4F-EF + H2so 4 'NH 4HSO 4
+ 2RF (4); NH 4F + H2so 4 'NH4HBO 4 + HF NAM NEI4 HSO4 + NH 3 '(NE 4)2S0 4' (6).
93-95% sulfuric acid is used for the decomposition of the salt mixture
consisting of 8cwl. ammonium bifluoride and 20% ammonium fluoride; decomposi-
tion is carried out at 180-1900C. Table 2 shows the experimental results
for the decomposition of NH F with sulfuric acid in a steel-boat, which
was placed in an electric t6bular furnace with a constant stream of dry
air; the experiments were conducted with temperatures maintained constant
.to within t 30. The heating time varied from 5 to 30 min. The HF evolved
was absorbed by water in vessels made from organic glass, the melt was
weighed, analyzed for residual fluorine, and the fluorine yield was calcu-
lated. With 30 min reaction time and 180-1900C, the fluorine yield
amounts to 97-98%. The ammonium bisulfate melt obtained contains about
40% free sulfuric acid. Neutralization of the latter with the calculated
amount of ammonia converts the ammonium bisulfate into ammonium sulfate.
Fig. 4 shows the decomposition curve of ammonium fluoride and -bifluoride
with sulfuric acid as a function of its concentration, calculated for
ammonium bisulfate (decomposition time 40 min at 1950C). On the basis of
Card 3/6

25049
B/064/61/000/007/001/005
Production of hydrogen.o. B124/B206
laboratory results, the pilot plant of the NIUIF under the direction of
V. D. Podkopayev, designed a pilot installation for the production of HF
by decomposition of ammonium fluoride and -bifluoride with sulfuric acid,
which yielded good results. In order to select the most corrosion-resist-
ant material for the thickener and reactor, the steel types investigated
were immersed in anaqueous solution with 26% NH4F and 19% NH 4F-HF; the
specimens were in a -vessel made from NT"-i (ATM-1) graphite, with an ex-
ternal heating coil. The solution was periodically heated for 7 hr daily,
the specimens being held for 120 hr at 800C and 880 hr at room temperature.
Steel of the type )(23R28"3NT.(Kh23N28M3D3T) was most corrosion-resistant.
Moreover, the most resistant material was ascertained in a molten mixture
of H2SO 49 NH4F, and NH4F-HF at 190-2000C, the specimen being fixed to the
bottom of the vessel by a Teflon strip and the melt being mixed by a
mechanical mixer. The test lasted 92 hr with a continuous feed of the mix-
ture, and showed that steels of the type X23A23M3V (Kh23N23M3D3) and
OV23H28tOX3T (OKh23N28M3D3T) are the moat resistant. Data obtained for
alcb (St-0) steel (loss in weight 43.0 9/m2.hr) need a checkup under
working conditions. There are 4 figures and 2 tableso
Card 4/6

101
9
61
6~
S/ 4 /000/007/001/005
Y
Production of hydrogen ... B124 B206
B
24

ASSOCIATION: NIUIF
Table 1: Evaporation of ammonium fluoride solutions at various tempera-
.tures and Dressures.

Legendt 1) pressure, mm Hg; 2) temperature, 00; composition of the
evaporated solution, %; 4) sum of the salts.
CAKTall pemso
ra PSCMPGI
Temn".
' NH3
MA PT, CT. P W6
1
r
h
1
760 126 40.65 27,69 ".49 '0.681
760 146 57.14 30,89 91.99, 0,542
760 151 59.&S 31,30 93,98 0,525
560 113 35,63 25,13 62,54 0,707
560 .115 .38.06 26.69 64.75 0.703
460 109 36.79 26,54 65.61 0. 72k
460 123
50,47 29
79
8291
90
0"
460 30 54.70 30 86 88 43 0.560
460' 142 59.50 32.63 95,25 0,549
460 .147 62.33 32,61 98.21 0,523
Ti
Card 5/6

25049
S/064/61/6oo/ooVoo1/o0'5
12
B2
6
Production of hydrogen... B
o
4/

Table 2t Decomposition of
Decomposition curve
Fig. 4:
ammonium fluoride with sulfuric of-ammonium fluorides-with
acid (heating temperature 1800C) various amounts of H so '(% of
2 4

min
th of heatin
Le
endi 1) len the stoichiometric amount, cal-
g,
;
g
g
culated for ammonium bisulfate).
2j taken, 9; 3) fluorine yield, %; .
4 heating temperature 1900C.
Legend: A) degree of separa-
TO. e
tion of, F,

mrPoza
M&Xo;t no
$Topy
MIHIYM NH4 HIS04 Lew
so

5 10,72 420
80
to
20 5
5 10.72
10
72 80:0
93
0
,
, . ~O
20
20 is
15 34.4
34
4 96,0
9
. 4,0 ~O
30 5 10.72 96,8
30

30
.150 10.72

33 98,3
-310
.8 97.4 so 60 70 80 .99100
30 15* 33.8 .96.7 112304,
40

60
5
io.n
97,0

Card 6/6 5 10.72 98.0

BOGU61,~.T);':1Y) 1.1-.1 VULIFKVICII) TKICDAICYA,
Proftation of hydrogen fluorldo froma cilicon tetrafluoride.
lliz-.. no.7:45C-452 JI 161. (MIRA 14:7)
1. Vsesoyv-.n5-j rauchno-issIndovatel'sUy instit-at udobrordy i
inscktcfungitsidov.
(Hydrofluoric %cid)
(Silicon fluoride)

F=HIN, G.N - BOGDANOVA N S
Anti-influenzal activity of onium base salts. Farm. i toks.
25 no.2:209-220 Hrr&p 16~. (MIPA 15:6)
1. Vsesoyuznyy nauchno-issledovatellskiy khimiko-farmatsev-
tichaskiy inatitut imeni S.Ordshonikidso.
(INFLUENZA-MICROBIOLOGY)
(ONIUM Compaums)

FERSHIN G.N.; PQqPANDVA, N _-.; ZMAYEVA, K.I.; KRAFT, M.Ya.
.9 ~,S -
Some regularities in the suppression of influenza virus multiplies-
tion IV synthetic compounds. Farm.i toks. 24 no.6:690-695 N-D 161.
(YM 15:11)
1. Vsesoyuznyy nauchno-issledovatel'skiy khimiko-t&Mtsevti-
cheskiy institut imeni S.Ordshonikidze.
(INFLUENZA-)UCROBIOIDGY)

GUNAR,,*.I.; ZAVIYAWV. S.I.j PERSERM, G.N.; MIIDVANOVA, S.N.;
-BOGDANOVAI_N.S.; MAKEYEVA, 0.0.; KROTOV, A.I.
A? -Dicarbonyl e=pounds. Part 3.41 Synthesis, trsnfdiiKtions,
and biological activity of 2-prebnyldihydroresorcinol. Zhur,
ob.khim, 31 no,12:3975-398/+ D 161. (KIRA 15:2)
1. Institut organichaskoy khimil imeni R.D.Zelinakogo AN
SSSR; Voesoyuznyy nauchno-issledovatel'skiy khimiko-farma-
towticheskiy institut imeni S.Ordzhonikidze i Institut
malyariip meditsinskoy parazitologii i gellmintologii.
(Resoroinol)

MAKAROV, N.V.; POPOVA, Ye.G.; KRAFT, M.Ya.; BOGDANOVA, N.S.; POWMINA, L.M.;
PERSHIN) G.N.
Effect on influenza viruses and synthesis of N-acyl derivatives of
uracil. Farm. i toks. 27 no.1:63-68 Ja-F 164.
(MIIIA 17:11)
1. Vsesoyuznyy nauchno-issledovatellskiy khimiko-farmatsevticheskiy
institut imeni OrdzhoDikidze.

PFRSHTNO G.N.; DnODRIOVA, N.S.P- MAKIN, 5JI.; LIKKO,~hIRS"OV, V.M.
&-,djFLjkGXyl-rr!---~ anj
~ntdvlral activity of 2)
'--alkoxy- 6 5-dih:,4rof7rans ((-yclic of glutnrir
-!ArJoljyds derivat!ven), Farm. I toks. 28 n-~,.1:66-69 Ja-F
165. (MMA 18:12)
a. V,,escyuznnr riauclivio~-issiedcvatellik-iy k-hUnlkc-fal-mat,sevtl-
clp.skiy institut linent S.OrdzhonlMdze I Moijkovsk3y Institut
tonlcoy khlmlahoskoy WkhnclcgAA imoni M.Vdollionoseva, Mo,-,Iva.
'!ubmitted September 5, 1963.

NRa AP6034263 5/0597/0600
,AUTHOR.: Kraft., Me Yas; Katyahkinat Ve Vol Parohin, Go He; Bogdanova,
No So
-ORG: All-Union Scientific Research Chemical and Pharmaceutical Insti-
tute im. So Ordzhonikidze, Hoscow (Vseioyuzuyy nauchno-iseledovatel'-
skiy khimiko-farmatsevticheskiy.inatiiut)
TITLE% -Cyclic oxocompounds ae.potential antiviral agents
SO-URCH; Farmakologiya i toksikologiya, v. 29 no* 5, 1966, 597-600
ag:nt,
tOPIC*TAGS: cyclic oxocompound, antivirus
drug effect, pharma-"
.cology
ABSTRACT:. The 'antiviral properties of the compounds in Table 1 were
de.terminede These'compounds were test'ed on influenza RR-8 type A virual
i.n.V.itro and.in oulo' in' tissue'cultures. All possessed antiviral activ-,
ity,in vitro -and some inhibited viral growth in chick embryo epithelium.
These cyc-lic oxocomoounds are highly reactive and are thought to pro-
duce their inhibitory activity-by acting on viral protein in such a way
that the viruses cannot adhere to the cell membranes of sensitive cells.
Related compounds have been effec.tiveagainst keratitis infections when
'applied lo'callye Quinone derivatives with comparatively low redox po-

Table 1. Actjfri~y oi son*- and bl:CyClic
compounds
Activit Activit
No , Compound (n 4, Art Compound in
ar-O Coo COO
_OM w
+
a"

oo. of
ON

+

% A

tvt

12 0 as

ww'twP.
x
_0~~
_

,
no
d
I
ZxP1Aa&tL.a 0~ eymboAs
0- compound IM&Ctive in dilutions of IS1000;
+- compound active In diluttou2 of I.-1000;
47+ Compound active in diLutious of IiJ0000.
+++ Prepare CA act Ive in dilutions of
ItIO00009 ++++ - Preperation active in dilu-
a of 192000000. preparation active
C!CaI
I dl Utica$ of ItIO000000

Aq; _7
~btilp,'dtecovaied* td. po6scas good.ant'Avir#'I'1pro-pzrt4es,
-refuting' .1 , '- were don-,
a_the~r'y-. _t V 4.tptivir'al 'activi.ty and"hith' Zh
d ~nvolied the ~ Id
The colipoun hj$ present Btu y. -WeVe
f.o r th.eir, e.f f ects on. atk~nIagr'dupo,.of tiucl .eic, 4qd''Protel no with
dmiphisis on t -be:;vix.u and. only
heii.-extiecellul *ar 'tn*terference w0h'
''Speoindarily.. f or - tt~ir~, in''tr14cillular ef facts 'on rpptbidud~n i
The obj'ec . . 11 Y.:w .. ,g-v ruses.,
t was, to.'.fin4, a rbmPouihd that reacts ea~sil i-th~ Viiai Protein
but Which i's comp .ar.#tively.'ind~ifferent',-to the....'Prot'in, ok 44.hogt 'call;-
'The'. 'cofif igurat'ion of the ziole'6~le of the, couvhpound is
y~ ry 'lip 0
the 'specificity' o'f the . - t~ t
,And plays 'A. gre-at roleAM dru~go Li 14'anti-
,.Viral -activity..was di-splaiYed,b' 4-hydroxy~-beia6-nap~thdquin~ne,- ahd* its
Y
iau.tom'eric.-foim. 2-hydroxy-~.ilphhr.napthoqu,inone.-. Tho mosi*. e1koctiv* 'a -com-
pound was lrhydr.b?cy-beta-~n'i~th64iiinon,e.- -The* activiti,es of, the other
compounds tested are' shown in'Table !I.'. The moAt dffect.ive virus'neu-
-traliz.ing:com~o'unds'(no#' 'ifi, VIII" Xi,.,ahd XV).-were used.in the-
trdatment'of pneum-oniai'in white''m'iceo.-but were.not effective.- Orig.
art. has: 1 table~l
. 0 . - I . . ... [W.K. 501
SUB CODE:.. 06/'- SUBWDATE': .'2'ODec65/ ORI~G REP': 002t OTH REP: 005
Card 3/3

UXINSKIY, L.Ya.; BOODANOVA, N.T,
Toxic allergic neuritis of the optic nerve during strerptouVcin
therapy. Problotub. 36 no.1:115-116 '58. (MIRA 11:4)
1. Is Skvirskogo prativotuberkuleEnogo diopansera (glavnyy vrach
L.Th.Lozinskiy), Kiyovskays oblast'.
(MMV31S. OPTIC, die.
toxic allergic neuritis caused by streptomVcin (Run))
(STRICPTONYGIN, inj. off.
toxic allergic neuritis of optic nerve (Rue))

MAZOKHINA, N.N..; BOGDANOVAI.N.V.
Capillary method for determining the heat resistance of
micro-organisms. Kons. i a7. prom. 18 no.12:32-34 D 163.
(MIRA 17; 1)
1. TSentrallnyy nauchno-isoledovatellskiy institut konservnoy
i ovoshcheaushillnoy promyshlennosti.

If( ndi. Bc, t d & r N. "Avci,-jin,c th, -cndinrftif-n c"
V,
tho fci-mOL.Irn of &,r1 ict, Crbst ~.n
il-. Yirt,,v.-, Vol. ';XV1,
11-1,611~ 10 "Sfpt.. Inyl(h y, No.

KOSTROVAp Ys.L;-AqjDANOVAj_~*Vo-.,--
Bacterial spoilage of canned fi,.)h in tomato sauce. Kona.i ov.
pr6m. 17 no.9:37-39 3 162. (MM l5t8)
1. TSentralInyy nauchno-iseledovatellskiy institut konservnoy i
avoshcheaushillnoy promyshlonnosti.
(Fishp Canned) (Food-Bacteriology)

SEMENDYAYRVA, M.Ye.; -4np~j~~Uj, N.V. _
Reuropsychic changes in hormone therapy of BotIcin's disease.
Sovet. med. 27 no.6t6l-65 Je'63 (MIRA 17:2)
1. Iz laboratorii deystvitellnogn chlena AMN SSSR prof. Ye.M.
Tareyeva i Flinicheskoy infaktsionnoy boltnitsy No.7 (glavnyy
vrach N.G. Uleskver).

SIZE"MAYEVA, M.Yo.; MUKIIINA, D.N.1 BOGDANOVA, N.V.
Recurrence of Botkin's disease after hormonal therap7. Vop.med,
virus. no.9-.24&254 164. (MI RA 18

DALMATSKAYA, Ye.l. Prinimali uchastiye: GONCHAROVA, L.G., m1adshiy nauchnyy
sotrudnik- ZHELEBOVA, V.K.; BOGDANOVA, N.V., laborant
Y
Kinetics and statistics of the carbonization of sodium silicate
solutions. [Trudy) NIOK11IM 15:83-96 163.
(MIRA 18:2)

S/552/62/Ooo/o34/002/603
8,192/8382
AUT110116 i Kalenov, Y#.N. and BoXdftftovaq OOIq
TITLEI Tho aignificanoe of elootrie mounding in the investi-
gation of tho foundation relief of the Russian platform
SOURCE,j Moscow. Vsosoyuznyy nAuohno-ionledovatellskiy institut.
goof izichaskikh motodov razvedlci. Prilcladnaya
geofimilca. no. 54. 1962. 116 -~ 134
T Mr An attmiipt itj made to sunmarize the results obtained,
with dq@p Vorti6al alootric mounding during investigation of the
foundation relief ot tho Ituasian platform and to *valuate the
possibilitiba of this method of investigation by employing'the
concrete ragults,, The otothod of vertical electric mounding can
be compl~tOly tUg*0aIjfUjjy Used to investigate 'the surfooe of
pro-CambriAll dry#ttkljjhO foundations, not only in the west and
south-wont but aloo in the east of the Russian platform, including
the territorier. or tho mouth-aawtorn And eastern slopes of the
Voronezjj njAmajil, Rycizan'-Saratov depression, southern half of the
Tolanov ridge with its slopes and a large part of the Tartar ridge
with :Lt* wootarn nnd -eastern dips. However, evan with the base
CArd 1/ 3

The significance of ....
S/552/62/000/034/oO2/063
r..192/E382
lines AD = 5o-6o km it is not possible to use the method for
studying the foundations if the top deposits contain dolomites or.
jiydrochemical matter of high resistivity, such as encountered in
some areas of the Moscow and associat ad regions. The most signifi-
cant results for AD up to 3o-4o km can be obtained by the method
in those areas where hydrochemical deposits are abs6nt and where
the upper deposit contains mainly lower terrigenous conductinj~
substances or where the resistance' of carbonate or sulphate-
carbonate deposits is lowt It is therefore recommended that,
investigation by vertical electric sounding should be continued
since this not only permits investigation of.the foundationrelief,
but can yield information on the general characteristic of the
t,hickness and lithological composition of the carbonate o7r
sulphate-carbonate deposit. Further, investigations by means of
dipole equatorial sounding (carried out over limited areas)
indicate that the results of this type of sounding are I'distorteO
by horizontal irregularities but this conclusion has not been
fully verified due to the comparatively few data available. It i~l
probable that under different geological conditions the equatorial
Card 2/3

S/552/62/000/034/002/063
The significance of .... E192/F,382
solinding mothod will be more economical than vertical sounding
wid will produce fully satisfactory results. Recent years have
brought -now inothods of electric prospecting (telluric currents,
measurement of the magnetic field, magnetotelluric measurements)
whic1h appear to be more effective for investigating the relief
of' the foundations than vertical or equatorial sounding..
There are 8 figures.!
Card 3/3

MOKEYEVAY Ye.A.;j~qGDAnMA.M.,
Activity of potato lenticels in the process of ontogeny,
Uzb. biol. zhur, 7 no.5tl5-18 163. IRA 18ill)
1. Tashkentskiy gonudarstvennyy universitet imeni Lenina i
Tashkentskiy sellskokhozyaystvennyy institut.

ff-w-mit-g- WAR-mi-IFL-W-41 . W_
o_'W 0-11 W W V W-,W-
01 IY P-10 I I to 4.
0a it PJ 's I.-A-A-1. a a 8_7? Fp A IL a 'A 0 la it k
Oil 4"p IV t-4vitts
go f
39=ft
o0 ITIL~ X-11-X~x.
Is voit the type of IF c4tall No.
too, ""'o"
lestird fix wiMty. by the mte W
go a I ; its
go tat lottityler it, to loulatfiruic (11) at imorml. %oam velocity 141.3 III'to 1,
NMI Irmic, androrsnit-miml Intonate mrmnslictmovii runs. iffro.itif 11 All vit.+. ";.. dt".Z.11"
Couvrotim vanditkaus lite kloov* -Italy am MO-70" m t-Or-1. 2it j7JI, it-' it, slit. 03,
and ldh .1
100 S.cr velocity I I WO I A. 18% th6 1-1) PI.I. 114K r 41,3 W., 12 _'. Vol. of Cstal"t
00.2 troill" range, "Oft j, to::ri atio. (611461 prvionum). rquil. ml., p IN) imit. I IX: At Ml ', 3.10, :vi44 46.8, 91 '4 41 4
09-5 "i lks at am Ins than X11; drhyd"rnitlon to U. Higher 7 15 0.0) 7.1; at NO% 3 62 4AS 04.3 fa 7 04 Iii:
! torinp, favors side tractlim-. The mitit. of H fanned 6 : t ;;,n3 %
000 imlirlw"-rit (it the Icitath of the tim tit. V, ittod 12 min.). I 2~ 10.6i at (UN)" (14 A.0. .3A lmi~ 81.1. 0.4.
-f f - I) J ws-" It"- Alliarroil activit Woo 10.1. (2) Varlatlim cof $0 f"wn 11110101go MO rum,
thur 83F I'milAt
It. 4 11 "NIA k III,, di"ramil thr )ii-himillf from IN A to 4A imilo % (at 1147".,
-.41-AIN& lot r 41.1 11161 1. Thi% timifinm, tat the Whole, compktr
0ow :1; 31.31 3L.'4 at "LN NO'. 144mlk. toe taltinee
"-masir 4 it", --maly,t tittifoom, thir .11trwittik-a bring
tilt Inin.. 1, 41.1 -' V.4. 2 vul to) a" hird to wmw t%trnt tit dirccmpts. cif 11. (3) In mhts
111. .4 1 + 11, cow" the vAnic catto] I both the dthydroc"a-
11, Ily IIIAW AjjhY.lji,h-. A.A. AtINK11111441 III
tion I - 11 atut kvinist-n. 7W ve"it. The 4Kompa
InCf"WS With lite 14-111P. And %tilt the initial content at
It in the mit,t.; at t'-47 mW Ado". ilm, mtr of dec"m at
11 r%rvvti. that .4 it- fi-rusatkoa when the :rl
.11'.1 IN
It full. nutlorst quails. v it I ftv.. j$ IM Min. It
"tilt. owed in a Wis.. 0; A471. I im inlhw oikg,: 1"*"]
111171 A 19N. nrol *it 1.41 otmile "e. It 6W ainvA UK. SM A74.1
*a w
0 a, IV 9_1A
It I a rw 0 a W 1 111' So III a 4 3 4
0 0 0 0 0 0 0 0
0 0-0 000000
as
-00
nee
.66
-00
4119
as*
Zoo
wag
16#01
agoill'
Wee
too

00
00
00
be
00
Min! q~ 1+ t is
r
00
ell
00
Go
,4 j,;
00 La,
f-.-5 a ..f
go
a
Ailc
go is
0
so -Sig!
of
00
00
00
*a 16-ok-66-96 00 0 0
-10, -71
MAO

'T ff5;~;~
lose *see-** 00660 6
P. t
a I I IfW
0
0
01
sit
loss ~941641-
on
*09
002
0 OW 0 0 0 0 111 000 00000 0 Is 0 0 0 0 0
, : 0 0 0 0 * 0 0 * 0 * 0 0 cle 0 0 0 0 0
0 AS a AS!
it 'a@ AV Is IS
fill.
Sllil&vf$All 11108,11IT1114 v IS' a
F
[so, 00
00*

so=
coo
Poo
Poo
002 Z;
00-

so- Nupiii-id lit
'
-
M11 '
%W Vi
-
,A
l A11v $Ili 1.11111
101A I 11A
"
i
00
.
.
,
I
I
It
t
l
%
00

pi

1
1 3 U IL "'T"n
SA.1
va
al
awa
0 14
Ain

1
1
1
l
l
q
4
so

00 itiud~ -ant I
-
-
-
--
-
-
-
-
-
00
Ir 1 7 '0
41
K W
c-ru
v
T
v
,l
1
1 T-W
I '
T
0 0 it 0 flown not *01 fill itim #(wait IrR 44 11 11 if If 0 ?1 fl 0 1 1 t I A I
s
fee

Inc y
7
tti.,
J J.
i oot.
IL
ne-t~

60(,-bNNDVA1 c) - r\, -
PHASE I BOOK EXPLOITATION 1181
Akademiya nauk SSSR. Institut fizicheskoy khimii
Problemy kinetiki i kataliza. It) IX: Izotopy v katalizeXroblems
of Kinetics and Catalysis. IvI 9: Isotopes in Catalysi M08cowJ,
Izd-vo AN SSSRp 1957. 442 P. 3,500 copies printed.
Eds: Roginskiy,S.Z., Vinogradova, O.M., Keyer, N.P. and Yanovskly,
M.I., Corresponding Members, USSR Academy of Sciences; Ed. of
Publishing House: Vasserberg., V.E.
PURPOSE: This book is for specialists interested in the theoretical
and.practical problems of the application of isotopes in catalysis.
COVERAGE: This collection of articles forms volume 9 of "The Problems
of Kinetics and Catalysis'" Most of the papers were presented at the
Conference on Isotopes in Catalysis which took place in Moscow, March
31 - April 5, 1956. Scientists from the Academy of Sciences of
Card 1/14

Problems of Kinetics and Catalysis (Cont.) n81
of the USSR., the Ukrainian Academy of Sciences, institutes of the
chemical and petroleum industries, and several vuzes took nart.
Scientists from the six people's republics Chinap GDR,,
Poland, Czechoslovakia, Hungary and Rumania also participated.
This conference was the first of its sort not only in the Soviet
Union, but internationally. Several articles which could not be
included in the program of the conference are given in the text.
Each article has figures, tables, and a bibliography.
TABLE OF
CONTENTS: From the editor 3
Roginskiy, S.Z. Isotopes in Catalysis 5
PART I. CATALYTIC REACTIONS OF HYDROGEN
Voyevodskiy, V.V. Mechanism of the Homogeneous and
Heterogeneous Homolytic Deuterium Exchange 33
Card 2/14

Problems Of Kinetics and Catalysis (Cont.) 1181
Balandin, A.A., Neyman, M.B.2 Bogdanova, 0-..K. Isagulyants, G.V.,
Shcheglova, A.P., Popov, Ye. I. Tagged-atom Study of the
Dehydrogenation of Butane - Butylene Mixtures 45
Avdeyenko, M.A., Boreskov, G.K., Slin1ko, M.G. Catalytic
Activity of Metals in Relation to the Homomolecular Isotopic
Exchange of Hydrogen 6-1
Golovina, O.A. Roginskiy, S.Z., Sakharov, M.M., Eydus, Ya.T.,
Dokukina, Ye. S. Study of the Role of Plane Chains in the
Synthesis of Hydrocarbons from CO and H2 76
Tverdovskiy, I.P., Tupitsyn, I.F. Study of the Nickel-Boride
Catalyst 84
Discussion:
R.Kh. Burshteyn 91
G.K. Boreskov 92
Card 3/14

Problems of Kinetics and catalysis (Cont.) .1181
S.Z. Rollinakiy 92
G.V. Isagulyants 94
PART II. CATALYTIC OXIDATION
Antonova, I.N., Moshkina, R.I., Nalbandyan, A.B., Neyman, M.B.,
Feklisov, G.I. Tracer Study of the Mechanism of the Reaction
of Methane Oxidation 97
Langenbeck, Wolfgang. Autoxidation of Normal Paraffins 104
Margolis, L.-Ya., Roginskiy, S.Z. Mechanism of the Catalytic
Oxidation of the Unsaturated Hydrocarbons on Metals and Semi-
Conductors 107
Miklukhin, G.P., Rekasheva, A.F. Study of the Redox Reactions
of Organic Compounds Conducted With the Aid of Deuterium 117
Card 4A4

Problems of Kinetics and Cgt&1yqis,(Cqnt.) 1181
Vartapetyan, B.B. Use of the Heavy Isotope of Oxygen 018
in the Study of Biological Oxidation in Plants 124
Yelovich, S. Yu., Margolis, L.Ya. Connection Between the Ion
Mobility in the Oxide Lattice and the Rate of Isotopic Exchange 129
Stukanovskaya, N.A... Royter, V.A.,, Vaynshteyn, F.M. Explanation
of the role of oxygen of vanadium catalysts in the Oxidation of
Sulfur Dioxide (theses) 133
Discussion:
R.I. Moshkina 134
Ye. As Shilov 134
G.K. Boreskov 135
N.S. Yenikolopyan 135
B.P. Bruns 137
F.M. Vaynshteyn 139
Card 5/ 14

Problems of Kinetics and Catalyqis (Cant.) 1181
S.Z. Roginskiy 140
A.F. Rekasheva 141
SECTION III. CATALYTIC CRACKING OF
HYDROCARBONS
Panchenkov, G.M., Gryaznova, Z.V.,,Yemel'yanova, V.M., Ganichenko,
L.G. Conversion of Hydrocarbons on Deuterated Aluminosilicate
Catalysts 145
Andrianova, T.I., Roginskiy, S.Z. Study of the Mechaniam of
the Conversion of Alkanes on an Alum nosilicate Catallsid With
the Aid of Molecules labeled With Clk 152
Dorogochinskiy, A.Z., Mel'nikova, N.P., Shakhzadova, I.A.
Deutero-hydrogen Exchange of Certain Hydrocarbons on Alumino-
silicate Cracking Catalysts 162
Card 6/14

Problems of Kinetics and Catalysis (Cont.) 1181
Discussion:
S.Z. Roginskiy 168
G.M. Panchenko 168
I.I. Starostin 170
SECTION IV. OTHER CATALYTIC REACTIONS
Vinogradova, O.M., Keyyer, N.F., Roginskiy, S.Z. Study of
the Mechanism of Divinyl Synthesis by the Method of S.V. Lebedev
With the Use of Radioactive Carbon 175
Zhabrova, G.M., Kadenatsi, B.M. Study of the Coke Formation and
Divinyl Polymerization on the Catalyst of S.V. Lebedev 187
Brezhneva, N. Ye., Roginskiy, S.Z. Radiobromide Study of the
Mechanism of Homogeneous Catalytic Bromination and Isomerization
of Bromides 201
Card 7/14

Problems of Kinetics and Catalysis (Cont.) 1181
Discussion:
A.F. Rekashevs. 215
G.V. Isagulyants 215
SECTION V. ISOTOPIC E(CHANGE
Shatenshteyn, A.I., Zvyagintseva, Ye. N., Yakovleva, Ye-A.,
Izrailevich, Ye. A.., Varshavskiy,, Yao M., Lozhkina, M.O.,
Vedeneyev A,V. Acid-Base Cata.17sis of the Reaction of Isotopic
Hydrogen Axchange 218
Setkina, V.N., Xurbanov,'.D.N.,, Bylcova.,.Ye. V. Carbbnyl lons in
the Hydrbgeo Exchange Re&btions 234
Kursanov., D.N., Setkina, V.N., Vitt* S.V.j Parnes, Z.N. Study
of the Mechanism of Certain Reactions by the Method of Hydrogen
Exchange 242
Card 8/3.4

Problems of Kinetics and Catalysis (Cont.) 1-181
Brodskiy, A.I., Vysotskaya, N.A. Oxygen Exchange in Inorganic
Acids and Salts 245
Rozen, A.M., Karpacheva, S.M., Shavelev, Ya. V. Oxygen Mobility in
Oxides and the Kinetics of Oxygen Exchange 251
Spitsyn, Vikt. I. , Finikov, V.G. study of the Isotopic Exchange
Between Gaseous Oxygen and Salts cf Certain Oxygen-containing
Acids at High Temperatures 264
Oziraner, S.N. Isotopic Exchange Between a Solid and a Gas 267
Discussion:
Ye. A. Shilov 274
A.I. Shatenshteyn 275
A.I. 13rodekly 27
V.N. Setkina 272
Card 9/14

Problems of Kinetics and Catalysis (Cont.) 1181
A.N. Frumkin 276
A.I. Brodskiy 277
S.Yu Yelovich 278
S.M. Karpacheva, 278
A.I. Brodskly 28o
SECTION VIo STUDY OF CATALYSTS BY THE ISOTOPIC METHODS
Ke-yer, N.P., Isotopic Data on Active Surfaces of Catalysts P-83
Krylov, O.V., Fokina, Ye.A. Study of Sulfide Stability in the
Catalytic Deepipposition, of Isopropyl Alcohol wih the Use of
Radiosulfur~sx) 294
Krylov, O.V., Fokina, Ye.A. Study of the Acid-base Properties
of Catalytic Surfaces by the Differential Isotope Method 304
Card 10/14

Problems of Kinetics and Catalysis (Conto) n81
Starik, I.Ye., Melikova, O,S* Emanation as a Criterion of
the So'lid State(theses) 314
Protashchik, V.A. Determination of the Surface of Macnesium
Oxide Formed During the 'Thermal Decomposition of 9 Carbonate From
the Chemisorption of Radioactive Carbon Dioxide C140 2 315
Murin, A.N., Lurlye, V.G. Electric Conductivity and Diffusion
in Silver Halide Samples Subjected to Plastic Deformation 321
Korneychuk, G.P., Royter, V.A., Stukanovslmya, N.A., Rzayev,
P-B., Zhigaylo, Ya. 1r. Study of the Effect of the Conditions
6f:Catalysis on the Sulfur Conteht in the Barium-Aluminum-
Vanadium Sulfate Catalyst 32n-1
SECTION VII,. THE ISOTOPE EFFECTS
Tatevskiy, V.M. Methods for the Statistical Computation of the
Isotopic Exchange Equilibrium in the Gaseous Phase 339
Card 11/14

Problems of Kinetics and Catalyd18,(Gftt,) 1181
Mayants, L.S. Calculation of the Isotopic Shift in the Zero
Vibrational Energy of Polyatomic Molecules from Spectroscopic
Data 345
Lifshits, I.Me. Stepanova, G*I. The Thermodynamics of Solutions
of Isotopes 354
Brodskiy, A.I. Connection Between the Kinetic Isotopic Effect
and the Isotopic Conterit Variation in the Course of the Reaction 360
Varshavskiy,. Ya. M. Effect of the Thermodynamic Isotopic Effect
on the Kinetics of Exchange Reactions 3-63
Discussion:
S.Z. Roginskiy
A.I. Brodskiy
Ya. M. Varshavskiy
369
370
370
Card 12/14

Problems of Kinetics and Catalysis (Cont.)
SECTION VIII. PHYSICAL AND PHYSICOCHEMICAL RESEARCH METHODS
Gragerov, I.P. Rapid Mass Spectrometric Method for the Isotopic
Analysis of Oxygen in Organic Substances 373
Panchenkov, G,M., Akishin, P.A,, Vasillyev, N.N. Mass Spectrometric
Study of Aluminosilicate Catalysts 378
Karpacheva, S.M., Rozen, A*M. Method of Total Isotopic Analysis
of Water 386
Yanovskiy, M.I. , Kapustin, D.S., Nogotkov7Ryutin',V*A. Method
of Rapid Determination of Molar Radioactivity in Conjunction with
the Chromatogft-phy of Gases Labeled with C14 391
Brodskiy, A.I., Kalinenko, R.A., Lavrovskiy, K.P. Application of
Adsorption Methods to the Analysis and Separation of Gaseous
Hydrocarbons in the Study of Kinetics Witlt-th*.Aid of Tracers 399
Card 13/14

'Problems of Kinetics and Catalysis (Cont.) -1181.
daziyev, G*A., Yanovskiy, M.I. A Radiometrie Cell for
Measuring the Radioactivity of Gas-es During the tilufhetric-a
Chromatographic Separation of Mixtures 405
SECTION IX. SYNTHESIS OF TAGGED SUBSTANCES
Roginskiy., S.Ze, Basic Procedure in the Chemical Synthesis
of Compounds With Unusual Isotopic Composition 411
Kukhtenko, T..I. Synthesis of Certain Labeled Organic Compounds 423
Shatenshteyn, A.I., Izrailevich, Ye. A. Preparation of Deuterdt6d
Organic Compounds 430
AVAILABLE: Library of Congress
TM/ksv
1-26-59
Card 14/14

alit!
110

~,IAJW-V. It lVal,l ~,mwjl Ilia; un- nnj,~--., pan cu, j~
!vripril as n of thr ill mpu. vf di-On3i. L,

0
BOGDANOVA K.;, BALANDIN, A.A.; SHMWWVA, A.P.
Bffect of the structure of alcoholizoleculas on the kinetics
of their dehydrogenation. Izv.AN SSSR.Otd.khimnauk. no-7:787-794
Jl 157. (MIRA 10:10)
l.Inatitut organichaskoy khimii im, N.D. Zolinskogo AN SSSR.
(Alcohol) (Dehydrogenation)

BOG=VA, O.K.; BAUNDIN, A.A.t SHCFEEGLOVA, A.P.
Effect of the structure of alcohol molecules on the kinetics
of their dehydrogenation. Report No. 2: Alcohols C4- G~*
Izv. AN SSSR.Otd.khim.nauk. n0-7:795-800 Jl 157. MIRL 10:10)
l.Institut organicheskoy khimii im. N.D. Zelitskogo AN SSSR.
(Alcohol) (Dah7drogenation)

Cr T, 4 No Y)q,, ori
BALANDINO, A,A,; BOGDANOVA, OK,; SHGIWIA)VA, A.P.
Hffect of the structure of alcohol molecules on the kinetics of
their dehydrogenation. Report No-31- Comparing the results obtained
for different alcohols* Izv. AN MR. Otd. kh1m, neuk n0,8;909-915
Ag 157. (MIRA 11:2)
1. Inatitut organicheakoy khimit Im. N.D. Zelinskogo AN SSSR.
(Alcohols) (Chemical structure) Oehydfogenation)

.b~
t) 6 6- p/9 JV L-3414 0 , K, ,
BAIANDIN, A.A*: ~J;L,~. M,B*; BOGDANOVA, O.K.; ISAGULYMS. G.V.; SRCHJDWVA,
A.P.; POPOV* YS.I'
Dehydrogenation of butane - bntyleus mixtures using tagged atoms,
Probl..kine' i kat. 9:43-60 '37. (MIRA 11:3)
(Dehydrogenation) (Butane)

AUTHORS: Balandin, A. A., 3o-d--ava 0 K 62-1-4/23
-- I$
Isa,gulyants, G. T._,anyman! 1". B. , Popov, Ye. I.
TITLE: The Application of Radioactive Carbon in the Comparison
Between the Dehydrogonation Velocities of Butane and Butylene
(Primononiye radiougloroda dlya sravneniya 3kcrostoy
dogidrogenizatsii butana i butilena),
PERIODICAL: Izve-tiya AN SSS2 Otdeleniye Ahimichookikh Nauk, 1958, Nr 1,
pp., 18-23 (US3R)
ABSTRACT: The investigation (with the application of c14) was carried
out by means of a special catalyst under conditions especi-
ally favorable for tho obtaining of divinyl. Sinco it turned
U
out that divinyl can be formed from butylene and that butane
cannot be transformed into divinyl, it was concluded that the
reaction (d4virql from butane) passes only throuSh the atc-ge
of the formation and desorption of butylene. Therefore the
desorption of butylene cannot be a final stage of the entire
reaction. The author3 report on the carrving out of the in-
vostigation: The correlation between the dohydrogenition
velocity of butane and butylono in divinyl at the chromium
catalyst was found by maans Of COMPUtLtion3 -corresponding
Card 1/2 to the experimental data obtained already before. It was

The Apl,lication of Radioactive Carbon in the Co..lparisor. 6) 2-1 -Z/2 9
Between the Dehydrogenation Velocitii~s o-f Butanc und Butylene
shown that the ratio of the velocities of the dehydroeen-
ation of butane in butylone and of butane in divinyl is for
both catalysts of tho =iu order and corresponds to the
ratio 20:1. In the experiments with chromium catalysts the
velocity ratio in the formLtiori of divinyl from butane
corresponded to 1:1000 and in the experiments with an alurio-
chromium catalyst to 1:25- Furthermore it was confirmed that
the formation of divinyl fro,-,i butane takes place over the,
atage of the forination. of butylene. It was shcwn thut the
constants (in the denominator of the kinetic equation of de-
hydrogenation) repro3ant adjorption,coeffioients. There are
6 fi(mres, 4 tables, and 5 rei ure rice 3, 4 of which are ~31avic.
ASSOCIATION; Institute of Or-anic Chemistry imoni 11. D. Zelinskiy
t~ , AS USSR
(ln3titut ur,~-anichoskoy %himii imeni N. D. Zelinskogo
Akadom,ii nauk SSSR).
SUBLITTED: Janul'-rY 4 ~ 1957
2. Butylene-Dehydrogenation
ydrogenatio.n
-d 2/2 CPr'bon' otopo Chromium
is s (Radioactive)-Applications 4.
catalyst-Applications

C 0~6 AA) 0 A 6. ff ,
AU` THORS t Balandin, 1". A -) Academician 2o-2-3o/60
Bogdanova, 0. K-, Shcheglova, A. P.,
TITLEs On Free Energy, Heat, and Entropy of the Adsorption Displacement
of Alcohols from the Surface of an Oxide Catalyst by Means of
Water (0 evobodnoy snergii, toplote i entropii &&orbtsionnogo
vyteaneniya spirtov vodoy a poverkhnosti okisnogo kattlizatora)
PERIODICALs Doklady AN BSSR, 1958, Vol. 118, Nr 2, PP. 312-314 (USSR)
ABSTRACTt This work examined the kinetics of dehydrogenizing of binary
mixtures of normal structured primary alcohols by water by means
of an oxide catalyst. The authors ascertained the coefficients
of relative adsorption of water and examined the dependence of
these quantities on the length of the carbon chain of alcohol.
-K-propyl alcohol, It - butyl alcohol, and It -hexyl alcohol were
examined. The intial mixtures alcohol-water were produced by
addition of water to a dosed quantity of alcohol. The experiments
were made in the temperature interval of from 3oo - 3600C. The
data obtained here are grouped 'in a table. Another table contains
the values of the coefficients of the relative adsorption of
Carcl 1/3 water, which were computed for the experimental data by a formula

On Free Energy, Heat, and Entropy of the Adsorption Displacement 2o-2-36/6o
of Alcohols From the Surface of an Oxide Cat4lyst by Means of Water
which is given here. The coefficient of the relative adosorption
of water decreases in the case of increasing temperature. The
addition of water deminishes the velocity of dehydrogenisation
of alcohol by more than 45~ at a temperature of 32oP C. In case
of inoreasing temperature the slowing-down effect of water de-
creases. This mekes it possible to draw the following aonclusions:
The steam gets adsorbed by the catalyst the more, the lower the
temperature. The coefficients of adsorption of water at the ac-
tive centers of the catalyst are, in the examined temperature
interval, in the case of water 3,5 to 1,3 times as high as in
the case of alcohol. The coefficients of adsorption of water at
the various values, mentioned above, have similar values. From
the results of the experiments which were obtained here, the fol-
lowing appearst The coefficients of absolute adsorption of w&ter-
alcohols are, in case of primary alcohols of normal structure
a function of temperature and do not depend on the length of the
carbon chain of the alcohol..There are 2 figures, 2 tables'9--
and 5 references, 4 of which are Slavic.
Card 2/3

On Pro* Energy, Heat, and Entropy of the Adsorption Displacement 2o-2-3ol"40
I of Alcohols From the Surface of an Oxide Catalyst by Means ofWater
ASSOCIATIONs Institute for Organic Chemistry imeni N.D. Zelinskiy All USSR
(Institut organioheskoy khimii im. N.D. Zelinskogo Akademii
nauk SSSR)
SUBVITTEDt August 23$ 1957
AVAILABLE# Library of Congress
Card 3/3

SOV/ 2o-.12o-2 .1~9/63
kUTHORS: Balandin, 1. L., Member, Academy of Sciences, USSR:
Bogdanova, 0. X., Shcheglova, A. P.
TITLE: '_Fhe P_ro_d_u_c_t1-on_'of Isoprene by Catalytic Dehydrogenation
of Isopentenes *
(Polucheniye izoprena putem kataliticheskoy 6egidrogenizat-
sii izopentenov)
PERIODIUL: Doklady Akademii Nauk SSSR, 195a, void 12o, Nr 2,
pp. 297-300 (USSR)
ABSTUCT: This synthetic production in connection with the polyme-
rization of isoprene and the production of isoprene-rub-
ber with better properties than natural rubber makes the
method of isoprene production a problem of topical inter.a.
est. Cheapest and most promising are mineral oil and its
derivatives as raw material. The mineral-oil industry
disposes of considerable supplies of isopentane and iso-
pentenes which can be utilized for the above-mentioned
purpose by the method mentioned in the title. The con.-
ditions of reaction according to publications (References
1-4) are given. Por determining the optimum conditions
Card 1/2 the authors investigated this reaction at different tem-

The Production of Isoprene by Catalytic Dehydrogenatioii SOV/20-120-2-19/63
of Isopentenes
peratures and supply velocities of isopentenes as well
as by different dilution with steam. The results are
given in table 1 and figures 1-3,, The best conditions
for the dehydrogenation of isopentenes to isoprene are:
temperature 58o-62oOC, supply velocity per I liter cata-
lYst 5000-8000 ml/hour, and dilution with steam I ! 2,3-373
(by weight). The catalyst does not need regeneration for
a longer period of time. Experiments of results were also
made at 6ooOC and supply velocities of 67oo-72oo ml/liter/
hour as vell as a stea;n dilution of 1 t 3. The results
are given in table 2. Finally the kinetics of the reac-
tion was investigated and a velocity constant of 4~3
ml/min at 53oOC and 12,25 mi/min at 5900C was determine6,
The activation energy of the reaction is equal to 23,.3
Kcal/mol.
There are 3 figures, 2 tablesand 5 ref-erences, I of
which is Soviet.
ASSOCIVIONs Institut organicheakoy khimii im. N. D. Zelinskogo
kkademii nauk SSSR (Institute of Organic Chemistry imeni
N. D. Zelinskiy.,IS USSR)
SUBMITTED: Marc 79 1958
Card 2/~ 1. Isopentenes--Dehydrogenation 2. Isopentenes-Polymerization
3. Synthetic rubber--Production 4. Mineral oils--Applicationo

SOV/62-59-2-27/40
AUTHORS: Bogdanova, 0. K., Shcheglovap A. P., Balandin, A. A.
TITLE: Catalytic Dehydrogenation of Isopentane-Isopentene Mixtures
(Kataliticheskaya degidrogenizatsiya izopentan-izQpentenovykh
smesey)
PERIODICALt Izvestiya Akademii nauk SSSR. Otdeleniye khimichesk:lkh nauk,
1959, Nr 2, pp 350-352 (USSR)
ABSTRACT: In this news in brief the authors report on the dehydrogenation
of isopentane-isopentene mixtures by means of the continuous
flow method in a device described in reference 1, The results
obtained showed that the dehydrogenation of isopentand-iso-
pentene mixtures can be carried out'on the "chromo-aluminum"
catalyst by dilution with steam. Optimum conditions are:
6oo-6200, flow rate 5000-6000 ml/l per hou_-, dilutions with
steam in a weight ratio of 1:3- Under these conditions the
yield of isoprene is 38-40% of the initfial isoperitenet; and
88-92% of the reacted, mixture. The high yield of isop-rene
indicates that no decomposition of hydrocarbons takes place
under the influence of steame The catalyst is distinguished by
Card 1/2 a considerable selectivity and is able to operate for some time

SOV/62-519-2-27/40
Catalytic Dehydrogenation of Isopentane-Isoper-tene Mixtures
without regeneration. Th6 mixtures used were produced in the
laboratory of 3. A* Kaza-iskiy and N. I. Shuykin.
There are 1 figure, 3 tables, and 3 references, 2 of which
are Soviet.
ASSOCIATION: Institut organiche8koy khimii im. N. D. Zelinskogo Akadem-'Li
nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy
of the Academy of Science ,s, USSR)
SUBMITTED: July 4, 1958
Card 2/2

5(4)
AUTHORS: T1nadaaQy&t_Q, K., Balandin, A. A., SOV/62-59-8-5/42
Shcheglova, A. P.
TITLE: Effect of the Structure of Alcohol Molecules on the Kinetics
of Dehydrogenation. Communication 4: Catalytic Dehydrogena -
tion of Benzyl Alcohol
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimiaheskikh nauk,
1959, Nr 8j pp 1372-1377 (USSR)
ABSTRACT: A flow system described in (Ref 1) was used for the investi-
gation of the dehydrogenation kinetics. The constancy of
catalytic activity was checked in the course of the experiment
by means of benzyl alcohol and a mixture of benzyl alcohol
and its reaction products. The benzaldehyde contents of the
catalyst were determined by the method described in reference 4.
The reaction rate was determined from the amount of hydrogen
separated out per time unit. The two determinations were in
good agreement. The reaction was investigated at 4 different
rates of passage (1.02, 1.23, 1.33, and 1.8 ml in 5 min). The
benzaldehyde yield increased from 8.2% to the predetermined
yield of 61%. The results are compiled in table 1. The cal-
Card 1/3 culated degree of dehydrogenation and benzaldehyde yield are

Effect of the Structure of Alcohol Molecules on the SOV/62-59-8-5/42
Kinetics of Dehydrogenation. Communication 4: Catalytic
Dehydrogenation of Benzyl Alcohol
in agreement. In order to investigate the mixture mentioned
above the adsorption coefficient of benzaldehyde was deter-
mined during the reaction. (Results in Table 2). it is stated
that the reaction is slowed down when benzaldehyde is added.
A temperature increase results in a reduction of the adBorp-
tion coefficient. A change in the initial mixture of benzal-
dehyde and benzalcohol does not effect the adsorption coef-
ficient. With high passage rates it is reduced, but becomes
constant with particularly high rates (Table 4). According to
formula (1) A - -RT ln.Z2 (22 adsorption coefficient of benzal-
dehyde) the heat content and entropy in the adsorption dis-
placement of the alcohol by the aldehyde were determined. When
the dehydrogenation temperature is increased the aldehyde yield
can be increased greatly. This may be of practical value in
the preparation of benzaldehyde. There are 4 figures, 4 tables,
and 5 references, 4 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk
SSSR) Institute of Organic Chemistry imeni N. D. Zelineldy of the Academy
Card 2/3 of Sciences, USSR)

Effect of the Structure of Alcohol Molecules on the SOV/62-59-6-5/42
Kinetics of Dehydrogenation. Communication 4: Catalytic
Debydrogenation of Benzyl Alcohol
SUBMITTED: November 20p 1-957
Card 3/3

5(3) SOV/79-29-7-23/83
AUTHORS; _Bogdanova,~~ ~.,Balandinj A. A.f Shcheclova, A. P.
TITLE: Preparation of Butadione by Catalytic Dehydrogenation of Butane -
butylono LlixtureB in the Presence of Steam ( Poluchon-iye
butadiyena kataliticheskoy degidrogenizatsiyey butan-
butilenovykh smesey v prisutstvii parov vody.)
PEnIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 7t pp 2204-2212 (USSR)
ABSTRACT: One of the most important methods of synthesizing butadiene is
the catalytic dehydrogenation of butylene into butadiene.
Butylene may be obtained from cracking gases and in petroleum
pyrolysis or by dehydrogenolysis of butane. In this connection,
however, butylene is obtained in a mixture with butane so that
this mixture must be fractionated in the presence of a third
component. Industrial preparation of butadiene should practi-
cally be carried out without separating butylene from butane in
the above mixture. Earlier (Ref 1) the authors investicated the
dehydrogenolysis of butano-butylone mixtures over a chromium
catalyst at reduced pressure and obtained good yields in
butacliene. Some patents (Refs 2-4) offered only low yields.
The authors of this paper tried to investigate the effect of
Card 1/2 steam on the dehydrogenolysis of butane-butyleno mixtures,

Preparation of Butadiene by Catalytic Dehydrogenation of SOV/79-29-7-23/83
But6~he butylene Mixtures in the Presence of Steam
viz over a catalyst suited for dehydrogenolysi6 carried out in
the presence of steam since the latter ic the most convenient
diluent. Steam is known to favor, in the presence of some
catalysts and at increased temperatures, the cracking process
of hydrocarbons. Dehydrogenolysis of the above mixtures may take
place in the presence of steam over an oxide catalyst for the
dehydrogenolysis of butylene. Under these conditions the
butadiene yields were 40% computed for the butylene passing
through, and 75-0a;la computed for the reacted mixture. It is
not necessary to regenerate the catalyst also after longer
usage. The chromium-aluminum catalyst retards the dehydrogenolyda
of butane into butylene in the presence of steam and converts
the latter partially into decomposition products. Without cliluent
at 6350 the butadiene yields over the same catalyst were 11.61ifol
computed for the mixture passed through, in this case the
catalyst had to be regenerated several times. There are 4
figures, 5 tables, and 10 rorerences, 6 of which are Soviet.
ABSOVIATION: Institut organicheskoy khimii Akademii nauk SSSR (Institute of
Organic Chemistry of the Academy of Sciences, USSR)
SUM, TTED: April 15, 1958
Card 2/2

'S7 \7.2 66861
544 SOV/76-33-11--16/47
AUTHORSs Balandin, Ae Ao Bogdanova, 0. K Shcheglova, A* Po
TITLE: Influence of the Structure of Alcohol Molecules on the Kinetics
of Their Dehydrogenationq
PMODICALs Zhurnal fizicheBkoy khimiip 1959P Vol 33P Nr 11, pp 2476-2479
(USSR)
ABSTRACT: The dehydrogenation kinetics of the following alcohols was in-
vestigated on oxide catalyststiethanolt n-propanol, n-butanol,
allyl alcoholf isoamyl alcohol, isopropanol, benzyl alcohol,
and P-phenyl ethyl alcohol. The experiments were carried out
by means of a device and method earlier described (Ref 1). The
reaction constants of alcohol dehydrogenation obtained (Table 1)
increase from allyl lcohollto benzyl alcohol.1 The values of the
free energy of displacement from the active catalyst surface
and of the change AR are litted (Table 2). Moreover, the
authors explain the affect of the structure on the activation
energy (Ref 3) and the variation in the heat of adsorption dis-
placement and entropyo In additior4they found that the strueture
has some effect* Accordingly, an extension of the hydrocarbon
Card 1/2 chain in the primary alcohol leads to a decrease of the acti-

66861
SOV/76-33-11-16/47
Influence of the Structure of Alcohol Molecules on the Kinetics of Their De-
hydrogenation
vation energya Replacement of the hydrogen by a phenyl group in
P-position increases the activation energy by 0-3 kcal. However,
if the phenyl group is found on the same carbon atom as the
hydroxyl group, the activation energy decreases. A parallelism
was observed between the variations in entropy (hs) and
enthalpy (4H) (Fig 2) in adsorption displacement of the alcohol
molecules by corresponding aldebydes or ketones from the catalyti-
cally active centers which occurs during alcohol dehydrogenation.
This parallelism was observed for the first time in adsorption
proceaveae A logarithmic dependence between activation energy
and-reaction constant was found. There are 2 figures, 2 tableat
and 10 Soviet references,
ASSOCIATION: Akademiya nauk SSSR Institut organicheskoy khimii im. N. D. Ze-
linskogo (Academy o~ Sciences USSR9 Institute of Organic
Chemistry imeni N, D. Zel
Card 2/2

AUTHORSt Shcheglova, A. P., Balandin,
nova,_'01,
TITLEi Kinetics of Dehydrogenatiol
PERIODICALt Doklady Akademii nauk SSSR,
PP 1071 - 1074 (USSR)
67920
SOV/20-129-5-30/64
A. A., Academician,
of Isopentenesi
1959, Vol 129, Nr 5,
ABSTRAM In one of their previous papers the authors had dealt with
the investigation of the dehydrogenation kinetics of buty-
lene on a mixed oxide catalyst (Ref 1). Equation (1) holds
for the results obtained (Ref 2). It, however, holds also
for the dehydrogenation of alcohols on an oxide catalyst
(Ref 3). Of late, the catalytic dehydrogenation of isopen-
tenes has been acquiring great practical importance as a
method of producing isoprene for the caoutchoue synthesis.
The authors had earlier (Ref 4) determined,the conditions
of isopentene dehydrogenation under dilution with steam on
an oxide catalyst. The same catalyst served for the investi-
gation under review. It was confirmed by special experiments
that steam does not influence the reaction rate on diluting
Card 1/4 the isopentenes'(Fig 1). steam acts in a similar way as the

Kinetics of Dehydrogenation of Isopentenes
Card 2/4
67920
SOV/20-129-5-30/64
inert gases nitrogen and argon. The principle supporting
the method was desoribed in referenae 4. Isopentenes were
obtained by the dehydrogenation of isoamyl alcohol on alu-
minum oxide. The experiment was made with the fraction
having a boiling temperature at 31-380; it contained 2-me-
thyl butene-I and 2-methyl butene-2. Experinents with pure
isopentenes were carried out at 520-6000. Table 1 shows
the results obtained. As may be observed thercfrom the re-
action runs without the formation of appreciable amounts
of decomposition side products. Experiments with isopentenes
and isoprene were carried out between 530 and 5800. These
mixtures contained 22.2 mol% of isoprene. Data obtained
are given in table 1. On comparing the data obtained from
mixtures with those of isopentenes it may be observed that
the degree of transformation of the latter into isoprene is
much lower in the case of mixtures than with pure isopentenes.
Isoprene is adsorbed more strongly on the active centers of
the catalyst, and inhibits the reaction. Figure 2 shows the
dependence of the relative adsorption coefficient Z2 of iso-
prene on temperature, calculated on the basis of formula (2)z
Table 2 summarizes the data concerning the determination of

6792
Kinetics of Dehydrogenation of Isopentenes SOV&-129-5-30/64
z3 (relative adsorption coefficient of hydrogen). As may
be seen from table 2, Z 3 a 0.8 holds and is independent
of temperature. Thus, hydrogen is adsorbed on the catalyst
almost as strongly as isopentene. On the strength of data
obtained, rate constants were determined by the aid of
equation M- At 5300, 5400, 500, and 5800 the constants
are 4-3; 5.4; 7.7; and 10-7. The corresponding activation
energy is 23.3 koal/mol. Figure 3 shows the dependence
between 1g k. and the reciprocal temp.erature. The points
are situated on a straight line.'The Arrhenius equation
is satisfied. On -' the.strength of the known formulas (Ref 3)
the authors calculated the change of free energy, of heat
capacity, and of entropy of the adsorptive displacement
(Table 3). The authors state that isopentenes are more
quickly dehydrogenated than butylenes. Butadienelis more
strongly adsorbed on the active centers of the catalyst than
isoprene.1 There are 3 figures, 3 tables, and 4 Soviet ref-
erenoes.
Card -3/4

Kinetics of Dehydrogenation of Isopentenes
67920
SOV/20-129-5-30/64
ASSOCIATIOR.- Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.-Ze-
linskiy of the Academy of Sciences, USS ) el"'
SUBMITTED: August 2, 1959
Card 4/4

~ 57 68162
4(_4
AUTHORS: Bogdanova,__..O._K.9 Shcheglova, A. P., SOV/20-129-6-26/69
B61 and am i c i an
TITLE: Kinetics of DehydrogenatioA of Butylene
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 129, Nr 6, pp 1291~ - 1296
(USSR)
ABSTRACT-. The authors proved in a previous paper (Ref 3) that butadiene
is adsorbed on the aluminum chromium catalyst, that the relative
adsorption coefficient of butadiene is high, and that its numer-
ical value inoreases with decreasing temperature. In their in-
vestigations of butylene dehydrogenation, N, A. Shcheglova and
S. Ya. Pahezhetskiy (Ref 4) found a deviating equaziun k?) which
IS Similar I., -,,UcLv.Lon (1) of the authors (Ref 3). Absorption
was not considered in deriving equation (2), and it was main-
tained that the addition of hydrogen and butadiene does not re-
markably influence the reaction rate. This contradicts the au-
thors' assumptions mentioned in the beginning. The paper under
review describes the investigation of the kinetics mentioned in
the title on a mixed oxide catalyst. The investigations were
carried out in a device described earlier (Ref 6). The a-buty-
Card 1/3 lene used contained about 71*' of 0-butylene. The pure butylene

Xinetics of Dehydrogenation of Butylene
Card 2/3
68 1,62
SOV/20-129-6-26/69
as well as butylene-hydrogen-butadiene mixtures were diluted
with steam (I : 10 m01). The hydrogen content was varied from
21.8 to 75 mold (Table 1). Figure 1 shows the curves of buty.-
lene displacement by hydrogen at 6000 (a) and at 6200 (b).
Table 2 shows the dehydrogrenation rates of the mixtures buty-
lene-butadiene at 5BO, 600, and 6250. The butadienelcontent
was varied between 26.4 and 9Zfa. It appeared. that butadiene is-
formed as well as disintegrated in the catalyst. Its decomposi
tion increases with temperature and 'Ata increase in the mix-
ture (Fig 2:1,2). The correction with regard to butadiene dis-
integration was determined from the results and considered in
the data on the reaction of butylene-butadiene mixtures. The
curves 3 (Fig 2) were found by subtracting curves 2 from
curve 1. The relative adsorption coefficients were computed
according to formula (3). For butadiene, this coefficient
z 4.9 at 5600. It decreases at 6200: z2 - 2.9. For hydroCen,
z3 0.8; it depends on temperature between 560 and 6200. Steam
does not influence the reaction rate. The reaction constant -
- 7.26 at 5800, 9.3 at 6000, and 12.1 at 6200. Figure 3 shows

Kinetics of Dehydrogenation of Butylene
15WAO--if 29-6-26/69
the linear dependence between log kc and the reciprocal absolute
temperature. The activation energy, computed from the velocity
constants (k 0), was 19.1 koal, the pre-exponential term of the
ArrheniuB equation was 5 75 The change of free energy, of heat
capacity, and of ent (T;ble 3)p as well as the displacement
of butylene from the active catalyst centers by butadiene due
to adsorption (Table 3), could be computed from the adsorption
coefficients and their temperature dependence according to known
formulas (Ref 7). The adsorption coefficients of butylene, buta-
diene, and hydrogen (equation (1)) are I : 4.9 : 0-8 at 5600,
and I : 3.7 : 0.8 at 6000a The names of Podbilfnyak and
Bushmarin are mentioned in the text. There are 3 figures,
3 tables,ana 7 Soviet references.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelins
of the Ace. em o Scienceep USSR)
SUBMITTED: August 2, 1959
Card 3/3

S/595/60/000/000/009/014
E134/E485
AUTHORS: Balandin, AoA., jBong~dano Shcheglova, A.P.
TITLE: Catalytic dehydrogenation of isopentenes to isoprens
SOURCE: Vsesoyuznoye soveshchaniye po khimicheskoy
pererabotke neftyanykh uglevodorodov v poluprodukty
dlya sinteza volokon i plasticheskikh Mass. Baku, 1957,
Baku, Izd-vo AN Azerb. SSR, 1960. 233-239
TEXT: The paper is concerned with the catalytic dehydrogenation
of isopentenes and the conversion of isopentane-isopent-enes
mixtures to isoprene as part of the general problem of
manufacture of isoprene rubber from the isopentane fractxon in
petroleum, The authors studied dehydrogenation of isopentene and
isopentane-isopentenes mixtures in the presence of steam at
atmospheric pressure. Artificial mixtures as well as mixtures
obtained by dehydrogenation of isopentane on an Al-Cr catalyst
were used. The experiments were carried out by continuous flow
over a mixed oxide catalyst. Work on isopentene was concerned'
with the effect of temperature, flow rate and steam dilution ratio
on isoprene yield. Yield based on isopentene feed increased from
14.5 to 36% as temperature rose from 540 to 6200C but dropped from
Card' 1/f

S/595/60/000/000/009/014
Catalytic dehydrogenation E134/E485
92 to 85% of 'the reacted isopentene, Curves sho!-,ting the effect of
temperature and flow rate on isoprene yield are given (Fig,l and 2),
Best dilution ratios are 1;2 or 1:3 by weight. A complete mass
balance for operation with a li3 ratio at 600"C at a rate of
4500 g/litre catalyst/hour is given. Under these cir:u;-,ts+-an-,.e,,6,,
yield is 28 to 30% on feed'and 88 to 92% on reacted Isopentene,
The removal of carbon from the catalyst in the form of carbon
dioxide makes prolonged reaction without regeneration possible.
The results show that the catalyst acts selectively,
Investigations of mixtures 55% isopentane-45% isopeniene werv
carried out under identical conditions to study the effe-t of flow
rate and temperature, Conversion of mixture and yield of i3oprer6
increased with rising temperature but yield of isoprene ba,;~-::d on
reacted isopentene dropped from 94 to 86.5%- A full analysiz i.~
given. At 600*C, a flow rate of 4400 g/11tre catalyft/houx and
1:3 dilution ratio yield of isoprene on isopentene present was
38 to 40% and was more than 90% of the rea-,-~ed isopentene~ Un?.5-z
identical conditions dehydrogenation of isopentane To isops-n-!en-~
only to place to the extent of 4 to 65'0 ~J~ere is no ixre-,~
Card 2/1