SCIENTIFIC ABSTRACT AVRAMENKO, I. N. - AVRAMENKO, N. V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000102620005-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 6, 2000
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

FILONOV, V*A., insh. (deceguied]; YUDIN'p M.I. in*.; LOIA.,
V.N.., insh.;
MOVSHOVICH, V.S., inzh.; AVIW~~O_z # ., inzb,; PAVLISHCHKV,
V.B., -insh.
Nov technology for -.he -production of wode-strip stainless
steel vith
a thialumma of lose th4a 1,~ nm. Stall 23 no.1:0-61 j& 163.
(MIrtA 16 t2)
11 Zavod "Uporoahetallwe
(Rolling (Hatalvork))

AVRAMMO, I.Ya., inzh.; RAIDTAp P.P., inzh.
Reprocessing oi~ sup;IU4 pressed oil cakes in the
Armavir oll
extracting branch plant, HaBI.-sbir.prom. 28 no-3:34-37
Mr 162.
(MIRA 15:4)
1. Upravleniye pishchevoy proqrsUennooti Kmonodia-sko o
oovnaxkhoza.
(.Krasnodar Torritory-oil lmdutries) (Oil cakZ

SHCHERBAKCVP Vladimir Grigorlyevich; KCZ114INA,
N.P., doktcr biol.
nauk, prof., rat5eizent; ABDURAKHIMOV; A.A., kard.
tekhn.
nauk, retsenzent; kVRAI',ENKQ,_j.Ya.,
inzh.-tekhnclog,
retsenzent; red.; KISINA,.Ye.I., tekhn.
red.
[Biochemistry and Lbe commercial study of oil raw
materialal
Biokhimlia i tovar)vedenia maslichnogo ayrlia.
Moskva, Pi-
shchepromizdat, 19,53. 351 P. (MIRA 16:11)
1. Kafedra tekhnol-)gii zhirov Tashkentskogo
politekhniche-
skogo inatituta (for Abdurakhimov).
(Oilseed planta-Analysis and chemistry)

SKLYAR, V.A.; AV
,E~A~ X*P.t.; FAVLOY. D.r.; BOBKOV, N.V.; BERESTOTATA,
R.Y.1
SKRYMIK, Ye.P.; SIXONINKO, Ye.T.; SER YXVI, V.P.;
KOLYAKO, D.A.,
red.; SCLDATOVA. N.P.. otvatetv.sa vypusk; GRISENYAYZV,
B.G..
te khn. red.
[11conomy of Iresnolar Territory; a statistical vianuall
warodmos
khoziaiatvo Krannolarokogo kraia-, statisticheakJA
abornik.
Krasnodar. GoactatLzdat. 1958. 233 P. (KIRA 12:2)
1. Irasnodarskly kray. Statistichaskoye upraylt,niye. 2.
Nachallnik
Ktashodikrokogo'kraro-rago-ststiatichookogo upravlaniya
(for Kolyako).
(Krasnodar Territory-Statistics)

SAUNISKO, Vladimir Llyovich; KASSIMOVICH, Vadim
Alaksondrovich; TROITSKIT.
Anatolly Vasilleyvich; TRCCHUN,'Ivan Petrovich;
POTISHKO, Aleksay
Vastilyavich; A IHW Ukiemt $MAy_iah--. VARITIIB,
Arnolld
Mikhaylovich; . F,~ rodaktor; HAM, N.Y., redaktor;
SAXD-
KHVA14)V, Ta.A., vedushohly radektor; YALICHUX, G.I.,
vadushchiy
rodaktor; PATSALYUK, P.M.. takhaichaskly redaktor
(Atlas of machine parts; mechanical joints and
cou;lingo) Atlas
dotalei mashin; soadinonita i mufty. Kiev. Goo. lid-vo
takhn. lit-
z7 USSR 1956. 146 p. (MLRA 10:2)
icouplings) (Welding) (Yastenings)

POCHINDI, T.Ta.; UTTSBYA, S.D.; PrInImli, ~,
tche-stlyel Fcchinok, ?.Y4.;
sILINSXAYA, R.F., studentl FXXRBXEO, L-F-, stucLO44
AVRAIMO, L-F-P
studqnt; MRCHMO, I.Gol student
Thiazolotetrazoles aveL trissenes synthesized from lhems
Zhur.prikl.khts- 33 no-7051-355 JI 160.
(KIRL Il: 7)
1. 11yevekly gosudan tvenW ,miversitet Las
T.G.113evchenkoo
(Tetrasole) (Triazens)

_AVnRM~NKA, L11Z,; VILINSKIY, ".u.B.; GUSSTA, L.K.; IVABOV,
B.M.;POCHINOK,
V.Ya.; STNUTAMIKOVA, Z.I.; FATIRKAN, G.P.
Stabilizing effect oj' thiatolotatratoles and tatragolobenso-
thiazoles on silver iffiloride photographic emulsions.
Zhur.nauch.
t prikl.fot.1 kin. 'i no.4:294-295 JIJ-Ag 160. (MIRA 13:8)
1. Uosudaretvannyy wiiversitet Kiyev, Yilial
Nauchno-iseledovat,all-
Bkogo kino-fotoinetitutm, Shoetka i Institut kino-inshentrov,
Leningrad.
(Photographlo emulsions) (Tetrazole)

POCRINOKj, V,Taoj AVEAME'los bero,
Thiasolotstrasoloo and their tautomeriomo
t1krokhimozhurs 28
no*4.-53.1-517 162o (MIRA 15t8)
1. Kiyovskiy gosudarstvelnW universitat imeni
T.C.Shevehanko.
(Tatrasolt) (Tautcoorism)

AVRAMENKO, L.F.; POCHINOK, V.Ya.; ROZ'UM, Tu.S.
Zffeot of substituento on the farmation of the
condensed
tetrazole(lp5~-b)bersot:tdzaole. Zhurob.khim. 33
no.3:980-085
mr 163. (MIRA 160)
.I& Kiyevskiy goautlarstvannyy universitet imeni r.G.
Shevchadto
i Institute org~nichesUy.khWi AN UkrSSR.
(Tatrazolobeiizothiazole) (Substitution (Chemistry))

AVRAMENKO, L.F.; VILENSSKIY, Yu.13.; IVANOV, B.M.;
ZAYTSEVAj S.De;
POCHINOK, V.Ya.
Mechanism of the istabilizing effect of
tetrazoloberizothiazolio
derivatives on photographic emulsions. Part 2.
Nature o:r the
adsorption compowid. Zhur. nauch. i prikl. fot. i
kin. 8
no.6;419-426 N-D 163. (MIRA 17:1)
1. Kiyevskiy gosudarstvennyy universitet imeni T.G.
Shev-
chenko i filial Vseooyuznogo
nauchno-issledovatel'skogo
kinofotoinotituta, Shostka.
.e

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*Attract Ion of Atomic Oxygm in ]D
a lacharip in
WUr Ta"re "d Beveral of Its psactions, 0 L ~
1.
Anisenkop iab of xlementary proceames, Isult
;r
Mat Sol UM, gi jpp
10rar Iriz UW Vol ==, so 7
igiw6wirstiza of atomic 02,788A obtained In
this
XAmner may reach 0.1 = jFg. Ob"rv" affect of
*Ztlneulahlng the oxygea afterglow with
vater.~
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for,
404agtsut of rate of jolmmetric,
recombination.
Odwitted 18 Oct

tun/chemistry Begy- 21 Jun 49
Phenol
"Reaction of Oxygen Atoms With Benzene,"
L. 1.
Avrambenko, 1. 1. Ioffe, R. V. Lorentso,
Lab of
M- Processes, Inst of Chm Pbvz, Acad Sci
USSR.,,
2 pp
wDok Ak Nauk ssma vol Lxvi, No 6
Rxperiments to determine whether and in
what
liash-titien phenol is d1btalned in the
direct re-
action of benzene with atomic oxygen.
Obtained
o2Mn atoms by Imssing streGm of molecular
oxMn
tbrough higb--vo-Itage discharge (3,500 v)
-
151T10
UM/Chemistry - Benzene (Contd) 21 Jun 49
Prepared ben ene by decarboxylizing
benzoic acid.
Showed definitely phenol forms as result
of span-
tamous interaction. Submitted by Acad N. N.
Semenor 8 A;w 49.
1W 151T10

WeR/Chewletry ffydn0jP1 Ana 49
Hydrocawbous
OReactione of a Tree )~Tdzoxyl With Rydro-
carbona,* L. I. Avramminko, R, V. larentso,
Inst of Phys Chan, Aced 803. M=s 3 PP
%Dok Ak Nauk SSSOR- Vol. 1XVn, No 5
Expresses a formula fcr briving the constant
of the rate of the reaction of a hyftox7l
group with combustible kydrocarbons.. &3A from
tabular data given in tbo Instances of ethane,
ethyleneo and aostylene oalculates th.48
particular oomatant in eaoh caim. SWOqUed
14 jun 49.

A pl, -it).
1014 7004 ).-Villif Mists, to the 106(fitow I I I. tili
1
+ + + XY-
detti. 1xv t1w spottevest"k sowth C. A. 4A, 00%).
tart b 0 rl-K frost lew
fait ciao, W %~v too liectift IS
Of th* I"NP., I.*. thl Wilvalke "OMIT. drigmisifible
withill OA "., Is catalvilY isse tban I kvil,inuAv. Var
~in CQ. A - 4 kial-Awk. The rats mots. wv
10-l' tlff'wlal~ OW (1) 1.8 x

n. am Il
M. U."Alt. move Mr. Kh#vR, 24. $17-13
1101), d, i.A. 4j. A. -All "Patim to Alw" low
4M
-Ak deniva. K airvoHloubrts"sOll *vvia ealk (A)
Mt. 11 b0h bin-am towcasph a 161W at 4 wr
F and t 0 foldl arl.87,01111 I" the fula- is &td. ffm the
:bw
lotlarl" fill 01"4 If$ tin livr 1101 NMI 11) V41"Urvis"i
41tv low 37H 1PI 4M3' RIM., K X
Or C',
Tbiscak-a.axwnwsthal the
tNasl. at wombinalke of Oil an a Elan oul"T Is 1.3 X.
I"-polar tin./w. (d , CA. 411, 1414M). From the
wtvit" OAPM, The aftlit. of Ow rtwilms 4111 4 C(I
i~rfulAu

1. ATW-AKOP L. I. W"RENTSOP R. V.
2. ussR (6oo)
4. O.Vgen
7. Reactions of ovgen atons wIth :!omic and acotic aldo)Wdes.
Zhur. fiz.
khIm. 26 no. 8, 1952
q. Monthly List of Russian Accessions, Library of Congress,
Trinunry 953. Unclassified.

ma'Llla
llvc OIL
-. ~,
c"l)") at.
-4( IP I ; c 1 47, Q~U-qlwo
stli" of exptil. were mad to file rtacti, in Of 1 t. 0 with
Wont. In the first i-rti" t 0 Nvas oltailij, from 1~he
41,~.qmjpn. of HjO vapors, atift fit tilt next wrics t1it
react-on
t(x'j: PJJJCC J'jth #QSej fn~nn tile! decollipp. CI DID) 0 (0 and
(h!. The ~esctson ptodwts were tile same tit i~th ecries
ew!pt that Vitre was a differenct In the r1ttioo11orma)(1c-.
h)jle to acetaldrhyde; the ratio w-as yatirb I Igher Its the 11M
WAA. IA reaction tnechunkin was prolmied, aild
~tLyAt ions were corifirmed. y La ~~e a

'USSR/Chemistry - Reaction Kinetics 11
1-ug 53
ItElemental ReactLons of Atomic Oxygen
with
M ethane," L. 16ASWM&2 and R. V.
Kolesnil:ova
"doe
I
DAN SSSR, Vol 91, No 1, PP 107-109
Studied the reaction between 0 and CH4
using t6
method previously emplov!d in other
work. Ret.ults
indicate that the degree cf conversion
achieved
did not exceed teat indicated by other
workeru
fw-euterj, although data pertaining to
flamelcas
combustion were included. MeOB' was
found in the
reaction products inilicating that it
forms as a
result of the interattion of 0 and CH),
and is
converted to CH,) On the basis or this
data,
it was difficuN ,to ascertain whicl!k of
two poi-
sible reactions (primary or secondary)
forminE;
C1120 takes place. Presented by A toad
N. N.
Semenov 4 May 53. Z46rfe

USSR
Antnw of the sfAuence (ot the
-1216.w reacd ma 01 Mot 1 41 111AICIII;
(itokoland R. 1 .4.1
92 . 3 cf. following abstr.-Tba
of I it v re 61" of t nd ad,cals Is
lh=i',".'l I )r the etiZ 171413~-Ilith IIII&I.
Ckneraliteil k'il
nt Jc cqw~tlons are %tt u the for-
Wile] of primary,, mkwdary, tte. producti. P'll-k method
developed theorrWally it Applibd to es ptl- data and found 4
to be in good screcruent. J. Rovtar Lm~o

AV 0
112 referencremi. UnIjus features of oxliii~;j Ge Parii;"
l
Imtorbms in Ma%plisse, A. N. nsoft2!~Juw 4,-
j,Ch-rtkcw. I 1 1-8; ef 104 0141-$% rerww
mm9diAte Oct: IOU UhjtCmjAr;
bULAM~~ Petroleum, F It ll;tdd'
x311. .. hycilocarbWo of witrious structore in
V"
-Wmv. luex hAist, kj, lvativy. Mid. tq the
e
-io-in (be e Owing lWtvvtl's ArTfully mirwo.- heplant 2-hydtQ----
'r4l
at t m Nloscvw All-Vhkm rit"ting cm 14 411 May 14-51, m C, pcroxide,
th.. Vq', Wr 1.4305, d. U)072. A - (xr -
iurj,ew%e in the use of petrt)JeHill ill th,-t-icki iljjjjt% "M "O/d
101 - M.434' Af RD 37.11,8; 2-iatthylhetu-ne 2-hydm-
Rdir-.mated. A brief suntrit niveii N the tl~ im- 1,croxi(le, br,, 2
1 W~ 1-4270, dw 0-MG4. MRn 37-91;-
meris fo thI3 field in th-t la-,L 10 yeArs.
',2,4-triMetb)rl_l.tKtltAll.lle b~ft 31%
Davii1opment in ths tbmry of tWn nxidatim o! lwydrocar- ~7n. 73%
h)drvpcm%idc, in. -2o', R.", 1.45n,
bm o. N. 14 n INd. 'IfR. M
11-1 - it. 1,018, - .1k); I-OtYkyclohciane 1-hydr,pimoxide,.
rtvi* topics VISLq SA-Pol., ditectre n'00 1.4648. 0S. UAKIM, A
F-5-4. MPD 40-45; 1
w 9 be 48 :14
it
tim 1>1tween two taturatNi hydrocarDi7m; 1( halo Itingth it d. pro I
)-clitpaitaine I h)dropertyxide. 1h4,%: 34.5% nV
'actifily offee radicals: tfftct of bltadka~ on the eh 11 , ~G, 11-,
6 hidw% 4-hydroWr.
ordpagrafto competilkni betwern Ilm chitia resalon a d oxi,je, t4.1
761; I-nlethyl-l i2 3,4-tt-tra dirmajilitbaleme
Itaction among the mols.; brujorhing of cha a I-tAVdWjX9OXidf. 41
W-IN , nV 1-5148i it% 1.1114
And lintitingtiticlinmeta; dtvayof thainthwtiorw, f1to-rone
9-hydrivivrox;(le, in. 93*; i,4-dihydmupbtb3lcn~"
01 1*,M of &,Hl It pqraffirit; %all effccl, in :h;tirL it-actiom.
1.11 'droperoxide, W.% IW-S*. M" 1561.1 it 1 163' I'l-,
47*4 ~rnces. ~Ilechsnlsrn ofinegatire calf,11 Isis Laoxidaticia K
dip cn~vltthane 1-1vd,opero
of Z,W.40~60l.-Arcvltmr 81'. Oteftmer-%.
P~roxidelfroniautoiddAitionoigomo*
WA12 mal"Crelices. Mar UJIM"Wulmlle hydre- alloines and
cycloalkants. K. 1. lvanov, Yt
caillitil" with atainic oxygen.. . 1. Avmnm id R. V. and V. INJ~ 12
Kill
KO r1r U
nd till),*. j,rt,pcr1lc, rd 10111.;Ued and ( R1141"i , 1,
Me. MR-! Will ils revk-weil. 'If We$ t~
15 rcfmn mi products of Tetsilla. A. I.-
i1V I
cif b1drombims the prtestucti (if by& 1~romidc I at 1 1- A '
$Otniij. Ibid. 140-4.-o'rhe mccluk.
d N.'U~ r-"-1- t; . it.,
Y" MMY2 % ar -LW. F77 A HISHT oftNt fo"rmMT'K-ij A ri-iMuMil by
Rvalytinj the SutftX1d4.%!
~nccs, love itijamn of lailelatim jkm produ,:ts ill Tetralio. The
fractivnextd. ith 5% aq'j
of C44mbeled protylenit. A F. Lu %-Wkov: 11,41, 78-88. "41HIC01
colltnia"i CHO Is off 3.4-dihydro- -rillplid;0CH
'-S)Ikthc~iiolcl propyk one slid Ant ~~e LXhUtim
und tirm. (it r;ulii `4tt
met 111ily of fill, it lav jor4mitJ0.4 prryluc-tr. wttv: v
are WirkwLd. It reiNten . mothitnism lit 03it-ollion of ill vdni -
114110 - dib)-d rv- 4
114. NO-11W.-Mi rt;v1W "ilh
lion Of jt'j%~ry pyqtopttVjjG,,.,brL_I. y
* 0d

I -,~ I , It
Muslim
IN - - - -- - - -I- - ,
VIO
e Lr,
strand HNOm. 5
Ltd
H2-60~A rcvkw. it
04
uW pba#*.
I and petclOwn bils., 1~ P71m IL
~1=1. Ma. 107-74 ~.-A !"tew witb 10 tehr
Industnal t"40046 OUGAI41830n Of pehvlt%un by
'V Ttylato%
drourbons In I, d Oave, X Ts -Akil. Ibid.
TMI mum
of
V&mMn wax. P. Mot h nq V
and G. P. Ma-'~. .14 1-- . . 0 ".
t*WF7 o7
ric-AINJ ous IMM IM311 r tdol wgt I!( de.
Tbed In detail with d t. Conjit:ms
Z
for thu opth4dm YM412 are td ut lelph.
Fatty adds R4bigovich. A M.
,V0 nift-t
ences. Use of bydroxy stids fibm o1rdatim of petrollutm
bydrocarb6na at Urn-forming mateUs. 11, V.
C
flu AFM from 0"lation of to id and Iijuld peuelcurn frac.
tions am extensively dtvn~wd it W the prcpn. of vati'Uhts
on labmtory mid plAnt mdu 6 ttvitvo~l. A
MIN W-1 14,

V
ARY MIM" ~M AL111 d---
Irv V
D Cal
t"' 13 40V
i,
~ V, -,-- A

VIA
L, A* Itt
al
W-MAIIJ Sp"
O-entilivs 0' proo"tJ
bigb viAIMIC IA" Into 111v leak-tian
i
s dm
vir:V0 "~-PLAI%lint Use I t yIw (COIS, C1116, Qr
by
13:01M was the mt :Ay or t
ho widy of
61
hb
t~qjl-t J.A pIuv41v thg'ti d sualcrIA ubkh PM
1) ;ts nu ripwitaln It. Tilt App.
We bvbll
V-A% W) ("iplM at, I plev ut tht pivur 4 t1le'llyd1w
tt th, -I.., ' Cutvtx of INO c(m1w. 44
("ill'onil Inti, I) Pitt, 4 t4.
t~'r il:lthd irt-Akit041
lit ~Wwtk' Tt.e 1=1 deddy q!imt 0. I-s
pa AV 0 Cllttlin~'
tilt htsher
'A-IL L441 06, lit tht
Cl I )i ilk lij~q f-fily j
CIIAt).ul Atill altAoiril"I
tht 1-4,4xviMly A mp%um I
twill 111016 c"m Is (lit Woe.
Aildillon, Oveicaj,A It il i lAtrujing 2 If d1mris wi ~h the
14 11,0, A ~10111
n
uml to Wow b9l) V-1 ves 1 0. lit tilt "Un 1A lAltw1kne"
the 1,iiv;~.ry 1hr (I vi3titnt of actoldn mul Tlh-,
rw
tl:~ xttvt cc;wu with YU* C11.0,
(nJ.i With 4' 11 psillm). rt'~'14hkav'
Y~?') (140, A01 Cit., Rva4WA, 5 t4ll. hmilvt-S
111L I'dillavy mq'q Ill bh-~~ '11M alkil Ofe Alto
Co aut$ ctl~ lift, pro 1% kiv4d3l'y prtx1v?1-c3.
C. M. gotia)411T

'Kinetics Combustion. Exploisions. Topochemistry.
Catelyi;ia. B-9
Abs Jour Referat Zhur I(him:Lya, No 6, 1957, 18553
Author L.I. AvramenkQL,R.V. Kolesnikova.
Inst,
Academy of Scienecs of USSR.
Title Ex-nerimental Determination of Succession of
Elementar
Rcactions of At= and Radicals.
Orig Pub in symposium: rsepnyye reaktsii okialeniya
tiglevodoro-
div v gazovoy fize. M., AN SSSR, 1955, -167-209
.0
Abstract A more dutail,~,". report on work published
earUer
(Kh!-Uin, 1956) 61c,54).
Card 1/1 - 226 -

AVU42KO.L.I.: XOIWNIXM.L.R.V.
1;-'. - . , '~' ~6"ical,determination of the
Initial concentution of oxrgen
atoms In a stress. Zhur.fis.khta. 29 no.3039-341
Kr 155,
(MIRA 8:?)
1. Akadmiya nauk SIM, lustitut Watchoskoy fialki,
Nosoov.
(Ox7gen)

'V
US3R/Kinetice Combuation. Explosionb. Topochemistry.
1,'atalysis. B-9
Ats Jour Referat Zhw~ - 'Khimiya, No 6) 1957, 16554
Ai.thor L.I. Avrameako,-B.V. Kolessikova.
Title -VE _fhe _MecNEi_ei_ of Hydrogen Peroxide Formation
from
Atoms and Badicals.
Orig Pub Zh. fiz. khtmil, 1956) 30, no 4) 763-768
Abstract The dependenceof the amount of H202 forming from
the
discharge products in water vapor on tho distance between
the discharge and the trap was measured. The total con
centrationof the radical OH was determined spectroscop;_
cally. Cc)mpa:ring the amount of 3202 foand
experimenta."Lly
with the umount which could be expected, if it were pro-
duced of Q'i, the authors arrive to the conclusion that OH
could not be responsible for the formation of HpOs. The
formation of R 0 from 0 atoms and H 0 molecules on trap
walls cooled w2itg liquid air was obagrited, and it was
shown that H:?Oo was formed in the same way from gases
Card 1/2 227 -

AUTHORS: __AYz&=1k0, L. 1. 'Colesnikovaq Re Ve 9 62-58-3-3/30
Postnikov, L. Me
TITLEs A New Idethod for the Determinatiom of tha Velocity
Constants
of the Elementary Reactions of AtDms and Radioals (Novyy
metod Dpre!deleniya konstant skoroste*lement&rnykh reaktsiY
atomov i radikalov)
PERIODICALt Izvestiya Akademii, Hauk. SSSR Otdeleniye
Khimiohaskikh Nauk,
1958, Rr !i, pp. 277-284 (USSA)
ABSTRACT: The authors suggested a new method for the
determination of
the above-.mentioned velocity constants which was worked out
by them. This method avoids many a difficulty connected with
the measurement of the absolute concentration of the atoms.
The reaction of the oxargen-atom with different molecules
serves as example. All processes which.take place in the ex-
periment are ochem&tically represented (see soheme pp. 277
and 273)- By means of the sugGeated method of measurement the
summary volocity constant (in this case for the oxygen atom)
can be determined. This also applies to the velocity con-
Card 1/2 stante of individual primary elementary reactions.
It is

A New Method for the Determination of the Velocity
Constant* of
the Elementary Reaot:.onsi of Atoms and Radicals
62-58-3-3/30
pointeiL out that all conclusions are only valid in the
case
of sufficiently high AO-values (init-al concentration of
the
initial. substance) in comparison irith (O)0 (initial
concen-
tratiort of the oxygen atoms). On the basis of the
described
method (see formulan 1-16) the velocity oonateinte of the
elementary reactions of the oxygen atoms with molecules
such
as CO, CH 40'f CH 011 were determined. Moreover the
velocity
oonetarts Re reactions of the radicals CH and C2Hq with
the oxygen molecule were obtained. There are 13
referefices,
4 of which are Soviet.
ASSOCIATION: Institut khimiaheskoy fiziki Akademii nauk
SSSR
(Institate for Chemical PhysicsPAS USSR)
SUBMITTEDi January 21, 1957
Card 2/2

AUTHORS: Aj~ramer,~o, L. I., Kolesnikova, R. V.
SOV/62-58-10-5/25
TITLEt Reacticna of Free Ethyl Radicals lith Molecular Oxygon
(Reaktrii svobodnykh etillnykh radikalov s molakulyarnym
kislorc doir.)
PERIODICALs Izvosti.ya Akademii nauk SSSR. Otdeleniye
khimicheskikh nauk-1
1958, fir 10, pp 1192-1198 (USS11)
ABSTRACTz The defioienoy in most of the pape!rs previously
published
concerning reactions of aliphatic radicals with oxygen is
that the problem of the subsequent order of the formation
of reat.-tion products is not explained. The authors of the
pre8en-, puper chose another way to explain the, problem
concernir4; the reactions of the ethyl radicale; withmolecular
oxygen., They attempted to determine the primary products of
the interikotion of the ethyl radiual. with the oxygen
molecule.
In the experiments carried out tho authors suc!ceeded in
produc:lng ethyl radicals by the aotion of hydrogen atoms on
ethylene. The products of this reaction of th(i ethyl radical
with molecular oxygen (at tempora~tures of 100-3000 C) are
Card 1/2 either ethylene monoxide or aceta:Ldehyde and
hydrogen peroxide.

Reactions of Free Ethyl Ralicals With Molecular
SOV/62-58-10-5/25
Oxygen
The course of the eaction (C2H5+O-2 ) is to a high degree
influeni,.ed by thp surface state of the reaction vessel. The
formation of ethylene )):ide in the interaction of the ethyl
radical and the oxygen molecule takes place at the walls of
the reaoticin vessel, prepared in a corresponding way. The
interaction of the ethyl. radical w:;'th the oxygen molecule
neither directly nor by way of the intermediate reactions
leads to the0 formation of the formaldehyde (at temperatures
of up to 300 C). There are 5 figures, I table, and
8 refercnees, 3 of which are Soviet,.
ASSOCIATION: Institut khimicheskoy fiziki Akademii nauk SSSR
(Institute of Chemical Physics of the Academy of Sciences
USSR).
5UB11ITTEDt April 18, 1-957
Card 2/2

0
5(4)

AUTHORS:
Ayrarienho, L. 1. , Kolorqni~ova, it. V.
...
............
TITLE:
The Mcclaiiium of Forration of 11
in the Reaction
0 tind 1100

2
2
of Jlydrcgur Atoms With OxyCen Molecules' (0 :-,ickhani-me

obrazovnniya 11
0 1 11,0
pri rea!:t3ii atomov vudDroda a

2
2
molekuloy kinlorotla)~
PERIODICAL:
Zhurnal fi~:icheskoy
khinii, 1956, V~)l 32, Nr 12,

pp 2700 - 2706 (USSR)
ABSTRACT:
The reinAts obtained by other authors are given (Refs 1 to

7). They point to the f,.-.,ct that the formation of' water
takes

place in th,~ interior of the reaction vessel, wh.ile
hydro-

,;~en peroxide forms on the refrii.,erated riall of
the receivin6

vessel. The contradictions to be found in
previoiis papers

are prob~.bly due to differences in the
rnirface finish of

the vialle of reaction vessels. To
establish this more

clearly, hy~~rogen atomn forned in the
high-tension dis-

char.-c tube were made to react vith
molecular oxygen at

low pre8nurc (6 rim He,). The receiving
vessel was cooled

by liquid nitrogen. The wall of the
reaction ve;~-sel hA
Card 1/4
been pretreated with 'he
r.-action praducts of electric

The Mechanism of For-uttion of It 20 and H 202 in the
SOV/76-32-12-19/32
Reaction of Hydroeen Aorin With Oxygen l."Olocules
diitcharj~a In hydrogen ;itmonphoro. The absolute (ttom
concentration of hydroj-,eri was measmed by th(, he~ttinj;
of
a platinum wire or by bindlinj ~,Ath ethylo:.v. The tests
confirned the actumption that the '.;ator is forned in
the interior of tho roitotion veosel, and also that the
wall acts its actu,-Aor. It follows th:it the finish of the
WIL11 31irfacc also determines tho yieli. The tests further-
more confirned the opinion that the hydro,7en peroxide
in formed on the cooled wall of the receiving vessel. By
the additicii of ethylene aldehydes nre forned. If ethylene
is arlded to the mixturc of 11 a id 0 aldehydes form
generously, while an eth3,1ene--;iy(; 2'
.ro~en mixture to which
oxygen io added han t lower aldehyd~ yield and produces
no formaLdehyde. 'If the wall of the reaction vessel is
pretreatDo with the dischar.~.:o produ~.,ts of the arc in
water VaDor (and not in hydrogen), much less hydrogen
poroxile is produced, and by the addition of ethylene the
aldehyde yield is lower and no form:i1dehyde produced.
The inve;)tiCation proves that a chain reaction with atomic
Card 2/4 oxygen t~tkun place, for which tt~e 11ghting in
the vessel

The Mechanism of Fornation of R 2 C1 a n d if202in the
'JOV/76-32-12-19/32
Reaction of Hydrogen Atoms With Oxygen 901.1cillea
(such as It is found in the case of atomic oxygen and
hydrocarb-)ns) is yet another proof. The following
reacti-)n procesn has been entabli:31ied,:
H + 0 2 + wall -4 011 + 0 + vral 1
'~1120
011 + 112--) H 20 + H; 0 + If 2\10H + R
No molecular oxyEen pnrticipates in the formation of H 202-
Bore, the reaction is as follows:
0 + 1120 4 cooled surface -4 R 20 2 + cooled surface*
It %yac proved also by S. 11. Fonor and R. L. Hudson (Hof 6)
that this is not the case of a binding of two OH-groups.
Aondealcian 11. N. So~i!vnov was very holpful with hin
advice. There are 3 tables and 15 ref-roncon, 5 of which
are Scviet.
Card 3/4

The Mechanism of Fornation of 11 21) and 11202In the
"30V/76-32-12-19/32
Reaction of Hydrogen Atoms With Oxygen Molecules
ASSOCTATION: Akadem%ya nauk SSSH (Academy of Sciences,
USSR) Inatitut
khimicheshoy fi-.ik:[,,Mockva ( Cliem!.co-Physical
Institute,
klo scow I
SUBMITTED: Jan"ar.,t 30, 1957
Card 4/4

5W

AUTHORS:
Avramenkoj Lo 1*9 Kolesnikovap R. V.
SOV162-59-4-33142
TITLE:
On the Reaction of Atomic Hydrogen
W!3h Ethylene (0 reaktaii

atomnogo rodoroda a otilenom)
PERIODICAL:
IzveBtiy& Akidemii nauk SSSR. Otdelenftye
khimicheskikh nauk,

1959, Nr 4, pp 746-7-18 (USSR)
ALSTRACT:
Thin brief communication describes Vic investigation of the

reaction 11 + C211 4' The investigation was carried out by
the

discharge tube method on a plant desoribed in reference
15-

Two characteristic results which werD determined in the
ana-

lysis of the reaction products in two experimental
series

with different jet speed are shown in percentages in
table 1.

Hence it appeare that there in always leas butane
than ethane

and propane formation. The ratio ethane-butane
increases with

a higher jrfl. speed. The measurements of the
concentration of

hydrogen atoms (without ethylene addition)
showed that the

initial coni.,entration of H atoms ranks 2
orders higher than

the concont:ration of' the ethylene
ra.dicals (with ethylene

addition). :Renee it may be
concluded. that ethane is formed
Card 1/3
without the ethyl
rrtdicals containe4. in tho volume. Thus

On the Reaction of Atomic Itirdrogen With Ethylene
SO'V/62-59-4-33/42
only a proce(ta is possible which proceeds on the surface of
the reaction vessel. In order to check this assumption
experiments were carried out in a vessel whose walls had been
covered with ZnOCr2O,. The results are shown in table 2.
Hance it appVare tra the ratio ethane -butane changed
consider-
ably and approached the ratio obaervel in photochemical
tests.
It was found that under the conditions assumed (low pressure,
fast jet and clean vessel walls) the teaction of the hydrogen
atoms with ethylene does not take plaoe in the volume but
on the sur.race. In photochemical testn ethane is mainly
formed
during the disproportionation of the othyl radicals at a rate
pertaining to the volume process. In the discharge tubo
ethane
is mainly -,formed or the vesuol walls vith its
characteristic
rate. Por this reason the different re-sults obtained in
photochemical tests and in investigations in the discharge
tube might go back to the different mechanisms and rates of
ethane formation. The authors thank V. L. Tallroze and his
co-workers fo:~ the masts-spectrometricnl analysis. There are
2 tables and 16 references, 1 of which is Soviet.
Card. 2/3

On the Reaction of Atomic Hydrogen With Ethylene
SOV/62-59-4-33/42
ASSOCIATION: Inatitut k1limicheskoy fiziki Akademii nauk
SSSR (Institute
of Chemical'. Physics of the Academy of Sciencest USSR)
SUBMITTED: August 7t '1958
Card 3/3

5(4) BOV/62-59-9-8/40
AtITHORS -4y~ramgAka.,-I-,-I-.-,--Xolesnikova, R. V.
TITLEs Tho Reaotion Kinetics and Mechanism oX Oxygen Atoms
With Carbon
Monoxide
PERIODICAL: Izvestiya ikkaidemii nauk SSSR. Otdelen:Lye
khimicheakikh nauk,
1959, Hr 9, ilp 1562-1570 (USSR)
ABSTRACT: This _Ptiole contains a description oJI! a method
of determining
tho velocity constants for the vanishing of an atom or a
radical
during a roaction (by entering the bound state) on the forma-
tion of carb(in dioxide from carbon monoxide and oxygen. On
the
basis Of the consideration of a bimolocular spatial process
(collision of two components CO + 0 --y-00 2) with low
activat-
ing energy and a small steric factor, and also from the con-
sideration of a trimolecular process i:CO + 0 + M), a general
equation wits obtained for the velocity coefficient. In the
statistical[ consideration of the path of an O-atom in the
dis-
charge tubo, a function is found vhich expresses the
dependence
of the conoentration on the traversed path of the atom (7).
Card 1/2 This funot,~ion is aeouned to be linear
(interruption of the ex-

SOV/62-59-9-8/40
The Reaction Kinstios %nd, Mechanism of' Oxygen Atoms With
Carbon Monoxide
ponential series after the first teirm), the concentration is
determin(id at various "x" by experittent and herefrom the
veloci-
ty constant is calculated. If this Nnation cannot be assumed
to be linear, a graphic itnalysis of' the equation is made
(Pigs 100i the represented derivation is generally valid and
can be applied to any atoms and radi.cala desired. The
mentioned
functionti for CO and. 0 are represented on figures 3-5 nnd
the
results a,re discussed. It was possible to draw a conclusion
from these on the bimolecular process of the formation of CO
from CO and 0. There are 5 figures, I table and 17 referencei,
5 of which are Soviet.
ASSOCIATIONt Inatitut khimicheskoy fiziki Akademii nauk SSSR
(Institute of
Chemical Pl%ysios of the Aoademy of Sciences, USSR)
SIUBMITTED: December 11, 1957
Card 2/2

66868
Blemoutary Reaction of the formation of Oxygen
SOV/76-33-11-30/47
Atoms on the Glass Surface
products of a water vapor discharge were used. Special
experiments were made on the course of a chain reaction at
which the concontration of the hydroger. atoms was measured
according to tiro methods. It was established that the water
forms due to a chain reaction, which was also oonfi=ed by
experimente, with ethylene additions. The experiments showed
(Table 1) that the wall of the receiveir cooled with liquid
nitrogen, oauees the formation of the hydrogen peroxide,
according 'to the reaction 0 + R20 + cold surfaoe-~H 202 +
cold
surface,, :[nvestigationi) on the depen6ence of the
accumulation
rate of tho weiter and hydrogen peroxide from the rate of
addition oJ! the hydrogen showed (Table 2) that the formation
of the bydrogen peroxide docreases with a reduction of the
transformaition percentage of the oxygftn~ When ethylene was
added, i.9. at tho reaction H + 0 2+ Ul2H49 the formation of
aldshydee 1rae observed in -the reaction vessel (and not on
the
cold surfa:e) (Table 3). 'rho series of experiments in the
second reaotion unit yielded results liffering from those
Cara 2/3 obtained in the above described exporiments:
considerably ~rl

ATRAMMO, L. L I NOLASSIXOTA, R.I. -
.......
Kinetics and moobanium of the reaction between
ethyl radicals
and molecular ox7gen, 1xv.AN SSSR OtdAhimenatik
no.5:806-611
My 160. I:MIHA 13t6)
1. Institut khIslobeeloDy fisiki Akad4nii nauk
IIISSR.
(Radicals (GhGai8t'17)) (OJW90u)

85602
S/0621'60/000/006/015/025/XX
B020/'8060
I., Ko,lean1kova,_R- V,,
AUTHORS
TITLE: Kinetics and Mechanism of Interaction of Ethyl
RaL-c-elsiWith
Molecular Oxygen. Communication 2. Dependence of Reantion
Kinetics on the Third Particle
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleni-ye
khimicheskikh nauk,
!960i No. 6, pp. 989-995
TEXT: The first part of' this artiole has given a des0ription of
method
and measurement resvIts of recombination rate constants in the
interaction
of ethyl radicals with molecular oxygen for a constant
copcontration of
the third particle. Tho present paper provides the results
.)btained for
different concentri.tiona of the third particle, It follows from
the
empirically determined dependence of the effect3ve rate constant
of the
loss of ethyl radicala on pressure (Fig. ') that the rate
constant k"
of the lose is proportional to presoure in tha region concerned.
0
Fig. 2 shows different forma of function k" - fW calculated from
0
Card 1/3

856o,,
Kinctics and Mechanism of Interaction cf
S/062/60/000/006/015/025/XX
Etkyl Radioals With Molecular Oxygen. B020/BO6O
Communication 2. Dependence of Reaction
Kini:,-tics on the Third Particle
equatlen (4) for differert ratlo.4 of the .-,onstants, where the
concentration
of the third particle (M' is exprei3sed by pressure p for T -
4210K. It
may be stated that the loss of ethyl :radical' takes ~Iace
according to a
trimollecular scheme with oonstant '92, whose value has been
determined at
about 3.10-28 cm6.sqo*', and which holds for the case of the
third particle
bein
,,.g a H molecj1e. Fig. 3 shows the empirical dependence of the
quantity
I/k. on 1/pH 2 for the reoomtAnation of ethyl radicals, while
Fig- 4
illustrates the empirioa't deipendertca of the effective rate
constant of the
rec.ction of the ethyl rallocl. with oxygen atom on pressure.
Fig. r) shows
1/k as a funotion of 1/p for the reaction of etlayl :-adicaln
with molecular
ox.ygen. The absolute value of the rate constant of the
bimoler.~ul.ar reaction
in the formation of the high energy C, H 0 4 radical frem C211S
and an 02
2 5 2
molecule was determined all :K1, _ ,-.-;o 12 and the k4/k; -ratio
,~,f the decomposition rafe of the radical corcerned versul the
stabilization
rate of the high-energy peroxide radioal was deternined at
2.10-'7 cm*3,
Card 2/3

86410
S/06 60/000/011/002/01(,
A B01 3YB078
AUTHORS: Avramerko, L. I., Postnikov, L. M.
TITLE: Kineticis w%d Mechanism of the Interaction of kethyl
Radicals WLth Molecular Oxygen-
PERIODICAL: Izvest!.ya kkademii nauk SSSR. Otdcleniye
khimichaskikh
nau1c, * 960, No. 11 , pp. 1921 - 19'9:9
TEXT: A study has boen made of the reaction mechanism of
methyl radi-
cals with molecular oxygen it pressures ranging between
0-5-3-5 mm H9
and at temperatures of 1000 - 450OK- k special cystem was
uaed making it
possible to uppress side reactions (Fig.1) (Iijtht effect in
photoo'hemi-
cal reaction:). The main characteristic of the vyetem is
thei circumstance
that the production tiourae of'CH 3 radicals (place of the
thfirmal dis-
sociation of acetone) is separated from the reaotion zone of
CH 3 and 02
by a nozzle. It was observed that of the two
oxrgen-containing reaction
products - methyl hy1roperoxide and carbon diox:Lde - the
former is the
chief product. The carbcn dioxide amounted to -50% of the
anount of
Card 1/3

86478
Kinetics and MechaniEm of the Interaction of
S/062/60/000/01/002/016
Methyl Radicals With Mol,?cular Oxygen B0130078
methyl hydroperoxide. Formaldehyde could not be found.at
higher tempera-
tures either. Apart from the qualitative investigation of
the reaction
direction, it was alco possible to measure the rate
constants of primary
elementary reactions on the mentioned system. Fcr this
purpose, the au-
thors' own method (R(!f.10) was applied: on the tasis of
an assumed ~re-
action scheme, the effective rate constant of the
reaction of methyl
radicals with oxygen molecules can be determined by
measuring formation
of methyl hydroperoxide (Fig.2). The primary character of
methyl hydro-
peroxide ensures a linear relationship between the
reciprocal end value
of the hydraperoxide concentration and the reciprocal
initial value of
the oxygen concentraiion (Fig-3)- On the strenj;th of the
data obtained
it is also possible to determine the absolute value of
the rate constant
of the "quadratic decomposition" (kvadratichnaya gibelf)
of methyl radi-
cals k"'. The deterodnation took place by the method
described in
Ref.110(Fig-4). The results are in good agreement with
results obtained
by other authors (Table 1). Experiments were conducted at
temperatures
of 2000 and at 300 OK (Table 2). The curves obtained in
this connection
resemble those of Figs. 2-4. It was observed ths.t the
reaction of the
methyl radical with ;he oxygen proceeds practice,lly
without activation
Card 2/3

37-7,.~'00
80094
S/020/60/131 /C6/39/071
B0041BOO7
AUTHORS: Avramenkot L. 1.11 Xolennikova, R. V.
TITLE: Reaction of the Teopropyl RafteallWith the Oxygen Moloculo
PERIODICIL: Doklady kkadfixii nauk SSSR9 19609 Vol. 131, No- 6P
YP- 1370 - 1372
TEXT: The authors set theaselvea the task of investipting the
reaction mentioned
in tbe title under conditii)ne 'which excluded every
side-resotion of hydrogen used
for the preparation of tha isiopropyl radical with oxygen. This
mothod was already
employed in the investigatLon of the reaction of the iothyl
radical. with molecular
oxygon (Refs 2,3). Molecular hydrogen iras decom osed Into atoms
b,,r electric dis-
charge, and was caused to react with ~i:opyleneiThrough a nozzle
'the zone of the
reaction H + C 3H6 ----) teopropyl was separated from oxidation
of the isopropyl
radicals carried out at 1,r,OoC and 8 torr by means of 0 24
Preliminary experiments
had shown that in the oxidation zone (2 om behind the. nozzle)
no 9-atoms existed.
The oxidation products we).,e collected in a vensel cooled with
liquid nitrogen,
and then analyzed. The pe:roxide was polarographically analyzed
&e, well as by
means of titration of the separated I, after the add4tion of XI.
Acetone was
Card 1/2

80094
Reaatiob of the Isopropyl Rudical With the Oxygen
S/020/60/131/06/39/071
Molecule B(104/BOO7
determined by means of the ftrfurol method. Iaopropyl ilcohollwas
qualitatively
detected by means of m-nitrobenzaldshy4e.. An analysis for
aldshydes was made
polarographioally. As shown by table 1,, peroxide, acetone, and
isopropylalcohol
were found, whereas analyeiii for aldehyd,es was unsucceiieful.
On the assumption
that the reaction temperature for the formation of aldithydes was
too low, ex-
periments were untertaken, in which tho oxidation zone of 1500C
wag followed byLIK
a second reaction zone of 3!iOoC. As shown by table 2, the
peroxide yield do-
creased, and no more isopropyl alcohol formed, whereas the
acetone yield do-
creased only slightly. Also in this case a formation of aldehydes
could not be
detected. Herefrom the authors conoludo that at 3500C the
peroxide radical again
decomposes into isopropyl and C1 20 The acetone probably forms on
the surface of
the reactor veasel, which iv ccvered with KC1. There are 2 tables
and 6 ref-
erencea, 4 of which are Soviet.
ASSOCIATION: Institut khimicheskoy fiziki Akademii natik SSSR
(Institute of
Chemical Phys.ce of the Academy of Sciences, USS )-,
PRESENTED; October 269 1(1159p by V~ H. Kondratlyev, J,cademloian
SUBMITTED: October 20, 1959
Card 2/2

T
,-, A! KOLESNIKOVA R.V.
Kinetics and macbentsm of the reaction of the CH20H
radical with the
02 molecule. Izv.XN SSSR Otd.khim.nauk no.4.091.398 Ap
161.
(WRA 14t4)
I* Institut kbimiohoiskoy fisiki AN SSSR,
(Oxygen) (Radicals (Chouistry))

ILVRAMMOO L.I.; KOLESNIKOVA, R.V,; KUZNETSOVA, N.L.
Rate constant and mtobanism of the reaction of oxygen
atoma with
nethyl alcohol, Izv*AN SSSR Otd.khim.nauk no.4s599-603
kp 161.
(MMA 144)
1, Inatitut khim.4.cheakoy fiziki AN SSSR..
(Oqgeri) (Hothanol)

AVRAMENKO, L.I.; KOLESNIAOUS R.V.; SOROKINA, M.F,
Rate constant and the mechanism of reaction between oxygen
atomm
and acetaldehyde. Izv*A.N SS3R,Otdakhimonauk
no.611005-1010 JJO 1610
(MM 14:6)
Is Institut khWcheskoy fisiki M SS-IR.
(Acetaldebolde) (oxygen) (Chemi%;al reaction.. Rate of)

IAVRAMK9,._L,-I,.; KOLESNIKOVAO R.V.
Photochemical investigation of the mechanism of
reaction
between oxygen atonui land acetuldehyde. Izv. AN
SSSR.
Otd.khim.nauk no.7:1"L231-1234 Jl 161. (MIRA 14:7)
1. Inatitut khtnicheskoy fiziki AN SSSR.
(Oxygen) (Acotaldehyde) (Photochemistry)

AVR;Y,ENRO, L.I.; KCIIESUKOVA, R.V.-, t.UZNETWVA, N.L.
Rate constant ind mtchani.sm Df interaction t-~tvepn
oVgpn aLons arf-I
112-dichloroettane. ISv. AN SSSR. Otd.kMm.-iaO,
no.9-151;jr-1571
S 161. (141RA 14:9)
1. Institut khi.micheskoy riziki MI SSI.R.
(Et'liane) (Oxygen)

1 3.8
1

3
06!?/61/000/011/005/012
B101/B147
14 1,2%2,o

AUTHORSt
Avramenko.-L.-
. . . ..........I
_I._, and Koleanikova
, H. V.
TITLEi
Determination
of the rates of ele
mentary reactions of

hydrogen
al;oma. Communication 1.

Cor,stant of the recombina-

tion rate 11
4.
H + H2 _1P 2H2, and
constant of the reaction

rate H + 0.2 +
H2 -
HOI? + H2

PERIODICALi
Akademiya nauk 663R. Izvestiya.

Otdialaniye
khim.-.choskikh

nauk, no. 11,
1961, 1971-1976

TEXT i It wis the purpoEe of the present pnper to determine
oxa.-tly the
reaction convt~int in ternary collioions 11 ~ 0 2 + H2' So far,
the valu,2s
determinod by othor sciontists have differed by twc, orders of
ma~lnitude.
The method of meauuring thl? constant has already btien
published by the
authors (Ref. 7. Izv. V SSSR. Otd. khim. n., 1958, 277). The
device of
Fig. 1 was used for the experiments. Atomic hydrogen was
obtained in an
ozonizer tube (5) whose voltage Ras increased by a transformer
to 40,000 V
C'.1rd

29518
.Uetermination of the ratc,a of... B101/B147
To obtain n great number of H atome in reaction vessel (7),
the kr:all of
no-,-,zle (6) vas coated with phosphoric acid. The reaction
vessel was 20 mm i-n
diameter and 1.2 m long. Valve (2) was similar to valves of
Aqualungs
used by divers, and guarunzeed a constant pressure cf
electrolytic h2
leaving cylinder (1). The apparatus was evacuated ty an oil
forepump;
PH of the reaction vessel. wits 60 mn Eg, and the rate w of
the H stream was
90 m/sec. The experiments vrere conducted at room temperature.
Liquid N 2
wait used for cooling reo(iiver (10). Resultst (1) B20 2could
not be
tiltrimetrically detected in 10 without 0, additions. (2) With
0 additions,
6 2 2
(6-7)'10- M H 202 was til;rimietrica'Lly detected in 10. (3)
40 mm behind the
nozzle H 202formation is completed. Greatter length of the
reaction vessel
no longer affects the H202 yield. (4) H 202 does not form at
lower
prossures (10 mm). Hence, it is concluded thats (A.) H 202
formation is
indepondont of the length of tho cold wall and, thereforop
takea place in
Card 2/4 '

29511/0621161/000/011/()05/012
3
Determination of the rates of... B101/3147
the! bulk. (B) A third particle te.~:cs part in H202
fDrmation. The reaction,
therefore, necessarily follows the v ation H + 02 + H 2 __*
HO2+ H2' In
oxporimente with a cooled, receive, --aced only 40 am off
the nozzle, the
asymmetric epr spectrum of the H02 reAic&.1 could be taken
in the frozen
condensate. Its g factor hardly differs from that of
diphenyl picryl
hydrazyl. The total signal width is 23-26 oe. Wher, the
condensate is
thawed, the signal disappears. With a greater diste.nce
between nozzle and
receiver, H02k would not be detected. The reactions
H + 02 + H2 H02 + H2 (1 )! H02 + H02 --w H202 + 0 2 (2)1 V\
k"'
H + H + H2 Z" 2H2 (3) are written down. Reaction (2) in very
vigorous.
The method pub ished in Ref. 7 was used for determiming k.
The final
concentration tH2021f is expressed by [H2021f - L0210 -
L021fl where t0210
in the initial oxygen acnoontration. Since 0,1 and woro
constent
IH2 to 2)
Card

29518 5/062161/000/011/005/012
Determination of the rates of... B101/B147
under experimental conditions, the equation k1rk
Lk/ (k-km) [0 [ k/ (k-k'")) [ 02] 01 (1 0
H 21o_ 1H2021f)+(1H1o_ H - IH2021 f / 1021c)
is obtained. (1 - 1H 202*1f/10 Jo )k;/k is exapnded iri a
series, the first
two membors of which are used: 1/1H 202]f - 1/[H)0 - kTA
1021o (9). This
linear equation givess k - k,111/tanoL (10). Hence, 'the
determination of
I
kB is necessary. It was conducted by a method deactibed by 09
authors
LA/
(Izv. AN SSSR, Otd. Ichim. n. 1959, 1562). The experimental
data yieldedt
k"I[H)o W w tanp/[H (13). It was found: k-'[H]o - 9-10- 19
CM5/aec-molecule.
H - H
Hence, k"1- 5-2-102L Cal 6. e;ec- 1. molecules2is obtained
for an Initial
concentration CHI, as 1.12,1013 moleoulea/CM3, which is in
good agreement
with data obtained by other scientists. k a 1.2-10-33 cm 6-cm
-1 -molecules -2
in obtained from Eq. (10). This value is in good tgreement
with that given
by A. B. Nalbandyan, V. V. VoyevodskJy (Mekhanizm cikisleniya
I goreniya
Card 4/0 :j'

0
91)
2
S/062'61/000/011/005/012
Determination of the rates of... BIOI YB147
vodoroda. (Mechanism of hydrogen' oxidat ion and burning),
Izd. AN SSSR, 1949).
The authors thank Go A. Kapralova for taking the epr
spectra. There are
4 figures, I table, and 10 referencea: 4 Soviet and 6
noh-Soviet. The
two mont rveent referetinea to Engl ish- language
publientions read sit
follo-v!.: J. Alodur, J. Amer. Chem. Soo., 60p 2347 (1930)1
So No Forier,
R. L. Hudson, J. Chem. 11hys., LI, 1608 (1 95 3) 1 R, 1974
(1955).
AS'SOCIATION: Inetitut khimIcheskoy fiziki Akademii nauk
SSSR (Inst.itutb
of Chemioal Physics of the Acadomy of Scl.ences USSR)
SUBMITTED: June 15, 1961
Fie. 1. Diagram of apparattis. M Cylinder with hydragenj
(2) epcoial
valvej (3) tube with CaC1 21 (4 (9), and (11) tapal (,I)
ozonizer tubel
(6) nozzle; (7) reaction ve,3se.Li (8) manometer; (10)
rcceiverl (12)
calibrated vessel for 02; (13) gas meter for 02; (14)
transformer.
Ca r d 5

AVRAMETIKO', L.I.; KDIXSlv-':KOI', 1I.V.
Detection of 1102 radicals by means of olectron
parpnagnetic
rosonance. Dokl. U SSSR 140 no.5LI100-1101 0 161.
(MIRA 15:2)
1. Institut khiuLicheakoy Miki All SSSII.
Pre,Jutavleno
akademikon V.N.Kcmdratlyevym.
(Radicals(Chemintry)-Spectra)

AVRkMNKO, L.I.; KOLESVINVA, R.V.; KUZNETSOVAp N.L.
Rate constant of the reaction of oxygen atau with
amonia.
Izv.AN SSSR.Utd.khim.nauk no.6:983-989 162. (MRA 15t8)
1. Inatitut khimicheskoy fizikI AN SSSRs
(Oxygen) (Ammonia) (Chemical reaction, Rate of)

h2651
S/062/,52/000/011/016/021
B117/B101
AU THC RS: jLyzamaak&. Buben, 41. Ya. , Kolesni:cova, R. V. ,
Tolkachev, V. A., and Chkheidze, 1. 1.
TITLE; EFR study of radicals formed by hydrogen atoms reacting
with
benzene
P-'-'RIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniyo
khimiAeakikh
nauk, no. 11, 1!)62, 2079-2081 * '
TEXT: The authors analyzoe. tl,,ie epr spectra of free radicals
formod by
hydrogen atoms reactine with benzene in the gas-phase at 20 and
2000C and
frozen out with liquid nitrogen. -Experimental conditJons:
silent
14
discharge (6000 v, 150 ma), benzene concentz1ation, 6*10
molecules
per cm3; Lydrogen pressure, 14-15 mm lis; linear flow rate, 160
cm/sec;
duration, 12-18 min. The opr spectrum of the radicalo formed at
200C
Vy the reaction H* + C 6H6 :'Ls a triplet with a total
splitting of 93 i 5 00-
In addition each component of the triplet is split in".o four
lines at a
distance of 10 + 1 oe. This spectrum was identified as the
spectrum of
Card. 112

S/0062/62/000/01 1/0161021
EPR study of radicals formed... B11"0101
the C6H~ radical. Vhen the reaction temperature io raised up to
2000C,
not only the C6 radicalis formed, but also radicals of another
type -
obviously C6 H~ which show a singlet. Their relative azount
increases
as the temperature is raised. Hence the two primary reaotions
may occur
between hydrogen atoms and a 'benzene molecule-..
H* + C6H6 1;1C(;Ii~ M
% H2 + C6H; (2)
it is assumed thut at room teaperature reaction W mainly occurs
and at
higher temperatures reaction (2) takes place. The weak lines
detected on
the edges of all spectra were attributed to the background, of
which the
spectrui--i analysis took no account and which therefore
reqUires a separate
investij.:ution. There are 2 figu;res.
ASSOCIA'.'ION; institut khimichBskoy fiziki Akademii nauk SSSR
(Institute of
Chemicnl Physics ol! the Academy of Sciences USSR)
SUB~',I"MZ: June 15, 1962
Card 21".

5/062/63/000/001/0005/025
BI 01 /B1 66
AUTHORS: KoloBnikova, R. V., and Savinoval G. I.
TITLE: Rate constants and mechanism of the reaction of oxygen
atoms with ethylene, propylene, aad isobutylene
PERIODICAL: Akademiya nauk SSSR- Izvestiya. Ctdeleniye
khimichee;kikh nauk, no. 1,. 1963, ~6-45
MXT: A continuous vacuun apparatus was used for studying the reaction
of
C211 4' C3H6 and '-C411b 'With atomic oxyj;en produced by high voltage
c1tscharge in pure 02* Tho reaction products were condensed with
liquid
nitrogen and analyzed. Inflammation of the reaction mixture
proceeding as
chain reaction %as prevented by coverinC the wallei of the reactioil
vessel
1,7ith KC1 so that the qt4antity of the products formed corresponded
to T%at
of the 0 consumed. Based on the equations dorived previously (Izv. AN
SSSRV
Otd. khim. n. 1962, 985), the constant of the reaution rate was
determined
from the total aldehydes formed. The constant of the oxygen
consumption
was determined by moasuring tbeconcentration. of oxygen atoms, which
Card 1/4

S/C)62/63/000/001/006/025
Rate constants and mechtnism B1 C11 /B1 86
decreases alonC thu reaction vessel. Resul ts: (A) In tho
reaction with
C211 4 pthe formalJohyde component of the aldehydes formed is
80;0, at
530C and more than 90~,j at 20COC. Moreover, acetaldehyde
forms. CO and
CH20 form in equal quantities. The content of free 0 atoms
decreases -
, ;-13 3. 4
linearly along tile reaction,vessel. kC211 4 1-10 1
exp(-1350/RT)cm seo;M01-
ecules and the activatioa energy is 1350 50U cal/mole. (B) In
the
reaction with C 3116' the Cli;,O conponent of the carbonyl
compounds formed is
70,~# at 1000C, and 60-65,; at 200 0C. The second aldehyde
forming is
acetaldehyde. In additiDn acetone is formed(in a qaantity
'vl5tP, that of
tile acetaldehyde). CO forns in a lar6er quantity t.',,ian
acetaldehyde.
Consequently not onl., thi? CH , radical io oxidized to CO as
in case A, but
also tile CH CH. radical Is partially oxidized to CO.
3 -12. 3.sec-1. I
k 2.b"*io e xp ( -.5 ooo/n ) cm molecules" and the activation
G316
energy is 3000 -+ 500 cal/mole. (C) In the reaction with i-C
4118, 60 70,',-'
CLrd 2/4

3/062/63/ooo/ool/006/025
Rate constants and mechanism ... B101/B166
o:~ the carbonyl compounds .Is formaldehyde, the remainder
acetone,
Additionally, propylene fo=za ~n the same quantity as
formaldehyde, and CO
in the eame quantity as acotone. Hence, the following reaction
scheme is
derived:
C11 CH '0 + CH -CH-CII
/ / 1 ; CH + 0 CO + H + OH.
0 + CH WC 2 2
2 C 113 A C112+ CH 3- CO-CH3
The radical C(CII 3)2 is regrouped completely to propylene.
0. 3.sec_1.molOculeG_1
k.- 4-10-12 exp(-2%,550/HT%Jcm and the activation
I C4116
energy is 2550 cal/mc e. 11; was confirmed that in ~he
reaction of-atomic
oxygen with unsaturated hydrocarbons mainly the C-C double
bond is split
and that carbonyl compounds, predominantly formaldehydep form.
There
are 6 figures and 4 tablaqs The most inportant
English-language references
are: 11. W. Ford, N. Endow, J.'Chem. Phys., 27, 1277 (1957);
F. Kaufman,
j. Chem. Phys., 28, 352 (1956), L. Elias, 11. J. Schiff,
Canad. J. Chem.'
38, 1657 (1960).
Card 374

SJ'.n62/63/OQC/C01/OC6/025
Rate constants and mech,ir"I'.3cl Blol/B166
ASSOCIATION: lastitut Ichimicheskoy f zi"i Akadubraii nauk
SSSR
(:[xistil.uto of Chimical FhySics of the Academy of
Sciences
U..;STI)
SUBIMITTED: April 10, 1962
Card 4/4

r i-111r. _`11 jj WR 061-5111:M 51 q.,
L LZq~on6~_ EPF i)/Eilkq~/ViT (m_)/BDS S/062/63/000/004/004/022
AF.FTC Pr-4 RM/49/JD
AUTHOR: Avramerko, L,,X.,,~ KolesnWova, R#V., and Kutnetsova. N.L, G-
TITLEt ki;~_action ratt, constants arid the mechanism of reactions of
ox
zg Ln
atoms with m4thane and iothane
PERIODICAM Akademi:F& nauk 3 Otdoleni,
SS1. 1%vestiya -re khimienesk.,Lkh nauk#
no. 4. 1963, 620-627
TFMT: The abmAute values of -the reaction rate cDnstants '~f oxygen
atoms
wilh methane and ethare weie measured over the range 313.5830 K at
reduced
pre,ssure. The reactim adivation energies of oxygen at.=s with
mothane and
etLane equal ltp 7800 ind 5200 oal/M, and the pro-exponents equal to
3.4 . 10-13.
anel. 0.9 - 10-" re.-poAive3y wore determined. The two bksic
directions in the
interaction of oxygen atmitwith methane are: the first, the foraation
of
C& and H20; the soooDd. t1io formation of OF' 0 and H2. The basic
direction of
A, 2
tht interaction of, wqrgen titcois with rithano is the reaction
proceeding with
tht cleavage of the C.-C bond and the formation of CH200 HZ, and CH2.
There
are figure6 and 3 tatles.
ASMCIATION: Inst.3.tut ktimichefikoy ftzik~i Akademil rauk SSSR
Institute
of cherli-.vl, NLY~i~s ~,-f tho Acad,~my of Sciences USSR)
SU 1 17E 0: Jtinr. Z:,
Ceii d 1/1

L 1273h-63 EPF1'0/EWP(J)1Ewr(m)/BDS Pr-h/Pa-4 RM/WW
ICCESSION NR: 03C,02281 S/0062/63,fooo/006/09761'0980
AUTHOR: Avramenko. L. I., Koleqnilcova. R. V., Savino,E2. 0. 1.-
TITLE; The rate ecinstart and the inechanism of reaction of oxygen
vtoms with
-.n-butane
SOURCE- A~ SSSR. Izve.,itiya. Otd-Bleniye khimichesklkh nau~ no. 6,
1963, 9T6-980
ropiC TAGS- reacti,on of n-butane -with o)qrgen, formatLon of
formaldehyde and
acetaldehyde
ABSTRACT: A study hits been. mado on the measurement o t the
reaction rate constant
of oxygen atoms with n4rutane botween tojkperature IntBrvals of 40
,,o 195C for the
determination of the mapitude of utivation energy aad the
exponential Multiplier
of the speed of thci reaotion 0 P. n-C sub 4 H sup 10. The
activation energy of the
reaction rate constant iras found tD be 4100 cal/mole and the
exponiontial multiplier
value was found to be 1.3 x- 10 11uP - 11. Only a general conclusiom
can be made
concerning the reacition mechaniin between the oxygen I ms and
n-biatane. Assuming
that the main prodt,ots (if the roaction are formaldehyae nd
acetaldehyde, it is
possible to conclude thit the roaction of oxygen with nk-autane
res-alts in the rup-
ture of the c-c bord. Orig. artv. has: 3 figures, 3 tables, and 2
formulas.
hssocia~ion: Inst... of 0hemical Plysics, hcaderiq of Sciences, SSSR
Gard

KJW1&N1K,)Vt V.M.
Reactions involving nitrogen ato,-.is. Report No.l:
Certain properties
of nitrogen atni:s and thc ratu coz-.stants for the
recombination of
atoms in spe.ce and on various ourfaces.Izv. Al: !;SSR.
Ser.khim.nO.?,.
1196-1203 ZI 163. (MIRA 26:9)
1. Inatitut khimich(iskoy fJ.ziki AN SSSR.
(:Nitrogen)

AVRAKENKO, L. I.; KiLkSNENIKOV, V. 14.
Reactions of nitrogen atoms,, Report No. 2: Rate
constant and
the mechanism of the elementary reaction of
ni'trogen atoms vith
ethylene. Izir AN S51t Ser Dim no. 4:600-604 Ap 164.
(MIRA 17:5)
1. Inatitut kh1tricliciskoy f:Lziki AN SSSR.

i
a*sn~-
ana of *,Iim T.! troeeri atcmz%
rf A 7 6.

4( 2784 EWG(j)/EWr(* /EJ~ ",Wp(j)/EWp(t) V Pc_4/vr-4/N-4`
TWAIPRA..
ACCESSION KRs- APS006411 I F00/0L JD/RM S'0062/65/000/601/0028/0035
:AMDR: h7nenko.. L. I. 0101snikovai, R. V. -, Sivinova, G I
Tinc: Constants-, of the! sp~edsi of reaIction of atomic o)911~3enith
cyclohe no ,,and
~ben2ene
iSOUBM AN SSSR. lzvetltliya~ StOiya kfilmicheskaya, no. 1,i 1965,
28-35~
-ATOPIC TAGS: cyclohexanels b nzepe* cyclic hydrocarbon, oj~~ygen,
oxygen: compound,
aromatic compound
IABSIPACT: Constants of 6e I spoleds of reaction of atomic !oxygen
with !-,yclohexane
I
andwith-benzene ___ wer,a___ Melpipu~ed_!and AM -mechanism-of thes4
-reactions- w4re- examined
1, espe cially to clarif y_ 06 b o~_ha-i,lor of the --atomic
oxygenitith the-, aromaitic - and -the
The---energiiis c&.activatian _o:~_the atomin oxygen--reactiohs -with
isaturated ring
ic -benzene. werk found _to_be__4500_ and 4700 - col/M respectively.
--- 0119 -of -
yclohexane.and
ithe main directions of thes-t "ections is splitting of the ring and
formation of
redioals (aldehydea). -Drigi azt-fhasi 4 figumb-4-taWes, 7 equatims.
Card 1/2

.I- 385192:~5. JTA/ .2
ACCZI;SION NRs AP509965711 TJR/0062/65i'000/003/041)8104.12
AUTHOR: - Avramenko, L ko'va. R. V.
koiLearli Silvinovao C.,I,
TITLIk Tbe USE mi anil_t~he rate constant of oi
iygen a tom i'vith
S e. _t LI-v n-0
N%
SOURCM I A SSR* Stclrlya khtimicheskil ya, imo. 3, 196
408-412
TOPUf* TACSt acetylene, prvjpulslon, ran jell,, supersonLe.
9! ;ar' :Ithe mochant the reaction
ABSTAACTS The rate ~rlon it- and sm 0
0 + tl,%,.,)12 were studied. ati ?01-260C and 4-20 mm 11g. The
following
exprcission was obtained foll the rate constant:
3
_k~-'-2.9- lor-
~30 IM tvoc!'l-moleculi
The atomic oxygen w8 9 1-Rellellated by
b.'Igh-voltage-l'itscharge.f:rom~
mtolon-ular oxygen, -andithi). a or0aldohyde.1111yoxal.
~ 1 __2~ action products, I
c.arbon monoRide# and -hydirolleno were determined bit chanica I i3nd
-
I card., I, f2

138559-65
ACCE9~510N NR: AP5009~~i
it f
pola~ographlc analyalle At lov p:ressurs (4 ptn I ormaldehydi vat
the Only aldehyde pre0art 141le-At 20-mm Hs. botil formaldah)tde and
glyonai were formed, Tht ujost Irpiportant stop ln~'~tlie it6mic -oxygen
acet:11ens roaction is' fhe C"C bond# Oligs :rt, 6acs 12
foral'tlas and 3 figura's,
IPV)
ASSO,i."IATIOHI Inatitilt ~.ki~lv Leheal lki Akadeloll 'nauk SSSR
40Y fix
Scion!
UniFt i tu to-_-vV.Cl ht_Ml-W[j--!t by! its- A Cow-Mf
0
SUB CODIts OC-16
SUBIJITTEDI 02Apr63 ENCIL:
e[
NO ]REP SOVI 007- 002 AM, PRES s- i 3M
OT3ERs
f
Ca 1.2

L 31691-66 EWT(m)/EV1P(J)/T IJP(c) D.S/WW/JW/RM
ACC NR, AP6012522 SOURCE CODE: URI'0062/66/000/003/0417/0422
;AUTHORi A Krasnenlkov, V. M.
khimichealoy
'.IORG: institute of Chemical Physi:s, Academy of Sciences SSSR
(Institut
!fiziki Akademil nailk SSSR)
ITITLE: Reactions of nitrogen atans. Communication 4. Rato constant
and the mecha-
Inism of the elementary reaction o n trogen atoms with moleo:ular
hydrogen
i e
!SOURCE: AN SSSR. Izvestiy-a. cerk~ya khimicheskaya, no. 3, 1965,
417-422
TOPIC TAGS: hydrogen, nitrogcn, ammonia, kinetics, chemical reduction
1,ABSTFJ,CT: The purpose of thiv investigation was to elucidate the
mechanism of the re-
action. of nitrogen atoms with hydrogen molecules and to measure the
rate constant of
the elementary process on the basis of the method developed
previously by the authors
and ri.,:ported in rzv. AN WSR. Ot-d. Xhim. n. , 277 (1958). 7he
experiments were conduct-
led with vacuum flow apparatus. The walls of the reaction vessel
were coated with `7102
on which recombination of nit,',rogfin atoms takes place very ,ell
at a rate proportional
to the square of the concentr3tion of nitrogen atoms. Only the
following primary pro-
cess for the reaction of nitn3gen atoms with Ho nead be considered:
N,
N + III-Pl. Nil, + Nt + 71'keal/M
Card 1/2 UDC: 541.1214+541.127

L
F_A__C_ C__1'4_RsA_P 6-6 1-2 5'2_2 ----------
I/can
!
lead to formation of only two stable products, ammo-
Reactions of the N112 radical
nia, and hydrogen, which can be condensed in a liquid nitrogen
cooled trap. An attempt
was made here to detect these products. Hydrazine was not detected
even at 3000C re-
action temperature and 10 mm pressure in the stream. Ammonia was
found at 6 mm pres-
sure znd above and at room teriperature, A rate constant was
measured for the themo-
lecuU-.r reaction . N + *Ili + 91 --. Nil, + hi
at different temperatures and pr4issures. It was found that the
reaction of nitrogen
atoms with hydrogen proceeds with a ratw constant independfint of
temperature. The
rate constant for the mactio-a may be written as:
k a 1.10-32 cy,16.molecules-2.sec-l
10rig. art. has: 2 tables, 4 figures.
;SUB CODE: 07/ SUBM DATE: 2;30ct63/
2/2
i Card
ORIG REr: oolt/ OTH RM OOS

L U30-66 EW(m)1I"(i))1BWP(j RPL RM
P.CCESSION NRi' AP5022921i Ult/0062/65/000/008/1336/1345
5411.124 + 547.024
136
il 41, ~-~
),UTHOR: Avramanko, 1eviashkina,'L. Pj.; Koleanikova, R. V.
3/
TITLX t Reactions of the H02! radical. )Vart I. Mechanism of the
interaction qo
H02 radicals with saturaled anVOFs-itlarated hydrocarbcns and with
mothyl alcohol
SOURCE: AN SSSR. Izi%stAya. Ser.1ya khimicheakaya, no. 0, 1965,
1336-1345
TVIC TAGS: free rndcaL, reaction mechanism, hydrocarbon, Methyl
alcohol
MSTRACTs Th mechanism and prboary products of the interaction of H02
radicals
a ~ ene ?propylene, isobutylene and metbyl alcohol
with methane ethane, prop no, e~ ~ bol
am studled. The H02 radcals wore generated in situ by the
collislo-n--R-K-atoms
with 02. The ailent discharge zone vas coanected with the reaction
vessel through
a nozzle lined with phosphoric acid. The Interaction of H atoms with
02 occurred
at 60 mm Hg pressure. Die rhaction products were collected In a
liquid nit*r*gen
tamp. The duration of the actual. experiments was 20 minutes and the
total pres3uro
w,s3 60 mm Hg At 250C, naximum concentration of H02 radicals was 1.6
- 1011-1 mole-I
ciles per cP. The experime:nts were condupted at 230 and,2000C. With
saturated I --
~jdrocarbons except moth4nt, the M02 radical produces a rupture. of
C-C bond and fo~'-

-L WO-66
ACCSSSION NRi APS0229:28
mation of OH radicals and a cambonyl compound. There Lit no reaction
between H02 and
methane. Up to 2000C thers is no abstraction of H atmi frw a paraffin
molecule. i
With un3aturated hydrocarboml up to 2000C, the H02 radi,cals attack the
double bond,
with ilie resulting fo-Rat-ME-c a carbonyl compound and an alcohol
radical. With
methyl alcohol, the bra prAmar reaction products aret H202 and a Q12OH
radical.
Oric. art. has: 3 tables, 18 formulas.
ASSOCIATIONt Inxtitut khInicheakay fiziki Akademii nauk-SSSR (Institute
of Cheui-
cal Physics. Ac demy of' S4enop
a -t4j&SSR)
7
SUB14ITTEDi Mua64 ENCLi 00 Stm CODE I OC
No IMF Sovi, 007 OTHERt 000
Card 2
2
v

ACC NR- AP6032586 SOURCE CODE: UR/0062/66/000/008/1340/1343
;AUT11OR: Avramenko,
L. I.;, Koleanikova, R. V.
ORG: Institute of Chemical. Physics, Academy of Sci6ces )SSSR
(Institut khimicheskoy
.fiziki Akademii nauk SSSR)
TITLE: Formation of carbon iktcms in the gas phase and SOMC Df
their reactions
SOURCE: AN SSSR, Izvesti3ra. Seriya khimicheskaya, no. 8, 1966,
1340-1343
TOPIC TAGS: flame spectroncopy, carbon atom a electric dis
charge, carbon, water vapor
luminescence
ABSTRACT: A study has identified the species which cause the blue
luminosity
given by the reaction of C4"11. vith gaseous products from an
electric discharge
through water vapor. The experiments were carried out in a
previously described
apparatus which is usually empLoyetA -in.studies of atomic
hydrogen reactions (L. I.
Avramenko, R. V. Kolesniko,;a aiid N.'L. Kuznetsova. Izv. AN
SSSR. Otd. khim. nauk,
1962, 'j83).. Studies of the reaction of CC1. with gaseous
products of a discharge
througE water (case (CM.-watitr)) or through H2, 02, mixtul'es Of
02 + 112 + Ar con-
taininj:; 0'01%-'421 or mixtures 1)f Ar + 02 were carried out.
Studies of the effect of
0" NOI.N 0, and CO additives )n :Lumino'sity in case (CCI.-water)
were also conducted.
Spectri-, ol the luminosity prodaced in each case were recorded
and identified. It
was found that in case (CC1i,-,;jter), the luminosity is due to
the excited molecules
CH and.C20. It was shown that on1y the simultaneous presenee of
11 and 0 atoms leads
Lc-~jt UDC: 547-024+539,184.5+546-26 __j

KUDRYAVTSF,VA, K.P.; ZM:OVIITS, H.S.: ARUTYLqIOV,
I.S.; NOGAYHY, B.N.;
SPITUTH, V.'V.; JITAKINA, N.A.; U]MATNTA, G.G.;
DLATZV, X.Y.;
XR&MIX0, !~&Ljwaouvs ToKhop otv.rod.; BATKATOV, P.S..
to rA.
Cloonomy of tho Borth Ossetian A.S.S.R.; statistical
Narodnoe
khozinistvo, Severo-Osetinskoi ASSR; statistiaheskii
abornik.
Ordzhonitid,se, 1958. 130 P. (KIRA 12:10)
1. North Ousetlan A.S.S.R, Statistinhoskoye
upravleniye.
2. Nuchalltilk Ntatisticheskogo upravleniyu
Sivero-Osatinukoy
ASQ (for TSogoyev).
(.Ossetia--Statistics)

KVITNIVSKIY M.Ye. , kand.zaed.nauk; AVWI Love
I ~111 Ltev.
Allergic rea,tiona to hydrocortisone injections in the
lower
nasal conchae. 'J'hu:r,uOh., nos, i gorl. bol. 24
no.5:78-80
S-0 164. (MIRA 180)
1. Iz Nauchno-iseledovatellskogo institnta
otolaringologii
Minist-rstva zdravookhmnaniya UkrSSR (dir. -
zaal-u-zhennyy deyatell
nauki Profe, A.I.Kolomivchenko).

(v
00
ttATIAPS A
,
0 Age 12
oo io
fav
A
lox,
'4 ong So
uv
'4 o-*d Ch 04 d2
o ati
lot-
Is , '. ~ 3.
CH. I
one
0 11. 14-H
ot .l
ell N6 al
Jz

2 1. 2.100 69362
S/139/59/000/06/019/031f
B032/9114
OTHOR: Ayramenke, M,D,
--P .
T17LE: Some Z1;*5'fW1ftieh have an Effect on the-y-Radi
f rom a B,LW=-
PERIODICAL; Izvestiya vy's~slikh uchobnykh zavedeniy,
Fizikat
1959, Nr 15, PP 131-134 (USSR)
ABSTRACTs This paper was presented at the
I_jjtpr-Qn"fkLYJat'A
Conferg-nce on Accelerators (Tomsk, Yebruary 1958).
An attemptis reported increase the intensity of the
Y-radiatio.,a from a betatron using an orbital contractor
which alters the topography of the magnetic field at the
time of injection or the electrons into the accelerating
chamber of a betatron. The contractor is analogous to
that described by Adams in Ref 14. The pulsed current
enerator whieh was used to produce 2.5 amp pulses
9
-15 I't see long is shown in Fig 1. The pulsed generator
is s,,pichronised with the magnetic field of the betatron
by means of a permalloy probe whi(,,-h produces
synohronising
pulses fod into the input of the pulsed current generator.
Card The contractor is shown schematically in Fig 3 and
1/3 cons!ists of two turns of a wire fixed directly on the
accelerating chamber. It was found that the greatest

611? ~- -', ?
8/139/'59/000/06,/019/031+
B032/9114
Some Factors which have an Effect on the y-Radiation from a
Betatron
increase in the intensity of the y rad 'Lation from a
betatron is achieved when the pulsed current through the
contractor is delayed by 1 psec after the beginning of
the injection of electrons Into the ac-,.elerating chamber.
The Table on page 134 has the following headings:
Column 1 glves~ the intensity of the radiation without
the contractor in r/min.mi Column 2 gives the intensity
of radiation with the contractor included; and Column 3
gives the ratio Df these intensities. The largest
relative increase in the intensity is obtained when the
intensity *before the contractor is switched on is small.
The efficiencyo, f the contractor is found to depend on
the duration of the current pulses. The optimum duration
in the case of' the 22 MeV betatron at the Institute of
Physics of Metal;3 was found to be 8 psoc. The m imum
Increase U-iTHW-71ntensity with the contractor included
Card is obtained when the heating of the eloctron gun is
2/3 reduced by 10%. By feeding the current pulses into the
contractor coils through a coaxial cabhe the efficiency Ir

AVRAWNKO. N,,__~qpjtan
I
Without fuiih in ;mople,.# gom. Vooruah. S11 3 no.108 Ja
;r
XIA lij-:.
(OommnU,st youth league) (Military, discipline)

11 AVRAMINKO, N.D., burovoy meter
We are drilling wells under complex conditioas.
11of ti&nUr 5
no. 12:19 D 160'. (MMA 13:12)
1. Kontora burentyis No. 1 fiefteprowyelovogo
qpravlenlya
Malgobekneft'.
(MR140beii region--fti well drilling)

AVRAHINKO, N.M.
Noww"900"W.
Retention of the twith roots in the treatment of
periodontitis.
Stonatologlia 33 no,209 Mr-Ap 156. (xM 9-.8)
1. Zaved%Wus-ichiy suboprotesnym otdeleniyam
stomatologichaskoy
polikliniki lishins,ra MSSR-
(VOTA-DLULUS)

A VW[EVKO, N.M.
Dental cariesin chilihw suffoxing f-rom
tuborciCLosis of the
bones and jobits. Stmatologiia 42 no.,3'92 Mr-Ap'63
(MIRK 170)
1. Tz kostno-4metavnogo sanatoriya "Dermenzhi*
1461davskoy SSR.

OMIRA 16:4)

V58812-65- .(-j)l/MM-(t)/MT4b).- ~C-4,~Pr.4- ID/-IAJ/2U
1--ICCESSION NR-. AP501$694.~ UR/0070/65/039/006/1507/1508
AITHOR: Avramenkom. lw.v~~". A.0. Dupebova, O.hj.-
Elfl~et of expoitnentol cDaditionB on the effective dietributia2
ratio in zone
matting
S011RCE: Zhurnal fizidhiisko3~ kh'tMil, V. 39, no. 6, 1965, 16(i7-15o8
TWIC TAGS: gone M NDJKe lows refining, manoewcon COMMIMid
ABSTRACT: Zone mqltl4';w&o ca~rrletl out octOnethy1dichloro~sIlane.-
Factors-depcn..
den-4 on- the experl"A_Oondltioz~ and bhv~jfan adverse influence
ontheeffective
dist-lbution ratio 6verhoating of thc zone) were kept to a
minimum. The wlff~ of Lim zone WAS mWorm, And an Inert gav was wed
when neenssar~V.
As n result of five-zono ImsEelt, the tq),por fractlon (1/10th) of
climethyldleblorosilane
was purified .38-fold,'i. e. , untU the Impurityeontmt was 0. 035
mole %. Best results
were obtained wbon the zoac m Dltbwg was porformed in a verticia test
ttd)e; the offective
dlBtr ibution ratio was eBibnatal at 0. 15. Aft--,r fivo passes, thil
average content of
impurities in the upper hilf of I'M bar of dlmelbyleUr-blorosilam)
after fusion was 0.19i
mole %. A disadvantage a! the mothod Is tbut -,Um test tube
voinctimes cracks when the
1A

----------
L 518IN65-
,ACCESMONNHi
zont t approacbes the bo0cam'- Z~o raust go from top to bottolm). To
avoid broOcige,
the molten zone ehoiddbfikepVab>~Ut I cm away from the bottom.
Orig.art.bas: I-
tabl e.
AN PCIATIONs Mo9kova ~ni~rBtvcnnyy unill~ersitat im. Jk..V.
1001monooo"
-jMpcow Itate Univers]
SMIMITTED: 02Apr64 ENC!L-. 00 SUB COCiEt OC
OTIIEFIt
NO REP SOVs 004- 001
A
[Cc~d J

POPFWKA, M.Ya.; Al-RAMERO, 0.1.; ZAKHAROVA, V.A.
Electrocrystal,lization stresses in bismuth
depodits. Zhur. fiz.
khim. 37 Tio.5:.,,.165-1167 My 163. (MIRA 17:1)
1. Krasnoyarsk%y polltekhnicheskiy institut.