SCIENTIFIC ABSTRACT BELIKOV, S. I. - BELIKOV, V. M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000204320004-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

_~~L~KOV,-,~~rgpy..,I,vano,vicb,,jnzh.; DOKUNINA,
Natallya Aleksandrovnai
kand. tekhn. rauk; BURDINA, Nadezhda Nikola-yevna,
inzh.;
IOINZBERG, F.Te.,inzh., rsUsnzent; YAKUSHKV,
A.I.,prof.doktor
tekhn. nauk, retsenzent; B%ISHTEYN, S.I., inzh., red.;
STEPANOVA, A.A., red. izd-va,- IIOVIK, A.Ya., tekhn.
red.
[Allowances, fits and technical measurements in the
manufacture of aircraft] Dopuski, posadki i
tekhnicheskie iz-
nereniia v proizvodstve letateltrWkh apparatov. Moskva,
Oboron-
giz, 1963. 290 p. (MIRA 17:2)

Charging storage batteries on cars. Ayt. transp. 35
no.5:35 MY 157,
(Automobiles-Bateries) (Kuu lotO

BILIKOV, V.
route into the cosmos. lUn.tekh. 2 no.1:30-31 Mr 158. (XIRA
11:1)
1. TSenbrnl~nnya stiduya dokumentAlinvkh fillmov.
(SDace flieht)

ACC NR. AN7004844 COEE: UR/9003/67/000/038/oooh/ooo4
AUTHOR: Belikov, V.; Osipov, B.
ORG: 'none
TITLE: Electronic computer serves aeroflot.
SOURCE: Izvestiyas nop '38, 14 Foo 67, P- 4, Col.7
TOPIC TAGS: electronic computer, civil aviation', e4-X~&-' Q
ABSTRACT:
Last year Aeroflot transported 53 million passengers* .The newly established
firm "Avtomatika" will do the cybernetics work by which with the help of a
computer it will be possible to find out exactly the uunber of passenger
seats available. The Ministry of Civil Aviation of the USSR thinks that
the automated system of ordering and selling tickets will work 2 1/2 times
-faster.than the most experienced cashiers.
SUB CODE: 09P/ SUB~ DATE: ~none/ ATD PRESS: 5114
WN

112-2-3111
Translation from: Referativnyy Zhurna.1, Elektrotekhnika,
1957,
Nr 2, p. 83 (USSR)
AUTHOR., Belikov, V. A.
TITLE: Systems and the Technical and Economic Factors of City
Distribution Networks (Skhemy i tekhniko-ekonomicheskiye
pokazateli gorodskikh raspredelitellnykh .setey)
PERIODICAL: In Sbornik; Vopr. postroyeniya gor. elektr.
setey, Moscow,
M-vo kommun. kh-va RSFSR, 1956o PP. 33-72
ABSTRACTt It is pointed out that low-voltage radial networks
often
do not come up to the high standards of reliability and
qq9nomy demanded of city networks. For regions of four-
and'five-story structures with a considerable number of
responsible consumers, low voltage parallel-or multiple-
series connected networks with reverse-power'automatic
switches with reserve transformer power and reserve carry-
ing capacity are recommerled. For regions of new building
developments, intra-block, parallel-oonneated cable net- ,
works should be used. Extra-block networks using existing
Card 1/3 cables and overhead lines should be used in regions
of

112-2-3111
Systems and the Techni.cal and Economic Factors of City (ContJ
old building developments. Where faetory-made automatic
network
switches are not available, theLA-2,000 automatic air circuit
breakers in conjunction with two "M6-171/1 power relays can be
used for network protection. In 380/220-v networks the relay
should be switched on a 900 phase connection diagram and in
220/127-v networks, on a 600 phase connection. In most caBes
it
is possible to dispense with safety fuses between the
transformer
and the low-voltage installation. For regions where I to 3
story
buildings predominate and where there Is a small number of
responsible consumers, ring,series- and parallel- connected
net-
works are recommended. These networks would be without
automatic
switches, but woluld have safety fuse protection; they would
have
no reserve, or only a minimal transformer power and network
carrying capacity reserve. In.regions of new construction, the
ring, overhead intra-blook network should be used. In regions
of-old building construction the extra-block, series-or
parallel-
connected circuit utilizing existing-lines should be used.
In the latter case, the changeover to closed-circuit operation
must be based on.economic considerations. Individual,
especially
Card 2/3

112-2-3111
Systems and the Technical and Economic Factors of City
(cont.)
responsible consumers can be supplied with individual,
automatic
reserve by equipping the feeders to the house with
contactorg.
The utilization of high-voltage bi-radial networks for
groups of
four-and five-story apartment buildings is not recommended as
it may lead to excessive,capital investment or, in the case
of
transformer-point enlargement, to overexpenditure of
non-ferrous
metals.
Y&.K.Ch.
Card 3/3

BELIKOV, V.A.
Model Tirojects of educational workshon units for
schools.
Politekh.obuch. no-8:75-82 Ar, 157. (MLRA 10:9)
1. Glavnvv inzhener Unravlealya 'Kapitallnogo
stroitalletva
Hinisterstva. oroavesheheniya RUM.
(TechaicR1 education) (Workshops)

AUMR:
Sergeyev, A.S., Docent 105-58-5--23/28
TITLE:
Dissertations
(Dissertatsii)
PERIODICAL:
Elektrichestvo, 1958, Nr 5, pp. 89-91
(USSR)
ABSTRACT:
For the Degree of Candidate of Technical Sciences.

At the Academy for Cowmunal Ecorlomy imeni Famfilov (Akademiya

kommunallnogo, khozyaystva im. Pamfilova).

P.F.Gogichaishvili on
May 29, 1951 "Electric Energy Distribution

in Rural Areas with
Low-Storey Houses". Official opponents:

I.A.Budzko,Doctor of
Technical Sciences, and N.K. Arkhipov, Engineer.

V.A.Belikov on MV
3, 1954 "Investigation of Basic Problems of the

-S`uing- of Urban
Closed Low-Voltage Networks". Official opponents:

G.I.Atabekov,
Professor, Dootor of Technical Sciences and

N.A.Mellnikov, Docent,
Candidata of Technical Sciences.

At the Moscow Technological
Institute of the Pool Indusin

(Moskovskiy tekhnologicheskiy
institut pishchevoy promyshlennosti):

G.V.Drevs on February ig,
1947 "Electromechanical Equipment of

Mill-s,Grain Works and Grain
Elevators". Official opponents:
Card 1/4
P=fessor K.G.Markvardt,
Docent A.Ya.Sokolov and Engineer Galitsa.

Dissertations
105-58-5-23/28
At the All-Union Gorre rAn"ma P^13ftpehnin TngtailliA
(VsesoyLlznyy zaochnyy politekhnich6skiy in3titUt):
B.B.Lurlye on November 21, 1949 "Leona- rd Connection with
Introduc--
tion of Generator-Armature Voltage into the Circuit of its
Excit-
ing Winding'. Official opponents: N.V. GorokhaT, Professor,
Doctor
of Technical Sciences zmd Engineer A.Xe.Gurevich.
S.A.Esman on June 22, 1950 "Theory and kethods of
Calculation of
the Electric Drive and the Control Scheme of "Flying
Scissors".
Official opponents: I.G.KullbaohWj, Professor, Doctor of
Technical
Sciences ana Ye.V.Nitusov, Professor, Doctor of Technical
Sciences.
S.Ya.Duna,yevs on Jund 29, 1950 I'Analysis of
Transitorylkodes of
Operation in the Generator-I'Lotor System in Consideration of
Saturation and Eddy.Currents". Official opponents:
Ye.V.Ni,,6u3ov,
Professor, Doctor of Technical Sciences and K.V.Urnov,
Candidate
of Technical Sciences.
V.D.Yurenkov on FebruarY 5, '1951 "Capacitive Electric
Energy Ab-
straotion at the Antenna of Electric Transmission Lines".
Official
opponents; G.I.Atabekov, Professor, Doctor of Technical
Sciences
and N.A. Mellnikov, Docent, Candidate of Technical Sciences.
Card 2/4

Dissertations
105-58-5-2-V28
M.A.Son' kin on November 5, 1951 "Electric Drive with a
Control
as Current Function for the Mechanism of Rolling kills".
Official
opponents: A.N.Larionov, Professor, Doctor of Technical
Sciences
and F.A.Goryainov, Docent, Candidate of Technical Sciences.
G.P.Khalizev on June 25, 1951 "Problems of Theory and
Practice in
the Electric Drives of Rolling Staircases (Escalators)".
Official
opponentst N.V.Gorokhov, Professor, Doctor of Technical
Sciences
and K.V.Urnov, Docent, Canlidate of Technical Sciences.
G.B.Yakusha on October 6, 1952 "Melting of Iced Parts of
Open-
Air Transmission Lines of 35-110 kV Electric Transmission by
Means
of Electric Current". Official opp-cinents: V.V.B-argsc3orf,
Profeasor,
Doctor of Technical Sciences and 14.I.Tsarev, Caniidate of
Technical
Sciences.
At the Leningrad Institute f-r the Construction of Aircraft
Equipment (Leningmdskiy tnstitut aviatsionnogo,
priborostroyen.-A'.ya).
I.A.Glebov on November 4. 1',49 "Investigation of a
Synchronous
Generator with Ion Transforw-.r in the Exciter Circuit".
Official
opponents: L.H.Gruzov, Professor, Doctor of Technical
Sciences and
Card 3/4 M.I.Oranskiy, Docent, Candidate of Technical
Sciences.

Dissertations
AVAILABLE:
4105-58-~-2YZ8
B.V.Prolov on April 25, 1950 "Investigation of the Scheme
of a
Cascade Connection of an Asynchronous Machine with Ion
Trans-
former". Official opponents: A.Ye.Kaplyanakiy, Professor,
Doctor
of Technical Sciences and Engineer G.K.Zherve.
S.I.Barainskiy on April 16, 1953 "Investigation of an
Asynch-rono7az
Ion Cascade in Generator Operatiod'. Official opponents:
O.B.Bron,
Professor, Doctor of Technical Sciences ana N.D.Panot',
Candidate
of Technical Sciences.
Library of Congress
1. Scientific reports--USSR 2. Electrical equipment--USSR
Card 4/4

BELIKOV,,V.A... insh.
eating prestressed concrete trusses in a horizontal position.
Trudy NIIZB no.16:341-149 160. (MIRA 14:5)
(Prestressed concrete-Testing)
(Truar;es)
Xv.
11.,

BULGAKOV, V.S.0 kand. tekhn. nauk; MATKOV., N.G.0
kand, tekhn. nauk;
;, - I
~A inzh.; VASIL', A.P., kand. tekhn. naukp red.;
KLIY,GVA, G.D., red. izd-va; SHEVCHENKO, T.N., tekhn.
red.
[Handbook on injecting the channels in prestressed
concrete
elements with mortar]Rukovodstvo po inueteirovaniiu
kanalov pred-
varitellno napriazhenrWkh zhelezobetonnykh
konstruktsii. Moskva)
Gosstroiizdat, 1962. 28 p. (MIRA 15:9)
1. Akademiya stroitelletva i arkhitaktury SSSR.
Institut betona i
zhelezobetomp Perovo.
(Prestressed concrete)

MLIKOV V IL.1 BESSISRTNII, 1,3.; GIAZUIIOV; A.A.;
IOKIIVIDOV, E.S.;
V.A.j KUMILMOV, X4,3.; MRM, G.V.; SOIDATFINA., LJ.;
IEDWETIO, R.Ya.
"I'tuidamontal problems concerning the design of
municip&I electric
power dietribution. reWorks" by B.L. Ai2enberg and S.N.
Nikogosov.
Reriewed by M. Belikov and others. Slaktrichostvo
no.7:93-94
J1 162. (MIRA 15.7)
1. Moskovaldy inzhenerno-ekonomichosItty institut imeni
S. Ordzhonikidze (for Bolil;ov). 2. Giprokom=icnergo
(for
Bessmortnyy). 3. Moskavskiy energetichesldy institut
(for Glazunov,
Soldatkina) - 4- Mosk(rrskoye rayonnoye upravloniye
energetichaskogo
khozyaystva (for iokh7idov). 5. Leningradskaya
kabellmaya set,
Lcningpadskogo upravloniya energokhozyaystvom Glavenergo
Mhi".StOstva Plektrostantsiy 3S8R (for Kozlov). 6.
Mosinzhproyekt
(for Kuinetsov). 7. Upravleniye po proyektirovaniyu
zhilishcbno--
grazhdanskogo I kommunallnogo stroitellstva g. Moskyy
(for IUxer).
S. Akademiya kommunallnogo kbozyaystva im. K.D.
?arifilova (for
Fedosenko).
(Electric power distribution)
(Aizenberg, B.L.) (Nikogosov, S.N.)

SHPAN*0141 P.A.; BFLIKOV, V.A.
Active spectral method for testing diodo
irGdulation imoters.
Izm. teldi. no..1:43-45 Ja 164. -
I (MIRA 17:11)

ACC NR: AP71DO5261 SOURCE CODE: UR/0003/67/000/001/0087/0088
,%U711OR: Mistrykin, A. N. (Docent; Candidate of techAical
sciences); Belikov, V. A.
(Doceatt Candidate of technical sciences); Zhadin, K.i
P-'(Deceasedo, Do'c_~en, ~idste
z
of technical sciences); Padalko, L. P. (Engineer)
1ORG: Noscow EnGineering-Economics 'Institute im. S.
Ordzhonikidze (Hoskovskiy inzhene
n6-ekonomicheskiy institut)
,TITLE: Computers and education
SOURCE: Vestnik vysshey sbkoly, ~'no. 1, 1967, 87-88
TOPIC TAGS: computer techniquei, ('0n7PUrV`X" 77,FC11A~04-06LIf
*(-11) rA0A/
ABSTRACT-
One of ihe problems encotintered fn' training sEudents of
technical and
economic institutes of higher education ia the practical
mastery of computer
technology. To - this ef fect, the authors describe the'
experience at the bbscow
Engineer ing-Economic Institute,'where for several years
the'Ural-4 has been
used for diploma projects in the'Electric Stations and Systems
Department
-The authors conclude that the iise of mathematical methods
and computers will
help improve the mothodical cooperation between' the
Mathematics, Computer
Technology, and Engineering departments. In adlditio~, it i-
now 'practical to
create manuals of'a new'type so that the solutions r4 problems
contained
I*therein will require the application of cquputers. tuch a
manual is being
]S,~Bepax'Q- 09/ SUBM DATE:* hohe/ ATD FORMS: 5114
..,COVE: Ir". ____ (

BELIKOVI V.A., kand.tekhn.nauk
Principles of efficient construction of 6-10 kv. municipal
power distribution networks. Nov.tekh.zhil.-kom.khoz.:
Elek.i tepl. gor. no.5:16-31 161.
(KRA 18:9)

BELIKOV, V.D.; DENISOV, V.N.
------
MachamAsing the sprinkling of public gFdpi* and
flower bedis#
Gor, Pos. Mosk. 36 no.lOs42-0 0 162. (MIR& 15:12)
(Sprink1era)

BELIKOV, V.D.
Experimental study of the distributing apparatus
of rotary
snow loaders. Nauch. trudy AKKR no-32:117-126 164.
Methods of snow loading into transportation
vehicles. Ibid..
127-134 (MIRA 19:1)

~-~~JXOT, V..G.
. -4
"
Selecting the quantity of circulating fluid and the
turbocirill. in
developing efficient drilling conditions.
Aserb.neftekhos. 35 n0*7:
Jl '56. (nU 9:12)
(Turbodrills) (Oil well drilling)

B
I -, -,
XNA490SIT
PWIIO
Relation between
area of the bit.
the performance of a turbodrill and
Azerb. neft. khoz. 36 no,5:12-14 Xv
(Boring machinery)
the effective
157.
(MIRA 11.0t1l)

BELIKOV, V. G .
BELIKOV, V.G., Cand Teck, Sci -- (diss) "Appearance
of reserves
and means of increasing the indicators of turbine
driLling on areas of
the Eastern Pre-Caucasus." Baku,, 1958. 10 pp, (VAn
of Higher Education
USSR. Azerb Wer of Iabor Red Banner Indus Inst im M.
Azizbekov).
100 copies (KL, 20-58,96)

Effect- O-f-alx-bl~oad on the speed of rotation of turb
drill sbafts. Izv.vye.ucbeb.zav.,- noft' i gaz I no.11:37-42
'58. (HIRk 12:5)
1. Grozuenskiy neftyanoy, inBtitut.
(Turbodrills)

V, yc,-
93-58-3-7/17
AUTHOR: Belikov,, V. G.
TITM: Tooth 4acing in Cone Rock Bits (0 velichine shags zublyev
sharosheelanykh dolot)
PERIODICAL: Neftyanoye khozyaystvo., 1958, Nr 3, pp 29-33 (LWR)
AMTRAOT: Me article reviews the literature and experimental data
on cone rock
bits. V, S. Fedorov (Aef lj points out that the harder the forma-
tion and the lighter the weight on the bit., the smaller must be
the
space between the teeth of the bit. HIgh-speed M-Ing of cone rock
bits operations done by the All-Union Desijp and Planning
Scientific
Research Institute for Drilling Oil and CAs Wells (VMMnnmeft)
showed that formation breaktV efficiency increases with increased
spacing of the teeth [Bef 23. Mie author points oat Viat three cone
rock bits are of the M, 8, T. and K type designed for soft..
average,
above average, and hard formations renective These four tnes
. An analysis of bit
of bits differ in their tooth spacing (T~qble 1~1
performance invells of the Guderms Drilling Depar-tment (GUAermes
skaya kontore4xreiVa) under the authority of the State All-Union
Card V3

93-58-3-7/17
Tooth Opacing in Cone, Rock Bits (Co"at.)
Of
IV
Association of the Groznyy Oil and Gas 3ndustry (Gro2neft shows
that in
sandy forAatimas the performance of M type b:L-I,,s is gone-rally
superior to S t~fpe
bits (Table 2). r%1, Is substumYtiated by drilling data frcm
various Grozaeft'
oil fields (ft-ble 3). An analysis made by the Gro--V7 Petroleum
Scientific
ReseszmIt 1-asti-tute (GrozHII) also disclosed thei, M. 3.2 M tyye
bits perform
better ia semEy fox-miions thEm B type bits. M3P. beat results vere
obtained
in the Starogrozuensh., P-ia Mxderwes oil :mgionn. Experimental
drill.Ung an--n-led out by tha go-tvar 11re-sh-Kals, Drilling
Depextmnt in the Kara,-~,an,
and Chala-Sx, sandstane fomr-tionn hzas elso .ihcrm tbat X type
bits can be used in
ezep de-1,1ing of cla)vy and sandy foymvtions as well as clayey
formations inter-
beddecl -orith mexl or Imrd sandstone (Wblle 4). A emwarison of
data on drilling
in the fild--nr-,ka (Xkht-yrskaya), BugrnCyxr, ead Gox-.,-achiy
M.7.mch oil pools under the
authov:Lty of Ithe. State All.-Uhiaa Associmtiaii of the ELvznodar
Oil and Gas Indtistry
(KrasnoRpamefft-) has also discloaecl the superiority of M type
bits over S type
bits (R-af 41. Experizaental drilling carried out by the Petroleum
Production
Administration of the State All-Union AdmInistration of the
Abinskiy Petroleum
Madustry (1-TU Abinneft I) with MMM-10n turbod-rille using SM-12 M
tvOe bits and
VSS-12 S type bits also shave the. superiority of M type bits
(Table ;)* Hadever,,
Card 2/3

93-58-3-7/17
Tooth Spacing in Cone Rock Bits (Cont,)
the efficiency of the M type bits as compared with the S type
bits decreases
.Lue on the turbodrill shaft is inadequate
when the torc (Table 6). =s deterjore,
tion in efficiency is shown in drilling with TIM-101 turbodrills
and No. 14
M type bits of larger diemater (Table 7), as well as by data on
drilling in the
Bragany region (Table 8) eVen in OlWy formations (Table 9). in
1950,
P. D. Zenkov [Ref 71 was against the use of VEM-12 bits in
sandstone formtions
and at that time his conclusion was correct since the perfonwace
of the,.VSM-12
bits was inferior to that of the ZIS-7 bits (Table 10). At
present, hwever,
this cone-fusion is wrong since the xode~n WM-101' turbodrills as
compared with
the T1,4,M-9 3/4" turbodrills devi-lop a higher rotation zoment.
The author con-
cludes that the bits must be redesigned to suit the newer
turbodtills of hig'a
ratation moment, that bits with nexmr spaced teeth are best for
turbodri2ls of
2.aw rotation mment., that for present-day turbodrills M type
bits Oze generall-ly
better'than the S type bits for dri3JIng sandelone form-tions in
the Sqathern
regians, and that increased efficiency in rock breakup will
probably remUt
from using bits with the widest possible tooth spa-cing. He also
believes that
the potential posa;Lbi3ities of three cone rock bits in turbine
drIlling have not
yet been fauy exhausted. There a-re 10 tables and 9 references of
which 8 are
aovtet and one is Engliah.
AVAUJXSI: lZbraxy of Congress
Card 3/3

BILIKOV, V.G.
Adaptability of turbodrills to axial bit loading. Izv.
V.Ve. ucheb
zar.; neft' i gaz no.4:27-32 158. (MIRA 11:9)
I.Azerbaydzhanskiy industrial' W inetitimt im. M.
Azisbekova,
'(Turbodrtl1Q ' '

-
Drop method for the detection of thioaulfate Ions
with the use
of.aodium nitroprussiae. Naucb.dokl.vve.shkoly;
khln.i. kbimo
tekh. no.1:108-109 159. (MIRA 12:3)
1. Predstavlana kafedroy farzatsevticheskoy khimii
Pyatigor-
skogo goaudarstvanno farmatsevtichaskogo instituta.
(Thioaulfatpe) (Sodium nitroprussides)

rEDOROV, V.S.; IMLIEDV, V.G.
Starting up turbodrills. Izv. v7s. ucheb. sav.;
neft' I gaz 2
no.4:29-33 159. (MIRA 12:10)
l.Groznenski3r neft7anoy institut.
(Turbodrills)

. BBLIMV, V.G.
Turbodrills with a reduced number of stages and turbodrills
with
hollow shafts. Isv. vVe. uOheb. xav.; neft' i gas 2
no.8:27-30
159. (MU 12:11)
1,Groznenskiy neftyanoT institut,
kTurbodrille)

BILIKOV, V. G.
.4-,-
Practicability of the use of high-volumetric capacity
turbodrills
and h6llow-shaft turbodrills. Neft.khoz- 37 no.2:31-33
P '59.
(MIRA 12:4)
Owbodrills)

FEDOROV, V.S.- BELIKOV V G ISAYEVA, V.V., ved. red.;
BASHMJkKOV, G.M.,
tekhn, -~e-d.
(Methods of generalizing progreasive practices in the
technology
of boring] Metody obobshcheniia peredcvogo cpyta v
tekhnolcgii
bareniia. Moskva, Gcstoptekbizdat, 1962. 155 P. (MIRA 15:5)
(Boring)

.. BLLIKOV,, V.G.; ALFKSANDROV, M M.
More about the problem of determining the basic
hydraulic
pexameters of a turbine drilling rig. 12V. VYS.
ucheb. zav.;
neft' i gaz 8 no.1:11?-119 165. (MIRA 18.2)
1. Groznenskiy neftyanoy institut.

BELIKOVP V.G.
Formioaible axial load on a bit in electric drilling.
Izv. vys.
ucheb. zav.; neft' I gaz 8 no.3:21-24 165.
(~aRA 18:5)
1. Groznenskiy neftyanoy institut.

AUTHOR: Belikov, V.G. 32-12-15/71
TITLE: Short Reports (1) (Korotkiye 3oobshcheniya).
PERIODICAL: Zavodskaya Laboratoriya, 1957, Vol. 23, Nr 12,
pp. il+37-i437 (USSR)
ABSTRACT: For the purpose of aetemining the presence of
aniline in any
medium it is recommended in this paper to make use of its
reaction
to sodium-nitroprusside. The reagent is in this case used in
a
1% concentration after first having been exposed to solar
radiation
(for 6-15 minutes according to the time of the year) or that
of a
quartz lainp (20-25 minutes from a distance of 10 cm).
Analysis is
carried out in a slightly acid medium, and after 5 to 6
seconds of
reaction, a blue coloring should become noticeable. When
carrying
out the analysis according to the drop method it is possible
to
find a minimum content of UP to 0,71* with a ailuting limit
of
1:5G.000. This kind of reaction is recommended for the
determination
of the presence of aniline in antifebrine as well as in -the
air,
Card 1/2

Short R"orts ( I) 32-12-IV71
ASSOCUTION: Pyatigorsk Pharmaceutical Institute
(Pyatigorskiy
farmatsevticheakiy institut).
AVAILABLE: Library of Congress
Card 2/2 1. Aniline-Determination 2. Sodium
nitroprusside-Reactions

BELIKOV, V.G.
'r ........ ....
Purity test for chlorstone and labeline hydrochloride.
Redeprom. 12 no.6:31-33 Je 158 (MIRA 11:7)
1. Pyatigorskiy farmateevticheskiy institut.
(LMLINN)
(PROPANOI)

V.G. I C:-."(l f~;Ci in)'Tti of -,odium
urunride in tho 1-mrlit -Aklivi~. of
n, r :, tinns ("in orl
All 1e ."Mc in
ordt'llold'aid7o TNIT-111"I) 2150 1,~O.Aof~ ( 1" _rtl

5(2) SOV/156-59-1-26/54
AUTHOR: Belikov, V. G.
TITLE: A Drop Method for Indicating the Thiosulphate Ion by Means
of 3odium 11itroprusside (Kapellnyy metod otkrytiya iona
tiosultfata a pomoshchtyu nitroprussida, natriya)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Khimiya i
khimicheskaya.
teklinologiya, 19597 Nr 1, pp 100-109 (USSR)
ABSTRACT: It is very complicated to indicate the thiosulphate
ion in
the presence of sulphide, sulphite and sulphate ions. For
this reason a method has been developed in which the thio-
ul
s
"phate is reduced to sulphide with caustic sodas the residue
is calcined and has then added to it one drop of 0.1% sodium
nitroprusside solution. A durabley red-violet color is ob-
tained, The reaction takes place even with 2y thiosulphate
and a dilution of 1:10,000. The disturbing sulphide ion must
previously be removed by cadmium acetate and the surplus
cadmium must be removed by caustic soda. The second drop
method makes possible the stagewise determination of sulphate,
thiosulphate and sulphite in the presence of sulphate. Sulphide
ion reacts in solution while assuming a violet color after
the addition of one drop of 10% caustic soda and I drop of
Card 1/2 W% solution of sodium nitroprusside to a drop of the
solution

SOV/156-59-1-26/54
A Drop Method for Indicating the Thiosulphate Ion by MeanB-of
Sodium
Hitroprusside
to be investigated. Then 0-5 mole of a 5~ solution of cadmium
acetate and I mole 10% caustic soda are added to 1 mole of
the solution to be investigated. The precipitate is removed
by filtration and one drop is removed by evaporation and has
a drop of sodium nitroprusBide added thereto. Thiosulphate
reacts while assuming a red.-violet color. To,'determine the
sulphite one drop of 10~ potassium ferrocyanide solution and
a drop of 1% solution of sodium nitroprusside are added to
a drop of a saturated zinc sulphate solution. A drop of the
solution to be investigated is added to the white precipitate
fornyed. The precipitate assumes a red color when mixed through
in the presence of sulfite ions. The analysis can be carried
out within 5 minutes. There are 2 Soviet references.
ASSOCIATION: Kafedra farmatsevticheakoy '-~himii Pyatigorskogo
gosudaretvennogo
farmatsevticheskogo instituta
(Chair of Pharmaceutical Chemistry of Pyatigorsk State Institute
of Fharmnceutics)
SUBMITTED: July 199 1958
Card 2/2

BZLIKOT, V.G..(Pyat1gor9k)
New method of aniline detection in sanitary and hygenic
studies. Gig.
truda i prof.zab. 3 no,503-54 S-0 159. (MIRA 13:2)
1. Yarmateevticheskiy In6titut.
(ANILINX) (SDDIUM NITROPRUSSIDES)

BALIKOV, V.G. ,
"litutive analysis of tibone, cutiaone and phytoncide
preparations of onion v6nd garlic. Med.prom. 13 no.4:52-54
Ap '59. (MIRA 12:6)
1e P~atigorskiy farmatsevtIcheskiy institut.
(KCBMILID) (CuWammm) (PHYTONCIDES)

5 (2)

AUTHOR:
Belikov, V. Go SOV/32-25-8-11/44
TITLE:
New Color
Reaction of the Thiosemicarbazide With Sodium-nitro-

prusside
PERIODICAL;
Zavodskaya laboratoriya, 1959, Vol 25, Nr 8, P 931
(USSR)
ABSTRACT:
Reference I recommends a color reaction on
thiosemicarbazide M

based on the reaction of (I) with sodium
nitroprusside (II)

with hydroxylamine (M) and caustic soda (IV)
at which a red

coloring is formed. Thiourea produces the same
reaction and the

mixture (11), (III)v and (IV) itself is red. In
the present

case it was established that an ammoniacal solution
of (I) with

(II) has a red-orange coloring which turns to an
intense red-

violet at the addition of glacial acetic acidl this
coloring

remains for several hours. The Ammoniacal solution of
(II)

(without (I)) is a light yellow and becomes colorless after
the

addition of glacial acetic aoid. The article contains the
re-

action mechanism and two kinds of analysis, a macromethod
and

a drop-weight method. The reaction makes possible the
determina-

tion of 100 Wof (I) in I ml or 4 r of (1) in one drop
of the

solution to be investigated. There is 1 Soviet reference.
Card 1/2

New Color Reaction of the Thiosemicarbazide With
SOV/32-25-8-11/44
Sodium-nitroprusside
LSSOCIATION: Pyatigorskiy farmatsevticheskiy institut
(Pyatigorsk Pharma-
ceutical Institute)
Card 2/2

GRUZNOVA,
Detection and determination of aniline in medicolegal
Investigations.
Bud.-med.okeport. 2 no*4:39-43 O-D 159. (min 13:5)
1. rafedry sudebnoy khimii (2av. - doteent Te.A.
Gryaznova) i
farmatoevticheekoy khimii (zav. - doteent V.N.
Berushteyn) Prati-
gorskogo farmateevtichookogo Instituta.
(Aximn-AmTsis)

AMIKOV, V.G.
- - -------------
Detection of novdrsen~ol by means of sodium
nitroprusside. lzv.
vys.ucheb.zav.; khim.i. khim tekh, 3 no.1:78-79 160,
(MM 13iro)
1, Xafedra farmatoevticheakoy khimii Y~ratigorskogo
farmateevti-
cheekogo instituta.
(Ifeocinchop6n) (Sodium nitroprussid'e)

C. mmIrOV,--T-G-
RUse of sodium nitroprusside in the qualitative
analysis of
oharmacoutteal chemicalew by V*G* Selikov* Ned.prome
14 uo*6t
62 Je 16o. (XM 13:6)
(CHBKI=Tg KKDICAL AND PRMMCMICAL)
(NITRMWBSMXS)

BELIKOV9 V.G.
Sodium nitropruaside as a reapnt for salkaloids.
Mod. prm. 34
no.9;43-47 S 160* (WA 23;9)
1, Pyatigorskiy farmatsevticheskiy institut.
(SODIM4 NITROPRUSSIDE) (ALUWIDS)

BUT OV, V.G.j__4asistent; SMI"OVAt L.N.P studentka IV kt&w
-- - -- ---- I ' 1j,
Drop method for the do otion of penicil1in in medicinal
forms.
Apt. delo 10 nos 2:32-3 Mr-Ap 101* (MIRA 14:4)
1. Kafedra fax-mateevticheBkoy khi-ii Pyatigorskogo
farmatBevti-
cheskogo instituta (nauchnyy rukovoditell - kandidat
khimichaskikh
nauk doteent V*N* Bernshteyn).
(PENICILLIN)

BELIKOV, V.G.; BERNSHTEMP V.N.
Colorimetric determination cf pilocarpine. Med. prom. 15
no.11,
59-61 N 161. MM 15.- 6)
1. Pyatigorskiy farmtsevticheskiyinstitut.
(PILOCARPIM) (CMMMTRY)

SEMHTM, V.N.; V.D.
Sodi= nitroprui3side and its uses in analytical chemistry. Usp.
khime 30 no* 4.502-51,9 Ap 161. (MIRA 1414)
L Pyatigorskiy farmatoevticbeekiy institut,
(Sodium nitroprusside)

BELIKOV, V,G.
Qualitativo and photocolorltaotric determination of small
quantlUeo
of synestrol. VU. prom. 17 no.9.32-35 S163- (MIRA 17-5)
1. PyatigorskLy farmatsevticheskiy institut.

BM=OVp.y~.~.;,,jZK'MCHlKOVA, G.l.; BEMSHTEYN, V.N.; KUM
I.Ya,
New qualitative roa4tiono for apressine. Aptech. delo
12 no.3t
60-62 Hy4e 163 (KM 17t2)
l..Fyatigorskiy farmatowticheskiy Institute

BELIKOV, V,M.; MAYRANOVSKIY, S.G.; KORCHEMNAYA, TS.B.; GULITYAY,
V.P.
Tautomerism of nitro compounds. Report No.5s Polarographic study
of recombination of nitroacetic aster anion. Izv. AN SSSR.
Ser.khim.
no.3:439-444 Mr 164. (MIRA 17W
1. Institut organicheskoy khimli im. N.D.Zellnskogo AN SSSR i
Institut elementoorganicheakikh soyedineniy AN WSR.

BELIKC'i- V.G. D.1, l.:r,j. ta~,Jn.
., il!zl:.; (;C)f A;HAREW. elfI
Mining an extraizely thin flat aaa;ii idth a
-.~crapjr-plcv unitu.
Ugoll 39 no.5:54-56 Y), 164. (MIM 17:8)
1. Kombinat '131ollk-ov). 2. PorsetslAy nauobino-
inledovatallsUy u..-,ollk%yf in-Aititt (for
Goncliqi-mko).

Subject
Card 1/1
Authors
Title
Periodical
Abstract
AID P - 4770
USSR/AeronaUtiC8 -.; accelerometer
Pub. 135 - 28/31
: Belikov,, V. I,, Col. and M. P. Sheynin
: For wider use of load factor indicator
: Vest. vozd. flota, 8, 93, Ag 1956
: The authors suggest the use of an accelerometer during
the execution of aerobatics.
Institutlon ; None
Submitted ; No date

131LIKOV, V.K.; B=V, H.S.
Bxperience in organizing practical work In agriculture.
Politekhoobuch* no.6:14-54, Js 157. (MIRL 12:4)
1. Skhodnenskaya arednyaya ;shkola No.2,.MAmkInskogo rayona
Moskovokoy oblasti.
(Agriculture--Study and teaching) (Fihld work Mucational
method))

BV,LIKOV,
How we organized a school machine-trRotor stRtlon.
Polltekh.obuch.
no.8:62-63 Ag '57- (PI.RA 10;9)
1. Skhodnenskaya arednvaya shkolm No.2 Khim):inskago rayona
Moskovskoy
oblasti.
(Farm mechAnisstion--Stu4 nnd teschirg)

BELIKOV, V.K.
The specialist in greenhouses and hotbeds. Politekh.obuch.
no-11:77-78 N '57. (MIRA 10:10)
(Hotbeds) (Greenhouse management)

WMIYLOV, V.X,; KITAYZV. I.Ge
I- ~Wmfw"
- "re on farm m
--MeRl"oo achanization. Politekh. obuch. no.2:87-88
F 158. (XIRA 11:1)
(?arm mechanization)

BZLIKDVO V.1
Preparing studente for practical vork in a rural
Rchool. Politekh.
obuch. no.5:36-42 My '59s (KU 12:6)
1. Skbodnenskeya aredrqaya shkola B16.2 KhImkinskogo
rayona Rookov-
skoy oblasti.
(Skhodnia--Agriculture-Study and teaching)
(Field work (Edixfttional method))

BELIKOVI V.K.
- . .....-
Work practices of enterprises of nonferrous metallurgy
4-n the
Ukrainian S.S.R. in the area of efficiency and
inventiors.,
Met. i gornorud. prom. no.1:77 Ja-F 165. ~ (MIRA 18:3)

BELIKOV, V. M., RODIONOV., V. M. and MACHINSKAYA, I. V.
"Methods for Obtaining Esters of Alpha-Nitro Replacing
Carbonic Acid.," Zhur,
Obshch. Khim., 18, No-5., 1948
Describes preparation of nitroacetoethyl ester, This is done
by nitration of the
acetic acid ester and subsequent oxidation of the resultant
isonitrosoacetic acid
w~her with potassium bichromate. Yield is 60% of theoretical.
Submitted 18 Apr 47.
PA 8/49T65

BEMOV, V. M.
"Quantitative Determination of Methyl Groups Connected to
Carbon,n Usp.
Khim.,, 21., No.4, 1952

MI

FT

Z

.it,
V. M. Rdikov (Ili

13toll wtis a
iidtis, trado,111
~V 24 Atli

(
cillowd byUc Nao~stfn

isoded 117 w ftlmrrH.Kft W ?A

W PtAll
ivrith mutinis it

'Aft,
COO I- ;i ~Cirvmd lViN. at (vigils "tefil

,
lk tile mixture WAS

it
N' 911-400" isliol' t.44&1 it%
14 -MOC111CUMM
iw-(~4
wl

n
A -g
'-d
d
m i
IMMO
1
WC It
dl
20
i
j

-
,
t
o
ai
.
g
y gqvc
.1
of
)eI!(NO0COA&
. .114 of n't? 143115
W

,
A

I.W24, Ts'fl

MiCCMNIC)
umi G.J1 it.

ctaat~st PmV4~ frilni. 016 g.~PHNhtc,;PhSOII (0. CA; 42,

4%?As) awl tiji mixt,'wiriiiii4l Ili M -)V~4 lim:After tjoat.

s

ill
mt With 41U, 40 tshil kill, wIth y10 there mo 0.1itilirw

-CCII(NO
52** EA OCIACMCN.,W 146,"".
~
1
43W d
I 4NW
iL
A
4
i
W
o
4

-
il
ctt
i
.
t
ct
m
W
I
2. t pr
oi
Sim Ixeclita GAVIMIMV0
so
90
i

m
..
*

RtOtj
w" paW, voills ilry I Ict with, cWtill is M kvilt
, ,
'

da
ima tol
ys At
YkWilij Atfto~ 411a. Will 11.00 44
'

it r9pentlitivi, Is,
vs

t 14() t
'

(1
7 g. RACCHlNO,
a 7 tot. EtOR

,
Vcr NI with Suva 50~ E10
~C1
6M1
410 j
II:

4
fA
.
*
,
aficir cvalin. aW Acidificition

PH
PH

EELIKCIV, V. Y.
"The Transformation of Nitrocarbox7lia Acids." Cand Che::
---ci, Inst of
Organic C! emistry imeni N. D. Zelinskiy, Aced Sci WS11 21 Dec
54. (VV,) Q$ Doc 54)
Survey of Scientific and Technical Dissertations Defended at
U33R
hi gher Educational In titutions (12)
50; Sm. 1,o. 556, 21+ Jun 55

BELVON V X.
--- a-OW As A-MMMIMW
Certain reactions for the condensation of asters of
aliphatic 4itre-
carboxylic wide. Izv.AN SSSR *td.khlm.nauk n*-7:835-862
ii. 156.
(XIMA gtlo)
I.Institut organichookay Wail imeni N.D.Zelinsksgo
Akademil nauk
SSSR.'i
(AcIds. Fatty) (Condensation products (Chemistry))

7 ~.Z
77% - 7 ~-~

50) SOV/62-58-1 2-14/22
AUTHOR: Belikovt V. M.
TITLE: On the Diazotization of p-Oxybenzoic Acid and
p-Sulfophenol
(0 diazotirovanii p-oksibenzoynoy kisloty i p-sullfofenola)
PERIODICAL: Izvestiya Akademii nauk sssRI otaeleniye
khimicheskikh nauk,
1958, Nr 12, PP 1466-1467 (US'SR)
ABSTRACT: Although the reaction investigated in this paper is
not what
is generally known as diazotization, this expression was
maintained as it perfectly interprets the introduction of the
diazo group into the organic molecule. This work was carried
out under the supervision of V. M. Rodionov, Member, Academy
of Sciences, USSR. The Rodionov-Matveyev reaction (Ref 1) was
extended to the p-oxybenzoic acid and the p-sulfophenolt and
diazo compounds in yields of 70-90% were obtained. The treat-
ment of the diazo solution which had been obtained from p-oxy-
benzoic acid according to a method suggested by Zandmeyer, led
to the formation of m-ohloro-p-oxybenzoic acid and p-chloro-
o-nitro-phenol. This points to the fact that the original
reaction products are 2-oxy-5-carboxyl-phenyl cliazonium and
Card 1/2 m-nitro-p-oxy-phenyl diazonium.

SOV/62-58-12-14/22
On the Diazotization of p-Oxybenzoic Acid and p-Sulfophenol
There are 6 references, 3 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii imeni N. D.
Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni X. D. Zelinskiy
Academy of Sciences, USSR)
SUBMITTED: April 141 1958
Card 2/2

5(3) SOV/62-58-12-15/22
AUTHORS: ~.tayranovskiy~ S. G., Safonovat E* N., Novikov,
S. S.
TITLE: Heat of Hydration of 2-Nitro-Pyrrole (Teplota gidratatsii
2-
nitropirrola)
PERIODICAL: Izvestiya Akademii nauk SSSRs Otdeleniye
khimicheakikh nauk,
1958, Nr 12t PP 1488-1489 (USSR)
ABSTRACT: In the present paper the authors mention briefly that
the
hydration of 2-nitro-pyrrole was immediately proved by measuring
the heat effect. It was found that in the transition from
glacial acetic acid solutions to diluted acetic acid solutions
the displacement of the absorption spectrum taking place in the
ultraviolet 2-nitro-pyrrole spectrum is connected with the
hydration of molecules of the dissolved substance. It is ac-
companied by a heat effect of -1-5 to -1-7 kcal/mol. In the
course of the investigation the mixing heat of acetic acid
with water at 21-220 and at a concentration of 25-35~ was
measured. This heat is equal to zero if the content of acetic
acid is 280% of the final mixture. There are 1 figure, 1 table,
Card 1/2 and 4 references, 2 of which are Soviet.

SOV/62-58-12-15/212
Heat of Hydration of 2-Nitro-Pyrrole
ASSOCIATION: Institut organicheskoy khimii imeni No D.
Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy
Academy of Sciences, USSR)
SUBMITTED: May 16, '1958
Card 2/2

50)
SOV/62-59-5-35/40
AUTHORS:
Yershova, L. V., Gogitidze, V. N.,
Belikov, V. M., Novikov, S. S.
TITLE:
i2reparatJon'. of
Gem-dinitroparaffins (0 poluchenii gem-

dinitroparafinov)
PERIODICAL:
Izvestiya Akademii nauk SSSR% Otdeleniye
khimicheskikh nauk,

1959p Nr 5, pp 943-945 (USSR)
ABSTRACT:
For-the investigation of the influei~ce exercised by the
carbon

chain in th6'gem-mdinitr6-compounds upon their physical
proper-

ties the homologous seties'of gem-dinitro-compounds was

synthetized. For this purpose the alkyl acetoacetic esters
were

nitrated.*This method was applied for the-first time by G.
Chan-

cel (Ref 1). It renders it possible to extend the caAon
chain

in stages, i.e. the initial product is extended each time
by

one carbon atom. In the course of the present investigation,

a series of gem-dinitro-p-a.raffins from 1,1-dinitropropane to

1,1-dinitrodecane was in this way obtained. Of the synthetized

compound3, the molar refraction of the dinitromethyl group

was
determined (Tabla 1). Moreover, also the physical constants

and
boiling points were determined (Table 2). There are
Card 1/2
2
tables and 6 references, 1 of which is Soviet.

. ll~,epar4ion of Gem-dinitroparaffins SOV/62-59-5-35/40
ASSOCIATION: Institut org&hicheskoy khimii im. N. D. Zelinskogo
Akademii no*
SSSR (Institiite of Organic Chemistry imeni N. D. Zelinakiy of
the Academy of Sciences, USSR)
SUBMITTED: . November 11, 1958
Card 2/2

AUTHORS: Novikov, S. S., Beliko sov/62-59-6-23/36
TITLE: Investigation in the Field of Nitropyrroles
(Issledovaniye
v oblasti nitropirrolov). communication 1. New Synthesis
Methods of the Pyrrole Rin (Soobahcheniye 1. Novyy metod
sinteza pirrolinogo tsi~cl al
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh nauk,
1959p Nr 69 pp 1098 - 110i (USSR)
ABSTRACT: In continuation of a previous paper (Ref 1) in
which the con-
densation of nitroacetio acid eater with aldehydes was
investi-
gated, this paper deals with the reaction of
a,P,P-trinitropro-
pione aldehyde with formalin and methylamine. Together with
Mannich's base a compound with the melting pdint of 1700 was
found, to which according to its ultimate analysis and other
chemical properties the chemical structure of 1-methyl-3,4-
dinitropyrrole was ascribed. The reaction scheme is given. For
the purpose of proving it, the splitting-off of the methyl-
amino group in the cyclization was investigated in order to
ob-
serve which hydrogen atom remains in the ring. With the diam-
ines there is in this case a competition between the two
amino-
Card 1/3

Investigation in the Field of Hitropyrrolee.
Communication 1. New Synthesis Methods of the
Pyrrole Ring
Card 2/3
groups: (02N)2C ---CN02
2 /CH
R ITH HN-R1
2
SOY/62-59-6-23/36
(R 1-CH3
It was observed thatp independently of the aminogroups chosen,
methyldinitropyrrole was always obtained. In general it could
be determined that it is always the more basic methylamine that
remains in the ring. The methylamino group may also compete
with the methylamine. The reaction of methylimide with ethyl-
amino and CH 20 yielded comparative quantities of methyl- and
ethyldinitropyrrole. In the course of further reactions it was
possible to synthetize dinitropyrrole immediately from dialkali
salts of the tTinitropropione aldehyde, by pasaing over the
methylimide stage. By means of this new method of synthetizing
dinitropyrroles also the previously unknown 3,4-dinitropy-rrole
could be produced. In the experimental part the production of

Investigation In the Field of Nitropyrroles. soy/62-59-6-23/36
Communication 1. New Synthesis Methods of the
Pyrrole Ring
the different substatictes is described in detail. There are 7
references, I of which is Soviet.
ASSOCIATION: Institat organicheekoy khimii im. N. D. Zelinskogo
Akademii
nauk SSSR)(Institute of Organic Chemistry imeni X. D.
Zelinskiy of the Academy of Sciences, USSR)
SUBMITTED: September 30, 1957
x
Card 31,

50Y

1UTHORSt
Safonoval E. N.0 Bolikov, V. U., Novikov, S. S.
W7162-59-6-30136

TIffSr
Some Reactions of'the fttropyrrole3
Asrocie-ea With the

Mobility of the N-H Bond (Nekotoryye
reaktaii nitropirrolov,

svyaza=yye a podvizhnostlyu svVazi
N-H)
PERIODICALt
Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh naukq

1959t Nr 6j PP 1130 - 1132 (USSR)
LMRJLCT.-
In a previous-paper by the authors (Ref 11 it was
found that the

nitropyrroles, which do not have a
substituent on the hydrogen,

are acids, and that their
acidity depends on the'nitro groups bound

to the pyrrole
ring.-(2-nitropyrrole weakly acid, 214-nitropyrrole

stronger
acid, and 215-nitropyrrolezacid.). If, as is aammd, the

chemical activity of the nitropyrrales is connected with
-the

mobility of the hydrogen atoms in this compound, the
change in

chemical activity must depend onthe iissociation
constants of-the

nitropyrroles. In order to prove this, the
formation of salts,, the

oyano-ethylation, and the
methylation, of the pyrroles mentioned

was investigated. it
was fihown that all three nitropyrrolet form

stable sodium
salts, wblle -the ammonium salts are unstable. The

hydraoine
salt of 2-nitropyrrole could not be produced, the other
Card
1/3
two PYrroles formed normal hydrazine salts. When put
into diluted

Some Reactions of the NitropyrrolesAseoc-istal With the
qW62-59-6-30/36
Mobility of the N-H Bond
sulphurio sold all salts were again decomposed into the initial
products. With the oyanoothylation it showed that the more
said the
nitropyMle, the more aaid S, catalyst had to be used for the
reaction. (Catallysts in the order of the nitropyrroles
mextioned:
CH3Wa.9 Cli5COOKICH5COW). Me-thylation of the
2,5-dinitropyrrole
by dimetbylsulphate occurred less readily than with the
two-other
pyrroles, The N-H bond whioh, in dependenoe on its mobility, is
able to reazt in the aforementioned manner, is also responsible
for the motion of the hydrogen atoms of the =ethyl group, of
the
alcohols) or of the carborjlio acid. The character of the atom
to
which -the hydrogen 4.9 bound is of minor importance. In-the
experimental part the syntheses of the different, salts, and
of*the
oyanoethylated and methylated compounds of the nitropyrroles
mentioned are described in dets;il. For some of the compounds
synthetized, the baoterio-static activity was determined in
t7heVUa-YI
(1fSssoyuzuyy nauchno-issledovatellaidy
khiniko-farmat3ovtichookiy
institut imeni OrdZ110nikidze (All-Union Chemicopharmacoutio&I
Sdientifto Research Institute imeni Ordzhoaikidze~ by Professor
Card 2/3 N. G. Pershin to whom the authors therefore express
their gratitude.

Some Reactions of the Nitropyrroles Assocleted With the
SCIV/62-59-6-30/36
Mobility of the N-11 Bond
There are 2 Soviet references.
ASSOCIITICK: Institut organiobeakoy 'chi-ii im. N. D.
Zelibsk6go Lludemii nauk
SSSR (Institute of-Organio Chemistry inerii N. D.
Zelinskiy of
the JLoademy of Sciences, USSR)
SUBUTTED.- December 8t--1958
Card 3/3

50) SOV/62-59-7-22/38
AUTHORSt Safonova, E. N., Belikov, V. M., Novikov, S. S.
TITLE: An Investigation of flitro-Pyrrols (Issledovaniye v
oblasti nitro-
pirrolov). Communication 2. Synthesis of Some flitro-Pyrrols
(Soob-
shcheniye 2. Sintez nekotorykh nitropirrolov)
PERIODICAL: Izvcatiya Akademii nauk SSSR. Otdeleniye
khimicheskikh na-ak,
1959, Nr 7, pp 13o7 - 1311 (USSR)
ABSTRACT: In a preceding paper a 11-methyl-derivati7e of the
configuration
H-methyl-3,4-dinitro-pyrrol was obtained from the authors by a
new method of synthesis. The anti-synthesis of this substance
was not possible. Therefore, some other mono- and
dinitro-pyrrols
with or without N-substituents were synthesized and their chemi-
cal qualities and ultraviolet spectra rere co,~tpared with those
of the substances in the above named paper. In the table the
data of all nitropyrrols are represented which are described in
other publications (Refs 1-4). Some methods of the sXnthesis of
nitro-pyrrols, which are described in publications are indicated
(Refs 3,5,2). Like the scheme besides N-methyl-2,4-dinitropjrrol
Card 1/2

An Irvestigation of Nitro-Pyrrols. Com,nunication 2. 1;yn-
00-1/62-53'-7-22/38
thesis of Some Nit Pyrrols
P8 2 and IU NO 2 2-nitro-pyrrol,2,4- and 2,5-dinitro
pyrrol were got now by nitrification
3 1H3 and methylation, which were not yet
0 N described in other papers. The used me-
2 0 thod of nitrification by Rinkes, ob-
2 taining 2-nitro-pyrrol, was chanGed
and improv*ed in some points. In the
T
C113 experitaental part the syntheses are
described in detail. There are 6 figures, 1 table, and 7 refer-
ences, 1 of which is Soviet.
ASSOCIATION: Institut organicheskoy khimii im. 11. D.
Zelinskogo Akadeinii nauk
SSSR (Institute of Or.-anic Chemistry imeni N. D. Zelinskiy of
the Academy of Scicnces, USSR)
SUBMITTED: September 30, 1957
Card 2/2

5(3)o 5W SOY/62-59-8-16/42
AUTHORS: Novikovp So Sop Yogorovp Yu. P., Safonovs, Z.N.#
Semenovj L. V.
TITLE;
Investigations in the Pield of Nitropyrroles.
Communication 3.

Ultra6violet Absorption Spectra and
Tautomerio Transformations

of Some Nitropyrroles
PERIODICAL:
Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,

1959, Nr 8, pp 1438-1444 (USSR)
ABSTRACT:
In the present paper
the ultra-violet spectra of 8 nitro-

pyrroles are
investigated. The bands of the various compounds

are given in
table I and shown in the figures. The spectra

were interpreted
as indicating that the position of the

F02 group in the
pyrrole nucleus can be determined by means

of the ultra-violet
spectrum. The already supposed structure

of
1-methyl-3,4-dinitropyrrole (Ref 1) could be proved. The

tautomeric phenomena were investigated in a series of deri-

vatives not substituted at the nitrogen of nitropyrrole and

it
could be shown that the acidity of these compounds increases

with the increasing number of nitro groups. The same effect

could be observed by regrouping the nitro group from position
Card 1/2
P into a. This phenomenon was considered 'an
inductive effect

SOV/62-59-8-16/42
Investigations in the Field of Nitropyrroles.
Communication 3- Ultra-violet
Absorption Spectra and Tautomeric Transformations of Some
Hitropyrroles
of the nitro group on the polarization of the N-H bond *
There are 6 figures, I table, and 17 references, 6 of which
are Soviet.
ASSOCIATION: Inatitut organicheskoy khimii im. N. D.
Zolinslmgo Akademii
nauk SSSR
(Instit'ute of 'Organic Chemistry imeni 11. D. Zelinskiy of
the AcadeW of Sciences~ USSR)
SUBMITTED: November 30, 1957
Card 2/2

5-361o 77378
SOV/79-30-1-39/78
AUTHORS: Belikov, V. M., Yershova, L. V., Novikov, S. S.
TITLE: Concerning the Action of Nitric Acid on Nitroolefins
PERIODICAL: Zhurnal ob3hchey khimii, 196o, Vol 30, Nr 1, pp 191-
192 (USSR)
ABSTRACT: The action-of HNO 3 on nitroolefins, specifically, on
1-nitrobut I-ene, 1-nitroprop-l-ene, and nitroethylene,
was investigated. The nitrates of CL -hydroxy acids
were obtained as final products. From nitrobutylene
the nitrate of CL -hydroxybutyric acid (I) was obtained,
and from nitroepropylene, the nitrate of lactic acid
(III. Nitroethylene formed very unstable products.
An attempt to isolate a discrete compound was unsuccess-
ful. The reaction probably takes place as follows:
ON02 ONO,
11NOs N11,011
11-C11=C11-N0j -- R-G11-C11=N0011 111-elf-C0011
Card 1/2

Concerning the Action of Nitric Acid 77378
on Nitroolefins SOV/79-30-1-39/78
Compound (I) was obtained in 47% yield, bp 1150/2 mm,
nD20 1.4365, d420 1.2849, and (II) in 39% yield, bp
960/3 mm, nD20 1.4356, d420 1.3672. There are 3 refer-
ences, 1 U.S., 1 French, 1 U.K. The U,S. and U.K.
references are: M. Frankel, K. Klager, J. Org. Ch.,
2:3, 494 (1958 ; F. Patti8on, 0. Brown, Can. J. Chem.,
34, 879 (190.
ASSOCIATION: Institute of Organic Chemistry, Academy of
Sciences
USSR (Institut organicheskoy khimii Akademii nauk ShR)
SUBMITTED: January 14, 1959
Card 2/2

NOVIKOV, S. S. ; SLFONOVA, 3. N. ; ELLMOV, V. H.
Chemistry of nitropyrroles. Report NO-5: Synthesis of sub-
stituted derivatives of dinitropyrroles. Izv.AN SSSR.Otd.
khim.nauk no.6,.1033-1056 JI 160. (MIR& 13:7)
1. Inetitut organicheakoy khImii imeni N.D.Zelinskogo Akeclecii
nauk SSSR,
(Pyrrole)

S/062/60/000/009/015/021
B023/B064
AUTHORSt ,Pel!kov,,,Y; Mayranovskiy, S. G., Korohemnaya, Ts. B.,
and Klimova, V. A.
0
TITLE: Tautomerism of Nitro Compounds, Communication 1. Study of
the Mechanism of Tautomerie Conversionsof Phenyl
Nitromethane
PERIODICAL: Izvestiya, Akademii nauk SSSR. Otdeleniye khimicheskikh
nauk, 1960, No. 9, pp. 1675-168o
TEXT: The authors investigated the tautomeric conversions of the
nitro
compounds as thoroughly as possible by the polarographic method.
They
used phenyl nitromethane because its tautomeric conversions proceed
comparatively slowly..They determined the constant (K.) of the
acidic
dissociation of phenyl nitromethane in water both
potentiometrically and
polarographically, and obtained K N a 1.6-10-7 mole/l. The
dissociation
kinetics of phenyl nitromethane was investigated in buffer
solutions at
PH betwien 7 and 10. The constants of the rate of dissociation were
Card 1/4

Tautomerism of Nitro Compounds. Communication 1.
S/062/60/000/009/015/021
Study of the Mechanism of Tautomeric Conversions B023/BO64
of Phenyl Nitromethane
experimentally determined with all components of the buffer
solution. The
rate of interaction of phenyl nitromethane, with water as
standard, is
H20-- 8 -10-7V6?i a sea. The kinetics of the transition from
the aci- into
kiD
the nitro form was also studied at pH between I and 6, It is
found that
the rate of isomerization is independent of the hydrogen ion
concentration
at PH< 2, and may be expressed by the eguation
kH2U
AT) +
C6H5CH - NOOR + H20 - .1 C6H5CH = NOO + H30
The rate of isomerization increases at a further increase of
PH. In generA
the rate of isomerization is determined by the stage of
dissociation of
the aci form. The constants were - like in the determination of
the
dissociation rate of the nitro form - determined with all
components of
the buffer mixtures. The aci form is a stronger acid than the
nitro form.
The behavior of the phenyl nitromethane ion in buffer solutions
at PH 4-6
showed that in the PH range of from 4 to 4.7, the rate of
development of
nitro forms is practically independent of the pH of the
solution. At a
Card 2/4

Tautomerism of Nitro Compounds. Communication 1.
S/062/60/000/009/015/021
Study of the Mechanism of Tautomeric Conversiona B023/BO64
of Phenyl Nitrom(~thane
further increase of pH, the rate of formation of the nitro form
decreases
in proportion with the reduction of the acid concentration. In tnis
stace,
the rate of formation of-the nitro form is determined by the stage of
recombination of the anion under the formation of a non-dissociatod
nitro
form. The rates of dissociation and recombination of the nitro form as
well as the rate of dissociation of the aci form were experimentally
determined. On the basis of the kinetic analysis of tautomeric
conversions
of phenyl nitromethane it is found that the anion may appear in two
forms:
as aci anion and as nitro anion. As a result of the kinetic
investications
the authors obtained a picture of tautomeric transformations of
phenyl 0+
-nitromethane in aqueous solution for the special case in which only
H2
occurs au a base. See Scheme. Thus, it may be concluded that the
duality
of the reactivity of the phenyl nitromethane ion is apparently due to
the
coexistence of ions of two types. The isomerization of these ions
proceeds
at low rates. These rates determine under certain conditions the
direction
of the reaction to the one or the other side. This phenomenon may, in
the authors' opinion, contribute to claiify the duality of the
reactivity
Card 3/4

Tautomerism of Nitro Compounds. Communication 1.!. S/062 60/000/009/015/021
Study of the Mechanism of Tautomeric Conversi6n's B023 B064
YB
of Phenyl Nitromethane
of other tautomeric compounds. G. S. Salyamon and Ya. S. Bobovich (Ref.12)
are mentioned. V. I. Slovetskiy and V. A. Shlyapochniokov have taken the
spectra. There are 1 table and 12 references: 3 Soviet, 6 US, 1 German,
I Danish, and 1 Swedish.
ASSOCIATION: Institut organicheskoy khimii im. N.D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: March 24, 1959; completed June 8, 1960
H
kW H&O+
Cs14CHjN0x+H20 == CoH,C-HNO,
kHo+
NR
At 0 4 K
Ho
CHjjCH-NOOH+HjO, CHCHNOO-H,04-
1=0
K~=2-10-TMIA k,,"~-8-10-'AIM-cex k"r-200.,IM-ceg.
Card 4/4 K,-1,3.1"MIA. PAg-4,14-10-fAffil-cex hAHj?+-t8.4/,W-Ce'C.

84854
S/062/60/000/010/007/018
/C3 6 0 B015/3064
AUTHORS: Mayranovskiy, S. G , Belikov. Korchemnaya, Ts. B.,
klimova, V. A., and Novilcov, S. S.
TITLE; Tautomerism of Nitro-compounds.flInformation 2.
Folarographic
Investigation of the Kinetics of Tautomeric Conversions of
Phenyl Nitro-methane
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye
khimicheskikh nauk,
1960y No. 10, PP- 1787-1795
TECT: In a previous investigation (Ref. 1), the polarographic
activity
of the aci-form of phenyl nitro-methane was determined. The
present
paper describes the technique applied and gives the experimental
data
obtained. The polarographic behavior of the aci- and nitroforme
of phenyl
nitro-methane was investigated, i.e.,the kinetics of the
transformation
of the aci-form into the nitro-form at pH 1-4, the nitro-form
into the
anion at pH 7-109 and the anion into the nitro-form at pH 4-6.
Moreover,
the dissociation constants of the aci- and nitro-forms were
Card 1/3

84854
Tautomerism of Nitro-compounds. Information 2.
Polarographic Investigation of the Kinetics of
Tautomeric Conversions of Phenyl Nitro-methane
S/062/60/000/010/007/018
B015/BO64
polarographically and potentiometrically determined. The
experiments were
conducted in an optical polarograph, and the current was measured
with an
H_91t~M-91) microammeter. The potential of the dropping
electrode,~pras
checked with an AM -1,'(LM-1) voltmeter, and determined with a
11-4`~ -4)
potentiometer. The exp riments were carried out at 25tO-10C using
various_
buffer solutions, and the PH was determined with glass electrodes
and
An-5 '(LP-5) or ATT-59 (LP-59) potentiometers. The potentials of
the half
waves at PH 1-15 are E1/2 - -0-52 v for the nitro-form and E 1/2
' -0.66 v
for the aci-form. Investigations of the dissociation kinetics
showed that
the ionization of phenyl nitro-methane in buffer solutions can be
described
by an equation of the first order. The ionization rate was
investigated
in the presence of various bases. The rate of transformation of
the aci-
form into the nitro-form was found to follow the equation of a
reaction
of the first order throughout the PH range investigated.
Investigations
on the recombination kinetics of phenyl nitro-methane showed that
at
PH 4-5 the dissociation of the aci-form and the recombination of
the
nitro-form take place simultaneously. The values for the
dissociation
Card 2/3

Tautomerism of Nitro-compounds. Information 2.
Polarographic Investigation of the Kinetics of
Tautomerio Conversions of Phenyl Nitro-Lethane
84854
W/062/60/000/010/007/016
B015/BO64
oonstante of the aci- and nitro-forms under the action of bases
and acids
were computed with the help of Br6nsted's equation (Tables 1,2).
The
authors thank D. G. Knorre for advice. There are 11 figures, 2
tables,
and 5 references: 4 Sovig-t-and 1 US.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo
Akademii
nauk SSSR (Institute of Organic Chemistr;~ imeni H. D.
Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: March 24, 1959
Card 3/3

"15 14 ; 7
eo8l/62/000/004/074/087 I
Bi3q/Bllo
AUTHORS: Zimakov, P. V., Volkova, Ye. V., Pokin, A. V., Sorokin, A. D
p:.
Beliknx,-Y. M.
TITLE: Use of nuclear radiation energy-in the process of the
polymerization of fluoro-olefines
PERIODICAL: Referativnyy zhurnal. Khimiyaj no. 4, 1962, 557, abstract
024 (Sb. "Radioakt. izotopy i yadern. izlucheniya v nar..
kh-ve SSSR, v. 1. M.", Goatoptekhizdat, 1961, 219-226)
TEXT: The processes of the separate and combined radiation
polymerization~,
of tetrafluorethvlene and trifluorchlorethylene have been investigated
witli
the aim of eliminating some of the defioiencies in existing methods of
fluoro-olefine polymerization. It has been found that
tetrafluorethylene
and trifluorchlorethylene can easily be polymerized under various
temperature conditions and mediums with comparatively low radiation
intensities. The resulting polymers have a high degree of purity. The
possibility of producing various fluoro-copolymers by radiation is
demonstrated. Both radiation polymerization and radiation vulcanization
might be carried out in the case of fluor-containing rubbers.
[Abstracter,:
note; Complete translation.)
Card 1 /1

BELIKOV, V.M.; MAYRANOVSKIY, B.G.; KORCHEMNkYA, TS.B.;
NOVIKOV, -:B.S.
Tautomerism of nitro compounds. Report 3t Effect of
temperature and
ionic strength of solutions ou the rates of phenylaitometham
tautomerio v
transitions. Izv*AN SSSROtd.khim.nauk no,61UO&-11U Jo 161.
1-4 (NLU 14:6)
1. Institut, organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(MsthAn ) (Tautomerism)

S/019/61/000/018/043/073
A15Z/A126
AUTHORS% Fokin, A.V.j Volkova, Ye.V.1 Belikov, V-M-j Abkin, AX.)
Khom
yakovakiy, PPI.; Gantmakherp AMM"W14Rrasnousov, L.A.
TITLE: Process of obtaining polytetrafluoroethylene
PERIODICAL: Byulleten' izobreteniy, no. 18, 1961, 42
TEM Class 39c, 2501. No. 141301 (675645/23 of August 3, 1960). A
process of obtaining polytetrafluoroethylene through a
polymerization of tetra-
ethylene fluoride in a water medium in the presence of
initiators, the distinc-
tive feature of which consists J!~ that, for the purpose'of
obtaining a high-
purity polymer, Y-radiation Cow is taken as initiator.
Card 1/1

VOLKOVA, Ye.V.; FOKINj, A-Vo; BELIKOV9 V.M.
Polymerization of tetrufluoroetbylene by the action of gamma
rays. Zhur.VKHO 6 no.ltU3-114 161. (MIRA 14:3)
(Ethylene) (Gamma rays) (Polymerization)
s,~
I

S/844/62/000/OJO/079/129
D423/D307
AUTHURS: - Volkova, Ye. V., Pokin, A. V., Zimakovj P, V. and Beli-
"Ov
TITLL: Certain opecial features of the radiation polyincriz'ation
of tetrafluorethylene by the action of B and radiations
6OURC~;: Trudy II Vaesoyuznogo soveshchaniya po radiatsionnoy khi-
mii. Ed. by L. S. Polak. Moscow,jzd-vo AN SSSR, 1962,
465-469 'k ~^
TEXT: Recent investigations are described of tile radiation poly-
merization of TFE in the solid, liquid and vapor phases, using
Co 60 and Sr 90 as the d- and 3 sources.'Irradiation in the liquid
phase was carried out at 20 - 250C using CIM 3 as the solvent with
a dose-rate of 11 rad/sec. Conversion of monomer increased with in-
creaue of dosage and concentration of monomer. The polymer obtained
(VTFE) contained up to 21,,j chlorine, which was explained by the
fact
that the CKC1 3 also participates in the reaction by.interaction of
Card 112