SCIENTIFIC ABSTRACT BOGDANOV, S. V. - BOGDANOV, V. I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000205820020-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 9, 2000
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

SOV/79-29-1-31/74
Investigation in the Field of the Oxy-Derivativas of Anthracene. II. The
Bisulfite Compound of the 1-Nitroso-2-Anthrol
5 references, 2 of which are Soviet.
ASSOCIATION: Nauchno-isaledovatellikiy inititut organicheskikh poluoro-
duktov i.krasiteley (Scientific Resea=2: Imst. of Organi-a 1hter-
med-4std Pm&cts arA DyeB)
SUBMITTED: November 25, 1957
Card 3/3

.AUTHORS: Bogdanov, S. V., Gorelik, M. V. SOV/79-29-1-32/74
TITLE: Investigation in the Field of the Oxy-Derivatives of Anthracene
(Issledovaniye v oblasti oksiproizvodnykh antratsena)
III. Transformations of the Bisulfite Compounds of 1,2-Anthra-
(31,41)-Furoxane III. PrevrashchAniya bisullfitnogo soyeAi-
R
neniya 1,2-antra_
1,41)-furoksana)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 1, PP 146-153 (USSR)
ABSTRACT: The investigations in the series of 1,2-naphtho-(3',41)-furoxane
(Ref 1) had proved that in alkaline medium a rearrangement of
the bisulfite compound of 1,2-naphtho-(31,41)-furoxane into the
,2-nitro-l-naphthylamine-4-sulfonic acid and 1,2-naphthoquinone
~dioxime-4-sulfonic acid takies place. The similarity of the
chemical properties of the bisulfite compounds of the oxy-
derivatives of anthracene and naphthalene (Refs 2,3) permits
the 'assumption that the bisulfite compound of 1,2-anthra-(31f41)-
furoxane would behave in a similar manner. The experiments
really proved that the bisulfite compbund of 1,2-anthra-(3',4')-
furoxane (I) is;transformed in alkaline medium into the 2-nitro-
1-anthramine-,4_n sulfonic acid (II), 1,2-anthraquinone dioxime-
Card 1/3 4-sulfonic acf-d (III) and 1,2-anthra-(3L,41)-furoxane (IV).

SOV/79-49-1-32/74
'Investigation in the Field of the Oiy*-Darivatives of Anthracene. III. Trans-
formations of the Bisulfite Compounds of 1,2-Anthra-(3',41)-Furoxane
Compound (II) is the main product In the soda medium, (III) in
caustic lye medium. Compound (II) Is converted on heating with
50% E2SO4 into-the 2-nitro-l-anthramine, on the action of
alkali liquors into the 2-nitro-l-anthrol-4-sulfonic acid M,
on reduction with tin chloride into the 1$2-anthradiamine-4-
sulfonic acid. The lp2-anthraquJ.none-dioxime-4-sulfonic acid
(III) is transformed on oxidation with nitric acid into the
1,2-anthra-(39.4t)-furoxane-4-sulf,:)nic acid with alkaline
liquors into the 1,2-anthra-(31,41)-furazan-4-sulfonic acid (VI),
and on reduction with tin chloride into the 1,2-anthradiamine-
4-sulfonic acid. The scheme illust:rates the transformations of
the bisulfite compounds of 112-anthra-(31,41)-furoxane in
alkaline medium. There are 2 figures and 5 references, 3 of
which are Soviet.
ASSOCIATION: Nauchno-isaledovateltakiy inetitut organioheskikh poluproduktov
I krasiteley imeni Voroshilova (Sc:Lentific Research Institute
of Orgwdc-Iut&emed1ate Products and Dyes imeni Voroshilov)
Card 2/3

SOV/79-29-1-32/74
-- %n
. ;nvestigation in the Field of the Oxy-Derivatives of .1 thracene. III. Trans-
. formations of the Bisulfite Compounds of ',2-Anthra-(31,4)-Furoxane
SUBMITTED: Rovember 25, 1957
Card 3/3

50) SOV/79-29-4-40/77
AUTHORS1 Bogdanovf S. V., Gorelik, M. V.
TITLE; Investigation in the Field of Oxy Derivatives of Anthracene
(Isaledovaniye v oblasti oksiproizvodnykh antratsena).
IV. 1-Nitroso-2-anthrol-4-oulpho Acid and 2-Nitroso-l-anthrol-
4-sulpho Acid (IV. I-Nitrozo-2-aritrol-4-sullfokislota i
2-nitrozo-l-antrol-4-sul'fokielota)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 4, pp 1225-1229 (USSR)
ABSTRACT: 1-nitroso-2-naphthol-4-sulpho acid differs greatly from the iso-
meric 2-nitroso-l-naphthol-4-sulpho acid due to the mobility of
the sulpho, group (Ref 1). It was interesting in this connection
to.synthesize and examine also the corresponding nitrosoanthrol-
sulpho acids. 2-nitroso-l-anthrol-4-oulpho acid (I) was obtained
by the authors in different wayEi: by treating the bisulphite
compound of the 1,2-anthraquinoziedioxime with hydrochloric acid;
through the effect of hydroxylataine and hydrochloric acid on the
bisulphite compound of 1-nitroso-2-anthrol; by acid hyclrolysis
of 1,2-anthraquinonedioxime-4-sulpho acid and by the reaction of
1,2-anthraquinone-4-sulpho acid with hydroxylamine hydrochloride.
Card 1/3 1-nitraso-2-anthrol-4-sulpho acid (II) was synthesized by di-

SOV/79-29-4-40/77
Investigation in the Field of Oxy Derivatives of Anthracene. IV. I-Nitroso-2-
anthrol-4-sulpho Acid and 2-Nitroso-l-anthrol-4-sulpho Acid
azotization of 1-amino-2-anthro*1-4-oulpho acid, subsequent
elimination of the diazo group and introduction of the nitroso
group into 2-anthrol-4-sulpho acid. The structure of the nitroso-
anthroloulpho acids was proved by reduction to the amino compounds
and further treatmentt nitrosoanthrolsulpho acids form colored
complexes with heavy metals and differ greatly from each other
with respect to the degree of mobility of the sulpho group.
Compound (I) is completely stable in an alkaline medium$ does
not react with aromatic amines in aqueous solutions, and changes
in diluted nitric acid into 2,4.-dinitro-l-anthrol. Compound (II)
loses the sulpho group when rea.cting with alkali lye and aromatic
amines, and is accordingly transformed into 1-nitroso-2,4-dioxy-
anthracene or 4-aryl-i-nitroso-.2-anthrol. These properties of
the nitrosoanthrolsulpho acids are similar to those of the cor-
responding compounds of the naphthalene series. There are
1 figure and 4 references, 3 of which are Soviet.
ASSOCIATION: Hauchno-issledovatellskiy institut organicheskikh poluproduktov
Card 2/3 1 krasiteley (Scientific Research Institute of Organic Inter-

BOV/79-29-4-40/77
Investigation in the Field of Oxy Derivatives of Anthracene. IV. 1-Nitroso-2-
anthrol-4-sulpho Acid and 2-gitroso-l-anthrol-4-sulpho Acid
mediate Products and Dyes)
SUBMITTEDt March 3, 1958
Card 3/3

50) SOV/79-29-9-9/76
AUTHORS: Gorelik, M. V., Rodionov, A. N., Bogdanov, S. V.
TITLE: Investigation in the Field of Anthracene Oxy Derivatives. V.
On the Problem of the Structure of Bisulfite Compounds of Nitrose
Anthrols
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 9,
pp 2852 - 2854 (USSR)
ABSTRACT: In previous reports (Refs 1,2) the bisulfite compounds of
1-nitros&--2-anthrol and 4-nitroso-l-anthrol were ascribed the
structural formulas (I) and '(II). The complementary data con-
firming the two formulas were obtained by spectral analysis.
Already earlier, the difference shown by the ultraviolet spectra
of 1-nitroso-2-anthrol, 1,2-anthraquinone dioxime, 1,2-anthra-
-01,41)-furazan'$~, 1,2-anthra-W,41)furoxan, as compared with
the spectra of th4eir bisul-fite compounds, had been pointed out
(Ref 2). A not lower change in the absorption spectra occurs
with the formation of bisulfite. cbl--ipounds of 4-nitroso-l-anthrol
(II) and of 1,4-anthraquinone dioxime (III) (Fig 1, Curves 2 and
3;- Fig 2, Curves 2 and 3). Formulas (11) and (III) explain the
Card 1/3

Investization in the Field of Anthracene Oxy Derivatives.SC'1/79-29-9-9/76 ,
V. On the Problem of the Structure of Bisulfite Compouiids of Nitrose Anthrola
spectral change as being due to the saturation of t~he C-C
bond of the quinoid ring in consequence of bisulfite affilia-
tion. To'provo this, it was necessary to compare the absorp-
tion spectra of 1)4-an*:hraquinone and 2,3-dihydro-1,4-anthra-
quinone (IV). The passage of 1,4-anthraouinone (Fig 1, Curve 1)
to compound (IV) (Fig 2, Carve 1) was found to be concomitant
with an equal change in the absorption carve, the same applying
to the formation of bisulf-,te compounds (II) and (III). The
maximum at 265-270 mp is typical of the syptem of bonds (IV),
wherein two carbonyl groups are conjugate with the aromatic
molecular part. In the derivatives of 3,4-dihydro-1,2-anthra-
quinone, in which a carbonyl group does not participate in
dow the conjugation process, the maximum shifts by 35-4o mp to
the shorter wave range. The infrared spectra of compouhds
(I) and (II) point to the valency oscillations C-H in the
groups CH 2' The same bands are also present in the spectra
of the other bisulfite compounds (I-III and V-VII) (Table).
Card 2/3 The presence of the 02 groups in the bisulfite compounds

Investigation in the Pield of Anthracene Oxy DerivaLivea. S0-1/79-29-9-9/76
V. On the Problem of.the Structure of Bisulfite Compounds of Nitrose
Anthrols
of nitroso anthrols is satisfactorily explained by formulas
(I) and (II). Thus, the ultraviolet and infrared snectra of
bisulfite compounds confirm the structure that had been
earlier suggested for them. There are 2 figures, I table,
and 5 references, 2 of which are Soviet.
ASSOCIATION; Nauchno-issledovatellskiy institut oraanicheskikh poluproduk-
tov i krasiteley iraeni Voroshilova (Scientific Research In-
stitute of Organic Intermediates and Dyestuffs imeni Voro-
shilov). Fiziko-41-himicheskiy institut imeni -Karlpova (Physico-
chemical Institute imeni Karpov)
SUBMITTED: July 25, 1958
Card 3/3

t,.xi-,-'Uivcs o.n.o plananthrene. Part 2. Zhur- 'Or-lik 5
no. 14:2)
I'a, c
4 ssleftvc,tucl I:ikiy ir-,-t iLt or_,zz- c. cs-ikh polupi odiktcv
i hrenj Voroshilc-va.
(Ph:I~nzinthrene)

BOGDANOV, S.Y.; NMCBXDP Sa.
Action of dietkorlpboophoroue acid on 1, 2-naphtboqui none. M2ur. VKM
5 no.6:713 1601, (MIRA 130-12)
1, Haucbno-looledovatellakly Institut organicbeekikh poluproduktov
i krasiteley is. K.T4.Vproshilova.
(Phosphorous acid) (Naphthoquinone)

BOGDAMOV, S.V.-, SHIMMLY31TA, LS.
Frdro3W derivatives of pbenanthrene. Part lt 1-Nitroso-
2-phanautbirol and its bisulfite compound. Zhur,obekbime 30
no*7t2229-.2235 JI 160. (MIRL 13t7)
1. lauchno--imeledovatellakiy institut, organioboWdkh poluproduktov
i krasitelay iseni X.Te. Vorombilov&6
(Phonanthrol)
0

GORELIK, M.V.; BOGDMV, S.V.
--------------------
Anthracene derivatives. Part 7: Reactivity of 1,2-anthrafarazan
and 1,2-anthracelenodiazole. Zhur. ob. khim. 30 no.9:2949-2954 S 160.
(MIRA 13:9)
1. Hauchno-issledovatel'skiy institut organicheskikh poluproduktov
i krasiteley.
(7wazan) (Selenium compounds) (Anthracene)

GORELIK, M.V.,; BOGDAIIOV, 3*Y*
Anthracene derivatives. Part 8: Bisulfite compound 1,4-anthraquinone.
Zhur. ob. khim. 30 no.9:2044958 S 160. 1(MMA 13:9)
1. Naachno-iseledovatellakly institut organicheBkikh poluproduktov
i krasiteley.
(Anthraquinone)

GOMMIK, N.V.,- BOGDAROV, S-V.; RODIONOV, A.H.
-----------------------
Interaction of 1.4-naphthoquinons with Godium bioulfite. Zhur, ob.
khim. 30 no.9:2959-2964 S 160. (MIRA 13:9)
1. liauchno-iseledovatellskiy institut organicheakikh ooluproduktov
1. krasiteley i Fisiko-khimicheskiy institut imeni Karpova.
(Baphthoquinone) (Sodium sulfite)

BOODMOV, S.V.
Ina ti Ition in the series of hydroxy compounds of the naphtha-
levr'go
n series and their products (reaction of the oxidizin sulfona-
tio rg. poluprod. i kras. no.20-12 161. WRA 14:11)
(Bydrov compounds) (NaphthaUns)

BWD - TCIDFSS-SELEKTOR, Z.V.
Bioulfits conpound of I-nitroso-2, 7-dihydroxymphthalene.
Zhur*VBHO 6 no,5084-565 161* (IMIA 14;10)
I* Nauchno-iseledovateltakiy inotitut orpnicheskikh poluproduktov
i krasiteley imeni K.Ye.Voroshilova.
(Raphthalenediol)

B~ Ovs S.V.; TODIUS4ELEKTOR, Z.V.
2-Nitroso-1., 7-dihydroxymphthalone-4-oulfonic acid. Zhur.VKHO 6
m.5:585 161. (NIRA 14:10)
1. Nauchno-issledovatellskiy institut organichaskilch poluproduktov
i krasiteley imen' K.leVoroshilova.
,(Naphtholenedionulfonic acid)

WOVP S,V6j SHIBRYAXNAl L,Se
Hydrwq derivatives of phenanthrens. Part 2: Some products of..
the converoions ofthe bisulfite compounds of lj2-phenknthro-
(31W)-furoxan. Zhur& obs khim, 31 noo 2:522-528 F 161#
(KUU 11+ t 2)
1. Nauchno-issledovatel'skiy institut organichookikh poluproduktov,
i krasiteley imeni. K.Ye. Voroahilova.
(P~wcxsn) (Phenanthrene)

BOGDANOITI S.V..; TABACHNIKOVAt N.I.
-------------
1--Woro- and 1-mothoxy-2~-nitronaphthalone-4-milfonic acidso, Zlhtu-
ob.kbim. 31. no*6:1912-1916 je 161. (MM 14:6)
is Hauchno- iosledovatollskiy i4stitut organicheakikh poluproduktov
i krasiteley imeni KeYeoVoroshilovas
. (Naphthalenesulfonio acid)

BOGDANOV, S.V.; TMRES-MIMOR., Z.V*
Bisulfite compound of :L-nitroso-2., 6-dihydroxynaphthalene. Zbur.
7MO 7 no.1:118-n9 162. ' (AMA 15:3)
1. Hauchno-iseledovatellskiy institut organicheakikh poluproduktov
i krasiteley.
(Naphthalonediol)

06
06
00
go
0: 1
*0
00
00
degree of ionization of the p
Tom lure and _e In
Ya. Bogdamv and K, S. Vul'fumt.
COWN. T4111111. a . mi. V.'R, S, S. 40, M-410943)(in
En t6bi.-Hiptl. evidence on the = OCCUM11%
wit,
during mpulm dischar with K, or A
indicates the following tol"'h267, d1wharge . fit the
first inutuent after the breakdown. (lie electrons move
with high velocities owing to the action of the elve. firld.
and their temp. attains very high values. INring the
succeeding time Interval the degree of imitation mcd the
temp. of the su begin to Increase timaust of collisions of
tlectrons with atonts and ions. As the degretuf Ionization
increases so dues the Intensity of %park title%. since, owing
to the high energy of the tle-ctruns, the process of ioniza-
tion becomes more prutimble it= processes ut excitatims,
When the discharge vanishes. a Vactual recombination of
lons and electrocis begins anti this is accompartiml by
radiation of a continuous bacligmund and arc lint-A.
J. W. Perry
A tTLLLUA!~&L URRATURE CWtVICATIGO
SM1040 .10 Out, oft
to 41t, 0o W,,_,~ 'U' a V
No 01 1
0 0 0 go 0 0 0 0 0 0 0 0
t-, 1,4 f) IL
Ti - ~~ 1 -
VA 4-
---- --
I-so
"to
*00
0
we
too
0
0 0 0

BOGDAMT, S.Te.
hiacbanization of precision investment molding and ways for its
automation. Avt.pron. no.1:36-38 JR '60,
OGRA 13:5)
1. Giproavtoprom.
(Holding(lounding))

BOGDANOV, .3. Te., inxh.
Automatic control of molding processes In small-lot and serial
production. Kekh.i avtomeproixvs 14 no*8-.31-32 Ag 160.
(MIRA 1318)
(Kolding (Founding)) (Automatic control)

S/108/6-/016/008/005/006
22523. D280/D304
AUTHOR: Bogdan~-.,, S. Ye.
TITLE: Certain v:i-ticular cases of measurement of mean values
of homogeneous and isotropic'random fields in d two-
dimensionnl plane
PBRiODICAL: Radiotekhnilka, v. 16, no.8, 1961, 67'-7'4.
TIMT: The problem of mean values of random processes is often en-
counter.ed in radio applications. If the problem of determining the
accuracy of measurement of given.RMS errors[0,0(SK0)3 is confined
to the correlation theory, then in general the magnitude of this el,ro~.~
is determined from the formula (for homogeneous processes and fields)
in which n - number of the
+ averagin.g. boints; d 0 _.cky
n
(skuj - standard 'd'*eviation of
the random field from its
average value; d - ZIS error.
Card 1/6

25523 S/108/61/016/008/005/006
Certain particular... D280/D304
of the measurement of average value of this field; p the values of'
norma,lized correlation function for points No. i and No. k..In the pre-
sent article the author proceeds to aetermine the distribution function
for a few paths of integration in an isotropic and homogeneous fieldit
First-the differential distribution function
of distances along a section--:"
of a straight line a. From r (1) ~, 2 npH 0,< 1,