SCIENTIFIC ABSTRACT BEKASOVA, N. I. - BEKBOTAYEV, A. T.

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CIA-RDP86-00513R000204210008-4
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December 31, 1967
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Copolymerization of Boron-substiluted Borazoles S111901160 002/008/017/017 With Hexamethylene Diisocyanate B004/BO54 R H11-1 H O-C-N-(CH NUN 0 2)6- R , g 10 1:1.5 _NH(CH rR-2- INH(CH 9- 2 6 2)6NH- eel H NH(CH n L L 2)3- j Linear or three-dimensional copolymers were obtained depending on the ratio of components. SUBMITTED: February 16# 1960 Card 2/2 23-131 1 V1 122-0~ 1 1~12 S/4,90/61/003/004/004/014 B101~B207 AUTHORS; Korshaki V. V., Bekasovaj__N.. I., Zamyatinap V~ A... Aristarkhova, 0. 1. TITLE: Copolymerization of bla-(alkylamino-)alkyl. or aryl boron with organic diisocyanates PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 3, no. 4, 1961, 521-524 TEXT: The papers by B. M. Mikhaylov et al~ (Ref, 1; Izv. AN SSSR, Otd. khim. n., 1957, 11251 Ref. 2: ibid., 1958, 7771 Ref- 3; Dokl- AN SSSR~ 121, 656, 1958) showed that polycondensation of alkyl- or ary! boron di-- chlorides with primary amines does not lead to linear polymers, but to cyclic trimers. In the present study, the synthesis of linear polymers by copolymerization of bio-(alkylamino)-alkyl- or aryl boron with hexamethylene dilsocyanftte or toluylene di.isooyanate was carried out according to the following equation: IR R' R'HN-b-NHRI O-C-N-R"-N-C-O -B N-?-fiN-R1'-NH-C- n Card 1/4 21131 5/-1,90/61/003/004/004/014 Copolymerization of B101/B207 The following compounds were synthesized as initial substances: 1) bis- (methylamino)-butyl boronj 2) bis-(ethylamino)-butyl boron (according to Ref- 3)1 3) bis;(Methylamino) 4) bis-(ethylamino)-, and 5) bie-(phenyl- amino)-phenyl b ron (according to Ref. 1). Copolymerization was carried out at a molar ratio of 1 ; 1 and three-hr heating to 500C, then to 100, 150, 200, 250, and 2750C (bis-(mothylamino)-butyl boron) was only heated to 150co) The authors used ampoules which were evacuated af'%F-er passing through of N2' The monomer was, obtained from the copolymersby means of benzene, and thG copolymer aomposition was determined by means of elementary analysis. The intrinsic viscosity of the 5% copolymer solution in tricresol was determined at 200C. Tables 1 and 2 give the data for the copolymers. The figure shows the thermomechanical curve of the copolymer from bis-(phenylamino)- phenyl boron with hexamethylene diisooyanate. The copolymers obtained con- tain B, N, and C atoma in the chain.. They are solid, brittle, transparent# yellowish or reddish substances which are stable to air moisture and do not decompoaeeven when heated beyond the melting point. There are 1 figure, 2 tables, and 3 Soviet-bloc references. ASSOCIATION: Institut elementiorganicheakikh soyedinenly AN SSSR (Institute ON of Elemental Organic Compounds, AS USSR; Card 2/4 21131 !3/190/61/003/004/004/914 'Copolymerization of B101/B207 MOVED: july i 196o Table 1: Copolymers with hexamethylene diisocyanate. Legend; 1) initial compound;-2) intrinsic viscosity; 3) softening tempera- ture; 4) weight, increaoe after three-day storaee In the air; 5) polymer residue after 1-hr boiline with water; a) insoluble, swells. Table 2: Copolymers with toluylene diisocyanate. Legend as to Table.l. Temne;'S. Y"Awle"Ne OMMM coax 9TPWD=ee* TypM P43f a me" now* b4spa nocae "X. MCIOMUlt WaSOOOPAMAMU11 U&N &$#- unr4cunn. T= OTTO" aRqCxxff P Po Foe% e USFIRR 'Sit .5 T"GUKO 44) (T)* Im I~Myle. % % 0,28 GO 0,0 71.7 0,10 70 0,0 010 lie PACT- ROPSIOTCR, ca ua yx&*T WO 010 69.0 0,14 13D 0,0 0.0 0.24 115 0,0 0.0 Card 3/4 41 _1110r;11. W~ ap 21111 S/190 61100376041C041014 Copolyineri zati on of COPO B 101 Y3!207 IlezopuR opra. 11pniaAmmarl Towneporyps floem TPOI Cy"" OMTOR naxamps nocne HA "NEIR"011 v SOAG qhca. % C 0,10 60-07 0.0 0,0 (C~II&NUhISC4'H,* 0,08 b0 I'a 0,0 (CHOMSBC1115 0.00 Mo 0,0 0,0 (cA4MIhDc~Us 0.10 140-170 -O'o 0.0 0.10 140-160 1.4 03,7 Figure. Thermomeohanical propertiee IM of the copolymer from bis-(phenyl- amino)-phenyl boron with hexa-: methylene diisocyanate. 80 LaGend: a) temperaturee C.ard A/4 ~--' -'a-&MA S/190/61/003/004/005/014 BIOI/B207 AUTHORS: Korshak, V. V., Zamyatina, V. A., Bekasova, 1. 1., Ma Jui-jan TITLE: Copolymerization of boron-substituted borazoaes with hexa- methylene diisocyanate PERIODICAL: Vysokomolokulyarnyye soyedineniya? v. 3, no. 4, 1961, 525-529 TUM In the present st'udy, the authors aimed at obta',nine heat resistant., polymers. They proceeded from boron-substituted box;azolos which, by way of migration copolymerization with hexamethjlenediisocyanate, reacted accord in& to the followinE'equation: 0. _C-N1I (Cut), Nil-c-, B \N1 I 1DR+0 C N (C111),N.C.0 RD n S Card 1/4 If 21132 S-/190J61/003/004/005/014 Copolymerization oil,A., B101/B207 no DR \N1 0)-N R (CHOS- The molar ratio of components was 1 1 or 1 1-5. The boron-substituted borazoles were synthesized accordinj; to the method proposed by B. M. Mik).aylov, T. V. Kostroma (Ref. 0: Izv. AN SSSR j Otd - khim , n. 1 1957 1 1125)- .4. F. Zhit.,ach provided trimethyl borazole. The compound was copolynerized in 1;lusu ampoules from which air had been d.isplaced by means Of ?"2 and which, subsequently, were evacuated and sealed. The ampoules were heated for 3 hr to 1000C and 3 hr each to 150, 200, and 2500C. Table 1 gives the data of the polymers obtained. In the case of aliphatically substituted borazoles, therinomechanical testing yielded the highest softening temperBture for tri- methyl. borazole. Tri hen 1 borazole yielded copolymers which melt only at high temperatures. rAbstyracter's note: The authors provide data on softeninj; temperature and melting point-3 The resistivity of ntoe copolymer from B-trimethyl borazole with hexamethylene diisocyanate 1 : 1.5, was 11 3 2.5-10 ohm-cm, tan 0.0072 at 10 cps. at room temperature. At 150()C,*' Card 2/4 12 3 2 S/190/61/007/004/005/014 Copolymerization of ... B101/D207 these values were U-10 11 ohm-cm, and 1.1, respectively. (This study waz made by T. S. Xttyazeva and Z. V. Lyamkina). The oxporii:ient of copoly-ieriz- ing.the components in dinyl solution (boiling point 2500C), rouulted in a 25-3Y/'* of the calculated boron lower copolymer yield (60-6%) with only contbnt, &na, Drobably, conaisted mainly of po1yjvqcyrnxiric aciel. The therrial properties of these copolymers differed greatly fron tiose of tho Copolymers obtained without solvent. There are I fit,-urc, 2 tubles, and 10 references: 3 Soviet-bloc and 9 non-Soviet-bloc. The 2 rv!'*!rerca,3 to B"nelish-language publications read as follows: S. J. Gruszos, 2. -7. Stafiej, J. Atner. Chem. Soc., _80-, 1357, 1950; M. Lappert, 'roe. Che..,11. Soc., 1M, no. 2, 59. ASSOCIATION: Institut elementoorganictieskikh soyedinenly AIT SSSR (Institute of Elemental OrCtinic Compounds, AS USSR) SUBMITTED: July 1, 1960 Card 3/4 21132 S/19o~6i/co 3/oO4/005/014 Copolymerization of ... B1 01/~207 (1-1) O ~nVexcuffasa aftswom Toll Table 1. Copolymers M MP804 coo?"We. , nog"Reps UW_W RO- 9nemirulk from B-substituted 2 (RBNHJ. . and 60p. MNOA " . AN- a Fpmono 11"WANK I xo;to a To- bora-oles with hexa- 'IMSUO I wat.11;1ene diisocyanate. Lej;end; 1~ R in CHI 73.4 (A )11Ce=a-ruuoo6pa3noa -so- 2 molar -ratio IAOCTSO. ISIOPAO" Re: le: diisocyanatel, borazo 3 intrinsic viscosity; 1.5 of a PaCT20.( ~14 Paelso. 91,7 a ~npwpwinoe TDOPA00 W - a~ in cresoll b) in PROTCA. il&6yzao? Pn&TCH. IIAGYXSeT JAOMNO 112SO4; 4) polymer residue r, H, 1:1 0.34 0'14 - (PTo me after 1-hr boiling in 1; 1,5 lo pacyw ( ))[a PACT110. 61.0 w 0 wuter; 5) shape of the PH&TCRI PM&MR. polymer; 6) gelatinous 'na6yxavr u&6yxaeT substance, hardening in M46HO, i:1 we Otte 0.10 - C4 n 41PO!PA-1 an Rlyqyxoflo-~ the airi 7) insolublet ' t . 1 5 a 10 0 22 04 8 Aoonaa CU0:14 P03 PAI noo Ty oo w swolls; 6) transparent, , , , W solid substance; 9) ditto ; "AN, t..j 0,24 0.06 (PTo me 10) transparent, rubber- 1:1.5 to Pacyllo a PaCTS0. - like resin. PnOTCR' POWN114 11116YU&I 'Uft6YxAVT Card 4/4 COHN 1.1 TTO NCO (00 wo 05,7 S/074/61/030/001/002/003 B013/B055 AUTHORS: Zamyatina, V. A., Bakasinva.-N. I. TITLE: Polymer Compounds of Boron PERIODICAL: Uspekhi khimii, 1961, Vol- 30, No. 1, PP- 48-59 TECT: The present survey deals with publications on the preparation of polymer compounds of boron and on studies of monomer boron compounds and formation of polymers. The following Soviet authors who work in these fields are mentioned: B. M. Mikhaylov, F. B. Tutorskaya (Refs. 16 and 17); A. V. Topchiyev, Ya. M. Paushkin, A. A. Prokhorova (Refs. 18 and 19)1 V. M. Sleptsov, G. V. Samsonoy (Ref. 36)1 V. V. Korshak, V. A. ZamyatiniL, N. 1. Bekasova, Ma Zhuy zhan' (Ref. 47); A. F. Zhigach, Ye. B. Kazakova, I. S. Antonov (Ref. 55)1 K. A. Andrianov, L. M. Volkova (Ref. 80); A. V. Topchiyev and coworkers Ref 89 1 1. V. Kamenskiy, I. K. Sanin, V. I. Itinskiy, G. D. Krylova Ref: 90~. As may be seen from the oompara- tively small number of publications dealing with polymer compounds of boron, this branch of high-molecular chemistry is only at the stage of development. The synthetic methods are not worked out thoroughly, the Card 1/3 Polymer Compounds of Boron S/074/61/030/001/002/003 B013/B055 properties of the polymers are not always described and the polymers themselves are scarcely available since many of them were only obtainable in quantities of a few grams. Owing to the demands of modern engineering, however, studies in this field are being continued. On the basis of theoretical premises it seems possible to obtain high-melting polymers resistant to beat and chemical attack. Phosphoborines, which are expected to possess good mechanical properties, seem moat promising in this respect. In all probability, polymers containing borazole rings in the main chain will have a rigid spatial structure. Studies of various linear polymer compounds containing -B-N- and -B-P-chains showed that they are not high- melting, less resistant to heat and can be transformed into low-molecular cyclic compounds at high temperatures (phosphoborines). The properties of polymers containing -B-C- bonds have scarcely been described. A dis- advantage of many of these compounds is their readily occurrin4 oxidation by atmospheric oxygen. Though, in general, the polyanhydrides and poly- esters of boric acid and boric-acid derivatives are easily hydrolizable, various individual compounds are highly resistant to hydrolysis, oxidation and heat. There are 100 references: 22 Soviet, 43 US, 14 British. 9 French, and 18 German. Card 2/3 N Polymer Compounds of Boron S/074/61/030/001/002/003 B013/BO55 ASSOCIATION: In-t elementoorganicheskikh soyedineni AN SSSR (Institute 2~ of Elemental Organic Compounds AS USSR j Card 3/3 NORSHAK, V.V.; ZAMYATINAI V.A.; BEKASOVA6!.I.; OGANESYANt R.M.; SOLOMATINA, A.I. xt-WMWww W -- Polyesters of boric acid. Izv.AN SSM.Ser.khim.- no.8:1496-1502 Ag '631 (MfRk 16%9) 1. Institut slamantoorgmAcheskikh soyedineniy AN SSSR. (Boric acid) (Eaters) KCFtSHAK,. V.V.; BEKASOVAj N.I.; CHURSINAO L.M.; ZARATINAp V,A. Reaction of 1,2-dipheikyldiborans with amines and organoborodiamines. Izv. AN SSSH, Ser,khim, ao,9:1645-1648 S 163. (MMA 16:9) 1. Inotitut elementoorganicheakikh soyediseniy AN SSSR. (Diborane) (Amines) (Boron organic compounds) KORSWO V.V.; ZAMYATINA, V.A.; CHURSINA, L.M.j EEKAWVA N I. Polycondensation of B-triohloroborasole with bifunctional 3ompounds. Vysokon.soad. 5 no.8s.3.127-lln Ag 463* (KERA 16:9) 1. Institut eUmptoorganichaskikh voyedimniy AN SSSR. (Borazins) (Polymrization) KCRSHAK, Y.V.; ZAMYATINA, V.A.; EEKASOVA, N.I. Polyoondensation of 102-diphanyldiborans with diamines. Izv. AN SSM. Ser.khim. no.9tl648-1651 S 163. (MMA 16:9) 1. Institut alamentoorganichaskikh soradinaniy AN SSSR. (Diborans) (Amines) iy 3 MAWWAV HHIWWAAY Ac=xoN m, , Anoo4698 a)-2 AMGIiMISSO P0-4/1V-4/' S/0190/63/005/008/11V/1129 ED' AMM: Korshak, V. V.; Zeswat IV, A.; Churs, ~a, L. M. j Be asova, It. - 1. ton% MWMMSW~ at, TrM.." Polyconde" f 2,4,6-trichlord e th difunctional compound's SOURCE: Vy*sokopolekul 4aray"y soyeftneniya, v. 5, no, 8 1963 3=-429 TOPIC TAGS: methylphospblaylpolybor4zine, tetrametbyldifilloxypolyboratine,, 2,4,6-tricbaordboraxine., diWtyl methylpbosphonate,, l,,3-dibutoxyjjj#3P3-tetr44-~ methyldlailoxane, dimethyl sebacatep 2,4,6-triebloroborawl -dibuttyl metbyl- .. 1 .1 1.1- pbosphonate copolymer,' 2$4,6-trieblorobor&iLine-1,3-dCibutoxy-l,).,3,3-+.Atromtby3, dIsIlox=* copolymerp 2p4p6-tri6laoroborazine-dimethyI sebacate copolywro poly- condennation ACT; Reat-reallat~nt~'~bleb'-Wlting, insoluble I era -,been eynthesined TF qq2LMA_ ave M by polycondeneation (at 1000 under nItrogefi,'then_a_t_2V0_C and ~ mm 3g) -of VIth dibutyl 2,4,6-tricblordborazine (1). , - methylPbosPbonate (II) p l#3-dIbUt0x)u, lplp3p3wtetramethyldisiloxane'(1n)$, or dimethyl oebacate (IV'). Compounds I arA 1", 11 yield a powdery yellow copo:Lymr vb1ch is insoluble in the common orgavIc -solvents , melts above 3=0 ozd hu'a reduced viscosity in cresol of 0. 19 jeoti-. centration unspecified]. The copolymer is elowly hydrolyzed by air moisture, and. C*rd ACCRMOX IM: AP3004698 cold vater. The formla (1) of the copolymer is given in the Raclo-Surs; accord- Ing to. elemental-ana.4sle date, n w 7. Compounds I and in y:te]A*,a brltt:Le daLrk-brcvn copolymer malting above 300C and vith a reduced viscosity in cresol of 0.16 [concentration unspeelfied]. 114evopolyner le-insoluble In the ccomon- - solvents and Is stable to- eVi wolsture; its for=1&* (2), deterifted by eletental analysis., Is given in the Enclosure, Interaction of I and 17 results in"tharmal t degrad&Aon In addition to PolyconUrAution an& y1elds a copolymer vith = In .'T -o The copol7mer nalts above 300-01 and has a reduced viscosity areased aen content* of 0.2 (solvent end coutentration.vaspecified]. Orig. art, bas-..'. 2.formlas, -ASSOCIATIONt Institut elemen.toorgenichaskikh soyedlneuiy AN SWR (Tzatitute Or 2MPMEA0, MSR)_ SUMCWM: arDeaft DAU AOQ: 26ftsO MM: 02 SM OME: CH.P MA w MW SOV: 00o OTMI . 009 Curd ght "Z~ 7-7 KORSHAK, V.V.; BZ_WQV _A, ~N. I,; CHIKISHEV, Yu. Go; ZAlff ATINA, V.A.; TSETLIN, B*L~.; HAFIKOVp SoR* Radiation synthesis of borazole-based polymers Vysokom. coed. 5 no.10:1447-1450 0 163. iMM 17:1) I. InOtitut OIOMentoorganicheakikh voyedinaniy AN SSSR, KORSHAK, V.V.; SOLOMATINA~ A.I.; BEKASOVAC N.I.; ZAWATINAp V.A. Polyconde-anation of tIrimarle dimet4lphoophinoborine vith boron- subatitiated borazoles. lzy. AN SSSR Ser.khim. no-10:1856-1857 0 163. (MM 17: 3) 1, Institut elemmtoorganicheakikh soyodineniy AN SSSR. jk 'ACCEW10N NR: AP4010050 S/0062/64/000/001/0172/0174 'AUTHOR: Bekasova, N. I.. Zamyatina, V. A.; Korshak, Vj V. TITLE: Copolymerization of tri(ethyl"ino)bo and B-aminoborazoles with hexametkWlenedilsoryanate SOURCE: AN SSSR. Izvestiya. Ser. khim. n 1, 1964, 172-174 TOPIC TAGM boro-orginic polymer , linear ~aro-organic polymer ,cross linked boroorgnnic polymer , tri(ethylamino)boron hexamethylene-diisocyanate copolymer , B-aminoborazole hexamethyleneditsocyanate copolymer, borazole copolymer ? ABSTRACT:* Linear polymers containing B-N bonds were obtained by copoly.- merizing tri(ethylamino)boron and hexamethylonediisocyanate. Essentiallv the same product was obtained with reactant ratios of 1:1 and 1-1.1 New ..1 Ine boro-organic polymers containing molecules of the borazole ring in the bisic chain were obtained by copolymerizing bmvn-oubstituted borazolee with 1/2 77T ACCESSION NR: AP4010050- -'-.'methyleneditsocyanate. Reaction of B-triethylamino-N-triethylborazile with hexamethyloneditsocyanate. 1: 1., gives a linear polymer; product of 1: 1. 5 rat is a polymer cross-linked in several places with the diisocyanate as evidenced by higher fusion temperature and lowered boMn content. Reaction of B-trl (dim'ethylamino)borazole with hexamethylenediisocyanate, 1:1 and gives a linear polymer. Here the lowered ieaction temperature indicates the* catalytic rc~ action of the dimethylamino group situated at the B atom. However, block .'Polymerization of allZmixture'at higher temperatures does give a ciross linked I er. Orig. art. hail; I table and I equation. 0 YM P a, ASSOCIATION: Institut elem~entoorganicheskikh soyedinenty Akademii. nA SSSR (Institute of OrganometaUtc Compounds,,Academy of Sciences SSSR) DATE ACQ: 14Fe 64 SUBMITTED. 08Jul63 b ENCL: 00 CODE; NO REF SOV; 001 SUB CH OTHER: 004 P. 2/2 Card; ZAKYATINA, V.A.; BEKASOVA, X.I. Polymer compounds of boron. Usp. khim- 33 no.10:1216-1231 0 164. (MIRA 1711l) 1, Institut slamentoorganichaskikh noyodineniy AN SSSR. ACCESSION NR: AP5001600 5/0062/64/000/012/2223/2224 AUTHOR- Korshak, V. V.; Zamyatina, V. A.; Bakasova, N. I.; Komarova,L.G~ ?017co Mdensati.on0 1.3,5-triphonylborazin-e SOURCE, AN SSSR. Izvestiya.-Seriya khtmicbe8kaya, no. 12, 1964, 2223--2-;24 TOPIC TAGS: borazine, triphanylborazine. thermal stability, polymer ABSTRACT: The thermal stability of 1,3,5- triphenylborazirke (I) and 2-methyl-1.3,5-triph4anylborazine (11) has been studied. Heating of I to 400-420C produced evolution of hydrogen and pol-Icondensation to form a polymer with a molecular weight of 7000. The polymer is trans- parent and brittle and melts at-above 50OC; it is stable in air but pirtly hydrolizes i.n cold and boiling water. 1R analysis suggests the following struccure: G~b ~t4- NCO,$- Card 1/2 C$Ha L 21140-65 ACCESSION NR: AP5001600 :11eating of 11 to 400C caused no polycondensation, and virtually no evolution of hydrogen. Apparently trifunctional borazine has a lowe &thertaal stability /than aifunctional borazine. OrIg. art. has; 2 for%lulaso ASSOCIATION: Institut elormentoorganicbeskXkh soyedinaniy Akademii inauk SSSR Academy of Sciences, .SSSR). SUBMITTED: 04maY64 ENCLs 01 SUB CODE; OC, GO NO REP SOV: 00'0 OTHERs 003 ATD PRESSs 3165 3 L 20374-66 Ewr(m)1EwP(j)1T1ErC(m)-6 WINIAMAN 'Ace NR AP6006539 SMCE COM UR/0101/65/000/011 0016/ 18 (A) j? 'AUMORS Akimov, B. A.; Bekaso" N 1 11 Zhigach, A. F.; ZamWatinap V. As; Korebak.p " * H-4 Saris IV G " 1ORG3 none TITLE. Syntheste,of thermostable ~olymers.on the basis of b 00=8 .2ELzq)A and carbo compounds- SOURCES Plasticheskiye:mas oy no 11t 1965t 16-1.8 TOPIC TAGSi copolymerization, boron compoundt organoboron compound, thermal stability, . polvaers organic wthetic process, thermomechanical. property~ ABSMCTs The following polymers were syntheeized.i N, RoHM a-CHI 'ZL at VM6~ L 20374-66 , rACC M; ~ AP6006539- ~resulte are presented graphically (See,Figo 1), iFig. 1. Thermomechanical curves for !W . the polymers obtained by the polymeriza- z z Ition of: 1 - B-methyl-N.-triphenylborazole V, and dichlorodimethylcarboranel 2 B-methyl-N-triphenylborazole axid Oj bisbydroxymethylearborane; 3 - N- #V 7 t i h lborazole and bisbydroxymethyl- W P ~ Irbor ane; 4 - B-methyl-N-triphenyl- borazole and diaminodimethylearborane. W ZW 940 io~ It was found that polymers syntheoizedifrom 9-triphonyl and B-methyl-N- triphenylborazoles and di-(oxymetbyl)-oarborane possessed the highest thermal stability. -It is suggested that theincreas ed stability is due to the pres~nos ' of the highly stable B-0 bond in the molecule. Orig. art, has& 2 graphs and 4 equations.'- , SUB-CODB:07 ,I I/ MM DAM. none/ ORIG RMs 003/. OTH RU s 007 3 vmb L 45225-66 EWT m P(J)/T ACC N" AP6027771 (h) ' SOURCE CODE: !JR/0190/66/008/008/1383/1385 AUTHOR: Korshak, V. V.; Bekasova, N. 1. ORG: Institute of Organoelemental Compounds AN SSSR (Institut elen-entoorgani- chesk soyedineniy AN SSSR) TITLE: Heat resistant polymer from B -trim ethyl- N-triph epylbo razol e /5 SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no. 8, 1966, 1383-1385 TOPIC TAGS: heat resistant polymer, polymerization ABSTRACT: An ampul containing 1. 5 g of B -trim ethyl-N-triphenylborazole was evacuated and filled with nitrogen, soldered under vacuum and heated at 450-480C for 25 hr. After cooling with dry ice the ampul was opened. The dark and brilliani polymer obtained (1. 26 g) was pulverized and boiled in dioxane in order to remove traces of borazole. The polymer does not dissolve in alcohols, ethers, or - aromatic and aliphatic hydrocarbons. Its decomposition temperature is above 500C. [DW] SUP CODE: 07/ SUBM DATE: 02Jul65/ OTH REF: 006/ card UDC: 678.86 J6 01202:9-; ACCESSiON VIRt AP5MOW8 UR/ODh8/65 09AW3 1 /029/008A3 4WHOR: I vstign~v'r Vi Bel.-Bekasova, 061D. 4 mut influence of polar impurititison the absorption and J2 dra -A' of: chlor pigments in nonpolar solvents ZRqportj k3th Conference on -----bold, Kha r1kov 95 June to I July 196V SOURCEs AN SSSR* Izveatbiay. Seriya fizicheskayas v. UP no* 89 1965# 1399-1403 TOPIC TAGSa absorption spectrums luminescence spectrums solution propertyp chlor- aphyll solvent action ~1BSTRAC?i The fluorescence of ch2oropWI in nonpolar solvents is considerably Increased by the presencoo of small quantities of polar materials* Onwof the author* has advanced tho1ollowing explanation of.this phenomenon (Izve AN SSSR#:: Ser fiz.v 239 Us 1959) a The chlorophyll molecules (or the molecules of magnee- lu*-cwtaining chlorophyll analogs) arii associated in nonpolar solvents and the dimers do*not fluoreacel the presence of polar molecules leads to dissociation and the formatian of fluorescing monceers* The,view of ReLivingston, (Je Amore Chan* P 1542s 19491 Quart. Raves 149 2P 1741 1960)p howevers that, the "activa- Soo*# n tibnO of chlorophyll fluorescence by polar molecules is due to formation of f u- L 6rd L 02269-66 ACCEMIONARI AP5DMW onfluorescing single molecules is still widespread* orescing solvates from n In order to settle this Vointi the authors have undertaken an investigation -of a bacterioviridin isolated from Chloropseudomas ethylicume This material was Selec- -developed a orption and fluor-. ted because its molecular associations have well bs ca bands in the'long wavelength region which are easily distinguishable from: escan ion and fluorescence of the monomer*- The absorption and fluorescence the ab3orpt spectra of the bacterioviridin in toluene were examined* !'When the dissolved air- W puq)ed out (with boiling of the solution)# the short wavelength band decrea3ed J In Intensity and the long wa"length band Increased, When air was again adxdttedp the spectra gradually (o*er a period of hours) resumed their original fo S lar results were obtained in bensene and carbon tetrachloride, When the bacter- iovirldin was.replaced by pheophytin these changes did not occur, The affect of c6nditione -favoring -association - (increased - concentrationj reduced temperature) was presence ot, nonpolar materials In which the pigment is relatively insoluble) -investigate hypothesis, The - dj, and the results were consistent with the authors authors regard the question of the mechanism of the "activation* of"thatluores- cence of.'chlorophyll pigmetits In nonpolar.solvents bypolar molecules as do 9-13, VIN+,"4949 OAg. ftA. h"A3 figures, Cotd 2 01249-~o 'ACCEWION 4M -k,5,MOSM ASSOCIATIM's Von* o0 IMS, 00 SUB COM Opt 00 W? MIM.1 005. ~ACCMION NR,. 3/002 AP4012979 0/64/154/004/0946/0949 AUTHORS: Yabstigneyev, V.B.j Bekasovas O.D. f TITLE: On photoreductton of chlorophyll a, bacteriovirldInp bacteriooblorophyll and provoohlorophyll In nonpolar solvents SOURCE: AN SSSR. -Doklady*., v. 154j no. 4j 19b4j, 946-949 TOPIC TAGS: photoreduotions chlorophyll as baoterioviridin, bac- terlochloropbyll; protoobloropbyllj phaephytin, nonpolar solvent polar solvent, phenylbydrazine, absorptions spectrums chlorophyll absorption, baoterlovirldin complex formation ABSTRACT: In continuation of earlier work on the InfTuenee of the solvent upon the absorption spectra of such p1gmentss the t3.tla sub-! stances obtained,from nettles s obloroblum thiosulfatophilum and chloropseudomonas ethylloumo rhodopseudomonas palustris and the in- terior membrane of pumpkin needs respectively were dissolved In toluene. 0.0-,) ml pheray1hydrazine was added to 6m1 solution and the,- I C,,d -1/3 It ACCESSXOX NR: AP4012979 mixture was subjected to spectrophotometry study after photoredue- tion. The equipmenu used for the usual and for luminesceut spectro-' photometry is described. The chlorophyll a spectra, 8btained after photoreduction at room and.at low temperature%~~;~O ) showed the usual maxl=m at 520 and an additional one at the latter 5 particularly pronounced at low temperatures. Increasing the tem- I perature resulted in rapid decrease of the 505 absorbance; addition of a polar solvent (e.g.. alcohol) also depressed formation of the latter maxUmm down to its complete disappearance. Solvents such as: benzene, pentane, xylene also gave 2-maxima. Bacterioviridin yielded similar results, except for greater stability of the longer 1%" 4 wave maxixmm (!~60 m/4). Protoohlorophyll had one at 470 m/-.. The other pigments were almost eolorless. Measurements with fluoresoent~ s6lutions gave essentially tho same results for tho first 2 pig- ments. 1z is concluded that the apparent presence of 2 forms of photoreduoed chlorophyll a and baoterloviridin in nonpolar solvents may be explained by oomplex formation of the pigment with pher.71- hydrazlne6 AddlUon may proceed either at the Dasio ring of conju- gated bonds ov a$ the 4=$V4 NAMOSiUm MOM Of Ofifis Thii ir6uld Cord 2/~ ~ACCESSION NR: AP40129T9 facilitate electron migration,-thus afford photoreduer-lon at very low temperatures. This-complexed form may cause the appearance of the long-wave maximum. No ohanges in the .520 maximum were observed throughout the experiment. Orig. art# has: 2 ftgures. ASSOCIATION*. In3titut biokhimJI.A.N. Bakha Akademil nauk SSSR (Institute of Biochemistry, Academy of Saiences SSSR) SUBMITTED; 19JUnb,3 DAM ACQs 2bFebb4 MICL:' 00 SUB CODE: CH NO FM SOV: 010 OTHM: 005 card 3/3 YUSTIGNEW, V.B,; M Photoreduction of chlmpbyn A# baoterloviridin.* bacterio-- ehloropb7n and: protochloropbyl2 In nmpolar solventa. Dokl. AN SSSR-154 no-404"49 11 164. (HIRA 170) 1, Inatitut blokbJmil im, AoN. Bakha 0 SSSRo Predatavlono akadenikcas A.Ns Toreninym, BUASOVAj O.D.; KOKINv K.A, Effect of the deomp6gition of son freshwater macropbytes on the quality of water. B:Lul.MIP.Otd.biol. 67 no.3.x152-153 my-je 162. (MM 150-1) (Freshwater flora) (Water-Ponution) USSR/Cultivated Plants Potatoes& Vegetables. Melons. etc. M. Abe Jour : Ref Zhur Biol., fio 4., 1958) 15596 Author ; 160, Oelpov.-RAG. BekasQya Inst : ALTicultural Instituic of the Academy of Sciences, Turkmen SSR. Title : Potato $owing Methods in the Kolkhoz, (Sposoby posadki kartofelya v kolkhoze)o Orig Pub : Tr. In-ta temledeliya AN TurkmSSR, 1957, 1, 157-166 Abstract : At the Andryev Kolkhoz in Ashkhabadakaya Oblast' in 1954, the effect of the density of potato planting on the yield was autided, Two tubers were placed in each cluster with 60 x 60 and 70- x 70 cm. the spacinG bet- ween clusters. The variation in planting of 70 x 30 centimeters with a sinele tuber in the hole was also tried out* The best results were gotten with the Card 1/2 Abs Jour Ref Zhur - Biol., flo 4, 1958, 15596 60 x 60 cm. combination (16.7 tons per hectare) and with tho 70 X 30 eme combination (15-3 tons per hectare). The dense plantina not only increased the yield but decreased the nxmbor of excrescent and off-shootinG tubers* Card 2/2 bi BEKASOVAI V.S. 031nical and morphcaogioa:L obanges in tubarcuosis of the talocrural JOint. Ortop.t travm. i protep.r 21 no-8148-52 Ag 160. (MIRA 131U) 1. Iz kostnokhizurgicbeekogo otdeleuiya (sav.;-kand.med.nauk ye.H. StanixUv!lbva) Moskavskogo nauchno-iseledovatellskogo instituta tuberkuleia Minzftiva RSFSR (direktor - kand.med.nauk V.?,-OChermysbev). (ANKM-TUBMCULOSIS) BMWOVJL V S -(NoWma 1-18P 4-y Streletakiy per., do 3/5v ko'-fus 3p ki. Treatment of tuberculosis of the talocruml joint by the metbod of astragalectowq with reimplantation of the astraplue bone and. compression arthrodeals, Ortop,,,~travm. i protes. no.306-41 162. (MIRA 15:6) 1. Is koetnokhirurglohookogo otd*loniya (sav. - doktor ved. nauk Ye. N. StaniBIATISTO Hookovskogo naudhno-iesledovateltaRogo institikta tubarkulaza (dlr. - kand. sod. nauk T. P. Moebalova) Ministerstva, zdmvookbmnenIy& RSFSR. ANKLE-TUBUCMMIS) (EMISION OF AMR) ARTMWESIS) (AN= BONE) (TUNSPLANTATION) ~ BMUSOVA V. S. Treatment of primiu7 and,organ-destructive forms of oeteo"U- cular tuberculovis bV the Intraosseous adminiatration of streptcayein. Probl. tub. 40 no.4:60-64 162. (MM 15:6) 1, Is kostnokbirurgichookogo otdoleniya, (sav. - doktor medi- teizwkikh nauk Ye. N. Stanislavleva) Hookovskogo gosudarstv9=0go naudbno-insledovatellskogo instituta, tuborkulaza Ministerstva Mravookbranedya RSFSR Mr. - kandidat.moditsinakikb nauk T. P,, Yloohalova, sam. dir. po naucbnoy obasti - prof. D. D. Aseyev) (STRMYMCIN) (DWES-TUBERCUU)SIS) (JOINTS-TUBERCULOSIS) KAU4YKOVI P.Ye.p doktor med,nauk., prof.;. EEKATYx_Aj-j-kand.mod.nauk Study oil the thermal properties of ready.-to-woar clothim on a model device. Gig, i san, 26 no,9:41-4/o S 161- (MIRA 15:3) 1. Iz kafedry obohohey i voyennoy gigiyeny Voyenno-meditainskoy ordena Lenina 4kademii imeni S.M. Kirova. (CLOTHIRG-TESTING) oodwe"m d 16"66 fL4:;j!:tt*vwbk j tow.".. 1136, m I No. A. us.--da fewcois ow 404 bodw in &q. 40% LAX(h wAid dno*v& tvwt ly"wom vA the 14*W gov, kw4 L A Vvasov. WJU=g L,D,; MAURIO N,G, -- . -- ~~, W*Y* ~,-- I I I Distillation of ulneral ell by surface evaptration. Soob.AN Grus.M 16 no*3:213-220 135, (MIRA 937) 1.Akadealya nank Grusinakey SSR, Institut khlmli lueni P.4.Xe3Jklelyr- vilie Prodstaylaze chlano*-kerrespondenton Akadeall GaLTSItsishvilis (Mineral oils) (Distination, Dentractive) 50) "AUTHOM BekauriJLSL,-, Shuykin, W.I., SOV/62-58-11-17/26 --re-g6'rov, Yu.i_._, Shakarashvili, T.S. TITLEz Separation of Higher n-Alkanes From the Fraction With Its Boiling Point at 190-3500 of the Sokol ovogorskaya andMirzaani Petroleums (Vydeleniye vysshikh n.alkanov iz fraktsii s t.kip. 190-3500 sokolovogorskoy i mirzaanskoy neftey) PERIODICAL: Izvestiya Akademii nauk SSSR. Otdelaniye khimicheskikh nauk, 1958, Nr 11, PP 1376 - 1382 (USSR) ABSTRACTs In the present paper the authors investigated kerosene-gas oil fractions of petroleum from the 8d1V3MyMMtLt=(Ural) and Mirzaani (Gruzinskaya SSR) deposits. Under laboratory conditions fractions were separated by means of direct distillation which evaporate in the temperature rants of 190-3500. The properties of the distiUstes obtained are given Table 1). 10 normal alkanea of the compotdtion -0 11H247C 20H42 from the fraction with its boiling point at 190-350 were identified by means of physico-chemical methods and infrared spectroscopy. The working methods applied were already described in previous papers (Refe 1 - 6). In the investigated fractions Card 1/2 the content of each separated hydrocarbon was ascertained. The Separation of Higher n-Alkanes From the Fraction With SOV/62-58-11-17/26 Its Boiling Point at 190-3500 of the Sokol ovogorskays and Hirz&Ani Petroleums data are given (Table 5). Parameters characterizing the motoric properties have been determined. The results of these deter- minations are given (Table 6). As can be s8en from the table,,the fraction with its boiling point at 190-350 of the Mirzaani pe- troleum as compared with the same fraction of the Sokolovogorskage petroleum has a slightly lower characteristic. There are 2 figures, 6 tables, and 16 references, 11 of.which are Soviet. ASSOCIATIONt Institut khimii im. P.G.Malikashvili Akademii nauk GruzSSR (Institute of Chemistry imeni P.G.Melikashvili, Academy of Sciences, Gruzinskaya SSR) Institut organicheakoy khimii im.N.D. Zelinskogo Akademii nauk SSSR (Institute of Organic Chemistry imeni N.D. Zelinakty, Academy of Soiences, USSR) SUBMITTEDs March 22, 1957 Card 2/2 BUAURI, N.G.; SH=IN, N.I,j SHLXARLSHVILI, T.B.; TWOROV, Tu,P* -- - -1, -,~- 1. ae,,,--,~ Normal alkanes included In the composition of liquid funle for jet engines and the synthesis of some of their analogs. Trudy InstAhIm. AN GrL%x.SSR 14:177-191 158. (MIU 13:4) (Paraffins) (Jet planes--hel) Al, wouvrwwAna mourmir urrarAntriolm BXOAMJIX 5 Wr"CAINITAMMIMFO OfAkWO V133 km"30jew Cowen fm ftur" ed Amu" cbm"" IVA swum of chmRuuv aid ebma~x 9-ho"aw r P-im, pol. vy and. fti. ~, one" Mg to be poolow at Oe" ft"Ifted sow"s. awa, 13 on* 777,7 -nan2 5M SOV/62-59-1-113//38 AUTHORS: Shuykin, N. I., Bekauri, N. G., Shakarashvili, T. S. TITLE: Contact-Catalytic Transformations of n-Hexadecane in the Presence of Gumbrine (Kontaktno-katalitiche*akiye pro- vrashcheniya n. geksadekana v prioutstvii gumbrina) PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheckikh nauk, 1959s Nr 1, PP 110 - 114 (USSR) ABSTRACT: In the present paper the authors investiCated the trans- foroation of n-hexadecane in the presence of natural and activated gumbrine. It was shown for the first time that these transformations at high temperatures (450 and 4000) and hydrogen pressure of 30 atmospheres absolute pressure in contact with natural and activated gumbrine take place almost equally. In this case the degree of transformation of n-hexadecane amounts to 58%.The effect exercised by activated gumbrine saturated with zinc chloride solution (20) differs, however,,,considerably from that of pure gumbrine. In this case the formation of cracking gases is reduced approximately a threefold and~the yield of the Card 1/2 readly boiling fraction (up to 1000)f which mainly consists Contact-Catalytic Transforintions of n-fleyadecane in the SOV/62-59-1-10,1,1M Presence of Gumbrine of isomer alkance, ntrongly increanes. Thus n-hoxadecane is transformed in a degree of BVp. Natural gumbrine was supplied by pit Nr 1 "Tetra" (30 m deep) of the deposit near Gumbri Gruzinskaya SSR. The compositions and ?roperties of natural and activated gumbrine aro given in *table 1 . The main reaction during the trancsforn-ition of n-hexadecane is its hydro-cracking In which isomerization products are formed. The dehydrooyclization takes place simultaneously in which high-boiling aromatic hydrocarbons are formed. There are I figure, 6 tables, and 7 references, 5 of which are Soviet. ASSOCIATION: Institut oreanicheskoy khimii im. H. D. Zelinvkogo Akademii nauk SSSR (Institute of Organic Chemistry imeni N. D. Ze- linskiy of the Academy of Sciences, USSR) Institut khimii im. P. 0. Melikishvili AN GruzSSR (Institute of Chemistry imeni P. G. Molikiahvili AS Geokgian 3SP) SUBMITTED: may 17, 1957 Card 2/2 .5 (3) AUTHORS: TITLE: PERIODICAL: Shujkln, H. I.f Corresponding Member BOV/2C-126-1-20/62 AS USSR, B Catalytic Polyo7clization of ffigher Alkanes (Kataliticheskaya politsiklicatsiya vysehikh alka-nov) Doklady &ademii nauk SSSR, 1959, Vol 126, 11r 1, pp 103 - 106 (USSR) ABSTRACT: A group of scientists detected at the same tire (Refs 1-3) the reaction of the catalytic dehydrocyclization of alkanes which ha,ie a chain of carbon atoms in the molecule (not less than 6). This reaction was investigated mainly in the case of hydrocar- bor.s of simple composition. They gave as final yield benzene, toluene, and xylenes. AccordinZ to the,,multiplet theory of A. A. Balandin. and other theories it could, however, be expect- ed, that hiCher alkanes of normal structure (beainning with the n-decane) are bound to yield condensed systems of naphthalene, phenanthrone, and still more complicated polycycles under con- ditions which favor dehydrocyclization. This is in fact, the case (Ref 4) (see scheme). a-Naphthalenes can be partly or complately isomerized into: tho P-form in this reaction. This Card 1/4 formation is, however, possible with an intermediate stase of Catalytic Polycyclizaticn of Higher Alkanes SOV/20.-126-4-28/62 a substituted benzene with a subsequent closing of tho aide chain (see a-~heme). This is based upon a previous paper of the first author (Ref 5, see scheme). In the present paper transforrat.tone of n-heptadocana and n-octodecane were in- vestigatod in the pre3erce of 0.50/'of jp~latirum preci itated on aluminum cxide and on "gurabrine" (bleaching earth5l or palla- dium precipitated at 4500'and a hydrogen pressure of 30 atm (Ref 6). The initial alkanes were isolated from the fraction 190-3500 of the Sokolovogorskaya.and Mirzaanskaya petroleum (Rof 7) and carefully clemned. 0 liquid catalyzates were cb- tained as the result of the experiments which were thoroughly investigatel according to an earlier described (Ref 4) method. These catalyzates contained products of the polymerization, of hydrocracking, and %f the dehydrceyelization of the initial alkanes. After. a small fraction which boils out up tc 100ohas been dietill.-d off,.aromati3 hydrocarbons were isolated from. the rest of the individual eatalyzates by means of the chro- matographio adsorption on ailica gel of the type ASM. By msans of further fractionat'ing in a nitrogen atmosphere a greater content of toluene an~d xylona and platinum was obtained on Card 2A 'gumbrine" in fractions which boil out up to 1500. Therefore, be~talytic Polycycliz&tion of Highfir AlkeLnss sov/2o-126-i-2a/62 Is Ole to initiate aromatization reactions. Figura "gumbrine" 1 shows the properties of the avomatio hydrucarbDns which boil above 1-500. Thay hn7e a blue-Creen fluoresQence. The mixture was divided irt'~ 5, 6 zones respectively by ultra-.iolet illumi- nation with a luminaacence of different intensity &rd colcr (wave length 360 m~). The comparisor of the spectra showed that the f racticn. 11 (Yigs 1 1 oural,%re) is in this connection most similar to 1~4-,-nanthrane and its homologues. The spectru-m-,of the: P ctio- IV (Fics 1:2 cursivo) is similar to that of a-methyl- Ira " &:3 1 :.ours!,.ro)o aithough the two spectra did -naphthalan~! (F.. I not agra,i. Thus alkyl phons~nthrenos with the side groups C -C 3 4 axi~st ir. tha Afractior. I!. They rap-~esent probably a mixture of "-1%ropy-1- &nd- phananthrones with a rhrysone admixture scheme). The inveatigations are continued. There are I figure, I table, ani 7 Soviet references. Card 3/4 ~Gatajytic polycyclization of Higher Alkanes sov/20-126-1-28/62 ASSOCIATION: Inst'itut organicheakoy khimil im. No D. Zelinskoga Akademii nauk SSSR (Institute of Organio Chemietry imeni No Do Zelinakiy of the Academv of Sciences#V55R), Inetitut khimli Im. r. go XvIZU10-Till AXademll nauk GruzBSR (Institute of Chomistry Imeri Po Go MelikishvIli of the leademy of Sciences, Gruzillskaya SSR) SUBMITTED: February, 21, 1959 Card 4/4 BAKA ~_URI, N,G.; SHUIXIN, V.I.; SHAKARASHTILI, T.B. Catalytic transformations of I tridecane. N tatradecame and I pentads- oane under hydrogen pressurs in a flow system. Soob,AV Grus. Ma no.6t655-662 ro 160, (MIRA 13:9) 1. AN GruzSSR, Institut khinii im. P.G. Nelikashvill. Tbilisi i AN SSSR, Institut orgenichaskoy khtnii im.N.D. Zelinskogo, Moskva Prodstavlano chlauom-korrespondenton Akademli G.V. TSitsishvilis 2. Chlon-korrespondent AN SSSR (for Shurkin). (Decane) C- BXAMI, N.G.; SHUMN, N.I.; SNUUSHVILI, T.S. Improving the motor characteristics of a normal undecane and dodecane, Soob*AN Grux.SSR 23,uo.3:323-531 11 1609 (MMA 14i1) 1. Akademlya nauk GrusSSR,. Institut Waii imerd P.G.Wikishvilip Tbilisi i AN OSSR, Inatitut arganichoskoy Wall imeni N.Zeliuskogo, Moskva. Predstavleno chlonon-korrompondentom Akademii GeYeTSitel- sh,will. (%decaue) (Undsoane) C-BIUURIp H.G.1 SHUMN9 N,,I* Contact-bata3jytia conversions of Cjj-C]gftpaIkanes under byd"gen preesurs in a flow systm, Ixv, AN SS3R* Me khlmq mAuk nf),21 3n-318 7 161, (MIU 14t2) 2. Institut orgazicbeskoy kbimil 1no R.D.Zolinpkogo AN SMR i Institut lrbi-14 imJ'GAelildshvili. AN GrasOR. (Paraffins) (catalysts) T7r N.I.j SHMRASHVILIj, V.S. Conversions of -&-nonadecane and siomme over metal oxide catalysts In a flow system under hydrogen pressure. Izv. AN SSSR. Otd. kbim. nauk no.2:318-325 7 161. (NIRA 2.4t2) 1. Institut kbial I im.P.G.HelikJohvili AN GrjjzWR J Institut organi- obeekoy kbinii. im,N,D,,Zelinskogo AN SWR (Nonadecane) (Eicosan;) (Cata3,yeto) h0195 S/08IJ62/000/013/038/054 B156/B101 AUTHORS: Bekattri, 'I*, G., Shuykin, 11'. 1., ShakamahviIJ, T. S. TITLE: Motor fuel properties of high-molecular alkanes of'narmal structure improved by catalytic cyclization PERIODICAL: Referativnyy zhurnal. Xhimiya, no. 13, 1962, 530, abstract 13M169 (Tr. In-ta khimii. AN GruzSSR, v. 15, 1961, 141-157) TEXT: The catalytic transformations occurring in normal C -C alkanes 11 18 In the presence of catalysts have been investigated. The catalysts were 0.5 % Pt/Al 0 -5 % PdZAI 03, 0-5 % Pt/gumbrin, and,O-5 ~ Pd/gumbrin. 2 3P 0 2 The'ex6eriments were carried out in a flow of H at 45000 and 30 atm. It 2 was found that under these conditions cyclization and isomerization occur resulting in the formation of products with higher calorific values (+30-990 kcal/kg) and lower solidification points 16-48-50C love Starting with C16-0 in the presence of 0.5 % Pt~gu I., 17t mbrin or 0 - 5 . /Vmbrln, normal alkenes undergo partial hydro-cracking,.as well as polycyclization Card 1/2 S/081/62/000/013/038/054 Motor fuel properties of... B156/B101 and VolyWcclic aromatics are formed. It is-proved that the 0-5 ~ Pt/gumbrin and 0-5 Pd/gumbrin catalysts are more active in dehydrocyclization, hydro-oracking and hydTogkYkqjy*AjL.rea.o.ti.ona than b.5%pt/Al 0 or 0.5 % 2 3 Pd/AI203* A method of forming aromatic hydrocarbons during the catalytic transformations of normalalkanes is proposed. [Abstracter"s note: Complete translation.) Card 2/2 ~t~ A x Ile- PHASE BOOK EXPLOITATION SOV/6 195 Nauchnaya konferentsiya institutov khimil Akadcmly nauic Azarbayd- shanskoy, Armyanskoy I Gruzinskoy SSR. Yerevan, 1957. Materla* nauohnioy konferantaii Institutov khinii Akademly nauk Azerbaydzhanskoy, Armyanskoy I Orazinskoy SSR (Materials of the Scientific Conference of the Chemical Institutes of the Academies of Sciences of the:Azerbayfthan, Armenianand Georgian SSR) Yerevan, Xzd-vo AN AraWanskoy SSRO 1962. 396 p. 1100 copies printed. Sponsoring Agency: Akademlyanauk Armyanskoy SSR. Institut organi- cheskoy khimil. Reap. Ed.s L. Ye. Ter-Minasyan; Ed. of Publishing House: A. 0. Slkuni; Tech. Ed.s. Q. S. Sarkloyan. PMPOSE: This book is Intended for chemists and chemical engineers, and may be useful to graduate students engaged In chemical re-. search. COVERAGE: The book contains the results of research In physical, Inorganic, organics and analytical chemistry, and In chemical engineerlng, presented at the Scientific Conference hold in Yorevan,:20 through 23 November 1957. Three reports of parti- oular Interest are reviewed below. No personalities are mentioned. References accompany Individual articles. Materials of the Scientific Conference (Cont.) SoV/6195 petroleum fraction contained 9.6 and 2.5% of normal paraf. fins and 1T,5 and 26.8% of IsopAraffins, respectively. The study showed the possibility of usin rea to separate nor- mal alkanes when their content in 2.94n hydrocarbon mix- tures. The method In Important In dewaxing petroleum and in detemining the exact content of alkanes and Isoalkanes In hydrocarbon mixtures since branched paraffins are extremely desirable components ofgasoline and ligroin-kerosene frac- tions used in jet engines. Bekaurl N. 0U N. 1, hu~kin, and T. S, She"r-sh,111. The Motor Fuel By Catalytic -Contact Con- version of Normal Alkanea of The Kerosene-Gas Petroleum Fraction of Oil. (Institut WWII Akademiya nauk Oruzinskoy SSR) 306 Conditions for the Isomerization of n-alkan I n . t h e .. k'sIr W.S a n9 a & petroleum fract:L:ns CoF b o A.'-ff. Ingi at 190-350*0, and the properties of Ogumbrin" (a local Card 4/11 MFAuTa N. a I Cat&2yU* po2yayoUsation of bigber alkanes Report to be mmitted for the Sixth World Petroleum Congress, rrmkhwts 3&26 jum 63 JUN 25 19G3 MSE z am ZxPwrUTICIK SOV/%l9S Nauchnaya konterentelya Institutov kh1m11 AkaGemly nauk Aserbayd. shan.skoy, ArwWanskoy I Omainskoy SSR. Yerevan, 195T. Materialy nauohnoy konferentall, inatitutov khlull Akadewdy nauk Azerbaydzhanskoy, AraWanskoy I OrusInskor SSR (Materials-of the Scientific Conference of the Chemical Institutis of the koademise of Solences of the Azerbayd1hans, Armen1#4 and Georgian SSR) Yersvanri Izd-vo AN Army4nskoy SSRp 2962, 396 P. 1100 ooples printed, Sponsoring Agencys Akadeuiya nauk A skoy SSR* Institut organt. cheskoy khlvdl. Reap. Zd.s L. Ye, Ter-PUnsayan 1. 5d I~Abllshlng Noun* s A.* 0. Slkunt; Tach.,Ed.j 0. 3. 3arIdsy;noOfL -PURPOSZs This book is intended for ohads and o~ewtloal engineers, and may be useful to graduate'students on sod In chemical re- search. Card:2/21 Materials of the Solentiflo.Conferince (Contd) ST295 COVERA09i The book contains the results of 'research In physical,, Inorganic, organic, and analytical chemistry, and In chemical engineering, presented at the Scientific Conference hold W, Yerevan, 20 through 23 November 1957. Three reports!of parti- oular interest are reviewed below. No personalitieslare mentioned. S- References accompany in4ividual articles. TABLE OF CCW=T3: VMXCAIPCHRMTRY Teltsishvill, 0. V., and Ye. D. RosebashvIU. Use of the Nagp-.'- Method In Studying Some Complex Cobalt Compounds 5 Nanobashvili, Y*. M., and Li V. Ivanltskaya. The Zffect of Y-Radlatlon-on,Colloldal Solutlone of GaIlluu, Indium, and Thkl2lux Sulfide v 23 Ye- SmIrnn Zul fugarov, Z. 00 is-Andl. a. Haradova. The Zfffot or the con t1ons of Synthesis and'Formatlon on the Card Materials of-the Scientific Conteranoe.(Cont.) SOV/16195 petroleum fraction ontolned 9's and 0,5$ of norm% paraf., fA fint and 17,5 and 29. % of isoparaffins,, 'respectively. The study showed the possibility of using urea to.separate nor. mal alkanes when their content is 2.5% In hydrocarbon vdx- ftres, The method is important In dewaxing petroleum and in datemining the exact content of alkanes and Isoalkanea In k. hydrocarbon mixtures since branched paraffins are extremely desirable components of gasoline-and ligroin-ker osene frao- . tions used In jet engines.-, -DekaurJLB N. ~L. X. .1. Shuykin, and'T. S. Shakarashvili, -The _ Broblem of Enriching Motor Fuel B y Catalytic-Contaot Con- of Normal Alkanes of The Kerosene-Gas Petroleum -Fraction of Oil (Institut khim:Li Akademiya. nauk Gruzinskoy SSR 6 ) 30 . Conditions for the isomerization of n-alkanes 0 0 R49 ' A* S~ Y ~ 1 .. kz I n t h a vs. e,n a.. g A a. petroleum fraction o b o 0 Ing iLt.190-35000j, and the properties of "gumbrln" (a :Local vard Materials of the Scientific Conference~(Cont.) SOVII5195 silicate mineral) as'a oata3,vat.oarrier have been deter. mined. The study was of interest because this petroleum *fraction Is used as diesel and*jet, fuel and.le degraded -alkanes'. Optimum for these purposes by the presence of n conversion conditions were obtained with hydrogenation under 30 atm, H In a flow reactor at 4500C with a hydro gon/hy drocarbon molar ratio of 3t 1 and a hydrocarbon space veloci ty of 0.5 hr-1. Catalysis with 0 .5% of Pt or Pd on Ale 0. or "gumbrin " caused an 'extensive conversion of normal t undeoane and dc-decane and Improved the motor properties of hydrogen~tion-eracklng products by inoreasing their heating efficiency by 80 koal?kg and reducing their pour points by to 48.;50c. ..Mazedallyev, Yu. 0.j M. A. Dalinp and T. I, Mamedov. Cata- lytia Dehydrogenation of the Isopentane Fraction Vartanyan,, S. A.., V. N. Zhamagorta yan.. and Sh. 0. Badanyan. .Synthesis and Investigation of Aminoacetylenie and a-Alko- .'xyvinylacetylenio'Aloohols 3:36 "4 Card 9/13 . EEKAIURIv NoG,; SHAXAMHVILI, T,S. CatalytIc loomerization and aronatization of higher allanese Trudy Inst.khim.AN Grus,SSR 16:57-65 '64 (MM 16s4) (Paraffin3) (Aromatization) (Isomerization) E94URI, G.1 TOPMIDZE, L.F. _j_ Possibility of replacing platinum by some metallic oxide catalysts. Trudy Inst.khim.AN Gruz.SSR 16S51-56 162. (MIRA 1634) (catalysts) (Metallic oxides) .~ -,-. - BHKAURT, N,G.; WHASHIASHVIIII, T.K.; GAFT1111ASHVIIIJ, P.T.; Hydrogmation of pb(mtl in tho presenca of new- catalysu. Soob. M Gruz. SSR 34 no.1199 Ap'64 (MIRA '4737) , L. --r SHAKAPASHVIL! S.; B."'Auril, N.G. .Syrthesis of al:,cyl aromatic. hydrocarbrric. Scob. 0 Gma. SSR 35 nf-..2.' 3,15-338 Ag 164. (MIRA 17.32) 3, Gruzinskly po'11Wkhn1che.,;kiv Jnntitut, iment V.1,1enina, ThIlIP1. SuWtteo April 16, 1964, SHAKAWHV1LIp T.3.1 BEKAURI, ki.o. Ooptaut-extal)rtia conversions of normal octylbonzeno and 0 -bu'wyluphtW one s Soobe AN Oms c, SSR 40 no, I 181-88 0 165, (MW 38%12) 1. Submitted Fabruary 24P 1965. IffMMOMMA,A.; ILI IU, A.-; EXIAMI, H.; YANICOVSKAU, T I -.- -ummmullkaft 70th anniversary of birth of Anns. Vasillevna Tonkikh,.71xiol,shur. 42 no.3:327-329 Mr 156. (KM 9:7) (BIOGRORMI Tenkikh, Anna V.(fts)) gEgAb-ATI-kk V, I "On the Question as to the Mechanism of Death Caused by Burnap" Dok. AN, 429 No. 59 1943 Thst Physiology I. P. Pavlov, USSR Acad. Sci. 1943 00 A *00 see MLT-- Adomi aloe 1,6,r=.j=Abv *&Mmd~*Wft Goo -000 roe 00 000 6*0 400 See go* was liku 's-d"Go 40 1 1#"" .40 am@ u Hit 10, a 0 list it to .6 Tie * 0 0 *-*1* 0 0 S 9 0 e * 0 * 0 OL* 0 4P.00 0 0 9 0-0 COALS. EARTSHNIXOV, I.A.; BEXAMU, I.T.; MOISSINY, Te*A. Influence of the vagus and sympathetic nerves and the carotid sinus on coronary blood circulation. Tray fixtol. inst. 4:211-220 149. (MVOUS STNM, STWATMMIC) (ML11A qi5) (VAGM RENY ) (BLOW-011MUTION) (CAROTID SINM) -1 ~ - .* ~ ~~. MUM I& v4 "Tropic Effect of the NervousSystem and leuroparalytic Ikeratil v" Dok. AN v ?0, No 4. 1950 Inst of Pbysiology I.P. Pavlov,, USSR Aoad. Soi. MMAURI, N.V. Loma trophic disorders and prolonged tissue anesthesia. Vop. nalrokhir. 18 no.5:37-42 8-0 154, (MLRA 7:11) 1. Is laboratorit nerwnoy trofiki Instituta fiziologil imani I.P.Pavlova, Akademil, vauk SSSR.. (PROCAIU# anesthesia and analgesia, off. on oner, trophio disord, in tissue) (ATROPHY, experimental. aff. of procaine anesth. an local traphic disord.) (ANESTESSIAp WGALv procaine, off. on exper, local trophic disord.) l ' * fn~ VwXwc - ihysiology FD-923 Card 1/1 Puly 33-6/29 Author Bekaurl, N. V. 111ina, A. I., and Tonkikh, A. V. ~Title Physiology of pulmonary blood circulation Periodical Fiziol. zhur. 40, 295-301, MaY/Jun 1954 Abstract The flov of blood in veins is usually uniform and pulsation in veins is less pronounced than in arteries. When cardiac activity slackens the blood flow stops first in veins, vhile in arteries the flov of blood continues even though at slow pace. The number of visible arterioles and capillaries in lungs is not constant: their number may fluctuate depending on changes In the conditions under vhich experiments are conducted. "Spontaneous" fluctuations in a number of visible arterioles and capillaries have not been observed. A specially manufactured condenser number 1 (OS-1) was used and all observations vere conducted on varm-blooded an'-ls (cats and rabbits). Photograph of OS-1. Nine non-Soviet references. Institution IALboratory of Nervous Trophicity, Institute of Physiology imeni I. P. Pavlov, Academy of Sciences USSR, laningrad Submitted October 28,, 1952 ~-Uula~,, V~ Rolo of seotioningp anemization, and removal of the spinal cord of-rAbbits in developing trophic tissue disordere, Nauch.,soob. -Insto fi2iol*' AN SSSH4w614U5-n6 (~[IFA ~410) - 1. Laboratoriya nervnoy trofiki'(zav. - A.V.Tonkikh) Institute fiziologii imeni, PAvlova AN SSSR. (SPIML COFO-SURGM) (TISSUES) B:&KAURIj,A.-V..;-VOLKOVA, M. 1. Treatment of the severe form of iridooyclitis using alcohol- novocalne retrobulbar anesthesia of the eye. Sov.med. 25 no.12: 133-234 D 161.~~ (MIR& 1532) 1. Iz laboratorii nervnoy troliki Instituta fiziologii imeni Pavlova AN SWR (zav. laboratoriyoy - zaalushennyy dayatell nauki prof. A.V.Tonkikh) i glaznor klirdki I laningradskogo moditsinakogo instituts, imoni I.P.Pavrola int. - prof. E.E.Androyev)o (DUTIS (LOUL AIWSTH&SIA) BEKLURI, N.V.; KOROUV9 V-I-; STSPOCHKIM, N.A.; REISAKOVA, K.G. Effoot of pilocarpine and atropin on the size of the Mil and intraocular pressure in rabbits in normal conditiona and in disorders of the innervation of the 6ye. Fisiol. shur. 47 no.7:821-825 A 161, (NIM - ': 1) 1. From the Laboratory of Tivphic Innervation,, I.P.Pav2ov Institute of Fhpiolo Le ad. XALOT , " IOLOGICAL EF.PFM) (PUPIL (Z33)) (INTRAOCULAR ?=SURE) (En.MBRVATION) BEKAURI, N.V.; BABENKG, Z.I.; ZHUKOVA, G.N.; MOISEYEVA, Ye.l. Effect of an interruption of the central pathways of the sensory innervation of the eye on the secretory activity of the cj2lary bo14. FizIoLzbur. 51 no.3025-329 Mr 165. (MI RA 18 15) 2. lAboratorlya fiziologli vegetativnoy, nerVnoy BiSteMy i nervnoy traflki Inatituta fIziologil Imani Pavlova AN Leningrad. KEVANISHVILlp G.Sh.; RAVANE, D.K.1 BEVURIII-4.- Diffraction of a plane electromagnetic wave on a lattice consisting of rectangular plates. Radiotekh. i elektron. 21 no.1:136-139 Ja 166. (MMA 19:1) 1. Tbiliaskiy gosudarstvennyy universitet. Submitted March 8, 1965. BEKAVAC, L. Preparatiowand renovation of elements on topographic maps, p. 67. VOJNIK GLAMIK (Jugoslavenska narodna armija) Beograd, Yugoblavia. Vol. 13i no. 1. Jan. 1959 Monthly List of East European Accessions ZW LC, Vol. 0., no. 6,# June]959 Uncla. IMXAU, G. L. Possinwe of the tonic component of skeletal sumoles. Soob. AN Grus. SSR 20 no.109-103 Ja 158. (NI3u 3116) 1,Institut fisiologii In. ak&dezik&.I,S9 Beritashvili AN GrusSSRg Tbilisi. Predstayleno a1cademikom 1J. Beritashvill. (MUSCIR) BZWA, G. Law of propegsted excitation in tetanic and tonic neuromotor units. So6b.AN Gruz.SS,R'21 no.5:.593-598 *9 '58. ~ - -; (MIRA 12:5) 1. AN GrmjSSR, Institut fisiologii, Tbilisi. Tredstaylbuo akademi- kom I.S.Beritasbylli. (MUSCLI) MMOUS SYSTJIM) MMYAt 0. L.., Candidate of Blol. Sol (dIss) -- "on the fuwtlorAl aspects of tetanlo and tonic- nmwomotor units", Tbilisi, IM, published by the Acad Sol Georgian SSR. 13 pp (Tbilisi State U im Sta3in),, 3.60 copies (IL., No 21., 1959y 113) BARITASHVILI) I.S.0 akademik, red.;,BMWA, G.L.#, red.; DZIDZISHVILI, N.W., red.; NINUA, K.V., red.izd-va [Gagra Symposium) Gagrakie besody. Tbilisi* Izd-vo AN Gruz.SSR. V01.4. [Structural and functional characteristics of the cortical neurons] Strukturrye i funktsional'rore oso- bennosti korkovykh neironov. Pod obahchei red. I,S. Beritashvili. Tbilisi,, Izd-vo AN Gruz.SSR. 1963. 405 P. (MIRA 17:4) BEKAYA, G.L.; MONIAVAp E.S. Projection of the cerebellum to the paleocortax. Tmjdv Inist. f12iOl. AN Gruz.. SSR 13s89-94 163. Paths connecting the cerebellum with the neocortex. Ibid.:95-101 (MIRA 176) ONIANI, Tengiz Nestoravichi BEKAYA, G.L., red. (Problems of comparative physiology of the nouromuscular apparatual Voprovy araynitellnol fiziologii nervno- uqshechnogo apparata. Tbilisi, Metsiniereba,, 1964. 273 p. (MIRA 17-.12) 1~_ACC NRs AT5024229 SOURCE CODEt UR/3167/65/016/600/010177~ AUTHORZ Bekaya,.G. L. ORG: TITLE: Changes in electrical activity of the sensory notor system during'stimulation of the tactile area-of the cerebellum SOURCE: AN GruzSSR. Insfifut fiziolokii. Trudy, v. 14, 1965 Sovremennyye problem deyatel'nosti I stroyeniya tsentrallnoy nervnoy sistemy (Present problems of the activityand structure of the central nervous system), 101-406 TOPIC TAGS: cortical activity,-,CNS,activity, cerebral cortex, tactile area stimulatior cerebellar stimulation, toquj~jipg fesponse ABSTRACT: Changes In the'electrical activit' of the sensory motor cortex during y stimulation of the tactile area of the cerebellum was altudied in nembutal-narcotized cats and in curarized cats. It was found that widely spaced stimulation of-the para- medial region of the cerebellum evoked potentials both in the sensorimotor cortex and In the thalamic relay nucleus. Hore.frequent stimulation (7 to Ii shocks/sec) elicitee- recruiting responses in thiB cortex, and.high-frequency stimulation produced desynchroul. zatio.n. Stimulation of the cerebellum produced various responses in the -cortex depend-. in on the functional state of the animal. It was concluded on the"basis of these and, 2- Card 1/2 Def at TI),ili,si S-Late U. P- 4 me 810N696 CANA04414 nor$ "2..68c. s.j.e.% do. w0 4 ua-c" pArV6 f0eva-, 6-crWO.-Im q- kvg-" ~ Sh. 200. 4" b-&L -166. - 7. 104W *.-Jp 2940. Amo.. 0404*484 Aevomoeo% 11"-Mm WWO-oft cot" ad, OPOPWIGNaR ~ad 0 A%A.-fMdafQ P&MO."10 VNI ma., 104M Or. Tfim~ dram, amm, v. 7. 194016 3oW 1"06 22AL "L SAIJ-0- JO-8869 03-60 -#10 e a &9A a v0 We GAI.A. sAmpe-b" to eo& a *- Ov, *a I-epla, ML 2P.M seems Ketosis a Hasso.sa. re.d.0,00s: A.""q pwftooa~ 19W. 274 964. begat.e.da 31-83-6 *At cab bze. 6-PA-MC-1. M-30%mer 1944.M9WjC)L IH 6&e. 5 QW, goft W'. 6. 4A, 19514 6j. %LOL .4.w 3 -01 Q..w ra%*.MAGADO Xov*saoa Apq. AGONS. MICAW"W"TAN POAM a L -8 Comes seesparm soak 0 rprams. 3*4k SO C.- Iq - - 164~ OP. M7. 44 IOSI. Coofw AH rpys, Ca. v. AID 6. 3946~ 3&w j"k U4, M. 841.0-speo bellhaft. he J04.8.6.b able. c As. 4 64 9-9*- Q 3004 2AL 3PR-4-000" AAe*4G-AP4 KSPONS.00.& POCIm"Absedfb gos~ DPW famov . SmAommomes, a p " o"' TG~ INS. 4, 3m. M4. 2-L $06, .66.&.23. SAID&# vesor g#&. d--b .62cm, , OX as 4.D4 orb "L 2"u 27.& H.Faveswa sweeps 940ASOW romme. npomso*Aww ^ftass psas. "A"Oe's OOPMO.Msdab YWA44. IOSL In & 3ow 10". ZIA. "T. J.6440 CaJ646A,06. T26 M.-~ for aw" 4t a MAYA.: 1. L. "Changes In the Blotins. Total Nitrogen, and Carbob7drate Volume in Buds and Leaves.0 Cand Blol Soi, Tbilisi State U imsni L V. Stalin. Tbilisi. 1954. (KL, No 1, jan 33) Survey of SolentIflo and Technical Dissertations Defended at USSR Higher Mucational Institutions (12) SO: SUN No. 556, 24 gun 53 it B-z"AYA, 'I.'. and "MICITI'M-p V. "'The chevjd&l corpcsitic-n of tle nu U of , s rn i re!j 4. We te Georgia," Trudy Tibi-lis. gros. un-ta im. W"tal3na, Vol YA"711a, 1949, p. 61-65, (In Georgian, ronw-A in Rus!-Aan) SO: U-52402 17, '-ec. 53, (Lotopis I -eburnal 'nykh Statey, ;T!o. 25, 19V'I. EEKWOV, A. EEKBASOVs A. - "The Problem of the Psychology of Initial Mastery of the Russian Language by Kara-Kalpak Students." AcadenW of Pedagogical Sciences RSFSR. Inst of Psychology. Moscow, 1956. (Dissertation for the Degree of Candidate in Pedagogical Sciences). So.: Knizhnagra Latopis',, Wo. 6., 1956. UMIN, Sergey lisenofontovichl WZUVANOV, Vaniliy I-sonidovichl BEKBAULOVAI Turmw A"gazinqym,; SOKOIA)V., A.G., rod.; PROXHOROV, IWA of apectrol lineal region $~vm 2095 to 180 1 ] Was spektrall- rqkb linii; 'Alast' 2095-1840 1. Ilma-Ata. Izd-vo Akad. naulL.Kazakb- skoi SSR, 1960. 27 p. _ ~ Supplementt 10 plates (in porftfolio) - (MM 1419) (Spectrum awlyois) 11 -1- ,EEKBOTAYEV, AITI... Pot"sium sodium feldspars in the alkali rocks of the Borauksay Massif. Trudy Inst. geol. nauk AN Kazakh. SSR, 121133-.11a 165. (]CRA IS:9)