SCIENTIFIC ABSTRACT BELOV, N. V. - BELOV, N. V.

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Isomorphous Interactions Between Zirconium and BOV/20-125-4-56/T4 Titanium The structure analysis confirmed on the whole the formula of this mineral (according to M. Tb. Kazakova and Yes, 1. Semenov,, Ref* Na aZr3Ti3~n2 [,,iO4]eF4. The most essential change car- out by the authors was the affiliation of a third of Ti to Zr and the removal of each 8th O-atom from the silicon-oxy- gen radical (which is less visible for the analyst). The two interpretations by Ye. 1. Semenov (Ref 2) are from the first dangerous in view of the numbers obtained by a detailed analy- sis (M. Ye. Kazakova)o Us Is 80MGn0V iSp howeverf right in the case of.Seydoserite in its~cation distribution as was con- firmed by the X-ray structure analysis of the authors. Only two maxima were determined on the corresponding projection. One of them may be ascribed to the Mn-eation, the other one to the Ti. After the identification of the higher maximum with Mn the-authors.immediately discovered a mistake in the case of the distances between these two cations and the surrounding 0- -atoms. This mistake could be correcied only by the exchange of Ti and Mn. It could, howeverl not be concluded from the Card 2/4 height of the Ti-maxima that Zr is contained in them. On the Isomorphous Interactions Between Zirconium and SOV/20-125-4-56/74 Titanium contraryv the chemical and radiographic analysis pointed out clearly that a fourth of Zr is replaced by Ti. Thus the assumai isomorphism wouldbe in any case unilateial. After the detec- tion that 1/4 of the Zr-atoms is replaced by Ti in Seydosprite, and correspondingly the halt of the Xg-atoms by Mn, not 1_.1y , one, but 2 paradoxes are solved. The Mn which inclines towards high oxidation degrees is transformed from the bivalent state into a trivalent (or ? even tetravalent) one. Correspondingly the tetravalent Ti becomes trivalent (like in the case of~py- roxene, Ref 4). The reaction T14+ + Mn2+i=!T13+ + Mn3+ (Xn4+,?) a renders the radius of the TJL3+ (R - 0083 A)immediately comman- 0 L 3+' 4+ (0.6 A).and to that of Mn surable to that of Zr 7 (0-71 A with that of Mg 2+ (0,78 AO)- It is not necessary that'the reac- tion is finished, a corresponding tendency is sufficient. These statements are illustrated by other minerals. There are 4 Card 3/4 Isomorphous Interactions Between Zirconium and SOT/20-125-4-56/74 Titanium Soviet references. ASSOCIATION: Institut kristallografii Akademii nauk SSSR (Institute of Crystallography of the Academy of Sciences, USSR) SUBMITTED: Jan uary 21, 1959 Card 4/4 3 (8) AU',"EORSi Mamedory Kh. 3#1 Xlevteova, R. F.) BOY/20-126-1-41/62 ' Bel*vq_.A._jf Academician TITLE: On the Crystalline Structure of the Tricalcium Silicate Hydrate TSH - 6CaO-2SiO 0 - C 2'3H2 a6 [Si 207](OH)6 - Cla Asi 207](OH)2- .2ca(OH)2 (0 kristallicheakoy atrukture gidrata trokhkal'teiyevogo silikata TSH w 6CaO-2Si0 2. 3H20 Cs`6 In 207)(OH)6 - Ca 4 In 207] (OH)2.2Ca(OH Y PERIODICAL:. Doklady Akademii nauk SSSR, 1959,701 126, Nr 1, Pp 151-154 (USSR) ABSTRACT: The investigation of the ouspidine'structure (Ref 1) became an important step towards further investigations of several Ca-silicates, above all of wollastonite and xonotlite (Ref The main peculiarity of cuspidine and of the investigated structure of tilleite (Fig 1) was, compared to the'Mg(Fe)- and Al-silicates, the r8le which the (S1,041-tetrahedrons play In ,the latter and which is played by the diorthotic groups [,-,12O~j Card 1/4. -in the Ca-silicates with respect to geometrical reasons. on tho'Crystalline Struotura*of the Tricaloium SOY/20-126-1-4"./62 Silicate Hydrate TsH -.6cao-2SiO 2*3H20 Ca6lsi2 07] (006 Ca 4[3'207](OH)2 -2Ca( 6H)2 The variety of the motives to which this group belongs in the Ca-silicates is considerably limited by a certain inertia of .the diorthotic groups and the existence o: onl on di ction pj-( eg, re .with a dimension of 3-7f I (height of the grou Pi 1:1 cursive). Thus a "tilleite band" occurs in both initially mehtioned.Ca-silioates as a mineralogical radical (Figs 1. 1). Figure I shows that a part of the ti'lleite band.consists of 8 octahedra and two IS'207] groups. The 14 O-atoms of the two. last groups are, however, not sufficient to counterbalance the cation charges. This is compensated (according to Ref 5) by additional anions F, OH in the ouspidine structure. The latter oonsistp completely of tilleite bands of a most simple formula3 Ca 8[~i 20 712(F' OR)4- 2Ca. 415'2071 (F, OH) 2 * The second variant of the two most simple geometrical solutions for such a formula is realized in nature. In this case the members of Ca-octahedra of a tilleite band continue Card 2/4 one another in forming somewhat longer 4-membered members. Od the Crystalline Structure of the Tricaloium SOV/20-126-1-41/62 Silicate Hydrate TSH - 6CaO-2SiO 2. 3H20~16 Ca61Si2071(OH)6 Ca 4[S'207](OH)2. 2Ca(OH)2 It seems that the latter strengthen the structure since they lie one behind the other. In the strunture of tillsite itself the tilleite bands are not fused, they are related to one another by additional CO 3-groups. This demands the introduction of an additional Ca-octahedron as well, so that the formula will be Ca 41si 2~71CO3 -caco3(Fig 2).,In,1958 (Ref'6) new data on the hidrothermal synthesis of the substance mentioned in the title (TSH) were published and a formula suggested. If the formula of the tillqite band is reduced from the formula of TSH 2 portlandite molecules Ca(OH)2 are obtained. It is assumed that these were replaced in the formula to the "side chain" outside the cuspidine nucleus (Table 1). They form a third layer with their 4'.OH particles which links the'tilleite bards (with 2 layers).'The additional Ca-octahedra (Fig 3) which replace,the CO 3 groups in tilleite Card 3/4 are placed here as well. The authors draw the conclusion that Ori thd Crystalline Structure of the Trioalcium SOV/20-126-1-41/62 Silicate Hydrate TqH 6cao-2sio 26 3H20 W, Ca6 Pi2071 (0H)6 Ca 41si2071 (PH)2-2Ga(OH)2 the'TSH ctructure is peoudohexagonal, similarly to anhydrous Ariaaloium silicate. The authors of referenoe 5,are therefore rathqr'wrong when they insist on a true hizagonality of TSH. This is confirmed as well by 'the thermogram. There are 3 figures, 1 table, and 6 references, 4 of which are Soviet. ASSOCIATIONt Institut khimii Akademii nauk AzerbSSR (Institute of Chei4istry of the Academy of SoionoeeAzerbaydzhan SSR) Institut krietallografii Akademii nauk SSSR (Institute of Crystallography of the Academy of Sciences,USSR) SUBMITTED: February 26s 1959 Card 4/4 3 0) AUTHORS: Mamedov, Kh. S., Simonov, V. 1.9 SOV120-126-2-42164 Belov# N. V., Academician TITLEt On Wdhlerite-Lovenite and Rinkite Mosandrite Groups (0 gruppakh velerita-lovenita i rinkita-mozandrita) PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 126, Nk 2, pp 379-381 (USSR) ABSTRACT: The 2 groups named in the title followed each other in modern text-books (Rafe 1, 2) and in mincralogical tables (Ref 3). Despite a somewhat closely-connected type-formula, they differ greatly with respect to their shape and the parameters of the elementary cells. The recently published results of an exhaustive investigation of the Zr,Ti-silicate of Lovozero - the Seydhozerite (Refs 4, 5) change'~he mineralogical picture considerably. This mineral was placed by its discoverer (Ref 6) into the Wdhlerite-lovenite group (zrO 2-content - 23 %). According to r6ntgenometrioal data it doubtlessly belongs to the Rinkite group. Moreover, this mineral should because of its ideal structure be'placed on Card 1/3 top of the Seydhozerite-Rinkite-group. The same test of the On Wdhlerite-Lovenite and Rinkite Mosandrite Groups BOV/20-126-2-42/64 structure (Figs 4, 5) proved.that ouspidine should be placed on top of the Wbhlerite-Lovenite-group. In the essential work on the cuspidine and other purely mineralogical publications much space was devoted to its close structural connection with another Ca-silicate, the tillite. By means of geometrical analysis of this simplest Ca-silioate there was determined an infinite mineralogical radical - the tillite band which all minerals have in common (Fig 1). With the aid of this band such an important compound as tricalciuzailicate-hydrate (Ref 8) is for cement-chemistry, could simply be npUt together" and a structural solution could be found. A second interesting result obtained in consequence of +ae tillite band determination is the aforementioned geometrical (structural) difference between both mineral groups$ mentioned in the title. Hence further (rational) combination of both these groups, which are already connected by a common type- formula is necessary. From figures 2-4, one may see that the minerals of the Cuspidine-Mlerite-Lovenite group are (at least from the geometrical standpoint) only a polymorphous modification of the mineral group Seydhozerite-Rinkite. Card 2/3 Perhaps in this case the term polytypical modification would On W6hlerits-Lovenite and Rinkite Mosandrite Groups BOV/20-126-2-42/64 be more convenient. This modification is characteristically expreased by the projection-surface of the cell which is nearly the same if slight differences in the length of the axis are not taken into account, In real minerals (MU 1) above all the composition changes. There are 4 figures, I table, and 8 ref erenoev., 7 of vhich are Soviet and 1 Gerftn. ASSOCIATION: Institut khimii Akademii nauk AzerbSSR (Institute for Chemistry of the Academy of Sciences of the Azerbaydd= SSR) Institut krietallografii Akademii nauk SSSR (Institute for Crystallography of the Academy of Sciences, USSR) SUBMITTED: February 26, 1959 Card 3/3 -24 Wr-WH* '~21/' 7000 66455 AUTHORS: Neronova, N. IT., Belov$ F. V*$ t;OV/20-129-3-23/70 Academician .TITLEt The Symmetry of Perroelectrice PERIODICAL: Doklady Akademii nauk SSS'R? 1959P Vol 1299 Nr 3P PP 556-557 (two ABSTRACT: B. A. Tavger (Ref 1) showed a short time ago that the point- symmetry (macrosymmetry) of ferromagnetios is described by the 31st group of the total number'of 90 Xheyeah-Shubnikov groups (plus-minus groups, black-and-white groupo), The main veotor is known to be the most characteristic element of ferroelectrics as well as of ferromagnetics, but in ferro- magnetics it is a polar iectoT, and in the case of ferro- electrics it is ari ordinary axial vector. The maximum symmetry of the axial vector i's oo 21 21 p and that of the polar m MI MI vector is -S -L These symbols are*of the "international" mt m m type, The 31st cryBtallographical group is a subgroup of the two groups of maximum aymetry, and it --upplies the required groups. A table contains the ferromagnetic and ferroelectric Cara 1/2 symmetry groups for the various crystal systems given in 66455 The Symmetry of Ferroelectrics BOV20-129-3-23/70 international denotations. In all cases (except in the -monoolinar groups) the Z-axis was chosen as the direotion of the main veotor,-An interesting survey of all spatial ferromagnetic and ferroelectrio groups will be published in the next issue of the pariodica."KristallografiyaP. There are 1 table and 4 Soviet references. SUBMITTEDs August 213, 1959 Card 2/2 BILOV., V. (MOBOOV) NOUS BAtter aus dem 2 lapitel der Kriatallohemis der Silikats report submitted for the Symposium,on SiUcates vith 1 & 2 cations, Berlin,, MM, 7-9 A.Pr 60 CHUKHROV, F.V., glavnyy red.; BONWXD2-KUPWT8rAYA, N.M., doktor geol,-mineral,nauk, zam,glavnogo red,; BARM OV, G.P., prof.# red.; -"-damik, red.; SHMIKOVA, O.M., doktor goal.!- ral.na d. [deceased]; SHANM, T.N., red.izd-,va; ZHLMMOVA, Ye eve Itekhn.red. [Minerals; a handbook] Mineraly; spravochnik. Mosk7a. Vol.l. [Native elements. Intermetallic compounds. Carbides, nitrides, phosphides, areenides, antimonides, bismuthides, sulfides, selenides, tellurideol SBmoradnya elelenty. Inteirmstallicheakie soedineniia. Karbidy, nitridy, foefidy. arsenidy, antimonidy. vismutidy, sullfidy, aelenidy, telluridy. 1960. 616 p. (MIRA 13:12) 1. Akademiya. nauk SSSR. Institut geologii rudnykh meatorozhdaniy, petrografii, mineralogii i gookhimii. 2. Chlen-korrespondent AN SSSR (for Ghukhrov). (Mineralogy--Handbooks, manuals, eta.) FZRMUK, Aleksandr Yevgenlyevich, aki'demik; SMIUCEMO, D.P., doktar &a ol *-mineral. nauk, oty.red.; B=Vt N.V. 0 akademik, red.; I VINOGRADOV, A.P., skedemik, red.; SHCHKRMOV, D.I., akads#k, red.; ISAUKOV, A*A,g red,; MCHERBIRA, V.V., doktor geol.-vineral. nauk, red.; KUN, I.R.. red.izd-va; ASMV, A.V., red.izd-va; XASHINA, P.S., tekhn.rea. [Selected works) lzbrann" trudy. Koskya, Izd-vo Akod.nauk SM. vol.6. ig6o. 742 r. (MM 13tll) 1. Chlon-korrespondent AN SM (for Saukov). (pagmatites) (Granite) - BELOV. N Studies in structural mineralo&7. ?art, II. Hin.sbor. - no.14-.3-31 160. (14IRA 15:2) 1. Moskvaj, Institut kristallografii AN SSSR. (Mineralogy) k. a 11. 24-.7100 78093 SOV/7 AUTHOR: Belov, N. V. TITLE; Trl~P-ro-mewr-ur-urystai Chemistry of Silicates PERIODICAL: Kristallografiya, 1960, Vol 5, Nr 1, PP 15-18 (USSR) ABSTRACT: The 7-year plan of the X-ray Laboratory at the CrystallograPhical Institute (Ren".-genostrukturnaya Laboratoriya Instituta Kristallografii) includes the further development of' crystal chemistry of siLicates as an urgent problem because of its importance for the industries producing refractory alloys, ceramics, glass, cement, etc. Crystal chemistry, particularly, that of silicates, was initiated in the USSR in 1935 with the organization of the X-ray Laboratory at the Crystallographical Institute In Moscow,: but after a brief period of studies and experiments, Interest to the subject cooled-off. Then, in 1953 when new ideas on the structure of silicates became urgently needed to Card 1/3 explain some structures inconsistent with the Bragg 'The Problems of Crystal Chemistry of Silicates 78093 SOV/70-5-1 -2/30 theory, to produce and develop new silicates and refractory alloys for industry, the Crystallographical Institute became very active, and new research centers such as those in Gorlkiy and Baku were organized. A new idea emerged that, contrary to the Bragg theory, the structure of silicates is not determined by the combination of SIO 4 tetrahedra, but by the combinatien of octahedrally coordinated cations, while chemically inert silicic radicals just adopt the spaces left between, and tetrahedra or their combinations deform themselves to fit into the spaces,between well arranged cations. If the latter are small N., Fe, AI)j.octa- hedra edges are of about the same length as the edges Of' Sio tetrahedra. Larger cations (Zr, Ti, Nb, Ta, Mn) on ~he other hand, form octahedra who'se edges are too long for SiO and, consequently, fills in the 4 31207 remaining spaces forming double rings, do,,.ible chains, etc. Thus, atomic radii of cations determine two Card 2/3 principally different types of structures, of which The Problems of Crystal Chemistry of Silicates 78093 SOV/70-5-1-2/30 those formed by small cations are subject to Bragg's theory, while the others, with Si.07 combinations, give rise to a new chapter in the crystal chemistry of silicates. There are also combinations of the two principal types. Since refractory and other properties of silicates are direct functions of their structure, new concepts on crystal structure are important and will be developed still further. Card 3/3 24-7100 78110 SOV/70 AUTHORS: Belov, N. V,., Tarkhova, T. N. TITLE: Cayley Squares for Cubic Point Groups. Brief Communications PERIODICAL, Kris t allograf iya, 1960, Vol 5, Nr 1, pp 129-134 (USSR) ABSTRAdT: The Cayley squares for point groups 432 and m3 of qubic System are compiled in a four-page table to assist theoreticians in crystallography; also simplified-designations for symmetry operations used in the table are explained'. A reference is made to a letter by E.-Tavora (13razil) stating that he was the first who emphasized great significance of Cayley squares In crystallography. The figures for point roup-43m. can easily be obtained from the table for ~32 by substituting 7 and m for 4 and 2, respectively. Similarly, point groups m3 and 23 differ only because of the occurrence of two-:fold Card 1/~ rotor in the latter Instead of the rota ry inverter Cayley Squares for Cubic Point 7811o Groups. 'Brief Communications SOV/70--5-1-19/~O of the former; consequently, the Cayley square3 for the the latter can be derived from those of the former by.substituting 2 for m ('fl. The relationship between the groups concerned is illustrated in Fig. 1. In any event, a rotary Inverter and rotor occupy Identical positions. Cubic crystals can have neither six-fold rotor nor rotary inverter. There is I figure; and I table. ASSOCIATIONi Gorlkiy State University Imeni N. I. Lobachevskiy (Qorlkovskly gosudarstvennyy universitet imeni N. 1. Lobachevskogo) SUBMITTEM September 11, 1959 Cayley Squares for Cubic Point Groups. BriefCommu.nications m In M Fig. 1. 78no SOV/10-5-1-19/30 PLYUMUM, T.T.; ZZWT, N.V. Determination of the structuwa of lovoserite from thevross sections of the three-dimensional Paterson function. Kristallograftia-5 no-2: 200-214 14r-Ap 160, (MMA 13:9) ~1. Institut kristallografii AN SSM. (Lovooerite) RUXAMVA, I.M.;-=V, N.V. False symmetry in the e~ructure of lawsonite, Kristallografila no.2:215-217 Mr-Ap 1600. (min 13 9) 1. Institut krisallografii AN SSSR. (lawsonite) S/070/60/005/003/022/024/XX E132/E460 AUTHOR: )3elov, N,V. TITLE,-. The Crystal Structure of Baddeleyite (Monoclinicl-zlro 1 2) PERIODICAL: Kristallografiya, 1960, Vol.5, No.3, pp.460-461 TEXTi The high temperature modification of Zr02 is cubic and has .the CaF2 structure with a Zr coordination number of 8. The coordination polyhedron is a cube. At room temperature this structure is unstable and goes over to a monoclinic form with dimensions very similar to those of the cubic form but with P =-100'. The structure of this form was originally proposed by K.Lonsdale but has now been worked out in detail by McCullough and Trueblood (Acta Cryst. 12, 507, 1959). It is shown that the coordination number of the Zr is lowered to 7 andthe way in which this happens Is particularly neat. The structure of baddeleyite can be considered as consisting of distorted square nets of oxygen ions alternating with oxygen nets made up of squares and triangles. The Zr ion touches 4 ions of the all square sheet and either 3 ions or 4 tons of the mixed sheet according to the way it is displaced in its own plane. The particular placing of the sheet thus gives either the 8-coordination of the high temperature form or the Card 1/- S/07o/60/005/003/022/024/XX E132/E46o The Cryptal Structure of Baddeleylte, (Monoclinic ZrO2) 7-coordination of the baddeleyite. The two possible directions in which the displacement --an take place explain the almost inevitable twinning observed in baddeleyits, Pauling's rules are satisfied. There are 3 figure3 and 8 references: 5 Soviet, 2 English and 1 German. ASSOCIATION: Institute of Crystallography AS USSR (Institute of Cry3tallographX AS USSR) SUBMITTED: March 5, 1960 Card 2/2 S/07o/60/005/004/002/012 E132/E36o AUTHORS: Indenbom, V.L., Belov, N.V. and Ner2nova, N.Me V, TITLE: The Point Groups of ColoZ-r Symmetryl(Coloured Classes) PERIODICAL: ~Kristallografiya, 1960, Vol- 5, No. 4, PP 497. - 500 + 1 plate TEXT: The concept of colour symmetry is applicable not only to plane and space groups but also to the point groups. For two colours there will be 58 (magnetic) classes. The coloured point groups have been derived before (0. Wittke and J. Garrido, Bull. Soc. franc# miner.cristall., 223-30, 1959) but in this case are lost among the 211 ways of colouring polyhedra which the authors described. All the 18 multicoloured classes are listed and illustrated by coloured figures. The ordinary 32 point groups have, in all, 18 pairs of,complex conjugate one-dimensional representations. These are listed and each is shown to correspond to a colour group. In the notation primes indicate the coloured element. The parent group is given first: Card 1/2 S/07o/60/005/004/002/012 pl~2~Eg The Point Groups of Colour Sy=e r ~00ured Classes) ~4-colour groups - C4 gives 41; S4' 41 C4h' 41/m and 4t/me 3-colour groups - C3 gives 31; C6, 31.2; 0 S6 , 31.1 and 31ail C gives 31-2/m and 31.2/ml; T. 2 6h -3t; Th , M31; C 3hf 31/m and 3'/ml 6-colour groups - C 6 gives 31.21; C6h' 31.29/m; 31.21/m4; T h1 M'3' There are 7 tables and 6 references: 5 Soviet and 1 French. 'ASSOCIATION:. Institut kristallografii.AN SSSR (Institute of Crystallography of the AS SSSR) SUBMITTED: FebruarY 3, 1960 Card 2/2 KLBVTSOYA. R.N.; TiizT-nv u v Oryatal atracture of spurrite. llris6allWafiia 5 no.3:689- 697 S-0 160. (KIU 13:10) 1. Institut kristallografii AN SSSR I Institut neorganichookoy khimii Sibirskogo otdcleniyo AK SSSR. (Sparrits) SEWT, N.V., akademik Berlin symposium on silicates witb monovalent and divalent cations. Zhur. VEM no.6:686-688 160. (MM 13:12) (Silicates) BAMIN, V.T,; BELOTj N.V. Crystal structure of paracelsian. Xriistallograf iii 5 no.6:e64- 868 N-D t60. (MMA 13:12) 1, betitat noorganichookoy khimit Sibirskogo otdoloniya AN SSSR, (calsian) N TAMBILLINI. V.P. Opening-up of i'use layern of lov permeability by means of pover- ful blasting chargas. Oaf,-prom. 5 no.9:6-12 S t60. (KIRA, 13:9) (Oil Valle) (Blasting) BzWV, N a v Orystalloohemical principles underlying the discussion of the Iso- morphous state' of boron In silicates* Gookhimlia no.6:551-556 160. -- (Boron). (Silicates) (Isomorphism) (MIRA 13:10) BELOV, N.VLPRIKHODIX6, N. Te., SDIONOV, V.I.; FIDRINSKAYA, V.A.; ~MC#EDLOV-PETROSYAN., O.P. Symposium on the study of silicates of monovalent and diva- lent cations* Zhuro prikl. khim. 33 no.11:259&-2600 H 1600 (Silicate o-Congresse a) (KMA 34-4) SROMOMM, D.P.; BUOY, N.V. -------------- Conoorning the.oo-called msulwdte.0 Zap. Vses. min. ob-va 89 no-3: 367-368 '6o, (KM 13-8) (Ohlorites) 80080, S/020/60/131/06/27/071 B014/BO07 AUTHORS: Walinovskiyq T. 1.9 Samuel, I. D., Belov" N. V.0 Academician TITLE-. The Crystalliurs %tV\xtk=fa 4~1 Vhe to'balt 'R'ho&anopentammine Nitrate Leo (NH3)5NCS>03)2 PERIODICAL: Doklady Akademii nauk SSSR; 1960, Vole 131~ No. 6, V'~. T%XT-. The crystals investigated were bred by the method developed by A. Werner. and H,, Huel2er (Ref. 1). Laue diffraction patterns were made. The crystals were found to belong Jo the cubic class; the length of the elementary cube is given as 10-73.t 0.02 X. The pyonometrically determined density is 1.766. It is found that the Cc atom is in the center of the cubic tuclausi that the Cc- and S atoms axe distribute& in the rook salt like the Na- and 01 atoms, and that the NE groups are ootahedrally distributed round four Co atoms. The further structare of the lattice is described in detail,, the Patterson projection (Fig. 1) being used for the c2arification of the position of individual atoms and atomic groups. There are I figure and 5 references, 4 of which are Soviet. kSS0C1kT10X: Moldavskiy filial Akademii nauk SSSR (Moldavian Branch of the Card 1/2 80086 The Crystalline Structure of the Cobalt Rhodanopentammine S1020J60 Nitrate--LCO(KH3)5NCS1(N03)2 B014/BW 131/06/27/071 ~cademv Of Sciences. USSR). Inetitut kristallografi:L Akademii nauk obbl% 'inevitute or oryevallographY of the Academy of sciencest USSR SUBMITTED: January 269 1960 Card 2/2 S/020/60/.135/003/021/039, I B019/BO77 -AUTHORS: V. V.,, and Belov, N. V., Academician TITL The,Giystal'Struoturej~f Hurlbutite P RIO E ICAL; ~Doklady kkademii nauk SSSR, 1960, Vol-135, Nb- 3, PP. 587-590; TEXT. In, earlier the authors presented the results of X~-ray dif- fraq4c'n ~tudiesi with C6Be P 0 and compared them with data of CaB Si 08. 2 2. 2 21 Sincel th'ey~llacked exact data of'the,x-coordinate, it was not possible to* deterline the a .tructure of hurlbutite, which is the task of this paper. A I In Tatle 1139 coordinates of the 13..basia'atoms of the hurlbutite are given, The spacings of the P and 0 atoms are between 1.55 and 1.60 A .those',of the Be and 0 atoms between 1.57 and 1.61 A, hnd the 0-0 summits of tho PO and BeO tetrahedrons are between 2.50 and 2.66 A or between 4 4 2.5.1 knd 2-72 A. The 'seven Ca-0 spacings are between 2.42 and-2.52 A. It caii be seen that.the dimensions for the PO and.the BeO tetrahedrons,are A 4 4 very similar and are found between,the.dimensions of the SiO and BO 4 4 Card -1/2 '.The 4 ybtal St ructure -of Hurlbutite S/020/60/1 35/003/021/039 B019/B077 tetra 4qdrons. The similarity between hurlbu tite and the feldepars is 'men- tion4 especially that of CaAl Si 0 8 2 2 and it is found tha t ,the structure of hu ~lbutito . is a key to decode the structure of the pa racelsian -Ba: tl Si 0 .) 2 2 ..There are only preliminary data given fo r the paracelsian, a det ailed research is announced. There are 3 figures, 2 tables, and 3 Sov et references. SUBM# TED: August 15, 1960 Y Y 013M, 0', 085 0.7ii~ 0. 0,121 0367 0,438. Bft ' 0 0 M .0,435-~ 04 0,126 0:3M 0,055 Be, . K 265 -0 421 0,933 06 0.412- 0,M O.W5 P, 0,264 0,418 0,560 0, 0,415 0,309 0,931 Ps - 0 059 0 197 0,060 0, .0,006 0,150 0,247 0 :1B8 0083 : 0,5()a Od ''0,184 0,421 0.745 0,189 0,085 0.993 Card 2/2:, BELOV, Nikolay Vasillyevich; DRAGUOV., E.S.,, red. izd-va; POLYAKOVA, T.V., UME-.red. [Crystal chemistry of silicatea with large catlonal Xrlata2lo- 'kbimiia oili)mtov a krupMmI kationud. Moskup Izd-vo Akad. nauk WSRs 1961. 66 p. (Chtenlia im, V.I.Vernadakogo., no.2) (MIU 15 S 1) (Silicates) (Crystallography) ZHDANOVp Geman Stepanovich;"BELOVp Mop "et retmensentl ARKMOV# V.I.p prof.p retasuzent; BIWT# retsenentj ZAMWVAp M,I.p prof.9 retoonzent; OOLOMWBERGp G.60"9 red.; GEORGIYEVA9 0.1.9 red..-, I I [Sol"if-state pbysicel Fizika tvardogo tela. HoakTal Izd-To.Monk. =iv.p 1961. 500 p. (MM 3.4,t (solids) Y~`~ LOP N, V. ii It-St. ANT bw 0 ~01 1 93 19 lop Ila Ila 1,111i uj u . 1 .3 a U I ;Ila m 14 8F 5 IL BS~OVL N.V. Studies in structural mineralogyf Report No.12s Min. obor. no.15:5-44 161. (MIRA 15:6) 1, Institut kristallografti AN SSSR, Moskva. (Mineralod) KUBERS V.; BEWVP N.V. Morphological aspect of hopeite. Kristallografiia, 6 no.6s82,`~- 827 11-D 161. (KM 14:12) 1. Ifineralogo-petrograficheskiy institut i Muzey Gumboltdtovskogo universiteta., Berlin i Institut kristallografii AN SSSR.. Mookwa. (Minerals) (Crystallography) PLYUKRIN, V.V.; BELOV, N.V. Crystalline structure of rubidium di%"Meta)fluobery2late RbBo2F- and its model relations to laminated silicates with (3i~O~radical. Kristallograftia 6 no.6:847-858 N-D 161. (MMA 14:12) 1. Institut kristallogmfli AN SSSR. (Rubidium beryllium fluoride) (Silicon oxiden) (Crystallography) VOIDDIRk G.F,, RLUMA NOVA$ I. M. BE v V. cm. tanine structuro of praoeodymium nltra-'14 bwcahydmt-9 pr(NO3)3' 6H20' Kristanografiia 6 no.6.-919-922 N-D 161. (MIRA 14-32) 1. Inatitut kristanografii AN,,SSSR, Praseodymium Inlti;ate)- ... "taUography) M BEIDV,_X.Y__t_~ademik; VAYNSHTEYN., B.K., doktor fizo-matem.nauk Tendencies in the development of modern crystallography; results of the Fifth-International Congress on Crystal- lography. Test. AN SSSR 31 no.4s99-104 Ap 161. (MIRA 14:4) (Crystanography"4ongr.esses) 4i~!V-p '11-v- Position of q uar tz in the system of natural and synthetic silicates. Zap Vsas. min.ob-va 90 no.2:168-171 161. (KM 14:9) iQuartz) (Silicates) BELOVS N.V. Priedel's theorem. ZapoVaes.minoob-va 90 no.3:257-259 (MML 14:10) (Crystal lattices) FOBEDIMSKAYAp Ye. A.; BELOV, N.V.0 akademik Crysta3line otruature'of eudidymits (NaBeSJ3070H). Dokl. AN SSSR 136 no...6:1448-1450 F 161. (MIRA 14:3) 1. Moskovskiy goeudaretvennyy universitet im. M. V. Lomonosova, (Budidymite) YAHZIN, I.I.-, NOZIK, Yu.Z.-, BELOV, N.V., akademik Neutron diffraction study of the cubic modification of FbF2. Dckl. AN SSSR 138 no.lsllO-lll Yq-Je 161. (MIRA 14:4) 19 Institut kristallografii AN SSM. (Lead fluoride) SOLOVIYEVA, L.P.; BELOV, N.V., akademik Crystalline structure of bertrandite Be4SiP.O?tH)2. Dokl. AN SM 140 no.3t(85-688 S 161. (HIM 1439) 1. Institut neorganicheskoy khimii Sibirskogo otdeleniya AN SIWSR. (Bertrandite) 29117 S/020/61/140/005/013/022 B125/B138 AUTRORS: Ilyukhin, V. V., and..Relov, N. V., Academician TITLE: Crystal struoture of rubidium-di(meta)-fluaberyllate RbBe 2F5 PERIODICAL: Akadimiya nauk SSSR. Doklady, v. 140, no. 5., 1961, 1066-ib6g TEXT: Moat of the publicationson fluoberyllate systems have been issued by the Moscow laboratory of A. V. Novoselova (Usp. khim-, 28, 33 (1959)) and the Leningrad laboratory of N. AG Toropov and R. G. Gr-ebenshchikov ZhNKh,~j, 49 920 (1961), ZhNXh, 1, 12, 2686 (1956), Z1h1fKhq.1? T, 16i9 56), DAN, 114, 316 (1957))- rrebenshchikov Toropov also supplied M the monocrystalline RbBe 2F 5 plates for the study here described. The crystals are biaxial, have the low refractive index (1~332) characteristic of fluoberyllatea, and a very low birefringence (f~iO). They have perfect cleavage along plane (001). The crystals have specific gravity 2.809, are only slightly hygroscopic, and are subject to polymorphous transforma- tionsduring heating The crystals are tr clinic, and one cell has the parameters a - 7-98 1, b - 4.69 R, a - 6.12 1, 4 - 89040'. 0 - 910, y - 90027' (a:b- f-3). Reduction to the standard cell with three obtuse angles gives Card 1/4 S/02076~1/140/005/013/022 Crystal structure of... B125/B138 a =4,69 Rt b - 4.61 R, c -6.12 R, a - 90027t, P - 900201, 7 - 1200481, attbb, aptipw900, yf41200, i.e.,-the pseudoorthohexagonal cell is reDlaced by a pseudohexagonal primitive cell. The presence of piezoelectric effect, .together vith.statistioal analysis of the structural factors, rules out all 8ymmetry groups except P1. The peaks of the Patterson syntheses p(xz) and p(yz) are indistinct. Table I shows the coordinates of the seven basal atoms (21 parameters) for the C1 cell. In the indisputable BeF4 tetrahedrons the interatomic d1tances lie within the limits Be-P - 1-43 - 1-48 t, F - Fx 2.33 - 2.41. In the RbF6 octahedrons, the .Rb-F distances remain within the limits 2.82 -3 .06 2. The principal structure of Rb difluoberyllate is, in the authors' opinion, a close- packed brucite (phlogopite) layer of Rb octahedrons, oriented parallel to (001). A hexagonal-patterned network of fluoberyllate tetrahedrons extends between the layers of Rb octahedrons. In the fluoberyllate analog, the di(meta) silicate model, there are no layers consisting of empty polyhedrons. The layer of tetrahedrons oriented in two directions along the pseudohexagonal axis may be conveniently called "one-and-a-half- storied". The fluoberyllate network characteristic of RbBe2F 5 has the same projection as all known silioio acid networks of the pa4udohexagonal Card 2/4 29 S/020P61/140/005/013/022, Crystal structu re of.. B125/B138 type. There are 4 figuiest I -table, and 16 references: 13 Soviet and 3 non-Soviet. The three',,.references"to English-language publications reaA as follows,, Intern. Tabies for X-Ray Crystallogr. L, 19529 P- 530; .G. A. Sim Acts, Crystallofr*f 11, 123 (1958); R. M. Douglasso Am. Minera, All 517 (;958)- MiMITTED. July 14,A96.'1 Table. Coordinates of,bas'-sl atoms (in hundredth parts of the cell axes) in the structure of RbBe F ~2 ATOU4. ...... Z. 77 W 0 F4 25,0 3314 5215 F 17 3t, 00 4 80 0 7 494 F& 54:5 4t,3 2, e t5,0 5 47 Bj LI;-'2' 0 1 ~` 20,0 834 46 7 Bi ~~JO 5~0. .~6,3 41 Card VOL.. 291~1 s)(026/61/140/005/913/022 Crystal structure of.*. B125/BI38 rij. 1. 'The oryetal.strubture': (plan view) of Rb-di(meta)- fluoberyllate with _alternating layers (brucite'type),of Rb -octahedrons and pseudohexagonal lattices (B~,,F A 5 00, OD pseudoorthohexagonal cell and a pseudobexagonal,primitivd..Qell are separately drawn. Card.4/4 FERSMAN, A.Ieksandr Yevgenlyevich, akadem:Lk; k1WUROVSK3Y,A.A.[d8cwwed1,otv. BE 4LDV., N.V. akademik., red.; VINOGPJXOV,, A.P.0 aka- C jkjL_ j A e red.; mHCHMAKOV, D.L., akadoziks red.; SAUKOV., A.A.0 red.; SHCHEWBA, V.V.., doktor geol.-min. nauk,, red.; POPOVA, T.S., red. izd-va; POPOVA, S.T., red.; PRUSAKOVA, T.A., tekhn. red.; GUSEVA, A.P., tekbn. red. (Selected worka]IzbraraVe trudy. Hoskva, Izd-vo Akad. nauk SM. Vol.?. 1962. 592 p. (MIRA 15:10) 1. Chlen-korrespondent Akademii nauk SSSR (for Saukov). 2. Chlon-korrespondent Akademii stroitel'stva i arkhitektury SSSR (for Mavurovskiy). (Precious stones) BEIDV, N,V., akademik,, xed.; GORqMV, A.M.v nauchnyy red.1 TYUNUM, M.S.; red.lzd-va- SHEVCHgNKO, T.N., tekhn. red. (checking, controlling, and improving techniques in the produe tion of building materials)Xontroll, regulirovanie i sover- shenstvovanie takhnologii v proizvodstys stroitallnykh mate- rialov. Pod red. N.N.Belova. Moskva,, Goestroiisdat, 1962. 158 p. (MIRA 16:3) 1. Akademiya, nauk SSSR. Komitet molodykh spetsialistov na ob- shchostvannykh nachalakh. (Building materials industry) BEWV, N.V.; PRGAibVA, N.I. Crystallochemistry and mineralogy of the,"lomonosovit" group in*the light of the orystanins struoturd of Olomonosovit" [with summary in English]. Geokhimiia no.1:6-24 162, (MIU 15s2) (Minerals)(Crystallograpb.v) BAKAKIN, VoVo; BMV, NoVo 1~ Crystallochemistry of beryl* Geckbimiia no,5:420-433 162, (MIRA 25:7) (Beryl crystals-Analysis) BELGV,,, N.V. Notes on structural mineralogy. Rep'drt Po.1,3*! Min, abor, no.16s 14-44 162. (MM 16:10) 1, rnstitutkristanografii AN SSSR, Hoakra, (Mineralogio~Ll chemistr7) BELOVI N.V. I- Un4mml forms of water inclusions in minerals. Trudy IGEM no.70:5~8 162. (KM 150) .I (Thermal analysis) AUTHORS: TITLE: 36136 S/07o/62/007/002/001/022 E132/El6o Shuvalov, L.A., and Belov, N._V. The symmetry of crystals in 'which ferromagnetic and ferroelectric properties occur simultaneously PERIODICAL: Kristallografiya, V,71 no.2, 1962, 192'-194 TEXT: There are 90 black and white point groups of which 31 permit the occurrence of a magnetic polarisation M and a different 31 permit electric polarisation P. There are 10 groups common to the two categories, namely: 62121; 6; 3211~ 3; 42121; 4; 22121; 2; 21; 1. These are subgroups of oo 2121. There are 3 further groups: mm'21; m; and ml, where the vectors M and P are constrained to be perpendicular. In all of the 10 groups ;ientioned first, except 21*and I where M and P may make any angle with each other, ~1 and P must be parallel. The 101 space groups corresponding to zhese 13 point groups have been listed (Ref.4: N.N. Neronova, N.V. Belov, Kristallografiya, v.4, 1959, 807-812). The above has assumed that M and P belong to the same antisymmetry group,.which is not necessarily the case. The relevant groups of double Card 1/2 The symmetry of crystals in which ... S/07o/62/007/002/001/022 E132/El6o antisymmetry are developed. There are no figures or tables. ASSOCIATIO N: Institut kristallografii AN SSSR (Institute of Crystallography, AS USSR) SUBMITTED; December 20, 1961 Card 2/2 SMIRNOVA, N.L.; BELOV, N.V. 6n tvo large groups of structural types corresponding to the formal4. AX2. Kristallograflia, 7 no.5z671-679 3-0 '162. (NIRk 15t12) I., Institut kristallografii AN SSSR i Moskovskiy gosudarstvenrqy universitet imani Lomonosova. (Grystallogra*y) -BELOV N.V.- KUNTSEVEH, T#S.; NERONOVAj N.N. Shubnikov,groupo (of antinymmetry) for infinite bilateral.bwWB. Kriotallografiia 7 uo*5t8O5-808 S-0 162. (NM 1549) lo Inotitut kristanografii AN SSSRl (-"A~ograpby) SMRNOVAI R. L. p BELOV., N.V. Structures from Tho6Qn cubes with alternate bipyramidal nets having a cubic or diamond-t* symmetry. Kristallografile, 7 no.6:826-834 N-D 162. (MM 16:4) ografii AN SSSR i Mookovskiy gosudarstvennyy ,I Listitut kristall versitet imeni Lomonosova. (Cryota,llography) S/070/62/007/006/016/020 B132/E435 AUTHORS; Kuzlminov, YU.S., Yamzin, I.I., Belov, N.V. TITLE: The magnetic structure of yttr ferrite PERIODICAL: Kristallografiya, v-7, no.6, 1962, 946-948 TEXT: Neutron diffraction examinations were made of poly- crystalline specimens Of y3FG5012 at room temperature and.at 3OO*C, which is above the Curie temperature. Very good agreement was obtained between the observed and calculated intensities. The nuclear contribution.wa3 calculated from the structure of S.Geller and M.A.Gillio (J. Phys. and.Chem. Soc., v.3, 1/2, 1957)-~ The magnetic contribution was calculated from Neel's model in which the spins of the Fe+++ ions ocetipying the octahedral ~ositionz (a) are antiparalle'l to the spins of the Fe... ions in the tetrahedral (d) positions. The ions in (a) positions were ascribed a room-temperature magnetic moment of $'a = 4.60jiB and the ions in (d) Positions - ILd, = 4.16 sLB. It was assumed that at O*K the moment of the Fe+4+ ions was 5 PB- The parameters assumed were: (in the space group Ia3d) 0 in general positions with (x,y,z) = (-0.0247, 0.0572, 0.1492);' Card 1/2 S/07o/62/007/oo6/oi6/020 .The magnetic structure E132/E435 Y in 24(c) positions. There are 2 figures and 1 table. ASSOCIATION: Institut kristallografii AN SSSR (Institute of Crystallography AS USSR) SUBMITTED: June 81 1962 Card 2/2 S/07o/62/007/006/017/020 E073/E335 AUTHORS:- KuzIminov, Yu.S., Yamzinj I*I., malltsev, Ye.l. and Belov, N.V. TITLE: Determination of the amplitude of Raman scattering of thermal neutrons on yttrium nuclei PERIODICAL: Kristallo-rafiyal.v. 71 no* 6,.1962, 9118 - 949 TEXT: The atlas of Hughes on neutron-cross-section gives the 24 2 value o= (8-0 +-0-3) x 10- cm 'It can be calculted from this 12 value that b 0.8 x 10- . cm. There was some doubt about Y this value since ~the references given by flughes did not contain information on the scattering of neutrons on yttrium. The authors of this paper determined. bY from the measured intensity of neutron diffraction on polycrystalline yttrium oxide, using a 15-mm diameter, 70 miti high specimen pressed from powder of a grain size .between 1 and 5 ji. The value of b Y was determined from tabulated values of b = 0-58 x 10-12 cm2 and the structural model of 0 Card 1/2 S/07o/62/0o7/oo6/0l7/O2O Determination of .... E073/E335 yttrium oxide, Ias published by W. Zachariasen (Nors1c. gool. tidss1cr, 9, 31o - 316, 1926; Struct. Rept., 16, 218, 1952). The average of three measurements of the anplitude of the Raman scattering was -12 b Y = (+o.816 + 0.07) x 10 CM . There is I fiSure. ASSOCIATIONS: Institut lzristallografii AN SSSR (Institute of Crystallography of the AS.USSR) Fiziko-taklinichoskiy institut AN SSSR (Physico- techni6al Institute of the AS USSR) SUBMITTED: June 8, 1962 ,_-BELW4-IL-Y4,SHAFRANGVSKIY, I. I. Role of E..S. Fedorov in the prebiBtorY of X-ray structural caI7stallograpby; 50th anniversary of the discovery of X-ray diffraction in crystals, Zap. Vass. min. ob-va 91 no.49 465-471 162. (MIRA 15-10) (X-ny crystallograpby) ASHIROV, A.; RUMANOVA, I.M.,,- BELOV N V akademik Crystalline structure of lesseriteI(WB30 5(.CH) 3) Dokl. AN SSSR 143 no.2:331-334 Mr 62. 10 Institut kristanografii AN SSSR (Crvotal lovaphy) STISHOV, S.M.I_gELOV. ,-j.,V,,_*ademIk Crystalline structure of a new dense silica (SiO2) modification. Dokl. AN SSSR. 143 no.4:951-954 Ap 162. (NIRA 15:3) 1. Moskovakiy gosudarstvannyy universitet im. M.V.Lomonosova i Institut fiziki vysokikh davleniy AN SSSR. (Silica) SHIBAYEVA,,R.P.1 BELOV, N,V,t akademik Crystall.1ne-structure.of rosenbugichite (CaINa)3(Zr,Ti) [SL20,71 (6,F)2. Dokl. AN S6A 143 no.68'1428-143 Ap '62. (~M l5s4) .(Minerals) AERASHEVP K.K.; BELOVJO N.V., akademik crystalline structure of bar:Uite (B&Be2Si2O7). Dokl.AN SSSR 144 no.3:636-638 Yj 162. (HUA 15 s 5) (Idnerale) (Cryot&Uography) SHIBAIZVAp RoP,j_~~LOVp N.V.., akademik Crystanine structure of.wohleritL Ca2Na(Zrq, Nb) [Si2O7](O)F)2* Dokl, AN.SSSR 146;no.4t897-900 0 162. (Km& i5m) i. inatitut kristallo afii AN SSSR. rMerite) RUDNEVA2 A.V.; NIKITIN2 A.V"_aX*X,,-~V. Wcademik Cefluorosil Ce-britholite. Dokl. AN SSSR 3.46 no-5-.1182-n83 0 162- (MIRA 15:10) (Britholite) NIKITIN, A.V.; BELOVp N*V.p akademik Cr7ital structure of batioite Na2BaTi2Si493,4= la2BaT2!,D2 IS'4932 I DAL AN SSSR 146 no.6:1401-1403 0 162. (MMA 15:10) (Hatisite) BOMOV SeVo- BEWT N,V. akademik "t.&Uine structure of aimpoonite Alj+Ta3Cb(r, ON)- DOkl- AN SSSR 147 no.3t683-M N 162a (MMA 15112) (Simpeonite) ASEEIROVO As.; MOM,, IsMel H=Vp N*V*# akademik ------------ "tal:Line structure of 4ydroboraoite CaftP6 6 0 Qft[tO4(OH)312-3R20. Dokl, AN SSSR 347 no*! D 162. (Hydroboraoite M-Ptals) (KMA l6s2) BELOV I N. V. "X'fiev inventory of silicate and related radicals infinite in one dimnsion." report submitted for 6th Gen Assembly, Intl Union of Crystallography, Rome, 9 Sep 63. Inst of Crystallography, AS USSR, Moscow* BAKAKIN~ V. V.; B=V -V. V - FLYUSNIKA is it "The crystal chemistry and infra-red spectra of beryl." report submitted for 6th Gen Assembly, Intl Union of Crystallography, Rome, 9 Sep 63- Inst Crystallography, AS USSR, Moscow. BELOVI N.V., Concerning a funIdamental generalization of V.I.Vernadakii. Ge6khimiia no.3t214-218 Mr 163. (KERA 16:9) 1. Institute of Crystallography, Acadeiq of Sciences, U*S*SeRof Moscow. (Crystallography) 4/070/63/008/001/004/02i 19132/19460 .:.AUTHORSt' Xualmino4s ~U.B*, rdazLn, X.X., T1TLSs A neutron dArrra6tion study of an yttrium-neoidywim ferrite ~th the garnet structure PERIODICALs Kristall gratiyag'v.8, no.1, 1963, 23L-24 : ' TBXT i A o1 ar st l i i f iti 4 a n men o on spec compos p y y A ' ' I 6 1 i rwh1o propered.by c - 3 T2 '- 5 Nd203 5IF0203, t4ohniques was Z 3 .. ' * ..examined at roori tomperature and at 360 C (abol e the Corte point) by neutrow diffraction. The wavelength was 14 ' ~ 1k R P th I 0 (J 1 11 ; 0) au . en et oood a . t -V#3 , no- L#PhYs prop .APP , 959, S9 scheme of.laternotions for'Sarnat structur:: Gnaostpoaitloft~ * p ~ f 4 t i M 0 0 4 , Neol o Ua r -are o s analysis or 8. llowlnS 51 3 2 S' o g 6 i ro ions ore 1n.-tetrshs4ml~V w1t1om oct. odr tions WaY, Pos s .24(d) ;and 6 rare.earth lons'ars in 24(c) positions wAt4 l ' t the G~b coordiAetion 8. (totrag. ,- anti-prism). He proposed the ML, latticis , a and oxchq~kzo intereetiew"d! - he t that the sub-lattice a was. "Snetimed anti-parellnl to resultant moment. The - Interaction c-d is weaker than K*P.Bilo;v and 'L.A.Mal*vakdys I on',tho other hand, ouggooted that t j, ' : tie** r a aub-lattico was not torromagn4tioally. ordered Ilav.'Aff. 80 'card An SOeO7O/63/008A*I/004/Q24- A noutro!n diffroac 9132/9460 tion4. t 1,7, v.25,! m6.21,~1961, 1371-1375). :',Tht latter suggestion ls,h#C4 h a own sxperJmentilly to:b 0 corrIc% The chemical unit callives cubid, X&3d -, with a) ~ 12A8 nd extra lines wore not -obverved.. Th6 intensities were measured and wees, n1:9 co3culatod. The dif f erences betwooo the intonalties above and bal W the C point gave,the magnetic tontributibn which was compared with calculated,from two su6-AattIc*v,(DOloV) and fro" three (Fautheftstlli V:ry good agreement w.10 Uslov's model was obtsined. The ncluxion.Vaj ih4ck compgaltion- 00 %mining's :specimen of .1:.f Y~03 11 ch~! i 5 N0203 5AX 26 1 fIllh should !'show. ixtis linei it OCV4 d aii 2 ri wow-e.;orderod these Werein .tfound. [Th an are -1 1AW 4h i AN 35SR ASSOC1.41rJOH; , InAitut'kristalletroft a -AS V&U)I-.'- stitute 'o C. Crystallogr phy Un V SUG"I*&W'' .'Aujost'. .4 C, ard V2 ,SMIRNOVA,.N.L.,- BELOV. N.V. Structural group of qutr~z. Kristallograftia 8 ne.3:34&350 It-je 163s (KCRA 16:4) 1, Institut krista3-lografii AN SSSR i Moskovskiy gosudarstvon- W universitet imeni Lomonasovae SHIUYEVA,, R.P.; SIMONOV, V.I.; B=V, N.V. GrystallJme structure-of the Ga. Na. Zr, Ti-silicate resenbuschite Ga3,5Na2 ~Zr(TisMnjNb)1SiA12F20(FjO). Kristallegraftia 8 no-4:506-- 516 n!1g 163. - (MRA 16:9) 1. Institut kristallografii AN SSSR. (Resenbuschite crystals) ZAGALISY,t%Y&,, Yu..G.; BELOV, N.V. Crystalline structure of zur*ite A1l3(OH).j8Si5O2OCl-,z [Al 2(CH/.j8.SiQ4]& 1Al(SiO4)4JCl- Kristallograftia 8 no.4.533-53? J1-AO 113 7KR:~ 16:9) 1. Institut kriStallo afii AN SSSR. rzunyite crystals) -6 M4P(q)/kW(m*)/KWP(B)/BDS AFMASD JD 0 i-AYCIS AP3004095 S/0070/63/008/004iO587/0594 AUTHOR: Belov, N. V. A new stock of one-dimensionally endless and similar radicals SOURCE: Kristallografiya, v. 8, no. 4, 1963, 587-594 -radical,* silicatb,' lattice, jffip TAM Si, 0, Ge, P; Be, F, Za crystalo onvelppe, orthoollicate, diorthosilLeate ABSTRACT: This work is-an expansion'of an Idea from the author's book (Kristallo- khimiya silikatov a krupny*mi kationami. Xzd-vo AN SSSR, M., 1961) that'silica i and silicate radicals in natural and synthetic silicates play the role of "pro- i tective envelopes" about other technologicarly more Important structural com- pone ts in the crystal lattice. He states that the first step in this "develop- mentle must be the formation of "piercing" silicate, chains with somewhat the same .':i metasilicate forimula [SiO33 but with various forms adapted to the basic struc. tural motif. This variety is attained by the simplest of means: by different proportions of the basic silicate increments (the orthogroup [Si04] and the Card 1'/,V,2- V 19460-63 ACCESSION NR: AP3004095 A large part of the second group is '-4iorthogroup ES 1207 ) in the chain. necessarily tied up-with large cations. The orthogroup isneeded not only Vith, small cations but also for more con4enient linking of basic diorthogroups. the author points out a great number of structural arrangements, some known for a 11ong time, some observed only in recent years (many in synthetic mnerals), and now some altogether new ones , Nine new chains are diacussed and are illustrAted in Fig. 1'(see enclosure). ;rig. art. has: 11 figuresi ASSOCIATION: Institut kristallografii AN SSSR (Insti~ut'e of Crys~allography, Academy of Sciences, SSSR) SUBMITTED: 12Mar63 DATE ACq: l5Aug63 ENCL: 01 i,SUB CODE: PH NO REP SOV-.1 018 OTHER: 006., r-4 7 /10~ POBEDIMSKAY&j, Ye.A.,- BF-LOV, H.V- !~~Wnftwftffiws"e A useful theorem in structure (or lattice) crystallography. Kristal- lograftia 8 no./+:674-675 -Tl-A9 '63* (MM 16:9) ~ 1. Institut kristallWafii AN SSSR i Moskovskiy gosudarstvennyy universitet imeni Lemonoseva. (Crystallography, Mathematical) EWP(q)/tWr(m)/bDS/ZdP(B) AUTcAsD m S/0070/63/008/004/0675/.0677 I-AdSTIO-N.NR: AP3004105 _XguElminov. Yu. S.; Belov, N. V TITLEC Amplitude of coherent neutron'scattering 'by gallium nuclei afiya, v. 8, no'. 4, 1963, 675 u- .677 SOURCE: Kristallogr TAGS; scat scattering, Ga, Y, 0, Fe, I TOFIC tering, amplitude, neutrons, coherent 'ferrits ceramics, diffrabtion ABSTRACT: -The: authors undertbod this study because data for this factor are not 1~' given in the revisededition of G. E. Bacon's book (Neutron Diffraction. oxford. 1962). Samples were prepared by ceramic procedures normally used to prepare A--ferrites. Cylinders 100 mm high and 10 mm.in diameter were constr 'ucted from 20 separate plates. Results were obtained from diffraction intensities off L with corresponding amplitudes, are various reflecting planes.~ These values, shown in Table I (sei enclosure). "The authors express their thanks to Engineer Ye. I. Malltsev (FTI AN SSSR) for his aid in measurements on the investigated It .,has: 1 table. samples...'Orig. art. card POBEDIMSKAYA, Ye.A.; BEIDV, N.V. Cr7stalline structure of mordenite (ptilolite) N A' Si = 8NaAlSi Kristallografiia 8 a8 ~8 40096- 24H20- 5012.3H20. no.6.-919-921 N-D'63. (MIRA 17t2) 1. Inatitut kristallografii AN SSSR. NIKITIN, A.V.; akademik Crystalline structure'of oUnohedrite Ga2Zn2(OH)2Si2O7-H2O 2CaZu[SiO4]-H20. Dokl. AN SSSR 148 no.6:1386-1388 'F .(K= 160) 1. Inatitut kristallografii. AN SSSR,, (minerals) (Crystallography)