SCIENTIFIC ABSTRACT BALASHOVA, L. D. - BALASHOVA, N. N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000103220011-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

Synthesis of Elemental-organio Comp S/020
ounds in /60/135/004/020/037
Which Silicon or Tin Are Directly Bound to D016/D062
Phosphorus or Arsenio
[(CH 3)3 Sn), P, Mention is made of a paper by B, Arbuzov and coworkers,
(Ref.- 1). N. Rodionova, S. Dubov, As Khokhlovaq and V. Fedotoya examined.
the spectra. There are 15 raferenoest 2 Soviet, 2 US, 2 Italian; 7 German
and 1 British.
PRESPNTEDi June 24, 1960$ by 1. Lv Knunyante, Academician
SUBMITTEDi June 23, 1960
MOM
Card 3/4
8/020/60/135/004/020/037
B016/BO62
-7 7
(CH#)o SiF.4 KPHm -o (CH&S Sl PHs + KF;
(CHo~SI-PHg+KPHI-*(CHa)*SI-PHK+PHs:
(CHj)sSI-VHK+Fsl.(CHs)s-((CHs)sSl)gPH+KF;
((CH#)oSl)tPH+KPHI-#((CHs)a3lhPK+Ptta.-
((CHt)t SQj PK + FSI (M)s ~ ((CH#)o SQ, P + KF.
Card.4/4
BAIASIX)VAO L.D.1 BRUXER, A.D.t soBoRmar, L.Z,
Interaction of silane and monoalkyloilanes vith hydrohalides under
overpressure in the absence of oatalyvtso Zhur,ob,kbim, 32
no~912982-2983 S 162, (MIM 1529)
(Silane) (Hydrogen WOW
L gE6-66 mr(MVEWO) RM
ACC NRI AP6 $923 SOURCE CODEt UR/0079/66/036/001/0073/007
AVMORt t 90&9r, A. D. &oborevskiy, L. Z,
ONG I TAN
TITLEt Metal organceetallic compounds. Part 2. Synthesis of silyl- wd alkylsilyl-
SOURCEs Zhurnal abhschey khtall, V. no. 1, 1956, 73-75
A~#6
i70PIC TAGS: oamnosilicon Seeund)4rganolithium compound, *Ilan*
ASSTRA"t Silylphosphines In which the silicon stoo is linked to alkyl-alkoxy or I
Alkyl-dialkylam1w groups, were synthesized. Thu3, action of the corresponding di-
nethy lalkoxychloroe Ilan* on lithium **thy 1hydrophosph ide produced ble(disethyl-
?ftethmysilyl)pethylphosphine (1) and bia(dinothyllsobutaxysilyl)oethylphomphine (11)1
2cil,pilLI+ICISI(CI46(011)--WC113PIS'(CH3won)j3+--Hsrlis+2LICI
(11) R v 1s"o.'C%H'j'
Reaction of bia(diethylmino)wothylchloroollans with lithium dthydrophosphide yleld--~i---
UDC: 547*241 + 547,245
!Card 1/3
L 16o76-66
ACC MR: ANW5923
'ed bit (dieftleminOmethliellylp~os (III)*,
CII&S1jN(CjH&6hC1 + LIPHg-o, HIP-$ I(CH8)jN(CjH&)gh + LICI
till)
Siollarly, ble(diethylamino)mthylallylmathylphosphine
H U4
%SW11N(Cjjj1~ji (IV).
was obtained fr*m the reaction of bis(diethylaminomethyl)chlorosilane with lithiulk
bothylhydMhosphide. When diethylaminc>dimethylchlomailane reacted with lithium
*ethy1hydroahosphide, the products were (diethylaminodimethylsilyl)methylphosphire
(V) and bie(diethyla=inodimethylailyl)methylphosphine (VI)i
3MIAL-CI -~311 C11A
Card'2/3
L i6o76-66
AOC NRt APS003923
Acetans macts In the emol fom with ccupound (V)-9 the Si-P bond to broken, and
heretofmv wkWscribed ccupound, diothylminodbnthyl-*-OothylvLnylozyaLlens (VII).
ON,
SUB COM 07/ SUM DATZ s IWM65/ ORIC RErc 003/ m rxr t ooo
d
vio', AP&ODS924-.: ?V0070-
SOURCE CODEt UR/0079/66/036/001/00'
O~WDR: .4riAlt- Ai 10%; Weabovs, L. 0. tSobvrovskiy L. Z.
"Ital 0~*Wmxmbtallie owT*was. Part 4. Reaction of dialkyl dlsulfid~ps
with sill con..wW tin phosphines and with alkali metal hydrophosphides
-SOURCE: Zhurni'll'obabdbey kbivdii v. 6, to. 1, 1966, 75-78
N~ C TAM, Ulcon !~%mq'wtanlc sulfur compound) ortanosodium compound
!orgwtip compowd
ABSTRAM The general scheme of reactions 4 alkali metal hydrophoaphides and
alky1hydrophosphidoe vith -dialkyl jisulf Idea can be repr*sente-d as follows I
IIiPM&+3A'S-Sft'--* P(SR12 + MoSft'+ 211SR'
Card 1/2 ---------
L 16077-M
ACC M AP6005924
The dialkyl disulfide splits to form the corresponding thiol esters of acids of tri.
Ivalent phosphorus. when silicon and tin phosphines were reacted with dialkyl sul-
.ifides, trialkylsIlicon and trialkyltin alkyl sulfides and thiol esters of acids of
I
Arivalent phoophoruilwore obtained. Depending upon the ratio of the reactaRis and
!temperature of the ptocess, the trialkyltin or trilakylsillcon groups may be par-
Itially or completely replaced by thiol groups, e. g., the action of mothylbis(tri-
ethyloltiOphostAhine CHjP[Sn(C2Ht)312 on diethyl disulfide at a molar ratio of 1:2
1forms compound (11) and (C2H5,)3Sn-SC2H!,. The compound (CHj)3Sn- 2H w obtained
SC 5 as
by reacting trie(trimethyloltln)phosphine with diethyl disulfide at 500. Heating
of trie(trimethylailicon)phosphine with diethyl disulfide gave rise to the follow-
Ing reantiont
SUB COM 07/ SUBM DATE% 1BJan65/ ORIG mr: 003/ OTH REF: 000
CArd 2
EWT(&)/EWPQ) RM
ACC N& ApOI6701
SOURCE CODEt
UR/0079/65/0)5/012/2207/2209
AUTHOR: Balashova, Ls D.1 Drukerp A. B.; Soborovskiy, L. Z,
ORGt none
TITLEt Investigation of element-olemntoorganic compounds. III. Synthesis of
SOURCE: Zhurnal obahchey ~Iip v. 35, no. 12, 19659 2207-2209
TOPIC TAGS, organic synthetic process, organotin compound, organolithium compound#
organosodium compound, organic phosphorus compound, chlorinated organic compound
ABSTRACT: The prepAration of the now compounds -- bis(trimethyl-
tinmethyl)-phosphlne (1) and'bis(triethyltinmethyl)phosphine
(II) by two methods are desoribed, The first method is by re-
notion of the corrtsponding trialky1tinhalide with sodium (or
potasslum) methy1hydrophosphide In liquid ammonia or with lithium
methy1hydrophosphide in an other solution acoording to the gen-
eral reactiont
2CH P1016 + 2&9nR) CH P(SnR '), + 2MeX '+ CH3PH2
is prepared in an 80_90j 3
Compound yield from the reaotion of,
trimethyltin bromide on lithium inathylhydrophosphido In ether
solutions Compound (11) in obtained in a 70% yield from the r
,aotion of triethyltin ohloride and lithium methylhydrophosphX~.:~~
The asoond method is by the Aotion 6if m_e_thYroU6r4h6iphW6~ojV,
I igrd 1/2 UDC 1 1; A
L :5tWr-66
ACC NRs ApOI670.1
,the 804ium derivative of trimethyltin or triethyltin aooording 0
,the Son-iral resotions
CH3PC1 + 2NaSnR CH P(SnR + 2NaC1
.2 3 3 3 2
The asoond method givee lower yields of oompounds (1) and (II)s
!about 10-15%. In thie osse the reaotions are sooompanied by a
.number of aide prooesses. Thus# In the reaotion of methy1d1ohloro-
,phosphine with the.sodium derivative of triethyltin, triethyl
lohloride (11%) and hexaethyldistannane (42.%) were Isolatedt
.0
+ 2CISn(C,H )
CH3PCI +.2NaSn(C2H, 3 CH3pNa2
2
~The reaotlowof triethyltin ohllorl4e with the Na-deriva
tive of ~j
Itriethyltin oan lead to the, formation of.hexaethrldistannanot k"
(C2H..),,8nN& +-Cl8n(C H --v.Naci + (qH3N!~--sn(c R
2
cJPRS1
SUB CODEt 07 SUDH DAM .18jan65 ORIG REN 001 OTH REFi 002
BALASHOVA, L. N.
Cand Med Sci - (diss) "Several types of remission and psychic
defect in schizophrenia with favorable course. (In relation
to tasks of work-construction)." Moscow, 1961. 14 pp; (Min-
iZtry of Public Health RSFSRj Gor'kiy Medical Inst imeni S. M.
K rov); 250 copies; price not given; Mt 5-61 sup, 201)
FEDOTOV, D.D., prof., otv. red. SEGAL, B.M,j zan, otv, red.;
AVEIGJA?U1, Ya.K.p red.; AVRUTSKIY, G.Ya., red.; AJXKSR,*D"RCVSXIYp
Yu.A.p red.; DAIAUQVA,,..LX.,, red.; BELKIN, A.I., red.;
GUROVICH, I.Ya.0 red.
(Problems of exogenous and organic neuropsychic disorders;
materials of the scientific conference of the State Scientific
Research In3titute of roychiatry of the MiniAry of Nblic
Health of the R.S.F.S.H. March 1964) Voprouy ekzogennykh i or-
ganichoskikb nervro-psikhicheakikh rasstroistv; materialy na-
uchnoi konferentaii Gosud&rstvennogo nauchno-issledovatel'skogo
instituta psikhlatrii NZ RSFSR. Mart 1964. 164 p.No*2,, 1964,
164 P. (YIIRA 17:9)
1e Moscows GoBudarstvennyy nauchno-lasladovatellskiy institvt
psikhlatril, 2. Direktor Gosudarstvennogo nauchno-issledovatell-
skogo institute p3ikhiptrii Ministerstva zdravookhranenlya
RSFSR (for Fedotov). 3. Otdel psikhozov pozdnego vozrasta, Gc~uu-
darstvennogo nauchno-looledovatellskogo Instituta prlkhlatrJ.i
Ministerstva zdravookhranonlya RSFSR (for Belkin). 4. Otdel
ektogenrorkh nervnopsikhicheskikh rasstroystv Gosudarstvennofi-,o
nauchno-isaledovaLeltakogo institute r-likhiatrii MinisterstVft
zdravookhraneniya R.ITSR (for Segal). 5 GoBudarstvemyy nauchno-
isaledovatellskiy I.nstitut psikhiatril Ministerstva zdravo-
okhrananiya H:;FSH (for Averbakh).
-BALAROVAP-14N,
Characteristics of the higher nervous activity in schizophrenia
patients in a stage of remission. Vop.klin., Patog. 1, loch. shiz.
noolt9-22 164, (MIRA AsO
1, Otdal vrachabno-trudovoy ekspertizy (zav, - prof* Dore*
Melekhov) GovuWaivennogo nauohno-losledovat4lakogo initituta.
paikhiatrii Ministerstya zdravookhranenlya RSFSR.
TIR-- f-mi~ --
Readers' wishes. Taket. prom. 19 no.6:90-91 is 159,
(Textile industrjr-Perioncals) (MIRA 12:9)
N]24CHINOVAi 1.
.1 KUZNSMAg I.; VASILIMA, V.1 BALASHOVA# M.1
Several results of an experimental study of budgets of vorkers' families.
'Biul.nauchAnfomo trud I. tar. plats. 3 no.l2tZ4-48 160.
(Some soonomice-Accounting)
RAWHOVA, M.M.; SAZONOVA, M.D.
New data on the stratigraphy and lithology of the terrigertaus
sediments in the lAver Carboniferous of the Southern part of
the Koza arch. Neftegat, geol. i geofit. no. 5:33-37 163o
(MIRA 17:5)
USM/ "ical Chemistry - Crystals
Abe Jbur : Referat Zhur - Klximiyaj No 4, 1957, 11054
Author -. Balashova M.N., Miarmnovekiy I.I.
Title : -MeMmuclan-OR Miner&u by Symmetry lbrw
Orig Pub : Sbornik: Kriet&Uogmfiya,, No 5,, Moscovj, Mat&llurgizdat, 1956p 203-212
Abstract , A synopsis of the distributiom of aftemlcrystals, by symetry form
B-5
Card 1/1
USSR Solid State Physlas Struotural Crystallography
Abs Jour #Rot Zhur - Fizika, No. 5, 1967 No. 11053
Author iBalaahova, U. N. Shifr&novakiy, 1. 1.
Inst I
Title iDistribution of Uinerals by the Symetry Type.
Orig Pub iKristallograftya, Uyp, 6. 9,, Metallurgitdat, 1956, 203
212.
Abatmot tA list of 1022 minerals is given, distributed by types of
sy=otry.
Cardt 1/1
STULOV, WAYRANOMY, lal*; HOKIY'J6'IWCIY, Y~A..- POPO'l, O.M.; 3*?M-
TIN. A.G.; HIXOIAYXV, V.A.; AMSHXLLS. 0.9.; GRIGORII-XV. P.Pi;
YXROFJIYZV, B,N.; TAUMIT, V,B,; SOLOVOYMY. S.P.; NIKITIS. T.D.:
RaMO, S.A.; DUBINIXA. V,N.-. ALTAYDINg V.7,; VIADIMIROY, B.N.;
UZIIAMYN. Y%Vq FUR-XAXMTSXIY, V,A.; KALININ.
,,-!MQT,&j~X.-U.j-,aAL'DAU. X.P.; DOLITO-DOBRCYOLISKAYA. 0.R.; LAV-
RUT I T19V 9 H. P.
Tlktor lvhnoviah Kikheav. Zap. Voss. win. ot-va 86 no.2017-320
'57o (nn 10.-6)
(Mikhoov. Viktor Iranovich. 1912-1956)
UUSIMVA, N.N. - SAL"DAU. I.P.
Scientific Session of the Yedoroy Institute in conjunction with
the All-Union Mineralogical Society. Zaps Too@, min, ob-T& 87 no.3:
624-632 158. . (MIRA 12tl)
(Petrology)
BAWHOVA, R-N-; MMYNSKITe V.A. ; SALIDAUt X.Fe
Joint scientific session of the Fedorov Institute and the All-Uhlon
Mineralogical Society. UP- Team- win. ob-va 89 no-3WU-620 160,
(Mineralogy). (MIRA 13:10)
BALASHOTA. N.V.-. SALIDAU. lop,; STULOT, R.N.
The Pedorov annivorsw7 session. 2ap.Tsss.uIn.ob-va 86 no*5:632-639
'57. (MIRA 10:10)
(mineralogy)
BAIASHO%I.,~!V.; SALIDAU, I.P,,l MUUMUU, V.A,
Scientific session on crystallography dedicated to the 40th
anniversary of death of lvgraf 8,toWovich Podorove Zapo Too@*
min. ob-va 88 noOsW-632 139. (MRA 13t2)
(PodorOT, Nwgraf Stepanovich, 1853-1919)
(Crystallography)
SWRAMOMIT, I.I.. prof. Prinizali uchastlye: MOKIYRTSKIT, Y.A.: firMT,
N.V.; GNMIM, S.M.; PISIMNYT. '~At.-Ko9p; ~ XIXH=Ao
~ _ _�k!p_
I.T.; MLIDAV, X.P.; KALININ, A.1,; DOLITO-DOBROTCLO TA. O.M.
PIOTROVSKIT, G.L.0 dotsent, oty.red.-, FURKAN, K.P., redo; KALYAYKO,
A.T., tekhred.
[Lectures on the morpholoEr of mineral crystals] Lektall po kristal-
lomorfologii mineralov. Ivov, lid-vo Llvovskogo univ., 1960.
161 p. (xIRA '1431)
1. Kafedra kristallografil Laningradekogo gornogo Institute (for
Xo1ciyevBkiy, Stulov, Gandelev. Pis'wennyy. Balashovs, Mikhaysys,
Salldau, Kalinin, Dolivo-Dob,ravollskaya),
(Minorals) (crystals)
SUPANOV. I-V- (Kasanl)g BALA HOVA, Molls (Kazan')j SCKOLOVA. N.G. (Kazanl)
Observation of lunar occulatatione of stare at the Kazan Astro-
nomical Observatory In 1959. Astron.tsir. no.20900-41 Xr 160.
(NUU1319)
(Occultations)
BALASHUU*-U,1;.; SALIDAUs E.P.; MOKIUVSKIYP V.A.
Conference of the Fedoroyakil Inatitute and the Ul-Union
Mineralogical Society* Zap.Vaessminoob-va 90 no.5:616-628
161. (MIRA W10)
(Mineralogical societies)
BALASIIOVA, R.N.; SALIDAU, E.P.; MOKIYEVSKIY9 V-A-
Fedorov meeting on the occasion of the 50th annivorsary of
the discovery of X-ray diffraction. Zap*Vsos.min.ob-va 91
no.5:621-634 162. (MIRA 15:3-1)
(X-ray crystallography)
BALASHOVAI M.N,; SALIDAU, E,P,
Saaalon of the Fsodorov Inatitute and the All-Union
Mineralogical Society. Zap, Vase. min. ob-va 92 no.5t6l.7-626
163. (MIRA 17t1)
M.14. ; "Or, I fi-,*'k*~ I Y, V. A.; S,!1,1 DALI, E.P.
Joint rv,el.ing cif Qic Fedurov inattluta and Mlnerrlcg'rn,l. Society
, I , 'Dirl.0t) ? 1 16'
- _V11 93 no.tt'sy 7--"35 -4 0
(), tjj~
".I!. Zal).V.
(MIRA 1814)
BALASHOVA M,N - MOMMKIY, V.A.; SA:,'7)AJ, F.P.
- -j - -!,o
Jotnt aesslon of the Fmloro7 Institutp and t-lie MJneraloglcnl
Soal.ety of the U.S.S.R. Zap. Vaes. min. ob--va 94 no.6s
717-748 165. Wln IS 112)
1. DeystvitAllnyye chleny Vse5oy-uznogo miner%logicheskogo
obshchestvt (for Moklyevskiy, Sqlldau).
YARCHENY.00 V.G.; TAUSEp A.M., prof *(deceased]; IMIROV, I.A.; SHMIDO
V.A.; HOIOZOVSKIY$ N,G,,, kapitan dallnogo plaveniya kontr-
admiralp red.1 BOHISOVt V.V.I red.!,rBAILAASSH~O%__MV-A* red.-
e
lokeikograf; BERDNIKOVI, N.D., red.- e a iojiaf; SAVINI b.V.j
led.-loksikograf; KUZIHINI I.F., tekhn, rod,
(English-Hussian naval dictionary. Approzimately 40, 000 words
aM phra sea] Anglo-rueskil voenno-morskoi elovar'. Pod red, V.G.
Morozovskogo. Okolo 40,000 slov i sochatanii. Mockvn# Vocnizdat
1962. 951 P. (MIRA 15:12)
(Naval art and science.-Dictionaries)
(English latguage.-Dictionarisa-Russian)
FILLER, Don Dzh.[Miller, D.J.1; PEYN, Tomas G.[Payne, T.G.); GRIK, Dsh.
(Gryo, George); BALAsIK)vA j~ .(translator); KALINNO, M.K.p
doktor geol., . au ; SHOROXHOVA, L.I.V ved. red.; VORONOVA,V.
tekhn, red.
(Geology of possible petrolew provinoes In klaak&l Geologiia nef-
tagazonoanykh provintaii Ali*vki.. Pod red. I a dopolneniiaki M.M.
Kalinko. Moakvag Gostoptekhizdat, 1961. 181 p. (MIRA 16t6)
(Alaska--Petroleum'geology)
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BAIMHOVA.N.A.
Use of tagged Mons for studying the adsorption of sulfuric said
on platinized electrodes* Dokl. AN SSSR 103 no.4:636-642 Ag'55-
(KLRA 8:11)
1. Institut fisicheBkoy khtmii AkRdemii nauk SSSR. Predst^vleno
akadealkom A.I.Irruakinym
(Sulfuric &old) (Adsorption) (Sleatrochemistry)
~" -,~. .
"The Determination of the Ion Adsorption anti of the Zero Point
Potential by Means of Tagged Atoms. . . '~40, Zeit!-chrift lFuer ilVsikali.5che
Chcmic (Periodical of ftsleal Cliemistryj,. Nw - -Oct 1957.
Ir- MgRnWVA. H.S.
BA
Tagged s,too tophniquo used for structural study of electrIc double
layer and adsorption of ions on metals. Tnidy Inst. fiz. khts,
no.6:12-19 157. (MIRA 11110)
(Tracers (Chomistrr)) (Ilectrochemistry)
J
AUTHOR by N*Ao Balashova PA - 2479
-TITLZ The-W-*i-*-if-T-&bki of Slootroohomistry
(A,ktualtnyy* voprosy alaktroobinii, Russian)
M IODICAL Vostaik Akadtaii Nsuk SSSR 19579 Vol. 27t No. 1, pp. 107-110t
('USSR)
Reoeivedt 2 may 1957 Reviewedl 4 June 1957
ABSTRACT' The Division of Chemical Sciences and the Institute of Physical
Ch:ai;try of the Academy of Sciences of the USSR organized from
1 0 October 1956 a consultative assembly for the treatment of
questions of the mechanism of electrochemical processes* This
conference encountered greatest possible interest of many
representatives of soienceep technology, and industryt and also
attracted several renowned foreign scientists (from the United
Kingdom, Hungaryp the German Democratic Republial Chinat Polandl
the'United States# the Federal Republic of Germanyt Francs, *to.)
With about 1000 delegates as participants, this conference was
unique in the history of the Soviet Union, Sixty lectures were
given during nine plenary meetings# and all lectures were devoted
to the fundamental problems of electrochemistry. In additiong five
sections were formed to deal with questions of electrochemical
regeneration, processes of chemical sources of ourrentl
electrolysis of smeltp application of electrolysis in chemical
CARD 1/3
The Present Tasks of Electrochemistry PA - 2479
(Aktual'Ayye voprosy olektroohimii, Russian)
industryt el,sotrodoposition in metals# *to. Altogether eighty
lectures were given in the sections. A.No rrumkin# Member of the
Aoadeayg emphasized in his opening lecture that during the last
five years electrochemical kinetics his reached the peak of its
development and has become a scientific branch of its own* As
tin* passed by# an intensification took place in the attention
devoted to phenomena of diffusionp to detailed investigations of
the nature of elementary collisions which determine the velocity
of electrochemical proosesest as well as to the investigation
of the structure of the double layer and of the effects of ad-
sorbed ions, ttame and molecules on the kinetics of the reactions.
Simultaneously, the relation between different branches of
electrochemistry and related branches of science was strengthened.
Most of the lectures dealt with general questions of electro-
ttohnioal kinetics, furthermore with problems of the proosesse
of the electrochemical regeneration of different anions, of the
mechanisms of the processes of the eltatrochemioal oxidation aud
with question@ of passivism (antivation of passive iron oto.~ or
with questions of ol*otroorystcllization from aqueous solutions.
For thefirst time in a public congress, one of the sections
CARD 2/5
The Present Tasks of Electrochemistry PA - 2479
(Aktualinyyo voprosy sloktroahimiit Russian)
doalth with the questions of electrolysis in the smelt. In
addition to the discussions which had boon scheduled in the
program of the conference, different questions of slootro-
chemistry were discussed in smaller groups of the Soyiet and
also foreign soientistal this led to a rapprochement of the
different view& and also helped to establish more intimate
contacts between the participating scientists.
ASSOCILTION:
PnSZXTED BY:
BUMTTED:
ATAILLBLIC: Library of Congress
CARD 3/3

AUTHOR
v~ "0
JAIASHOYA.Nek. IVANOYIV.Ae ati
KAZA I
TITLI Depen4ence-4 of Adsorltion cf clntioiis ~n PAINtir-irn Elsetro.-le
eotential
(zaT191mo;,9 adoorbtail kationoy ot potenbWa platino-
vogo el*ktroda.- Russian)
PERIODICAL Doklad$ Akadexii Nauk $BSA 1957, Vol 115, Ir 2,
pp 336-338 (U.S.S.R.)
ABSTRACT Yor the majority of settle a study of the adsorption of
cations on their surfate is -onpllcatsd by the phsaomen
of exchange between the cations of the metal, avd the
own or foreign solution catiors. 34ch ar- exohange was
not noticed In the aswp (.f P'L&*.JTJUV. This renders the
oomps.r1sor. of its e lea trochew.2.;3ul and adsorptive pro-
perties easy. No special studive of this problem are
known. Some results by Irbacter and Lcrens do not permit
any oonalusione on the connoction between the ad-
sorption phenomena and the strtiturs of a double elso-
trio layer on the surfate of the metal. From a ntimber of
works with a mercury electrode It could be seen that the
anordgazic cations (with "te exieptico of thallium ion)
do not posses& a 444&orbability, For uue-.~'Iarge
CLRD 1/4 cations it was found tb;t they even show a oertain nse&-
DapanCe=o, of Alcr.:i7n;~_o*,
Potential.
tive adsorptioa on the marcary Qf v-juzsntra%vd
tions. According to measurements 6f -,apacity t~e effo,:t
of a hyperequivaloAt advorptJor as sgalust a vqakly
negative charge was only provel fcr multi-charge cationg
of lanthanum and thortum. This was explained by thi
formation of anion-oation yaira ihich w6re adsorbed
on this mercury surface In a manner that the auioz was
Inclined to the solution. Ivor a itudy of the ntrioture
of this double electric layer it *at inter4sting to
determine the dependence of cation adsorption on pla-
tinum electr6as, potential. This was dors in the pre-
sent paper by the method of labeled atoms, I11.1 showa
a typical curve of dependence of the s4sorption of
cesium cations of a sulfuric &old solution on the
potential of platinum. All potentials are relative to
a normal hydrogen electrode. The rovulte show that the
mentioned dependence ***me to be more complex then
described in publications. A maximum value of catiou
absorption.occurs in the region of highest negative
charge, It apparently somewhat surpasses the value which
CAD 2/4 would be necessary for the forration of a doubl* layer
20-2-39/62
Dependence of Adsorption of Cat3ma on Platinum Slectro4e
potentials
surface. The adsorption of cations rapidly decreases
on a shitt of the potential in a positive direction,
This door*&** corresponds to the decrease in the ze-
gative, surface charge* In the sero point, however, the
oatios adsorption does not amount to sorov In the
0*20-0#45 w. region of potential# which corresponds
to the increase in positive suzfao* charge$ the ad-
sorption ot cations Increases. This can be explained
with regard to the specific adsorption of anions. That
on positive charged platinum the author explains by the
hyperequivalent adsorption of paloss
30 2- and 010- at those potentials. For the
4 4
first case It was' directly proved by the method of
labeled atoms. The considerable adsorption of anions
noticed Is the case of negative and sero -charges must
lead to an adsorption of cations which must supass
that which would correspond to a negative surface
CARD 3/4 charge. The curves recorded for potentials higher
20-2- 9-
Depend6nce of Adsorption of Catkm m Platinum E ectrodc
Potential.
ASSOCIATION:
MSUTID BY:
SVW?M2
ANULAILS;
positive than 0945 w. are most probably connected with
the development of adsorbed oxygen on the surface. The
suto& adsorption must therefore lead to decrease in
cation adsorptioni as long an the surface charge
remains positive* This explains the decrease of cation
adsorption In the OsO-0#55 rtgioa. In the ass* of
Creator quantities of adsorbed oxygea the potential
obifts, to the negative and the electrostatic adsorp-
tion of oitione issrouses After 0,7 W. is roachedp the
Increase, la-quantity of the adsorbed oxygow Is &a
longer ospaile at compensating the Influence of the
Inoreasi-Ag,positiVi oh&M e in pdt*atial. low the cation
adsorption agaia.decreanes. Surfact oxides say perhaps
be concluded from the observed *Islas and maxima.
(2 Illustrations# 5 Slavi* references)
not given. '
FIMMIN A.X.~ Aeadenicians 14mb, 89 1957
6-5-57
Library of Congress.
CARD 4/4
, :".- .., -
5W
AUTHOR: Balashova 9. A SCV/76-32-10-7/39
*;ik , ^*
TITLE: Adsorption of the Bromide and Iodide Ions on Platinum (Adsorb-
taiya ionov broma I yoda na platino)
PERIODICAL: Zhurnal. fizicheskoy khimiiy 1958, Vol 52, Nr 10, pp 2266-2273
(USSR)
ABSTRACT: The Investigation of the adsorption of surface active bromide
and iodide ions on. solid metals Is especially important for
the explanation of the structure of the binary electric layer
in the presence of ions. Investigations in this field had al-
ready been carried out by Z. A. Iofa and G. V. Rozhdestvenskaya
(Ref 7) and Le 1. Meavedeva and Ya. M. Kolotyrkin (Ref 8). In
the present paper invastigations of smooth and platinized
platinum in aoid soluti-)ns were carried out with the potential,
the duration of the experiment, and the temperature having been
modifiedb The desorption conditions of the bromide and iodide
Ions from the platinum surface as well as the penetration of
the ions into the interior of the metal were also Stu ied. The
Card 1/3 method of the radioactive indicntor3 was used with 101 and
53
Adsorption of the Bromide and Iodide Ions on Platinum
SOV/76-32-10-7/39
Br 82. In each experiment first the total and then the ir:-
35
reversible adsorption were determined. The platinization was
carried out according to a method described in reference 4,
and the calculation of the actual surface of the platinized
electrodes was carried out by means of data from work by
Ershler Oef 5). The maximum. adsorption of iodide on platinized
platinum was 3t7-10-9 gram equivalent/CM 2 at a potential of
. -9
0,4 Volt and after 30 minutes, for bromide it was -0,7-10 gram
equivalent/cm2 1 whereas on smooth platinum a value almost 20
times.higher was obtained for iodide. This high value is ex-
plained by the different 44sorption properties of the smooth
and platinized platinum. The increase in total adsorption with
the time taking place at the expense of the irreversible ad-
sorption so that both values agree after some hours Is ex-
plained by an intensification of the bond of the anions with
the platinum surface (clearer with iodide than with bromide).
A decrease in the bromide and iodide adsorption with an in-
crease in temperature is explained by a continuous migration of
Card 2/3 the adsorbed particles into the interior of the metal at a
Adsorption of the Bromide and Iodide lons on Platinum
SOV/76-3 2-10-7/39
velocity higher than that of the adsorption increase with the
temperature. The adsorption depends to a ereat extent on the
potential of the Pt electrodel it increases with an increase
in positive charge, and it decreases with an increase In the
negative charge of the electrode surface. Papers by A. 1.
Shlygin, A, N. Frumkin and V. I. Medvedovskiy (Ref 4), and by
Ae D. Obrucheva (Ref 1D) are mentioned. There are 3 figures,
3 tables, and 15 references, 15 of which are Soviet.
LSSOCUTIOIT: Akademiya nauk SSSRyInstitut elektrokhimii
Institute of Electrochemistry,AS USSR) ,Moskva (Moscow
SUBMITTED: April 18, 1957
Card 3/3
AUTHORS: Balashovaj N. A., Kabanov, B. H. SOV/2o-121-1-35/55
TITLE: The Electrochemical Behaviour of Zirconium in Sulfuric
Acid ( Elektrokhimicheskoye povedeniye tsirkoniya v sernoy
kislote)
PERIODICAL: Doklady Akademii nauk SSSHt 19581 Vol- 121, Nr 1#
pp. 126 - 128 (USSR)
ABSTRACT: In the present paper a report is made on the investigation
of the cathodic and anodic behaviour of zirconium and of
the no-ourrent time variation of its potential in IN B2 so 4
at 250. The experiments were performed in a hermetically
sealed glass device at a rodlet of zirconium. According to
the experimental results the oxide film which had formed on
the surface of zirconium when kept in air for some time
displaces the stationary potential towards the positive side.
For cleaned electrodes the displacement towards the positive
side amounts to 0,10 - 0,16 V. The laws found on occasion of
cathodic and anodic polarisation of zirconium In IN H 2 s04
Card 1/3 speak for a great influence of the oxide films. The cathodic
The Electrochemical Behaviour of Zirconium in SOV/2o-121-1-35/55
Sulfuric Acid
curves show a break in the range of potentials from -0,6 to
-012 Ve On both sides of the break the curve of the excess-
voltage of hydrogen satisfies the Tafell equation. The zero
point of zirconium according to the work function of the
electron seems to be neare;18%jaginning at very low current
densities (i - 2,10-5 amp e zirconium in very much
passivated by an anodic P
ilarisation. At a current density
exceeding 10-4 amperes/cm a gold-colored film it th an
effective ohmic resistance of the order of some dozens of
ohms is produced, In the case of an inverse course of the
curve of anodic polarisation a strong hysteresis can be
observed. The oxide film obtained on zirconium by anodic
polarisation reduces thevelocity of hydrogen separation
on zirconium. There are 3 figures and 7 references, 4 of which
are Soviet.
ASSOCIATION: Inatitut elektrokhimii Akademii nauk 3(,SR (Institute oil'
Electrochemistry AS USSR)
Card 2/3
The Electrochemical Behaviour of Zirconium in SOV/2o-i2i-1-35/55
Sulfuric Acid
PRESENTED: March 111 1958, by A.H.Frumkin, Member, Academy of Sciences,
USSR
SUBMITTED: March 7, 1958
1. Zirconium-4leatrochemistry 2. Sulfuric acid--Chemical effects
3. Work functions
Card 3/3
,BAI-ASIIOVA) N. A.
Ale a
10
A i
ve
talo.lotO3.
a
Or
as
I c
Sim .1 L
2 azi. ;f
I P.. z -
I A 14
a tv 1 ..1
g 2 10 Ar
ile k . -. 1,
At
M -_4 "0
Ala
IL
p M ..1. 10
~94 0. dc 0.
0 1 Yoe 0 .1
u
le -
lu~ I -i - -0 K : v i "
i R I
0; Im
fill 1 1
Wins
5(4), SO'1/70-4-1-38/48
AUTHORS: Kovbat L. D.p Balaohova, N. A*
----------
TITLE: The Detormination of the Sol-ability of Silver Ox-4deq In
Alkaline SDlutions by the Mothod of Radioactive lndicat-~rs
(Oprodeleniye rastvorimost'. okislov sorebrn. -, shuheicchn.,,kh
rn.,%tvorakh metodom radicaktivrykh indikatorov)
P --- R 10 D I CAL Zh-.irnal neorganicheskoy khirii, 1959, Vol 4, 1Tr It
225 1)
P -226 (USSR)
V
ABSTRACT: i tv
r,.*Ctn-.d VQ-*-xU'1o:1n by r'lt,i.
active indicatorA. The radioactive. iriotore ef oilver A(.; 110
was usod as indicator. On determining the sol-ibility at 250
it wtta found that satarated solutiono can 'o(~ obtaine~t cl,,,Iy
after 70-80 hours. At higher lemperaturL3 saturation ify ot-
tainod after 10-15 houra. The avlubillt~y of Ag,O in ftdkalire
solutions of various concentrations 'As in good agrecment.
with the data by Johnston and LaILO. The depenlence of th~,
sol,ability of A 1 1
920 on the concentration of alkali 1YC at 250
Card 112 is shown in figure 1. The solubility of Ag,O incre.,Mqor,
SOV/78-4-1-38/48
Tk,e Determination of the Solubility of Silver Ox.'de3 in Alkaline Solutions
by the Method of Radioactive Indicators
considerably with a rise of the concentration of lye of frcm
I to 5.na,-In 10 n KOH the solubility of Ag20 'a
6.0.10"4 equiv./lOOO K H 20. With rising temperature the
solubility of Ag 20 increasec. At 780 the solubility is four
times higher than.at 250.,The increase of solubility-is not
proportional to the rise of temperature* The presence of zinc
ions does not influence the solubility of AgO and A920'
Experiments of the 9-olubility of AgO in alkali solutions did
not yield any quantitative results* The authors thank
B* No Kabanov for his assistance.
There are 2 figures and 5 references, 1 of which in Soviet&
SUBMITTED: October 20, 1957
Card 2/2
24087
s/i66/6o/oo2/oo6/o12/b26
21 A050129
AUTHORSt Balashova, 11. A., Markulova, N. S.
TITLE: The aA-torption-alectroahemical method of separating radioactive
ziroosaom anci niobium
PERIODICALt Radiokhimlys, v. 2# no. 6. 1960, 699 - 703
TEXTs The authorsinvestigated in 1953 a method for separating radio-
aotive zirconium and niobium in aqueous solutions containing in many cases
low concentrations of stable isotopes of these elements. The method is based
on tho use of the difference between the adsorption properties of the ziroon-
ium and niobium ions under specially chosen experimental conditions. These
conditions are determined by the different state ofthe Ions of these elements
In the electrolyte solutions% Nitrate and fluoride solutions of zirconium and
nioblum salts were used In the experiments. It was noted that in strong oa-
thode polarization pure Mobium in deposited on platinum or stainless steel
from nitrate or fluoride solutions of a mixture of zirconium and niobium salts,
whereas zirconium remains in solution. The hydrogen deposit potential on pla-
1/4
Card 3
The adsorption-aleotroahemloal method ....
3/186/60/002/006/012/0-)6
A051/A129
tinum from the acid solution of potassium fluoride wall 0 03 M containing nio-
bium and zirconium In concentrations of the order of 10-io M. Tests showed
that the greatest quantity of n1obium passes to the electrode at the lowest
positive value of the potential. Experiments on separation of nioblum from
solutions where zirconium to prenent showed that pure niobium or niobium with
various contents of zirconium can be produoed.depending on the potential and
concentration of these elements In the solution. The deposition of zirconium
and n1oblum in several stages shows the best results. Attention is drawn to
the fact that nioblum95 is produced In the solution due to the radioactive de-
cay of ziroonium95 thus causing Impurities in zirconium. If oxalate ions are
present in solution the method mentioned cannot be applied. It Is suggested
that first the oxalate ion be destroyed by oxidation on the anode, then to
continue the electrolysis with deposition of n1obium. The results obtained led
to the conclusion that complete separation of zirconium and n1oblum Is possible
by the method suggested. This method is also recommended for a rapid qualita-
tive radlochemical analysis of the isotope mixture of Zr95 and Nb95 at low con-
centratIons of the latter In the solution. In this case it is suggested depo-
siting niobium on the cathode and carrying out a separate analysis of cathode
Card 'V 3
24087
S/186/60/002/006/012/026
The adsorption-alectroohemical method .... A051/A129
and solution. Various methods are considered for the removal of niobium
from the platinum or steel cathodes. One of these is the use of the action
of nitric acid to transfer niobium to the solution. It is pointed out that
an Incomplete transfer of pure n1oblum Is achieved here with onlY 70 - 90 %
of the Initinl wwunt rtmoved in ont hour. There are 4 figures and 20 refer-
encest 12 So-.!Iet-bloc and 8 non-Soviet-bloo. The references to the moat re-
cent English language publications read as follows: R. E. Connick, W. H.
Boas, J. Am. Chem. 800-1 73, 3, 1171, 1951; B. A. J. Lister, L. A. Mae-Donald
J. Chem. Soo., 4315, 190521 E, M. Lareen, A. Oamll, J. Am. Chem. Soc.p 72,
8, 3615, 1950; M. E. Holt, j. ElActroch. Soo.$ 98F 10 330 1951.
SUBMITTED: January 11, 1960.
Card 3/3
XU"INOY. V.Te.; BALASHOTA, N.A.
Tracer study of Iodine adsorption and desorption on smooth
platinum. Dokl.AN SSSR 134 no.4t864-867 0 160. (MIRIL Dtq)
1. Institut elektrokhtati Akademil nauk SSSR. Predstayleno akad.
A.R.Prunkin" .
(Iodine--Isotopes) (Platinum-Isotopes) (Sorption)
-MARINCY'-, V.-- -- - - - --- -- - -
Ye.; BAIASHOVA N.A.
-1.
Interaction of oxygen with the anions adsorbed on platinum from
solution. L)*l. AN WSR 139 no.3:641-644 JI '61. (MIRA 14-?)
1. Institut elektrokhimil AN SSSR- Predstavleno akademikom AsNe
Frunkinya. (oxygen) (Anions) (Adsorption)
BAIASIIOVA, tI.Aq ZJMKINI G.G,
Extent or ion adsorption on platinm as afrected by the
thermal and mechanicO treatment of the surface. Dokl. AN SSSR
143 no.2%358-361 Mr 162. (HIM 15%3)
1. Institut elektpokhinU All SSSR. Predstavleno, akademikom
A. N. Fhwkinym.
~Adsorptlon)-
kmetalo-Finishing)
BALASHOVAI N.A.; RASHXDVt St.
Effect of the electrolyte acidiV..on the.properties of cobalt
electrodeposits. Dckl. AN 66SR 152 no.4s896-898 0 163.
(MRA 1611l)
1, Institut slektroMixii AN SSSR. Predst&vleno akademikom
A.N. Frunkinyu*
Rk USIIOVA - A. A . ; B.N.; KON't, L.D.
Lead tranafer in a ponitivu electrode of a Inad acc=lator.
Zhur# prikl. khlm. 37 no. 4:906-908 Ap 164. (.1-11RA 17:5)
KAZARINOVP V.Ytt.1 BALA5RUVA, N.A.
Adsorption of ions as dependent on platinum polvential. DokI.
AN SSSR 157 no.5tll74-1177 Ag 164. (MIRA 1.7&9)
1. lnstitut slektrokhtmii AN SSSR, Pr,-datavleno okaderzJkom
A.N. Frumkinym.
-1, Or OA;~rflil LT
0 11,
A"
t rc
18W
. f . !. . . . A . .
A I , , I ~ I I . I . I I - I . I I , . - I
~ I ! ~.~ , , N I - I I . . . I .
k ~ . I I . I I e . - . . I . . . . .
A KAL -1 1 he migrat 1 on ~ ! I 0m Uu ( NL) 3 )2 and A kA 1 3 ';'liut ions) of oppez and gc4ld
. -- . .,~ ~ -1
I - ~- 1 q o , - ,~ ., 1, - ; ~;, ; 1 , , p . . I , ~~ I
~ L, ,, 1 1; 2
~-4~ I (IN NR A P I
t r f i,,q r d A i I I ~n
~a f I t 1 0 O,f I r
h i I 4 A 1. ,A..-
I B CO DF. T
I
2
V. I
vlrorpl-tc,rl n1 rittior-) and -n p1rit,!,u~',
I'rcm i i mi
kit. dirfvreni. yot.pntial,,:. E'li,ktr 'r, -
nm,5--~12-516 I-y l6i'),
T ii t i Lu t c ci'k t rok tr -. i -,N
KAZARINOVI V,Ys),,,* BAaHOVAp N,AO; KULF.;',NEVA, M.I.
----------
Stru.ture of the surface layer on platinim In alkaline soltitions.
ElektrokhImita 1 no.8s975-978 Ag 165. (MIRA 18t9)
1. Institut alektrokhioLit AN SSSR.
~A ~ , 11,".' -1,1 11 , -- . ; 'r, 'I - ~ 1 ? 1, - : ( -, v
. . , lm',Iffe
r,f t~~p de-n~lc P,,~rtrii la,,,--tr (-n platinum ot-Aled
Lit. Um.khlm. 34
)-1 1.) C 165, (Mlht,
I
I. Inst-ktait, o1s~trokhlm'U All S-S~Ro
CMAIWAV"LA
KALUW4W# T. 9.1 MAIA OVAO U.
la*Utut* ef gloctnwhmietryp UBU Ato6aW of Betowes (lutiftt
ll*kU*kMMig Ak&dWia No& 8=)q Hosew (for both)
P"41WO COII-qti2B AslashOo4oal comwAniogtimb No 129
9t CWL
Dw 196% Vp 418"192
Obtatr ot oulftrie and pboapboris &aid sAaerptlem on platimmoO
BAUSHOVA, N.A.; YEISTSVff, V.V.; MEDYNTliu, V.V,
Effect of various factors on the transfer of coprer and gold
from aqueous solutions to the surface of germanium and silicon.
Elektrokhimila 1 no-3074-2'78 Mr 165.
(MIRA 1802)
1. Institut elaktrokhimii AN SSM.
&AIASHOVAP IN.A.; KA,-ARINOV, V.YG.
ElectrocLemical method of preparation of radioactive solutions
of carrier-freo iodate. Radiokhimiia 7 no.6:739-741 165.
WIRA 19:1)
BAIASHOVA, N.A.; PANGAROV, N.A.; SEMMOVA, Z.V.
Connection between the struettire of electrolytic depoette
of cobalt and their corrosion resistance In sulfuric acid.
7ashch. met. 2 no.100-84 Ja-F 166. (MIRA 19:1)
1. 1nat1tut elektrokhImii AN WSR. Submitted July 27, 1965.
'D
CUCWSWAKIA
_FWMIN, A.N. KJOSUROV, 0. N. t KAZWKOV, V.9. RALASHOVA, _N. A*
Electrochemical Institute, Soviet Aeadsoq of Sciences (Institut
slaktrokhimiij Akadsaiis omk SSSR)j Moscow (for all)
Prapop Collection of CxochosloyAk Chemical Communications, No 2p
Pob 1966, pp $06-813
*StucV of the adsorption of cadmium cationa an a platinum electrodeq.0
L 34~21.46 EWT(m)/EWP(k)/EWP(t)/ETI IJP(c) JD/HW/WB
ACC NRI AP6003324 SOURCE COM UR/0365/66/002/001/0080/0084
AUTHORt Balashova. N. A.; Pangarov, N. A.1 Somenova, Z. V. 9
ORM Inatitutt of Electrochemistry, AN SSSR (Inatitut elektrokhinii
AN SSSR)
TITLEi Relation between the structure of electrolytic deposits of cobalt
%nd their resistance to corrosion is 11 ..
SOURCEi Zashchita setallov, Y. 29 no, It 1966 80-84
TOPIC TAGSs cobalt, electrolytic deposition, corrosion resistance, cobalt
compound, crystal orientation, cubic crystal, cathode polarization,.boric
said, sulfuric said
ABSTRACTt The relation between the structure of electrolytic deposits of
Co-and their resistance to c?rrosion was investigated with samples pre-
cipitated from electrolytes containing pure COS04 (500 g/1 CoSO497H20), 500
9/1 C0604 + 45 S/I HjB03, and 500 6/1 C0804 + 45 g/1 H + halide (4 x
10-3 N KC1, KBr, or I), The tesperaturtg pH of the 91:02rolyte, and the
current density varied during the experiments. Two parallel Cc plates,
with Pt cathode (surface 2 482) between then were used an &nodes. The
electrolysis was made for 2 - 2,5 hr at constant mixing of the electrolyte.
Card 1/3 uDc, 699.2~ , 620.193
L 34392-66
-ACC. NRt AP6001324
0
The deposits were rinsed with bidistilled H20, subjected to a X-ray
diffraction study, and then dissolved in 5 N 92S04 at 20 - 23C in the
atmosphere* All deposits obtained had hexagonal lattice wi'th different
planes of prodominant orientation, The temperature, pR, and composition
of the electrolyte considerably affected the direction and perfection of
the deposit structure. In an ordinary COS04 electrolyte witb the addition
of Hirp the deposit was oriented predominantly by face (1010) parallel
to t cathode surface. An increase of the pH from 1.6 to 5 improved.the
structure orientation add decreased the scattering of the"dpposit particleso
In the electrolyte without H3BO3, the plane of the base (0001)ww:sfpartllol
to the cathode surface. No cubic modification of Cc crystals a ormod
during the experiment* The proddainant orientation of the Co crystals
correlated with the changes of overvoltago of the discharge of Cc ionst the
cathode polarization was 200 - 300 my higher during the formation of do-1
posits, having an orientation (0001), than in deposits with the orientation
(1010). The rate of dissolving of Cc deposits in H2SO4 changed corres-
pondingly. The predominant orientation in the direction (0001) provided
for higher stability of the Cc deposits than the orientation (1010)~ The
single-phase deposits of hexagonal Cc with the orientation (lOiO) were
formed in the presence of Cl- and Br- ions. In iodide solutions the
Card 2/3
-rid
A&VOMIN dam babe vmwl
oil" N. IL *Ad A. T. %';V:w
1.
f i". (DA6*1 ftmyl SAAR, 114% M 9. 1.
3.
am% "460 w"Vallas w4bm of
ie W24 OAMM W- 1a 0 bw moca4& rewive"m is
*$me (to mw). Ow Almew &0O
XCN. elsfuodma-& A. IL
BAIAS LOVACMA, N.V.; SELIVABOVA, Ys.P.; ZHIVILIN, N.N.;
MANTAKIN, V.I., red.; SIMIN, A.A., red.; PYATAXOVA, N.D., takhn.red.
(Certified seed sowing In the U.S,!.R. (train and sunflower);
a statistic a, manual] Sortovye p err S SR (sernovye kulltury
I podoolnechnik): statititicheakiy sbornik. Moskva, Goo.stat.
izd-vo. 1957. 422 p. (MIRA 11!1)
1. Chlen Kollegil, Mentrallnogo statiatichsakogo upraylaniya SSSR
(for Hwakin). 2. Russia (1923- U.S.S.R.) TSentrAllnoys
statiaticheskoye upraylaniye.
(7iold crops)
KRZHE)UNSKIYI S.A., kand.takhn.nauk; KRYZHANOVSKIY, B.B.,\~nzh.; XAMEYXOv
V.A., kand.takhn.nauk; LEVIN, N.I., kand.takhn.nauk; BALAV_9_VA,
inzh.; SHUTILO, L.I., insh.
The technology and basic physicomachftnical properties of air- -
entrained silicate and air-entrained cinder silicate used as
insulating materials. Sbor. trud. ROSNIIMS no.2006-51 161.
(KRA 16s1)
(Insulating materials) (Sand-lime products)
KAZRACIMY, B.Uq BWdHOVAP N.H.
it
Mwafacture of the first original disk (stamper) from a recording
disk, Trudy VNAIZ no,,5s97-aO9 159. (ML 154)
(Phonorecords)
`/137/6?~WO09/025/033
AO%IAIOI
AM110M, Kaznachey, D, Ya,p Wlashova, N. N., Rozhdestvenakaya, A. K.
T177,F,t Flectrodeposition of nickel with low Internal stresses out of sul-
fnmIc electrolytes
PFIAIODICAL: Rcl'erativnyy zhurnal, Metallurglya, no. 9, 1962, 122, abstract
91791 ("Tr. Vnes. n.-i. in-ta zvukozapisi", 1961, no. 9, 157 - 168)
T W: Internal stresnes in NJ deposits olitiined cut of sulfamic electro-
lytes without admixtures, are much lower (by 1,000 - 2,000 k&/cm2) than in depo-
sits obtained from sulfuric acid electrolytes. In this connection sulfamic elec-
trolytes are recommended for galvanoplastics and precipitation of thick NJ de-
posito, Contamination of sulfamic electrolytes with mechanical organic wid me-
tallic impurities increases internal stresses.. A method is mentioned for elec-
trolyte refining. Intevnal stresses in NJ deposits obtained In aulfamic eldctro-
lytes increase with higher Do and pit of the electrolyte 'and decrease at eleva
temperatures. The considerable proneness to pitting in sulfamic electrolytes is
explained by high surface tension of the electrolyte (as compared to sulfuric
Card 1/2
3/137/62/000/009/025/033
Electrodepositiorfof nickel with ... A006/A101
; .1 1 ~
acid electrolyte). The addition of 0.1 - 1.0 g/I Na-laurylaulfate (I) reduces
surface tension and eliminatca pitting. (1) can be well,tombined with admix-
tures to reduce internal stresses. Hydrolysis of sulfamlo electrolytes increases
internal stresses in N4 '-depoafts. Refining of sulfamic electrolytes from SOFF
ions may be performed by 13~.(011)2 preoipitation. There are 17 references.
Authors' summary
(Abstract.or's notoi C plate translation]
Card 2/2
Sri
of Jitils.ll
'losrow Or,"-r of Linin ic;d Inst ov.
go Vecheryaya Moskva
Sum 71
(At*d.
tl,I.VKCN&#AbiAgN%+OANKN(h*tftdrtd.by
the ament *rA:Z- ft I M (C.A. 0. &U&). nor
tv""I yirm l 'I, 8~~4. make IbAm the firalting
VAC OW Sb-M% Ot ed Pfmambly *pWorms
a pwui lono" qibe4mv cl tio colopk% an" mwb as
A 11%. sod Ow drp" Is mmolk bn-auw Ow vvml*v
iqAmq iloptwilw imm the I-*Oro& puff"v.
06suuov. ff d. (C.A. 34,3WOO, tUhntA Out "wtal can
t* ekeftValevask"lum It KIRM fitwi nott totborMinsk, bul
V. sad U. CWAI Im fvpnKhwe tivis etpt. (;Iatufwv"%
tbrory t6t t1w awtal drpoMim o a wtmwtwy promm It
J. J. lliktrmlf
i-, 11 fir v T!, A T\i
A IT
Actirarsaw s4 Obso e4cfe"o evit"o N 04'.1.
14, Turv% %, awl A. T 'fil;' I
vu ~ VAitISIVITA11. ~ j M
.Vdbb 71, 73 111MA1 j..q'i%kAT 4.1 At%
. k~l '"'Ir to in liawlel. ar"t I'v qh~ , h~.na~ .4 it.
.AthRftlW JOU6411A16111 NUAIN11 On 1114111Wkit tit !0411111111%
:Itlamilka 01 a snartal An,% tha, %I-Ii-anAry 1-44itamv-t
matAt,hard in the t6vtht. Itivattimi at & Swo, e %1. A AS
""W41 '6111% Awd 11,111, thrtv Upt 10 litin. in A
N wAn. 4 AIN3% wititulul Mfl.ni. than J.4.vtwd in the
~'.w An. at ooh Inr~ '09, van. at 1-4 *W" shanar'd a
drup of the owwoltagr Aluring the W 3 5 sov., 'hwa
c%xaso. potentW: the drop ci the art-fq-tit.4ce Inaraw'. 'h*
,kvm ul initial pamirity it( The As Ttw ii-inte timir"k
1wrtred ni in a omit. of XCN shnitred. an thr (imcfary. an
I Irc
nitiAl the of the twitrutisl durins the W fc* mv 4d tlcvtto-
J. g%wtkin In I N AIN41i. C 11T. 1-fritrat"W"t
with KCN pitubw" an wtstlls=_tit~ uFf..V. in
omtrast to &be juw,ity ptmfuv~l 1.v avie,ntla- at,%.
"%,T~kvai in AgNit,. (its As thwirtmIrs Isti-Activaint in
kc.%*. t1w m,. J AS ci"Wittes in a AS it, cd pfigill"Vil
by rk"ftAii -is ad ASNO i~ a- nsthh hialml I an -an a wan-
Aa'tv%A2w%1 At rimwuw. nit. -a hvrA- %,t% vmv,...
vigirnsthiA its A11NO, 1.41,ming Ow
activating KCN tfrata"t. a III-aare irtitualount in AAMN
.~g u1ffK*1d to "toy the 4chroksts. am] the no tif
ctv-1416t" tweanw ttttul to that "mrit-1 an a wvc re-
1 .04fair Nrtl~W Vial""Or *kWh ~- LSt all Aj.NV 0, for
th- o4um Lasth ad tune. ArlitAtican in KCN firlinir" A
ha ur . a Weal jutittatom tit AtN' % I- -ta.-fe-Ir
itwis alwaor. tiamiLit troulto w"r 04,iml eiih A %'%a
r"'Migh! "hiCh 61CAMT ACIIVAt"l f-V KC.N;. 41-11T F101f
ohwh bAu wto im-liveting tilect am At. Thim
N-tl&mwm
T7M. 71-
('u,,- h".,nx Ow
" U., I.f", d
~. \ "-.! k!,. 1, )~
th, ~,-Jn M fin* gm,-^i "wihit
NALIVKIN, D.T., okadoulk, rodaktor; MM, Y.Y., redaktor; R&USIR-CM-
NOEYSOVA, D.M.; ZMLINGXR, To.A..; B~~Mjj.; RUPATSEATA.
1. L; CIMNOVA. To. 1.
[Regional stratigraeby of the U.S.S.R.] Rogionalluala stratiara-
fila SSSR. Vol. 2. LStratigraphy of the middle, carboniferous de-
posits In the central. and eastern Vwts of the Rassian Platform;
on the basis of foraminifer& studyj Stratigraflia arednekamennougoll-
vykh otlasheali teentrallnol i vostochnoi chastoi Rasokoi platfor-
my; no oenove Isuchoulls,forominifer. Pt. 1. [The Moscow Basin)
Mookovskata sinoklisa. Olay, red. D.Y.Naliftin. VA.Monner. go-
skva, Izd-vo Akedemil nauk SSSR. 1934. 270 V. (KUU8 12
1. Akademiya nsuk SSSR. Institut goologichookikh muk.
(Moscow Basin--Geology, Stratigraphlo)
15-67-5-5769
Translation from., Referativnyy zhurnal, Geologiyuo 19570 Nr S#
p 9 (USSR)
AUTHORS: Reytlinger, Ye. A., Balashova, N. N,
TITLE: Stratigraphy of theV-ddle Carbonlrarous Strata in
Rzhev Volga District (Stratigraflya arednekamennougoll-
nykh otlozheniy Rzhevskogo Povolzhlya)
PERIODICAL: V sbi Regionalinaya stratigraflya SSSR, Vol 2, Moscow.,
Izd-vo AN SSSR, 1954, pp 121-200.
ABSTRACT: Bibliographic entry
Card 1/1
32-7-23A9
AUTHORSs Raohkulik, V.J, 9 Bermang M.L*j Balashova, N.N.
TITM Short Reports
(Korotkiya soobahcheniya)
PERIODICALt Zavodskaya Laboratoriya, 1957, Vol*23, Nr 7s pps 829 - 829 (USSR)
ABSTRAM On this basis of the investigation of the luminescence properties
of rubber mixtures and - ingredients used in the cable industry
the advantages offered by the method of luminescence for an aoce-
lerated control of the quality of rubber mixtures and ingredients
are determined. By means of this method it in possible to determ-
ine the purity and quality of the component of rubber admixtures
and to deteot serious faults existing in these mixtursel further-
more, it is possible to sort out rubber and rubber substances of
apparently similar character* N*K, Balashoya developed a method
for the determination ct the strength of galvanically applied
silver coatings. A solution of 10 g chrome anhydride in I litre
001-h sulphurio acid was used for the coating of copper, brass,
iron, niokell and other metals with silver without any destructive
Card 1/2 effects.
32-7-23A9
Short Reports
ABSOCIATIONi Tashkdat Irmah'6f- the Cable Industry Institute
(Tashkentskoye otdoloniye institute, kabollnoy pmyshlonnosti)
Scientific Research Institute for the Recording of Bound
(Nauohno-iseledovateltakiy inatitut ayukocapisi)
AVAILABLE# Library of Congress
Card 2/2
BALASHOVA9 N.N.p mladshiy nauclaW sotrudnik
Resistance or table peao to the lima boan pod borer. Zashch. rast.
ot vred. i bol. 6 no,12145 D 161. (MIRA 16:5)
1. Moldavskiy institut oroshayumoGo tomledeliya I ovoshchovodetva,
Tirnepollo
ACCESSION MR: AP4018073
S/0119/64/000/00210012/0013
AUTHOR: Balashova, N. N.; Smagunova, N. A.; Tovpinets, Ye. 1.
e"
TITLE: R ducing porosity of nickel coating
SOURCE: Priborantroyenlye. no. 2, 1964, 12-13
TOPIC TAGS: nickel plating, nickel coating, nickel coating porosity, nickel
electroplating, electroplating
ABSTRACT: An experimaiatal investigation of the effect of additives to (a) nickel
electrolytes or (b) cleaning liquors upon the porosity of nickel coating is
described. Cation-active, anion-active. and nonionogen additives were: tentedi
each test was conducted with power on and power off, and the results were
evaluated by a microscopic count of visible pores per I cm These results with
additions to the electrolyte are reported:
Card 1/3
ACCESSION NR: AP4016073
Pore Count:
Power
Additive: On Off
10-15 sac
None Soo Soo
Sodium lauryl sulfate Soo 120
French t1pol Soo ISO
And with additions to cleaning liquors:
Pore Count:
Power
Class: Additive: On Off
None: Soo Soo
Cation Alkarnon D 90 330
Anion Sodium lauryl sulfate Soo, 390
Nonionogen OP-7 28 23
Card 2/3
ACCESSION NR: AP4018073
It is recommanded'that the parts to be nickel-plated be washed in a water bath to
which I - 1. 5 g/lit of OP-7 or OP-10 has been added. OrIg. art. has: 2 figures
and 2 tables -
.ASSOCIATION: NnChamprom (Scientific Research Institute of Clock Industry)
SUBMITTED: 00
SUB CODE% ML
DATE ACQ: ISMar64
NO REjr SOV: 004
ENCL: 00
OTHER: 004
Card 3/3
A ~ , ' A - . j I . ar )f,
"! I Ik M I T I FIL) F Ni C. I I I k , ['11 , F7 F I ,
BALASHOVAt N.N.1 YEFDIOV~ IvAt.
Improvement of the method for determining the surface tension
at the solution - air interface. Zav. lab* 30 no.1191367-1368
164 (MIRA 18t1)
1. Opytno-konBtruktorskoye byuro aytomatikio
!~ ~:fsl~z ~_. "I, "'!-
I. cff o' L -f nur Ctko, I -it C. t i ve I ~' ( ;-, U'o I orc~s Ity (i"* o -ir '. ~ ".o I y I, I .
I f , "
r-hic '-.lr. r1r., V .1 1 -. .
':~fv' - 1,
I I , A jn: . I
1. 1101if-, 1--richvskiv
BA,'.*IIOVA, N,N,, kand. kh,'m. nauk; TFF,'v.OV, TA.., inzi.,
ObtAining brIght alectrolytlo depositionn from cobalt-nlckP2.,
phosphor aliny. Priborostroenle no.2,.16-17 F 165.
X'rdl 18,3)