SCIENTIFIC ABSTRACT BARANOWICZ, J. - BARANOVSKI, B.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000103520011-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 6, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

-~k
YEPLUSKI, L. RO"-MRERG, S.; BARAVOW-BARANOWSKI, St.
Daily oscillations in motor activity of the rumen in sheep. Acta
physiol. polon. 10 no.3:365-374 May-June 59.
1. Z Katedry Fizjologii Zwierznt W. S. R. w Szczecinie.
(PERIODICITY) (STOMACH, -ohysiol.)

KIRKOR, W.; BAiWTOWICZ
. I- --)J-
Cyclodiones-1,3 and their derivatives. Pt.l. Acta. chim 8:69-82
162.
1. Npartment of Chemistry, University, Lodz. Presented by W.Kirkor.

. . . ., 7 ~ ~11 : ! . , I I
F . , . , , ,. : ~ . : 1 1 1 ~ .
, , , 1 . . I . . I
I . I.. - ~ I I .. I o . .. I I .: . ~ .!, , . . , , . . . . I : I

B,-!IA:I-,0WICZ, L.
"A school's tailless .7.o--',el aeroplane" p. 138 (Skrzycila 1 ~:Gtor, Vol. 2, no. ~, !'ar -,.3,
Warszawa)
SO: -.'orthly Li$t of East EurQpean Acce,5sjon5, Vol 2 "To 9 Library of Congress Se:- t 53 Uncl

BARANOWICZ, ROMAN.
Yfodernizacja obrabiarek do wysokowydajnego skrawania; tokarkit tokarki
rewolworowe, frezarki. (Wyd. 1) Warszawa, Panstwowe Wydawn. Techniczne,
1955. 160 p. (Modernization of cutting machines of high eftoleDcy; lathes
circular lathes, milling machines. 1st ed. bibl., diagrs.p graphsp tables~
SOURCE: East European Accessions List (EEAL), LC, Vol.%no. 3, March 1956

BADC,,CY,-,'IC'Z) R.
m.lo~ernizacja obrabiarek do .7soko,.-,,d j ania" (1-lodernization of'
1~ neCo s xaw
i7mchine tools for highly productive cutting , by it. Baranowicz. Reported in
New Books (Nowe Ksiazki), No. 13, July 1, 1955

KUSNIK, Witold; BARANOWSKA, 13ozens
Blectronhoretic studies on blood Droteins in nnlignAnt granuloma.
Polskie nrch. med. wewn. 29 no.4:443-446 1959.
1. Z II Kliniki Chorob Wewnetrznych -A. M. w Poznaniu Kierownik:
prof . dr med. J. Rogniski
(-UOOD PROTTINS) (HODGKIN'S DISRASE, blood)

KRAS111K, Witold; BAjWIOWSK&, Bozena
Aloctrophoratic changen of aenun proteirta during thn couGe
of malignant gramilom. Polskie arcch.med.wewnetrz. 29 no.10:
1365-1372 '59.
1. Z II Kliniki Chorob Vewnetrznych A. M. w Poznaniu Kierownik:
prof. dr nod. J. Roguski.
(HODGKIN'S DISUSE blocd)
(BLOOD PROTEINS)

R0SNERs Julian; BAlWIOWSKA, Bozena
Chromatography of amino acids in psoriasis. Przegl. derm. 50
no~5,399-40r-? 963,.
1~ Z Kliniki Dermatologicznej AM w Poznaniu Kierownik: prof.
dr A, StraS2.7nski.
(MINO ACIDS) (CHROMATOGRAPHY) (PSOFLIASIS)
(URINE) (BLOOD CMICAL ANALYSIS)

Synthetic plant-growth regulatavi.
Parnitowsli2i. Pr:cisml Or 0,
a Celic tie id a lid 1 '147.1; 1 m% C I)Ccf I Ny I? f I!( ti-;~ ~ I. Tl"v tv,ul'
Is
[A -we'llilil; tAilig, ilwvill u lkahl,~~,
Compli. ~i Ol'ir I~v kV

V*M S CtMTbhA6n: Of tA4 rd xr-a-aega re
the'ramimid" Altate.:J .D. Shujar utd j
,
..3 ovski (Stitt last.: "Hn..'Woh WF
ow). 'Dan ~
-11 2 3-7(1954) -T testmat of lodine
Ptah,
'
:,
~tlwa 4% HCHO Gpd 0.41"
p'fl ~.Ij protamlae iiysL
emnled Ila to
Ptelmstruefit with bile sOts h
a,
Ct i
l
t
G astened the rmcess
-
a
ezam
. M-PM
f
ucg~ by=u, cvuW bi veroml-to brink
HCHO

by the
w
el
i
9 r
w ova
im. O a
n e
as
n e
We
't he Ill dbonudeotide-thecty d Vzunjj~ s. stainlas(Ilemy-
am Pt~C.A i4l, Me). J~ A

POLAND / Microblolot, . Generul ifl-cilobiolopLy. F
V
Investigatory Methods and Techniques.
Abs jour :Ref Zhur - Biologiya, No 5, 1959, No. 1939-3
-Author :S~,ugar, D.; ~~-qranowska J.
- ---56 1 e
inst :Folish Acaden,17 OP jj(;6s
-,itle :Application o'~ 1131 to Quantitative Studies on
Grain Staining
Orig Pub :Bull. Acad. polon. sci., 1957, cl. 2, 5, .~;o 5-6,
165-168
Abstract :No abstract t3iven
Card 1/1

El-CERPTA YEDICA See 4 Vol 12/3 Med. Micro. Yar 59
850. THE ROLE OF PROTEINS IN, AND THE QUESTION OF LOCALIZATION
OF, THE GRAM REACTION - B a EA-nvw-s,.K-a_ J_ and S h u g a r D. Dept.
of Blochem. , State Inst, of Hyg., WWrazawa - ACTA MCROBIOL. POL.
1957, 6/2 (107-114) Tables I Illus. 11
Four-day-old cultures of Azotobacter exhibited a ieeble retention of the Gram stain

in the cell periphery. When such cells are exposed to solutions of protem such as
egg albumin, lysozyme or protomine, theGram reaction is intensified. In most in-
stances the addition of the protein results in intensification only in the cell peri-
phery. The increased staining can be correlated with the uptake of protein by the
bacterial cells from the solution. Pepsin and trypsin were without effect in these
experiments. Ruptured cells that had been treated with protein still retain the
stain. In some instances the retained stain seerned to be diffused throughout the
cytoplasm, Wyss Austin, Tex.
10 ~i'

Janina
M
I
echanism of Gran's coloring method. Postepy mikrobiol 2
no. 3: 397-415 163.
1. Katedra Biochemii, Panstwowy 'aklad Hgienv, lv-'ars2awa.

BARANUAISKA, Joanna; SHUGAR, D.
Photochemistry of model oligo- and poly-nualeotides. III. Cross-
linkiug and.staining properties of ultraviolet irradiated films of
ikimleic acids and eligonucleotides, Acta biochiM.Dolon. 7 no.4:
'160.
5-529~-
1. Department of Bioohemi5try, State Institute of Hygiene, Warsaw,
(NUCLEGSIMNS AM NUCLEOTIMS chem)
(ULTRAVIOLET RATS)
(NUCLEIC ACIDS chem)

BAWOWSKA, Krystyna B. (Sopot)
"Seaway distance tables to Polish seaports" by J.Zaleski, L.
Nowakowski. Reviewed by Krystyna B.Baranowska. Czasop geograf
33 no.2:276-277 162.

BAILANOWSKA, Krystyna B. , mgr
"Icing phenomena on the Polish shores of the Baltic Sea" by Jozef
Baczyk, Maria Czekanska. Reviewed by Krystyna B. Baranowska. Tech
gosp morska 13 no.4:112-113 Ap 163.
1. Wyzsza Szkola Ekonomiczna, Sopot.

t~7R
1176 547.65707
B,tr,%iio-x:,'Ka T. ColInska D Thr rreparation of Alpha-Naphtyla"tic
%rid.
()jr;,ytnywani& kvra.,;u alta-tialtylouctowego- I'memyAt Cho-
smvzny No 3, 1951. Tip 175-181. 5 tabs.
TWs arlivir (te,,il.% with the preparntion of alpha-chlommethyl-
implit.ilt-no in the prem-tive of 11,130, 'rhe aniount tit lljIN)j iLSM is
~svial)vr. J v 237 g per I Xg ill arld im%lrad of
1885 q , the yield of ehJL,,OMeUIYJaIJOII rt',I('11011 MIMIMI the same
VhI~.rOn-.vthy!atI,jn W35 !LLso performed using conAtnuous flow of
Iry TIC[ with 11,P0, in the presence of 5 g of ZnCl, and
1'.' 17 tit ifflva gel per I mole tit naphialetic I'lie y1eld of the former
reat,tiou x;Ls 54, .. of the latter 50- . A ust, of ehloromethylm~phta-
lene in agriculture is dbirumed.

BARANOWSTA, Terese.
Effect of atropine and pilocarpine on the equilibrium of axtarrA-I
=,aclas of the eye. Klin. oczna 24 no.1:23-28 1954.
1. Z Kliniki OczneJ Akad. Had. im. Gen.KiLrola Swiorczewskiago
w Szczacinie. Kierownik: prof. dr W.Starkiewiez.
(MUSCLES, OCULONDTOR, effect of drugs on,
*-,tropine & pilocarpine, on equilibrium)
W'.WPINN. effects,
*on ocvlomotor masclos, on equilibrium)
(FILOGARPINXp effects,
*on oculomotor muscles, on equilibrium)

I
BARAIIOWSKA , eresa
On the condit:oned ref-'ex naz,ure of v-isua! impre sc: ions with
special reference to visual acuiTy~ Roc7n. pom. akad. med.
Swiercze,vski ~ ~11,
L Z K-Iiniki Oczne ,i Pomorskiej AkaderLii' Medyc!znej Kiemmik:
prof. dr W. Starkil"k4icz,
( REF U, %A , C 0:'D I'I ~ I ON MO )OILTAL Pl-'RGITTIC,11)
OCITILAR )

-s v"'
i-:~-DICA Sec.l? V01#9/Q 0042alrr-0109Y Aur, 55
1298. BARANOWSKA T. Klin. Ocznej pomorskiej Akad. med. Szczecinie. * Or-
t-optycznz-t-cTR?urgicznc leezenie zezdw ukrytych. 0 r t h 0 p t i c a n d s u r -
gical treatment of hidden squints KLIN'.OCZNA 1954. 24/4 (241-
253) Graphs 6 Illus. 2
Orthoptic treatment gives a diminution of the sauint. the subjective relaxation
also causes increase of the fusion. If the squint returns the fusion is higher thnn
before the treatment. In.latent squints permanent improvement was seen in 20.8%,
in 54.2% it was transient, in 16.4% it remained unchanged. The best surgical in-
tervention in the majority of esopi(orias is folding of the internal rectus muscles.
24 references. Szm)-t - L6di

i
.~ . L I- ~ " !llfl~.iu,; vl:o-,~Iwua (1.41 , , ~
; ~ ~ i :~t ',. ! ' 0 io r It i L,, - 1, a 'L, K :t, I:!, ov i cc. C . I , , -
I L - t 1 , ~-,
i,. : z,ll , ~ -~ 1 1 .1
. - - i - - I cl:,

Teresla
The problem of d'stribu'ion o' pr~s;.-.at~c cc?
In
in the tl-eat::~ent of stral)-is-r-,jo 'wit"',
ponl. al'ad. med. swierc--c-ask!
1. Z Katedry Okullstuyki Medycznej ( Y, I e rc ,I "I
"r0.:
z :'."zyc:-,oani a-La .,e:,uja.-,yc,.
w S~*,czecinjo (Tllerow!, .:,eci. T.

E-Aiii'~14OWS','A-SI'C)KWISZF,WS?,',I, Dozera
ItAlity evaluation of som- t-r)trwtivn (,ruima againit carbon
-P 1111fi.de absorption thru the skill. FarmaeJa Pol -'~O 110. 8:
286-2`~,8 25 Ap 164.
1. Department of Toxicoio6ical Che-mistry and Industrial
Tcxicology ', School of Mr--~'Lcine, Loiz. Head: Doc. dr T.
Diilukiewicz.

BARANOWSKI, A-leksander
-- -- -- -.-- - - - ~ I
Aspects of soil geology concerning the suitability of the RS3
soil for apple fruit cultures. Rocz nauk roln roal 82 no.1:91-118
160. (EM 10:7)
(Soils) (Apple)

S/137/6P_/Ooo/bo1/129/237
A052/AlOl
AUTHOR: Baranowski, B.
TITLE: Statistical processing of fatigue test results of metals
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 1, 1962, 23-24, abstract
11155 ("Wytrzymaloso zmeczeniowa tworzyw i elementow metalowych."
Warszawa, 1961, 141-149'. Polish)
TEXT: The usefulness of application of mathematical statistics methods
for determining the durability and V1, of metals is shown on concrete examples.
I w
Various methods of statistical processing of data for determining durability are
considered. It is proposed to represent the fatigue test data in the form of
the W8hler curve with the subsequent processing of results by computing durabili-
ty for each value of the stress amplitude within the adopted interval of relia-
bility, using for this purpose Student's criterion. For determining *W~ it is
practicable to process the test results by the statistical step method. (W.
Dixon, A. M. Mood. J. Amer. Statist. Assoc., no. 40, 1948). There are 20 refer-
ences. V. Matorin
[Abstracter's note: Complete translation]
Card 1/1

S/123/6P-/000/009/007/017
A052/A101
AUTHOi: Baranowski, B.
'21TLE: The effect of tempering at 250 - 400 0C on the fatigue strength of
W I re
PE-RIODICAL: Rnferativnyy zhurnal, Ivashinostroyeniye, no. 9, 1962, 36, abstract
9B160 ("Wytrzymalosd zmeczeniowa tworzyw i element6w metal owy ell."
Warszawa, no. 56, Dyskus'., 64, 1961, Polish)
TEXT: The effect of -reaipering in the 250 - 400 0 C range on 6r of cold-
dra,...,n carbon steel wire (0-5~',' C) 2.5 mm in diameter was investigawed statisti-
ca-12y. In the initial state 1~1-, was 138.5 kg/mM,2. 6~ was determined on Schenk
machines (bending during rotation) on the basis of 5 x 1o6 cycles. To plot
eac,,] fatigue curve 85 - 100 samples were tested. It is established that an hour
tempering at 250 0 C in an oil bath raises 60 -01 from 72.5 kg/mm2 (in the initial
state) to 127.2 kg/r-,m,2. At the same time &' practically does not change. After
3-hour temDering at 370 0C in a salt bath 60 W 01 increases to 108 kg/mM2 and 6w
P 2 (in the initial state) increAses to 53.2 k&/mm2
,rom 45 kg/MlIn . The relationship
between the statistical value of ~w and the index 0,5.(6' 66) x has been
00.2 +
Card 1/2

The effect of tempering ...
S/ I 2316210010101J~IVWIG 17
A052/A101
confirmed. The positivc effect of tempering on the service life of wire rop,-s
manufactumd from tempered wire must be checked experimentally.
M. Shapiro
[Abstracter's note: Coi-,iplete translation]
uara ;212

c-, P ol 1, Z-i I I, -.-t F11-62/ I i C).~, Sta I c ten -.j le tes t of
nit, ~ a 1F
.1 . Hiltnilk P '3() D
I - --'i zela-rl~

BUIAVOWSKI Boleslaw, doc. mgr inz.
Statistical interpretation of impact strength tests. Hutnik P
29 no.2!53-59 F 362.
1, Instytut Metalurgii Zelaza,, ',Gliwice.

BARANOWSKI, B-oleslaw., doe. mgr inz.
Once more on Standard FN-60/H-04357, Rutnik P 29 no.4:128-
130 Ap 162,
1, Instytut Metalurgii Zelazay G-Uvice,

VAtellurgioal Abet.
VoL 21 Apra, 1954
Laborator7 A pparstus,
Instruments$ Ete.
Loll
T broVo M Exjt R 11mrannwaW and G.
2w-
2 -11n-Follsli]. A review of the existing tjTos of extcni;o-
meters is felloued by a short analysis of eir;rs and a dis-
cussion of the known met hods of c~libmt ion. Adescription
of 11 com rat er dovelop6d by tho Poliph Metallurgleal-_
ltv..rch rutituta in given, and some raltIM111011 CAM
Martens miriFr-extensometer. calibmted with the now
uced--S. K. L. A-
F2mp-t,jr, a re
bo, Ill, I I
b

Tht 111ttod effect lik a IiInArj altctrolyte tiolutioa Itom
the pAut of -iew of tile tJLWI lounalldca Of irruver6lbla,
Wqh).-Tbe Hilt(sif effect, i.e., tile appeatmice of a micri.
gralfirut Ill tile presenct of a,) clat's-11A elec. fidd, was
studit'd by allpans of Om'ag~r 1) jellumeanbig, ell I :! I.J."itiolls
betwell t1lixt!s Hild forces. The stationary 6tati. it, silinled
to lw that ill Which ililiolls alld iritiolt, ecillidly Share the
tFaU51)(Ol't DI ChitTgUh Olld tile Value ut tile
wimi, Br'adivsit N ca". P. vall a.

V
raecty6uiermlti-di Won metbod of Otermirift the
So lpt coefficients in aqueous solutions of
lt'rlAttulaa~kl,and, T. Mnt~- 3
YN17 -j- IMd"T'j-h 1`51111. MaP. PpiP4.
'Uff
-131 04 IRA in HaSlish).-Tht; thj~rmnggravitational Pirthild
Was 1110(ileed lot liquitl C(CCtl0I!itC sotll~' In ft (0110w~
At inanntr: a thin-ttralleil cylbidrient 63pfilar)
tnfl- .1 used for tile two walk whic-h muit ty. tuala-
tuil!ketl at difft-i-ent. Two OvOrm1w virrm fitted nnr
tit tile top and flit otht!r at tile ixttilin. to which it high n1- i
itmating voltage was eipplicil. Thc licat gtntritud inAlt!
tile tUt)V PiollaCed a horijitantal t41111). J;rfttl'etit With WIlk-ji
vrai assoed. the thermal diffujiyi Ott%. Thk device, %videh
the thermal diffultion proem in Ole presence an ext,mull
cite, field, PM-ed awful In testing binary rind tt!rnary w3wi,
The Soret fattort; wrre found Im CUS04 Poill's. and it Was
illjown that Solet's coeffs. did nuit depend oil power tl~jiut,
nc~roit0secoiien.fungiiigironiO.1to]N.
was notic-cable at about 0.5N, wit: 1e at 0.05N a decline ir.,,s
noticed. Compared to other inctliods, tile valtivs of tile
cocif.s. wem strialler by the rle0rathermal niciliod, This
may be due to llic elce. field, mid tit tit(- lik-olihooti u( ac-clir-
rence of "carrent-diffusivity effeck." PhenonlenoWictil
theary of the eicetrothernial diflumot nothod In fluid5.
lintranoask-i. Ibid. 439-42-Futiatiow: are tiev-cloped X~
for the teinp. rradipja und tna-- ump. diffurente in Vic
c:tvillary Jxtbe. U,c vtlocity of the rut-Telit ill 111c
c.&IP11lary tulw, tile onicn. changes in tile cniit~jinvis'nlld Vic
Somt CoLffs, Beritard kohiii-_1

BAFA!V,,TS1\I, B.
Bulletin - Vol. 2, no. 9, 29!;1,.
Phr-norenolor!ical theory of the Plectrothermal diffusion T,-,ethcd in fluids. In English.
p. 439.
SO: Monthlv list of East European Acressions, (EZAL), LC, Vol. 4, No. 9, Sept. 1955
Uncl.

Uenm of dructur`e on m~CL-mICIkI pw .NACS of Llp,~~7Lg~L
&UeL% D. Barallow-Iii (Prare 7TEI. Zji-W. Jlwwt~ , 1954, U. :1,77-
i~94 (in 11w Stl7i"to of M, .1 ;Iftd
ti. relatirm l&hyc-(n stnicturt.,and JuLch"Ilicil j.;upL:tI,,; %N~-,I#,
iuvestipiod 1)), tensicn, impact iv,%s n 3 lu~, ahoy
structural Stcels fconipositiuns given). The sarop),!s. bt,-til to
give teasile str-I gtbg of -110 ),-. per MIU.1 awl sultnlit',.~I to
quenchijig, i~iismgr and is~)tr;errnal treatmen0i during
norn the
__shqvtA_ different miweAructuics. Si)rcirmc~ts v,ith a
microiAtmAure uf temperetj iw~.-,teimt;te show,-a tht: 1-,est
propertim The iippearxnce of pewlite anti ferrilo. in tht micrc~
structure msulted in lower fatigue stren&tIL I~oflicnn ~'Ih- t",'U'l
30HGSA " hteel (cmtaining 0-:10 Nit 0.9511, Cr) was less fati,;ue-'
resistant than specinwms litat-frea4ed in thf. Grdinnwy way. The
-brittlent-sit,
-!tine steel, wlwn "hihiting tmuptr
ocatUr in tLe fatigue t-t rejultq, Th. le'latim)
and In"Itaiiieril propcitieq tnd Cie connecti(in fmi~,V.C,
res
i.~twux.,Iimit
,
(18 Werencus.)

V Phttionicuologl6ifthooy of clotuothermodiffusiou ill
'itall r-acmv).
liquitl!j. Bvi;
19,49%1,131 Summary); t
0. ptemling abstr.- rth r ev , pincut is presented oQ:
the pljv;)rlj)vlluh)R2 tj;r el them iffu,,Ivc
p 1) L m0litA (cf. CAA ill i 111f S, th c"I'lill"612:1 iogh,~I
u5e(L It '011conis A vior f to p. g I I., i. t1w Capil-
lavy, tile vele-city c Ime o lie live t .1 (111717clit in tile
"a pillary, wid conril. diallgvl ill tit,! uj,jwr atilt lowcr cou-
taillers. Res:111b;showed tll~ lint-al dellemielwe Of tile coacil.
ratio Intiveen bath comaine" oil tilt-. dumtjwt of thermodif-
fmiaii. Tito concil. ratio O~cvtdeil bF 23% tile ratlOattailicil
by the t1slial thumogravitallonal nuthod. Tile presenw
t1wory may atso wrvc for 6juid motals or salts. S. N.

13 ft R h,410 KS IV/,; b o C6dh,-/
USSR/Chemistry - Physical chemistry
Card 1/1 Pub. 147 - 19/27
Authors Baranovski, Bo gdan
Title Comments on the work of S. I. Dralkin entitled, "Transfer arid Distribution -
of Components of Metal Alloys in an Electrical Field".
Periodical Zhur. fiz. Min. 28/9, 1676-1677, Sep 1954
Abstract Co=)ents on the report by S. 1. Drakin (Zhur. f:Lz. khim. 27, page 1586, 19531
dealing in the nhenomem of transfer and distribution of components of metal
alloys In a constant electrical field, are presonted and analyzed. Eight
references: 1-USSR; 6-German and 1-Holland (1854-1953).
Institution : The Yagellon University, Faculty of Theoretical Physics, Cracov, Poland
Submitted : April 8, 1954

Distr:
AlIzi lhoalt 4 1 J',, t L
Illt-3 of certaint -Tos, I I 1 2 1 ~11!d
t i. I - 0 Jr, a -! ; I, (,z;; 1 1 f C~:. 1u
1-4. ~11(1 1:6, ',I;t(N0.),A!:!-,~.,:H:I, t) I i
mimmury t i I'; di:l 'I kt I "L'. i,1 iMIS f(Mll lz,lopdt,~ I A, and 1.6, cai-
1,,,,v of certaill tern,ty 5;,Ili.-,. WZ. by tilt: S,Avatioll of~ fl roi-,uc. a 11! 1
I ; 0. 33, C.,I(
ill the ~'All. SUL 11 tLrll,l; Qohm are k-n-,%vn to fom com. I :I _q, C,-,( :0. ..n~! J :017r
r Ijc
(H biwa v V.Inh ix I I "l1, h ( 'IMIJAIR., U." rt* 1
7r, L,
11 1 ill'44 L "al E
),LjijvLj I)y cr%,~vtjl. c~-, 1 1,1 !,Ills. that w,:t-. 1;.~Tllyi
h, S., es ol .,,1. 52, 1 M2& Thc~
-riL 1. (C -.1). - fvA by '-I Jy
by (if water fulln tf-rilary ,Balls. by~ rl.
)Topirtli- .0;, ~!)11
't of anhyd. cac!;. Ill rulch systc-M s. compc'sc: I of f!j~ ik)!!.; ill I J,,.
diffc-mit. molai ratios of dcrttolylc to i1tv r"'Iclectrolytc or
The f(Alolving nre the
jo th, LIld 4:jVC(r(, t
y c ~kcre prepli.
coln")AS.: obtaisM from molar a,;d (:j) Oic
Ile%v
-fr,:!Il 01i;
ratio in 1 1, 1:2, and 1:3, Lit r,CO(NII:b.11,0 from Crit-I V-01 1') 1 I-Imit I:;i i;)4,
fmm ilm%r Raoult's I ow to ll;z- u'.
m1olar rutio:, 1 :0.7 Plat I ; I J), 011. 1:1
~Fatio~ 1:2.5 an(I 1:3.5, 1;160~
11 : 1, 1 :21.5, und 1 :3, IAI .,,CC,( NII.). fr,,m inolm tatim 1:3.5
land 1 :4, Irmu MOlar r4dor 1 :0.5
frL.;n mol-Ir 1:0.5
"CC
N fioni molar tatit~

anti JImda ERMIaTma

iniminary 842-4XPub. 1957); cf.
preceding abstr.-Tbt
$Ord coeff. In Sq. S61:3. of electrolYtes can be dctd. by the
"eJect-416yMndiff- sil- -hod." The same method can
be
used also fre other liquids that are 90M COO(InCton of elec.
l
l
current, eg. mo
ten oRltsor mete
*11M. Iletlectrollitr.
modiffuslon tattbod has the atimntapol simplicity In &CCU-
r2te deta. of the internal raditts of a capWary by we4shing a
Hg rad of a kbmm length; " eliminates the cW Inaccuracy
f (h
th
ti
I
h
d
N
ff
l
1
h

A" o
e
ermotrav
ta
Dm
met
a
.
w.0
esaretcoe
.
t
joythetiqMWerm iffuslon method n4fulresknowledge of
Ah
e apt, OnMeters, phenomenological coeffs, of the liquids
d
i
f
h
S
l
kn
Un
er ventgat
on.dan.o
t
eem
Itatthe
ovra
. sp
i
tvolta
e that is a
d to th
c
gib
r
f th
e
a
e
e
e ampe
age o
ppl
g
rrent
d th
ti
l
A
hi
1l
d
4mli
n-wa
, an
e
me requ
"
t.
t
e
ghs3 capillary with ench end widened to a reservoir of I mi.
capacity was used. The capillary and the widened parts wen
surrounded by a cooling-water jacket. Each widened part
id
d
e
was prov
with a reversible electrode. Theapp.was.ver.
tical. After the app. was filled with the sDIn. of electrolyte,
the electrodes were connected to an a.c. source of several kv,
The liquid In the capillarybecamebeated. Outstdecooling
by water caused a horizootiA temp. gradient as great as
W/cm. that set up a horizontal thermodiffusion current
and, bemuse expansion changed the d. and conen. of the
goln.,avertimlenvectioncuffent. The latter current con-
veyed the component enriched at the wall of the Capillar
to

- the lower reservoir. This method of electrothermal diffu-
XiDnIldiffers from the conventional thermogravitairo-n-ar
I
-
iriRliDdinthat: (1) them 13 nobot wall, because the highest
temp. is Along the RSi3 Of the capillary. (2) thermodiffuslon
takes place in the p.em re of an external tlec. field, The
new method was used to det. the Soret coeft. of the following
sq. Wets_ CUS04; AgN03, a mixt. of AgNOs and NH,N0j.
! KCI,NaCI,HCI. For CuSO. snlns. this coeff. was: forlN
361n. 9.4, for 0.75N 9.1. for 0.5N 10.4, for OAN 10.5, and for C\

-
0.05N 7.8/degme; all the above figures for the Soret coeff.

A must be divided by 10W. Coeffs. for other so
I as. r
e n o i
given. 44 references. P. jimm

Z~~ K- I?
n of Components of Binary TAquid
We HIM, MR.-ar. let
a Field fr:)m the Point of Vitw of
of Irreversible Processes. B. RaMngw&Uj (Rull. Arriel. Polon.
Sci., ID55. Lifi), 3. (2). 11 usii. rheomOcal.
The equ ations d.d... thOSO (IOTived by
Shw.. (Z. phy,,ikal. Mix, J03, (A), 164, 22.3; Alff, Ab;.
(J. Ret. McfqW, 1033, 63, 44D).-J. L.

m----------
?,eels Im so or mt",. .6Ans.-
=5 th'! water iopor pjrtslu!r, bui in
tern may t* tcs~-41& fi,i -thi ant
I PM., vgadb tltvr 5vilt ~t
ropenlip This wnutd aNi "plain. tilt- j
r-joldtiv. afitl the amiratlahk Froons-'.
16-is-nct i0 v%plain tbt re As th
'11, the, Aittl Itie T
W (prectdini a%lr-) ind, AML-13 u ra VAOU
the W114A6 the
T, naq tion'sNO that is being formed tosy ;j~h .t
In Slope MS. "I
.0gi am R and M a mbit i the no. -A urva mo-ts.-un-ftacbed to ions inert
4kttdytL S.21on trolyte and dis,
untirat-411k 0qtftV" are iharattiilitd bY -the It the wi4_; mu'Pcurnt in the S010. Incitzges. furtherl: =d
Okbility to fohn- sad ibimpkx COWF&I AISO.Ittroary SO AS-.' mity thits lie I the ft,,ison vvh), vgiMe3 apow"_ c0,
ti 'iL th
A quell Y; C nj~tM roptities cunnov 1* ciplorita
electrolytes ha~lug i1Loih2otdtjc' propeAiei~ sm. assord OU,tie, 0
So= ,Wy JLY mc. interactitm'between the ehttr~btle fti
"notirctrohli~ thit forra empitx mob.. in the tom;blii the
UUvr CIDOK~At Dh O-Vrattr . Molt. - m-u"
MOD, CACSfAWINM.: CU106-4co(NJIX
;GAG, ii~
R and ~ UBY.SCQNJ%~.~~, Tb~ -ex~la
IM u 17bt ~htiraouttk Properties in tervary
of terrt~, 7. ly
!the IeTtW3 solmolan*emctr~ W trO Ytts lue explained as 1611P Jet
jnjerj~tt~at;oo is &j
nour3mufAytt the 11011DWint of mmur 6-ttralytes ik-ke.juto
accannt. not cal
. y tht efftit
ttl,- v01-01 Ions on the P Won funct -4~ bujA
art in Igo th
based en remvt~ tkcuostatk theories, the Wwent is' 'WlIkY of Incilrnpletv disw*n; in tolm it It-is 41$6~w.
that the Mots. Of doubic
coutinuods zntdi~tn. Nowevtf. ~ In 4
S, m2SLY be prctent'An-il
to tbil'armliph the autirwAk. prCept-Ales,cat. bter-o then 4Wiraoultk- ppoj~rtfes in tern S61ni. of titer,
tm d, Ittweeh the sotverk Ww'. the ater,
ttolytts zoay be attributed to dttrtue in t e no. a W
pre 0 IF
orvount", M*-ilx, in the mmPa. of1hydrates.; 71;is ini
'2ddtd moi4ectiblYte muls~- with tons taken Jut
I I err
~.It- is'sipifXant, that those cleetrul retition mod
ytes fliat dis'ptaxi ant - r ~,bc'bzsrd on the gimlioption,1hat the
Of
'. arC few hydrnted thpn the comjl(~neot kinsor d
ILI 'PTopell M. . W1
their stiq*tibi tion. RtxTht thepil"_ e- roots. of the ekt-kinlyie", 511pp"prt for s.q,c11J~p__k t
for- '111y. to. bydra
I=' 561vation 24 W'Ater _36165, assurne. tbal 1hum, is & filst bk folmd in the fait that the no. Of %VfktCr MO ti ~jja
f.h Ira -'ell'strang).y:a] -41ed to the inns. Thn I vIvhirn, p
m Wa st tt. "id doubk salts is, on the Wimle, sumitettluit
um fs iiddedlb a'idlh. in OrrtrMyt~.. its 24e-1-4.- rum, me t swts_ b~

1-1. " J.,
1-11. dif"rus!)n hi tho Li,juid -21;,-Micall. (11(jl-a:-~~I)
*To. `-8, ~uly-AIIFL13'
t u ~j

v. X-k,
M"fl,
refereum.

F.: ZYGADLO, J.- -3~-.RINCY,!SKI, P.
Inbestigatio.-. of vapor pressure in three-component aque-)us
solutions. !I-'. Interpretation. P. 425.
PR7'-,",,'YSL ChFT'1CZ1N,`Y
1,-,arszawa
Vol. 11, no. S. Aug. 1?55
SOMCE: Monthly List of East European 'ceelsions (EEAL), LC, Vol. 5, no. 2,
Feb. 1956

Category POL[UTD/Atomic and Molecular Fhysics - Liquids
Abs Jour Ref Zhur - FizilA, 1,10 1, 195Y, 140 9hY
D-8
Author Baranawski,.. B -
Title ~-Thermodynamic Theory of Separation of Components in Binary Liquid Alloys in
an Electric Field
Orig Pub Roczn- shem., 1955, 29, No 1, 129-131
Abstract Seport on preliminary results of the use of the thermodynamics of' irrevernible
prepesses to the probltm of beparating metallic components in binary liquid
alloys in an electric field, obtained on the basis of DraIdA work. (Referat.
Zhw-nal Kimiya, 1954, 47871).
Card 1/1

BAFLANM*151; I,
Thermod,,m--1-1.ics of T-roc.:=es.
Vol. 10, no. 12, Dec. 1916, ?oland)
EO: Yonthly List of East 'uropean Accessions 'EFAL) LC, Vol. 6, no. Jure Unc-1.

-n,-' 1clocular Fhysici, D-8
Abs Jour : Ref Zhur - Fizzikr, No 11, 1;9'58, No 2'076
luthor : Barnnuwski Bogdrn
Inst
Title : Hirrvti~n of Ca.-,yonents of Liquid '.';etnllic Allcys in Electric
Firld Froi-~ the Y( int cf View of Thor: :vdynr!L~ics cf Irn~versiblo
Erocessas.
Orig Pub : ~'~..c?n. chc.-.. 1956, 50, Ne 5, 841-81,,3
Lbstract : ~"ith the tid of tho theory L:f thoi- o1ynv-,-ic.,--, cf JrrL1vvrr.Ml,,,
processes, the author describes the Agrnticn of cc-1,munts of
liquid i-AcIlic slIvys thij influance ef cr extcrn-I
oloctric fiold. In ioothun-rl liquil rlloy i,,-. ckmcilorul in
%-.hich no cho--icrnl rorction U!kurl It i,3 thrt
a-ch alo-.~,ant of thu systc),-- rutrins its vnluc. The cose of
twc-col:Fmant r1loy io Ux:-')ino(1 in dotvil. Fcr-iuIrs rre
doriv,-~d for the -ivxi:-iiz, sayrretion of the conponents of F,
twj-coi-lp,nent --11,:y in ,moloctric ficld rnd Por tho lifflision
potuntial.
C~,rd 1/1

-7
iuntra of ImsTersible processes 5 a reTVO
Uke
B
X

qmnowxkI. Prac#
S. kg#p
_
'
MW in
i
.
menological e" ns In diffusion
Dummary)-ne pht
~
iffusion process
pocessm and the steady state In the th
In the latter steady state
*
tbermodiffuslon split-
-the thermodiflualon potential and the
ting in soln. of binary electrolyte are discussed. "Heat
I
transfer" plays a fundamental role in the thermoelectro-
~chendstry. This "beat transfer" is defined as the amt. of

A
rn
jheat that is tra-aslerred with a unit ma's of the given fo -
This ' beat
~Pojlrnt In the process of Isothermal diffusion.
.!transfer" is included In the equation of the Soret coeff. and
h

L
"in the equatOn of the thermopotential as well. 49 ref f.
cum

ARAIVO W S KI
Distr: LUC
Phenomena of diffusion and wandering in ti triefleldin.
'd ii tall* 11 )-Y-s rr-oin the therinodynamic kolnf-cT
Pracc_W~on_ e =-IroiTifin. ~ 11'arjaw,,
Lg:j
TOSS, 851~N(Pub. 1957)(Gcrillan stinumiry).-Theorctical
ronsidcrafluns of electrothermadiffusion (cf. picei-ding ab-
t~tract) show the relation li~tweeii turichim-lit of the liquid
metallic alloy with a given cornpOlILIlt uld h3th alliptrage
of the clec. current und time. Seim. of tile inetallie com.
pDntritsin theclec. fieldand thediffusion potctitialarevtry
closely interconnected. However, sepn. of tile metallic,
compontnts in a liquid alluy by this method would be
uneconomical. Only small samples of a valuable material
could be economically purified by thiza methtyJ of removing
detrialental impurities. The following equations are dc~
rived: (1) phenomemologic equation for a systern with
sev" compojents and (2) phenomenoloLic equation for
dild. alloys with 2 components. The -way is shown to cak.
(a) the max. seen. of the components iz tile clein field, (b)
diffusion poteuttul, and (c) el". coud. in the state of max.
Sepia. of the coulpolicrits. The tlaerlucd~llatllic thomy was
A, discilzed previously (C-4. 49, 11370J, 14441g). 3S riJer-
cyp

POLAND / Physical Chemistry. Solutions. Theory of' B
Acids and Bases.
Abs Jour: Ref Zhur-Khimiya, 1958, No 20, 66936,
Author : Stroka A., Baranowski B., Sarnowski M.
I n.-, t : No t C,
,Iven.
Title : 11-buiimentrical '-Ituillleo of Concentrated Solutions
of H 2O-Ca (1,703)2-KNO V
OriL,-. Pub: Roczn. chem., 1957, No ~D, 1025-1028.
Abstra,-.t: The dependence of' boiling points (B.P.) on the
quantity of introduced dry KN03(II) in the 50.0,
59.9, and 69.41,*; aqueous solutions of Ca(N03)2(I)
was investigated. The ratio of molar concenzra-
tions of II and I (a) in the investi~~ated solutions
Card 1/3

rOLAND / Physical Chemistry. Solutions. Theory of 13
Acids and Basco.
Abs Jour: Ref Zhur-Khiniiya, 1958, No 20, 66938.
Abstract: was varied froin 0 to 2. Introduction of II Into
the 50 and 59.91,0" solutions of I was accompanied
by an increase in B.P. With a < 1, B.P. of the
59.952 solution of I was found 1wer than B.P. of
the 501,'., solution of I. Wi th a ~> 1 an oppo site
fect was noticed. Introduction of II Into the
69.4% solution of 1 caused lowerin-,r of the B.P.
A minimum is observed at a = 0.5. Further in-
crease in the concentration of II causes gradual
increase in the B.P. of the solution. I-11hen a =: 1,
B.P. of the solution is found to be slightly lniOier
than When a = 0. The authors assume that the de-
viations from the Raoult's law of a given solLition
serve as criteria for the formation of Ca( N03)2'
KNC~ . 3H20 complex (III) in this solution (Ref-
Card 2/3
8

POLAND / Physical Chemistry. Solution5. Theory of B
Acids and Bases.
Abs Jour: Ref Zhur-j~himiya, 1958, No 20, 66938.
Abstract: Zhur-Khimiya 1956, 3405). The relationship of
B.P. of the first two solutions and of concentra-
tion of II is also explained by the formation of
III.
Carc, 3,13

/3
POLM/Physical Chemistry - Electrochemistry.
Abs Jour: Referat. Zhumal Xhimiya, 110 3, 1958, 7313.
Author : B. Ba=ows Z. Szklarska-Smialowska, M. Smia-lowski.
Inst : Academy of Sciences of Polead.
Title :Diffusion Constant of 1~ydrogen in Iron Cathodes.
Orig Pub: Bull. Acad. polon. sci., 1957, c1. 3, 5, Ito 2, igi-196,
XVII.
B-12
Abstract: The diffusion constant in iron at 200 was determined from the
liberation rate (LR) of Hp from Fe wire, which had been pre-
liminarily saturated with hydrogen by cathode polarization in
1 n. H2SO4 + As203' LR was determined volumetricaUy, Fe being
immersed in water. Two stages of H desorption from Fe with
DI = 5.0 - 10-7 and DII = o-6 . lo-? sq.cm per see were revealed.
DI and DII computed from the time necessary for the maxi
stationary elongation of the Fe wire at the cathod polarization
in 1 n. H2S04 + As 20 3 (RZh-Xh'm' 1955, 31330) are magnitudes Of
Card 1/2 _10-

POLLI / Physical Chomistry. Solutions, Thuory of .',cids B-11
i and Basos.
.',bo Jo'ur i Ruf Zhur - ldiivi., No 10, 1958, No 31837
ILuthor : B. 13nranoviski, ',. Fulinski
Inst : Acado-rNy ~ofScioncos of Poland
Ti Llo : Eloctrogravitational Soparrition of Binary Solutions of
Moctrolytos at a Small Distanco Bubvoon tho Mootrodus.
Orig, Pub t Bull. J',cad. polon. sci., 1957, cl. 3, 5, No 8, 821-825.
..bstract 'I. thoory of olactrogravitational saparatian (Murphy G.W.,
J. Bloctrochom. Soc., 1950, 97, 405) of binary solutions of
oloctrolytos is proposod. 11xprossions of tho courso of thu
olootrolyt,,s is proposcd. Lxprossions of the coursu of
tho aloctric potontial, tho concontrationand tho convoo-
tion currant in tho spacc botwoon tho oloctrodos, as vtoll
as of tho rolations bot-acon tho concontrations i n the top
Rnd bottom rosorvo Nrossols doponding on tho iiLicroparc-noters
Card 1/2

POLIND/Mysical Chmiistry - Soliitions. Theory of Acids
an~! Baecs.
Abs Jour Ref Zhur - lQiiniy-,., No 9: 195a, 23033
Atithor Anrunowski, B. anc! Sarnowski, 14.
Inst
Title A Seui-Eripirical Treatment of the Properties of Nonideal
Thrme-Component Solutions Containing an Electrolyte and
a Nonvolatilo Nc)n(!lcoLrk)lyt,c!.
Ori(L Pub Przeriysl Chum) 13, No 5, 2'10-272 (1957) (in Polish with
sur=,aries in EnGlish and Russian)
,',.bstract UsinU, the adsorption-based concoption of the solvation
prDcess, the authors have intrnduel~-,A an equation rela-
tln,,~ the ariotuit of ( /-\ 3:1) to tho Concentrait-lions
of the components of the solution and to three empirical
parameters. One of the parameters depends an the teriDe-
rature, the time of the isobaric e)qperirent, etc.; the
second parameter characterizes the effuctive number of
Card 1/2
7

PODUM/Inorganic Chemistry Complex Compounds. C.
Abs Jour Ref Zhur - Khimiya, No 10, 1958, 31974
Author A. Baranski, B. Baranowski, M. Sarnowski
Inst
Title On the Formtion of Complex Compounds of Calcium Chloride
with Urea in Aqueous Solutions.
Orig Pub Przem. chem., 1957,, 13, No 9, 505-506
Abstract The presence of complex compounds in the system H 2 0 -
CaC12 - CO(Ini2)2 was established by studying it by the
viscosinetric method. A lesser capacity of producing
the CO(wd 2)2' 2CaCl 21 CO(NH 2)2 CaCl 2, 3CO(NH 2)2 .2CaCI 2-'
2CO(IM 2)2 XaC12, 5CO(NII 2)2 .2CaCl 2, 3CO(IiI12)2 and
4co(mi 2)2 CaC1 2- complexes is observed at higher tempera-
tures.
Card 1/1

POLAND / Physical Chemistry. Solutions. ~xid and B
Base Theory.
Abs Jour: Ref Zhur-Khimiya, No 17, 1958, 56845.
Author a~ranowsk B~ogdlan~, Baranski A., Fulinski Andrzej.
Inst Not given
Title Heat Transfer of Hydrochloric .4,,cid, Sodium
Chloride and Potassium Chloride in Aqua Sol-
utions.
Orig Pub: Roozn. chem., 1957, 31, No 1, 229 - 240.
Abstract: The Soret coefficient (SC) in aqua solutions of
HC1, KS1 and NaCl in a concentration range of
I - 0.05 n., correct to e~-_10 percent, was-de-
termined by the electric thermo-diffusion method.
The SO versus initial solution concentrations
are presented on graphs. The SC values are prac-
tically constant at concentrations of 1 - 0.3 n.,
Card 1/2 26

~ ", - -,, !- " r ~ ~, ~; ~- ,~- 11 1 .1 C ,
BARAINCYISKI, B.
Comment on the article "Suggestion Concerning Classification and Definition of Systems
of Chemical Thermoctrnimics" by Tom-,Issi ; alsoi remarks by 'N. Tomassi.
P. 361 (Roczn-Lki Chemii) V61- 31, no. 1, 1957, Warszawa, Poland
SO- MONTHLY IMM OF EASF EUROPEAN ACCESSIONS (EEAI) X*, VOL. 7, In. 1, JAN. 1952

'9 1'0~ ISO < 25
FOUiND/Atmic md 11:olccular Yhysics - Liqui~s D-8
,'&s Jour R~:f Zhur - Fizika, No 11, 1958, Nc 21050
.Author B an,__ Doni c howi c z- Fig oni owa Jndwigr
Inst Not Given
Title Extensicn of the Fhononenologicnl Theory of Eloctrcthcrno~if-
fusion.
Orig Fub : Roc-,n. cher,.., 1957, 31, 1,10 ~, 927-9~5
I~bstrrct : A phonononalc;~Ic-l theory of the ol ectrotherr-,.cdiff us ion :-Cthod
has boon dovolo,~cd with c1lowmce for the inf'luonco of ther-
nodiffusion so-,crrtion on the ostc.bIisIT---.ont of the tc-7porrtiirc
Z-radicnt in p cerillrry. It now n1j,roxint,ticn is riven for
the vrluG of the r:cso trvnsfor butircon sj~,ro rcso~voirr, The
results of thu thoory nrc used to cRIculeto the Snurut ocof-
ficiontn of Pquoc-us soluticns Of CuSb4

VO pi e Ova "flon 'Y a
'trOrAbility ravaswomputs; Jacob,
4ufl. . S=Owskj (last.
JV41u, W=-W";V'm1
sens w
arr- , to
at
'm yappurmurelp! D
WOW Mtn - 0d6, of orm'antl ttwth."
;wx, Wdlmool
6 ivelocIty (V,.,Aw C034mulb IV tAl ftom
- , f
3W
20,:34;,11W 0 7bi
to
M r
i $A m 4. ;'gt A r#14, -T ~1
Sn
ot
um CAUM V to 4
TO
I TwiTy to Awl
ibif iW6 t4t
'My, Ims ~ the oppcwtv tatet. e of cow 0 V
Th
probably jidicale Saw; effect al

POLAND / Physical Chemistry. Solutions. Theory of B
Acids and ]Bases.
Abs Jour: Ref Zhur-Khimiya, 1958, No 2OjP 66930
Author : Bara=iski B.? Sarnowski M.
Inst :Not gi_v_e-n-.-'
Title :Application of Theory of the Debye's Salt Effects.
OriE Pub: Roczn. Chem., 1958, No 1, 135-138.
Abstract: Use of a specific expression for the osmotic pres-
sure of electrolytes and non-electrolytes (Refi
Zhur-Khimiya, 1957, 3890) is pro osed for solutions
that do not follow Raoult's law Nef, Zhur-Kinimiya,
1956, 50331, 77533), Use of the corrected expres-
sions of the non-electrolyte concentration permits
Card 1/2

1319'W"1 C " b , '4?'
POLAND/Physical Chemistry - Solutions. Theory of B-11
Acids and Bases.
Abs Jourt Referat Zhur - Khim, No. 9) 1959t 30610
Author : Baranows,~i, B., Fultnski, A.
Inst : Not given
Title : The Electrothermodiffusion Method in Plane
Coordinates
Orig Pub: Roczniki Chem, 1958, No 3, 595-609
Abstract: The method of irreversible thermodynamics has
been applied to the investigation of steady-
state electrothermodiffusion convective pro-
cesses (RCP) in two dimensions under conditions
of laminar flow. Phenomenological equations
have been derived for the velocity distribution
in the convective flow between twD plates and
Card 1/3
3

Poland
Blecta-0chemistry
N, 56
b", J"'r- Pnf D1ur-Yhir.Iyr_,,, Eo 6, 19)19
Baranowski B.;Szk1arska-Siuiai,_,,wska,
~, ~oq' , ~ic -A d
of sc--ence.;;
pit 1,:; Kinetics of Eydrogen Desoi~rtioil frOin Nickel
Rt 200.
0 131111. Acid. poInn. soi. SC'I'- CI'JLI"-i becl.
].c,58, 6., No 35 .170-1861 'iAr
et geogil. _%.
2~ ID ,, t r A determifiation was iti,,Qe of the iLaximum amount
of electurolyr~tc hydrogen (1) VII, a,-)soibud by a Nt wire
(diamete2l d 0.015-0.2 cn) oa cathod'i.c Polarization at i.
0.1 a/CM2 within 2-5
in 1 TIT F2804 + 0-05 9/litei' Aq2()37
nmrs, and on the basis of kinetics of dcsorption of I,
dv/dt, at room temperature, an attempt was mtide to calculate
the coefficient of diffusim D, of 1 in NI. It was found
th-4- V drops sharply with increase of d, On the curve of
log(dPdt) as a function of tine tj were. found two recti-
linear portions of large angle of inclination at low values
of t; according to the law of Pick they corre~qcmd to two
C.,rd: 1/2
and Szpdalowskil M.
D-20

UOUNrlix Poland
CA -2 XA, 0 R Y PhYsical Chemistry-Soititions.
~Tld b~lnvs.
JOUR.
T ll! L--,
B-11
Theory of acids
'74 527
2i C A 0 '3
I ~j f 1 Cj -1 S --* C 0 n E- C t C
t d v L t v c; 1 v t !-i e r r.~. c S 3 1 u I o i. o a r Y
A. e. ri i rn e o t 3 e o -
Ln~rm,),J-n31n--'-s ~,z i-everoible
.5 , ~ -) et,
st-re used
--ua-iono fj" t n,~ . nsi ty
A ae
no ..,cctr-;r-a, k L)f an ideal
11 4on ~trolvte in ti-.e iiiti
- o f a b ry t:1e,- a
La:d in tiie steud)r -,state -1' 1 if fLusion.
la*te- C."Se 1 a.;~' XJep2nd on
-:,aJient, the tem,:er-,3ture graa~-ent,
e cc-centraiion, The ob-
C -,G:.L, t r4 C
~)e arrdl-'Led to the
o,- t,,.c-.r!rodiffusic.,n coefficieits.
tlan

POLAWD / Physical Chemistry. EloctrochOLli0tX-j- B-12
Y 0
Abs Jour :Rof Zh, ir - Kli-: dj,--a) No 3, 1959, 110 - 7636
Author :Bux-anowski., Boeaan; Fulinski, Andrzej
Inst :Not -ivon
Title :Tilecry of Ejectrogravitational Sop-~xation of Solutions
of Dinary Eloctrolytes
Orig F0 :Roc"mi. 19-A 32, No 21 303-313
Abstra~;t :A thuorotical nmlyoia of the procoso of oloctrogravita-
tional juparation of aolutiono of binary oloctrolytoo In
tho casu of tw,~) pixallol, plano, rover3iblo oloctrodoa~
aisposed vorticolly at a ihort diatance from oacb other.
Abovo ard bolov JEW oloctrodoo aro locatcd rejervoira
contuining tto solution. On resorting to certain
slmplifyin~3 asourmptioni, cquations are dorivcd for tho dia-
~ 4- adio-, a M
tribution of concontrLatdon ~Iho concontrntion C-r, It
potontial withilin the ol;uco botwoon tho oloctrodos, and aloo
card, 1/12

-uO!A'l' v .1
ND / Fllyjical Chc-,Ostry. Eloctrochord3try. B-1 p
Ab3 Jour Rof Zlyur ITC, 0, 11959., 140- 7638
for tho ratio of concontratiom in tho raGorvoirs do-
pording uron n,-Aio of at,oady,itato Qiunrcilt flclrin'~--
through tl:o 3ystou to tho 1-,*Ld4L- cmront. -- Yu. Floihov
Ce.x-d 2A,
21 3

AjLh6thoa In a flat set-up. ordinates, 2x# is distance between the walls, A and b the
ertrotherraodiffusliA are
'Zbdo. 33N*Ows&i Mdru' I FA~ and breadth of the walls, V is rmmoir vol., I is temp.,;
_"d
ME, Warsaw). Komi h is thermal cond. of the liquid, X Is clec. cquly. of heat, V
summary).7-1he clec. thttmodiflusional method applied is tfftctive voltage applied to the working vol., Ix is spWifiel-
-heretofore in a cylindrical system for detns. of Soret coeff. oond., M Is current power, q is viscosity coeff., g is gravita- Coe
(C.4. $2, 6897 is pro for a t set-u useful for tion. p is d., x is cDucn., r is time, J is flux vector, m is the
app .9 tions. The soln. to be se should be mass passing per unit time, D and D' Are coeffs. of thumal
ac between 2 parallel, flat wadMh, co I ting of thin and di dtffusl e - x/A, and c - (Ils f(ILM).
sheets of ant tor, with electrodes at the upptr and Thesoreq'una"Zw can ~:'simplified by neglecting the =d-
J& lower ends of the walls. A genexal phenowlaa0logicall eave of elec. cond. on temp.' The changes of concn. in the
theory is worked out for such system. The temp. gradlent rcstryors, expressed for the case c -0, only, an given b -
is given by, dt/dE - -()Mxs1-2bM) - ((sin A WJ)Xsin A1.1 n.1/s, - I I + t-h a(I - s /11 - tanha(l - s --val-T
The -it. ftmp. difference 13 given by; 41 - xv (I -- where to, And x4 are the concn . In the up and lo
Co's A)1(2bhkA Wn A). 71,--eonrection velocity Is expressed! container, resp-, and a - lS5903AD'V/R% =
IRS' . V - B Icos A I - cm A + 414cm A - sin A 1 7 - D'(AS)4Xp/l575VDij. The results otained
I - (1)), wbere As - -AG'Walf oW V - XM A WM with those of the tbermogravitadoW,
.90ABInA, TheSeneralfiamequUmbsolvedfor t ; method, wing a much better sepu. by the eke. themo~
and boundary conditicus with the use of fuDctIDn C defined diffusloual method. A.
-(Dj '"OXIal) +
x4), In the eQuations: Y. 2 are the geometrical co-;
,SIB

FARANMSKI, P.
SCIENCE
PERIODCIAL: ROCZNIKI CITIET-III, Vol. 32, No. It, 1958
PATIAM-5KI, B. Stationary electrolysis in systens without convection.
I. Thermodynamic thecry-
y p. 863
Monthly List of East I'lurop an Accessions (EE'AI) LC Vol. 8, No.L,
April 1959, Unclass

TtgfYz-Iu system without convection.i
Dogdaln Ramputski and,
(Polish Aca I
r
:
RP
44
A
MR
-M
.
3
2
-The "ation--
,
:ary state was cons cred from die point of view of thermo-;
dynninics of irreversible processes for a liquid soln. of N
-Components (Ions and uncharged mols.) placed between;
patullel electrodes reversible to one iom An external poten-
tial was applied to thm electrodes, making natural Coll-'
vection Impossible and leading to comm. gradients. Hqua-
:tions obtained are of fundamental importance for the theory
of elec.-gr-avitational sepn. (C.A. 52, 19SMO, for they give
tile Initial equations for dc(g. tlili courlic of clianges of concu. I
and (if the limiting c. d. SCTZIC Special Cases, as dil. and
Ideal suins., tire discussed. The equation for c.d. In a binitr
'
ideal
l
I
l
so
n.
s analogous to that derived by Murphy (C.
A
TH 48
1
l
.
tu
ates thi possibility of selin. of
eut
n follows from purely: thermodyJ
l
ktn
A. Ptgleiv:lk~:
91,

BARANOWSK I. - B.- -
The rate-determining step in desorption of gases from solid specimens.
Bul.Ac.Pol.chim. 7 no-12:887-890 159. (EBAI 9:5)
1. Institute of Physical Chemistry, Polish Academy of Sciences.
(Gases) (Desorption) (Solids)

BARATTOWSKI, B.
Desorption kinetics of cathodic hydrogen from thin nickel layers.
Bul.Ac.Pol.chim. 7 no.12:891-896 159. (EEAI 9:5)
1. Institute of Physical Chemistry, Polish Academy of Sciences.
(Desorption) (Cathodes) (E~rdrogen) (Nickel)

BARANOWSKI, B.
The dependence of the cathodic hydrogen content in thin nickel layers
on the current density and saturation temperature. Bul.Ac.Pol.chim.
7 no.12:897-905 '59. (Mal 9:5)
1. Institute of Tlb-sical Chomistrv, Polish Acaderrv of Srtiences.
(Cathodes) (Hydrogen) (Nickel)

BARANOWSKI, B.
2he k:inetics of saturation of electrolytic nickel layers with
cathodic hydrogen. Bul.AcJol.chim. 7 no.12:907-910 159.
(KRAI 9:5)
1. Institute of Physical Chemistry, Polish Acadoa7 of Sciences.
(Nickel) (Cathodes) (Hydrogen)

BARANOWSKI, B.; FULINSKI, A.
Mass and energy transfer in a polythermic many-component two-phase
system. Bul.Ac.Pol.ehix. 7 no.12011-916 159. (MAI 9:5)
1. Institute of Physical Ghemistry, Polish Academy of Sciences.
(Systems (Ghemistry))

.=uu- Iq vaP-I~~N
7,9
J~ so
'f
t.4.. ~4T. MEVOWK23
zm%mrru
wrp,4T.
-4.T.
I's 'vxnl
-V =MY=
1"2,w
.-wTod J.
-"7.'V2-JOW=
-en= =mxy--w
_r=
TIV-6-7 '.--I
V.Z: '-d-

J3AWC,I%t,RKI, Bogdan;--- FULLNSKI, Andrzej
Electrogravitational enrichment of water solutions of cupric sulfate
at a small distance between electrodes. Rocz chemii 34 no.2:587-600
16o. (EEAI 10:1)
1. Instytut Chemii Fizycznej PDlskiej Akademii Nauk, Warszawa.
(Cr..pper sulfate) (Water) (Solutions)

BARANOWSKI, B.
Irreversible processes within the surface-phase treated thermodynamic-
a117. Bul chim PAN 9 no.3:159-162 '61.
1. Institute of Physical
Presented by M. Smialows
(Surphase chen

251~G31 /0 00/0 Og/O 0 1 /0 Ol
P/016
D238/D304
AUT110 1,: Bnranoviki, Bohdan, Doctor, Locent
TITLE: The thermodynamics of irreversible processes in
physical chemistry
I-ELIODICAL: Wiadomos"Ci cbemiczne, no. 9, 1961, 553-564
TEXT: This article was originally a lecture delivered at a meeting of
the theoretical group of the Instytat chemii fizycznej PAN (Physical
Chemistry Institute, PAS, Warsaw) on May 28, 1960. A short description
is given of the derivation and extension of known phenomenological
equations concerning irreversible efrects from the thermodynamics of
irreversible processes. The author discusses the problems of 1) deriva-
tion of these laws on a macroscopic scale; 2) determining their ranges of
validity; 3) their mutual relationship and 4) their connection with classi
cal thermodynamics. It is shown that equilibrium thermodynamics can give
1444-1- or no information on these subjects. The relationship of the

25133
1'/01 61/ooo/009/001/ool
The thermodynamics of... D238YD304
the connecting factor. Entropy is regarded as a scalar quantity having
positive sources, and its change with time, in any given element of volume,
is given by
'a s div.3'. + or (1)
a t
where s is the entropy of the volume element, t is the tir~e,j S the entropy
flow and er a so-called "entropy source" which originates from all irrever-
sible processes occurring in the system under.consideration. 6 is also
closely connected with classical thermodynami-cs t 'hrough the Gibbs equation
relating entropy to other internal and external properties of the system.
It is shown (Sion-MRthema ti Cully) that o' cun always be expressed as a sum
of the products of various macroscopic, time dependent processes (flows),
:Jr, and property, (e~g. concentration) gradients which may be regarded as
"thermodynamic forces"X, . In general, therefore, (Y i X i (4)
Eq. (4) may be written as a family of "phenomenological equations" which
describe the course of irreversible processes by introOucing a set of
Card 215

25133
P/016/61/000/009/001/001
The thermodynamics of... D238/D304
coerfici ents, L, such that Lik )(1, Analysis of
(5)
Eq, (5) provides the full phenomenological theory of irreversible r-rocesses,
The laws of Fick, Ohm, Fourier and Newton quoted above rel.resent special
cases of this equation and may, therefore, be derived frorn the consideration
of the entropy source. Thus, e~g., Fick's law, stating that transfer of
a certain constituent equals the product of a diffusion coefficient and a
concentration gradient, may be written as T = D x gradient c (6)
The range of validity of Fick's laif depends on the ideal state of the sys-
tem which may be determined from classical thermodynamics by introducing
activity coi-fficients and on the effects of other comlonents taking part
in the transfer. Traditional forms of phenomenological equations are only
approximate since the mutual interactions of coml-,onents and their activity
coefficients are not known precisely, and the laus apply only where the
departures from equilibria are not pronounced. The role of the thermody-
na.mics of irreversible processes does not solell consi,;t, of the derivation
of all known laws describing irreversible effec ts, but also of elucidating
problems which cannot be solved by the application of the simple laws.
This is illustrated by considering 1) the isothermal transference of metals
- I ~/,

25133
P/016/61/000/009/001/001
The thermodynamics of- D238/D304
in a constant electric field towards the anode, and 2) the problem of
isothermal self-diffusion and electrical conductivity in simlIe salts,
such as liquid or solid NaCl, Thermodynamics of irreversible processes
may also solve theoretical problems and suggest methods of experimental
confirmation of the results. This is exemplified by the discussion of
phase transfer in an isothermal 2 phase system, leading to a more correct
value of the partition coefficient. Many aj~rlications for the method
exist in the fields of, for example, electrochemistry, chemical kinetics,
relaxation processes and cutalysis~ Thermodynamics of irreversible pro-
cesses should thus fulfill a function analogous to that of thermodynamics
dealing with reversible effects, by providing a common theoretical origin
to experimental laws and yielding the maximum information about an examined
system with the minimum of effort. There are 7 references: 5 Soviet-bloc
and 2 non.-Soviet-bloc, The reference to the English-language publication
reads as follows: A.Z. Borucka, J.O.M. Bockris, J.A. Kitchener, J. Chem.
Phys~ 1956, 24, 1282.
AS.30CIATIOX: Instytut cbemii fizycznej, PAN lVarszawu (Ph%sical Chemistry
Institute, PAS, Warsaw)
Card 4/5

BARANOWS-KIP B.; CUKROWSKI, A. S.
The general equation of marker velocity in transfer processes. Bul
chim PAN 9 no-4:253-256 161.
1. Institute of Physical Chemistry, Polish Academy of Sciences.
Presented by M. Smialowski.
(Equations) (Temperature) (Isobars)
(Chemical reaction, Rate of)

BARANM4SKI, Bogdan; FULINSKI, Andrzej
Thermod1ynamics of irreversible procasses of two-phase BySteMS. I. ISO-
thermal manycomponent systems without chemical reactions. Rocz chemii
35 no.4:1-103-1116 161.
1. Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw.