SCIENTIFIC ABSTRACT ARBUZOV, S.Y. - ARBUZOV, Y. A.

Document Type: 
Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R000101920011-6
Release Decision: 
RIF
Original Classification: 
S
Document Page Count: 
100
Document Creation Date: 
November 2, 2016
Document Release Date: 
June 5, 2000
Sequence Number: 
11
Case Number: 
Publication Date: 
December 31, 1967
Content Type: 
SCIENCEAB
File: 
AttachmentSize
PDF icon CIA-RDP86-00513R000101920011-6.pdf3.62 MB
Body: 
ARBUZOV, S-To.. prof. 0-:741A =10 t a _,gWO ro ective effect of certain phnrmacological prepArations in radiation ?01"- injuries. Yest-ANN SSSR 13 no.6:10-22 158 (MIRA llt7) 1. Otdal radiobiologil Instituta ekaverimentallnoy meditsiny AMN SSSR. (RAD IAT ION PRMGT ION, chemotechnics, review (Rua)) 11BUZOV. S.Ya. ~Dataon comparative pharmacologiaRl characteristics of ethanol phenatine derivatives. Farm* i tokso 21 no.2:25-28 Mr-Ap 158 (MIRA 11:6) 1. Kafedra farmakologii i farmatdii (nach. - prof. S.Ya. Arbuzov) Voyenno-meditsinskoy ordena Lenin~ akademii imeni S.M. Kirovd. (ANAIMPTICSO beta-phenylosopropylamine nicotinic acid phosphate deriv. (Rus)) (NICOTINIC ACID. rel. cpds. same) .AnTJZOVj,-6Ja., MUIHIN, Ye.A. Scientific activity of Prof. A.I. Kuznetoov; on the 60th annlveroax7 of his birth ?am. i toks. 21 uo*2t9l-94 ifi-Ap '58 (MIRA 11:6) (aUTSOV, ANATOLII IVANOVICH) ARBUSOV) S. OYA - "Comparative Data On The Evolutionary Pharmacology Of Mcdern Stimulations Of The Central Nervous System." report submitted for the 21st International Congress of Physiological Sciences) Duenos Aires, 9-15 Aug 1959. KHARAUZOV, N.A.. prof., glavu.V red.; MIKMYLOV, V.P,,, prof.p zametitell glavnogo red.: BIRYUKOV, D.A., prof., otv.red.; AVzTIKWy B~Ggt doktor biol.nauk, red.; ANICHKOV, N.N., akademik. red.; S.V,, prof., red.;-ARBUZOY4--S,76. .___j_yrof., red.; VESELKIN. P.H., prof., red.; VOYIIO-YASKIETSKIY, M.Y.. prof., red,; DANIWVO I*Vov kand.biol.nsuk, red.; IMOTINUCIT, Tu.M., prof,, red.; 7.11MINp L,N,q prof., red.; WIN. V.S.', red.- IOFFH. V.1., prof.,' red.; KARASIK, Y.M., prof.; red.; KUPALOV, P.S.. prof.i red.; MWINA, A.A., kand.med.naulc, red.; VWFAKH. S.A., doktor biol.nauk, red* P A.Vol-prof., red.; 3VMOV, F.G., prof., red.; SMORODINTM, A.A., profol red,;~ CHISTOVICH, G.N., doktor med.nauk, red.; BESBDIN. I.K., tekhn. red. (Yearbook of the Institute of Xxperimental Medicine of the Academy of Medical Sciences of the U.S.S.R. for 19581 EzhBgodnik za 1958 god. Leningrad, 1959. 538 P. (MIRA 14:1) 1. Akadomiya meditsinskikh nauk SSSR, Moscow. Institnt eksperimen- tallnoy meditsiny. 2. Chleny-korrespondenty Akad-3mii maditsinskikh nauk SSS"R (for Biryukov, Veselkin, Win. Ioffs. Karasik, Svetle" Smorodintsev). 3-Daystvitelln'M chleny Akademii meditsinskikh' nauk SSSR (for Anichkov. S.V., Kupalov). (MEDICIRE, WERIMENTAL) :AMWZOV, Sergey Yakovlevich prof.; VINOGRADOV, V.N., red.; SHEYCHINKO. 7.U., teilli~.-r'ed. [Awakening and antinarcotic action of stinmlatore of ihe nervous 49teml Probuthdaiushchee i antinarkotichookoe deistvie stimu- liatorov nervnoi sistemy. Leningrad, Gos.izd-vo mad.lit-ry, Leningr,otd-nis, 1960. 268 p. (KIRA 13:7) (grINULMS) (MYOUS SMIK) ARBUZOV, S.Ya.j STASHKOVj A.M.; KOROTKOVA, V.P. Effect of ionizing radiations and certain chemical protective agents on physical endurance in animals. Farm. i tcks. 23 no. 5:459-464 S-0 160. (MIRA 13:12) 1e Otdol radiobiologii (zav. - prof. S.Ya. Arbuzov) Institut eksperimentalinoy meditsiny AMN MR. (RADIATION-PHYSIOLOGICAL EFFECT) (RADIATION PROTECTION) BAZZOV, V.A.,- NEXACHAIDUpI.Ya.; PATALOVA, V.N*j _AWZO--r,A,Y PETELINA, VoV.1 SHAMOVAp BoX. Distribution of sUfur meroamine in the organs and tissues of irradiated and non-irradiated animalo. Med.rad. uo,5&62-66 061. (141RA 14%11) 1. lz otdela radiobiologii (zar. - prof. So7a. Arbazor) Instituta eksperimentalvtoy meditsity MN SSSR. (Smmmau) (RADIATION PROTECTION) ARBqZ-QVI S.Ya.; STASHKOV, A.M.; KOROTKOVA, V.P. Comparative data an the protective and therapeutic effect of the derivatives of dienides of imidazoledicarboxylic acids in radiation injury. Radiobiologiia 1 no.3:385-393 161. (MIRA 14:10) (IMIDAZOLEDICARBOXYLIC ACID) (RADIATION PROTECTION) ARBUZOV, S.Ya. Problems in uharmacological protection from radiation injuries. Vast. =1 SSh 17 nb.)S58-74 162. (MIRA 15:4) (RADIATION PROTECTION) (NERVOUS SYSTEM,SYKFATHETIO) (PHARMACOLOGY) ARBUZOV, S-Ya. Effect of some now stimilants (phenatine and its deriva- tivem, pyridox7phen) ont he cardiovascular and nervous system. Uch. zap. Inst. farm. i Aimioter. AMR SSSR 3: 206 - 217163. (MIRA 16:9) 1. Chai:r of Pharmacology pnd Pharmacy of the S.M.Kirov Military-Yedical Academy, Leningrad. (STIMULkNTS). (CARDIOVASCULAR SYSTEM) (NERVOUS SYSTEM) ARBUZOr P"Wofs Role of:49 central nervous system in restorative and oom-1 pensatory..;processes following the action of radiation-protee- tive agents. Sborn.ved.prac.lek~fak.Karlov.Unir.(Hrad.Kral.) 6 no.ls57-75 163. 1e Kafedra farmakologii i farmatsii (zav. kafedroyt prof. SoYa. Arbuzoir) Voyenno-meditainskogo ordena Lenina akademii imo SoMe Kirova i Otdel radiobiologii Instituta eksperimentallnoy medi- tsiny AM SM.(zav. professor S.Ja.Arbuzt)v). w2wad A-MUZOV, S.ya..; C)V, V. T. Effeat Cf sm-~ isothluronium y,~T.J_dcnxine cp b3cod C*r0U2at_*Cln a-d SOME t~aicLiinms of fbe n,;:m%,uz: syzti.-m F rm. A I . a toRs. ;?6 no.5:5].9-525 S-0 163. (WiPA 17A~ &f,~dzra farmkologil i tmrm,~itt-li 0~4,70 - Prof. -_ ; - 1. oya o krbuzov) Voyenno-i"ditainskoy crdema lkin--'rou e-kadeirdi !men! Yd --:)Va. FETROVA~ L.A.; BELITSOVA, N.B.; ARBUZOV,,S. Ya. Alkylation of -phenylisopropylamine by pyridoxine bro- mchydrins. Zhur. ob. khim. 34 no.7s2390-2~92- JI 164 (KIRA 17t8) 1. Institut eksperimentallnoy meditabny PM SSSR, Leningrad. ARBUZOVY S.Ya.; SMIRNOVA, S.M. Sympatholytic and hypotensive effects of pyridokiphen. Farm. i toks. 27 no.4:420-423 Jl-Ag 164. (MIRA 17:11) 1. Kafedra farmakologii i farmatsil (zav. - proi. S. Ya. Arbuzov) Voyenno--meditsinakay ordena Lenina akademii imeni Kirova, Lenin- grad. ARBUZOV, S.Ya.p prof. Ilikolai Pavlovich Kravkovj, 1865-1924; on the centenary of his birth. Voen.-med. zhur. no.3:91-92 165. (MIRA 18:11) ARBUZOV, S.Ya., prof. Nikolai Pavlovich Kravkovp 1865-1924; on the centenary of his birth. Apt. delo 14 no.6:3-6 N-D 165. (MIRA M12) 1. Voyenno-ineditsinakaya ordena Lenina akademiya imeni S.M. Urova, Leningrad. ARBUZCrV S.Ya.; G&NER1,1OV, V.I. Fhammcolo,zlt-al cha-racterintlt~s of 5-ilsothi~,;m-nium and 1,,5-diisathiuranitm- pyrldcxtne. -Fanm, 1 toks. 2e noo6:6.86- 681) N-D t65. (M-1p", 19:2) 1. Nifedra farndrologil t fm-Tatoli Gav-, - yr-n'. -'-' . Ya, hr bu z ov) voyorrio-mediW"vokoy (ti-dann aRademil hncril Xf.roval Laningrad. _N _Ip~ 'jE..__3EPLT T,g~"r"& ACC NR'AP60-34256 SOURCE CODE: UR/0390/66/029/005/0521/0 AUTHOR: Arbuzovo S. Ya.; Aleksandrova, A, Ye.; Smirnova., be iqo ORG; Department of Pharmacology and Pharmacy, Military Medical Order C, of Lenin Academy int. S, M. Kirov, Leningvad (Kafedra famakologii i farmatsii Voyenno-meditsinskoy ordena Lenina akademii) TITLE: The effect of pyridoxiphen on the central nervous system SOURCE: Farmakolo.-iya i toksikologiya, %~. 29, no. 5, 1966, 521-522 TOPIC TAG8; central nervous s stem hematoencephalitic barrier, drug effect, animal experinienty 91)WEA104'(f rlC- 4)RVe,- The effect of a new adrenolytic agent, pyridoxiphen (a can- ABSTRAVOT: densation product of phenamine and pyridoxine) , on the central nervous system was studied. Experiments showed that pyridoxiphen did not disrupt conditioned reflexes in rats or change spontaneous bioelectricity in rabbit brains. In addition, pyridoxiphen did not decrease the group tox- icity of phenamine in mice. It wags-concluded that, like most adrenolytic agents, pyridoxiphan does not have a cen- .tral adrenolytic affect. Apparently this substance is' also -brain barrier. [is) Incapable of overconing the blood SUB CODE: 06/ BUBM DATE; 06Apr65/ ORIG REF: 004/- AR~91 891 No. 141 Card 1/1 of =;615.717-092:612.82 0' _x --- J_AL A 10 P 9 A I v V A X I z AA 11111 11 t . V.A. log ExPOZIMONIS 04 two-layered aluteriagg tiether to the Makeev ithiloring wolke. A, I. him-Um. it 'W"vv~t?rd1. lift. 1937, Nu. chem. '.e'str Aj _ IOU. 1, 3M.-Hillits. mtried out on a plant sade un the 2-layered sinictins of Fe urvs %hoWCA that Under like %Julv vomlitions the output of the plant WILS IC14% With 2-14VVItAt 8 mittethis than with Ow WmivestA jmwc~. 11w,pulorw _4111, 0 M. G N1 . "so A 04, 00 0 0 . 1 0 9 ~ " ! 00 00 A WALILUP&ICAt LITFRAT 41 CI.A111FKA110411 00 00 a a 7'..Z _'T u 0 A, 10 it, n I I a ad a 4 1 W b4 !I il a 0 0 A itissliw I's "492 4 I 0 0 0 :00 09 0 so 0 too 0 of a 0 0 0 0 0 0 0 C-, ~', - --. I .-- -, L -. I - -i~. ~~ - . . -- , ; . - , ~ I - . . , , s - - - :t J~ fl-OfTmi?"i -at O"t Mlyr,~, Phi A I / . . .. .1'o, , . I . 11 ARBUZOV, V.A. Drying and preparing samples of ore and concentrates for chemical analysis. Zav.lab. 22 no.5:599-601 '56. (MM 9:8) 1. Korchenskaya. rudoispytatelinaya stantsiya. (Iron ores--Sampling and estimation) 'c!L -'t- f- f 14 lo NIKITIN,- Aleksey Ivanovich; ARBUZOV,..-Y~~4~;#,-*A.topoy.~ch;.,BAZANOV, F.M., red.; YABIOBSKAYA, L.Y., red.izd-va; NMSON. I.X., tekhnered'o Cair*)ring iroA ores) Aglomerstaiia xheleznykh rud. Moskva, Goa. nauchno-tekhn.lzd-yo lit-ry po chernoi i tavetnoi metallurgii, 1957; 195 P. (MIRA llt4) (Sintering) -11 - I -~ - I -, ", , Z ONOPRIYENKO, V.P., kand.tekhn.nauk; LEDEDEV, A.Ye., kand.tekhn.nauk; SOLDATKIN, A.I., kand.tekhn.nauk; LOZOVOY, P.R., inzh.; PETRUHIN, B.A., inzh.- ARBUZOV, V.A., inzh.; Prininali uchastiye: FUREAN, D.Mq Pilot-plant production of sinter with a basicity of 1.2 from Herch ore concentrates. Biul. TSIICHM no.10:17-22 16o. (MIRA 15:4) 1. Ukrainskiy institut metallov (for Furman, Konoplya). 2. Kamyshbu- runsk~y kombinat,(for Kotov). (tintering) '(Kerch Peninsula--Iron ores) ARHUZOV V.A.- LOGUNOV) A.Aq TAVIMLIDZE, A.N.; FAUSOV., 4.N.; FILIPPOV., A.T. A quasi-optiol model and the asymptotic behavior of the scattering amplitude. Zhur. eksp. i teor. fiz. 41+ no.4:1409-1412 Ap 163. ' (MIRA 1634) 1. :Ob"yedinennyy institut yadernykh isaledovaniy. (Nuclear optical models) (Scattering (Physics)) ARBUZOV, V.A., akademik; DIANOVA, E.Ni; VINOGRADOVA, V.S.; SHAMSUTDIIZOVA, A.K. Reactions of tri-(Vv-c~anoisoproFyL) phosphite, ethyl-di-tert ( ~ , p , A -trichlorobutyl) phosphite, and tri-( A , g, 0 -trichlo- roethyl) phosphite with chloral. Dokl. AN SSSR 160 no.1:99-102 Ja 165. (MIRA 28:2) 16 Khimicheskly instit,7' Im. A.M. Butlerova pil Kazanskom goSu- darstvennom universitete im. V.I. Ullyanova-Lenina. LEBEDEV, A.Ye., ANTONOV, V.K.,; TATSI-YENKO, P.A.,-kRWZOV', V~Aq NEVOYSA, G.G.; PrInimali uithastlyc-2 ZAP.ArMIKO, V'.Yf-,,c KARPOIJETS, B.S. y Experience in the eintpriti.-, rl raw %unconcentrated I '~-.,Iba,-,3011 ore. Sbor.trud. UNII-M 161: (KRA 18:11) L 2om--66 EWP(J)/EWTW RM - - - - - - - ---ACC INN 'AP6012034 SOURCE CODE: UR/OC)20/65/1601001/009-97611 AUTHOR: Arbuzov, V. A. (Academician); Dianova, E. N.,- Vinogradova,, V. S.. Shamsut d"I ORG: Chemical Institute i-mo A. M.,Butlerov, Kazan' State University im. Vo Io Ullyancv- F Lenin'(Xh=c1ieskiy institut prl-Kazanskom-gosudarstvennom universitete) TITLE: Reactions of tri-(alpha-cMoisorME41j eos~hitej ethyl.-di-tert-(bets'pbetat ~.beta-trichlorobutyj) phosphit oetbyl) phosphite e$ and tri-tbetapbsta.beta-trichlore with chloral. SOURCE: AN SSSR.~ Doklady, v. 160 no. 1 5, 99-102 TOPIC TAGS: ga compound, A"o, or n;Lc pho4E chlorine compound, ester, chemical reactior ABSTRACT: Tri-(alpha-cyanoisopropyl) phosphite'wan found to react with !chloral at room temperature# forming.the di-alpha-eyanoisopropyl ester of alphas 'hydroxy~(beta,bet~L,beta-trichloreothyl)-phosphinic acid, splitting'off methac*l- onitrile. The reaction between-chloral and tri-ter-(beta,beta,beta-trichlorobutyi), phosphite produced di-ter-(beta,beta,beta-trichlorobutyl)-.~phosphorous acid, which in turn reacted with chloral to give the di--:ter-(beta,beta,beta-trichlorobutyll) ester of alpba-hydroxy-beta,beta,beta-tricUoreotlxylphosphinic acid. The reaction of chloral with.mixed di-ter-(beta',beta,beta-trichlorobutyl)-ethyl phosphite pro- duced the di-ter-(beta,beta,beta-trichlorobutyl).eater of alpha-hydrox~-betapbetag beta-trichloreoethylphosphinic acid and di-ter-(beta,beta,beta-trichlorobutyl)- :(betapbota,--dichlorovinyl) phosphate. Another complete pbosphite with electro- negative groups in the est.erl-radicals# ~ri!-(~4p~a,,~q~a,beta-trichloroethyl) ~-tarcj- 1/2 ARBUZOV, V.N. Strangulation of the Pregnant tube in inguinal hernia. Xhirurglia no.2:69 7 155- (KM 8:5) 1. 3rhirurgicheskoye otdolemys Beloyodskoy rayonnoy bolinitey Voro- shilovgradekoy obl&ati. (MMIUA, -INGUMAL, in preg'nancV strangulation of pregn. tube$ (PNIGNANO, complicitions. hernia, inguinal,-strangulation of pregn.tube) ARBUZOV, V.W. (Iugansk,, ul. Alekseyeva, d.3, kv.33) Stomach resection with an invaginate in retrograde intuamoception of the jejunum. KLin.khir. no,9984-85 S 162. (MM l6t5) le Kafedra goopital4noy khirurgii (mv. - dotsent N.N. Zemskov) luganskogo meditsinskogo instituta. (STOMACB-SURGMY) (J&MNUH-nMSSUSGKPTION) ARBUZOV, V. N, ARMOV, V. 14. -- "CERTAIN PROBLEMS OF STA81LITYCF RJI~OiT-AW;LE OLADCS ELYONU ~P-CPCVPTIOUAL L i mi T. "SuD 21; Occ 52, Mon-cow OpDcr? or Lcum AVIATION 1142T IMEW SERGC, (-,;',0Ztf0NJKIDZE (DISSERTATION FOR TUr DrGREE OF CANDIDATElt4 TEcHNICAL SCIUKCS) 50: VECHERUAYA MOSKVA, JANUARY-DECEMUER 1952 AHBUZOT, V.N. Stability of rectangular kreel,,~ supported plates shearing beyond t.he elastic strength. Inv,' v7s, nchebe zav,; av. tekh. no.2:44-52 '580 (XIRA 11: 6) 1, Noskovskiy aviatsionnyy institut, Xafedra ooprotivleniya materialov. (Blastic plates and shells) A-UTHOR: -Arbuzov, V. N. SOV/147-58-4-6/15 TITLE,: The St-abTI-Roy of Compressed Rectangular Plates with Various Bounda.-y Conditions Beyond the Limit of Proportionality (Ustoychivost' szhatykh pryamougollnykh plastinok s razlichnymi granichnymi usloviyami za predelom proportsionallnosti) PERIODICAL: Izvestiya Vysshikh Uchebnykh Zavedeniy, Aviatsionnaya tekhnika,, 1958, Nr 41 PP 36-50 (USSR) ABSTRACT: The stability is considered of compressed rectangular plates under the following boundary conditions: 1. all the sides of the plate are fixed; 2. the longer sides y = 0 and y = 2b-are freely supported while the shorter sides x = -a and x = a are fixed; 3. the sides x = -a. x = a and y = 0 -are freely supported while tfie.side y = 2b is free; 4. the sides x = -a and x = a ate freely supported, the side y = 0 is fixed and the side y = 2b is free. It is assumed that there is-an-axial stressed state. The difficulties attending the determination of the critical stresses in a plate beyond the limit of proportionality in an analytic form are due to the presence in the Card 1/2 formulae of various mechanical parameters depending on SOV/147-58-4-6/15 The Stability of Compressed Rectangular Plates with Various Boundary Conditions Beyond the Limit of Proportionality the required critical stress. For this reason the author introduces numerical tables from which the essential critical stress curves can be prepared, Minayev (Ref 1) has obtained formulae for the critical stresses by solving Bleykh's differential equation but the solution does not express the real stable state of the plate because o,' approximate relations which have been used. Stowell (Ref 2) has also derived a solution but thi-s is considered to be unrealistic due to an incorrect choice of Poisson's coefficient. The author of this paper bases his solution on Illyushin's equation wh-eh he solves by Galerkin's method, There are 4 figures, 7 tables and 4 references, 3 of which are Soviet, 1 English. ASSOCIATIO'v,: Kaf.edra soprotivleni-ya materialov (Chair of ftrO*.-.irxtIh rif Materials) Moskovskiy aviatsionnyy institut (Moscow institute of SURAITITED: January 13, 1958 Card 2/2 UNKSOV, Ye.P.,, doktor tekhn.nauk, prof., red.; ARBUZOV, V.N., kand.tekhn. nauk, red.; MCIELI, B.I., tekhn.red. [Innatigating the-atrength of materials used for the manufdature of tvrbine blades] Issledovanie prochnoati materialov lopatok turbin. Mookway Gos.*nauchno-tekIm.izd-vo maohinostroltellnoi, 1961. 165 p..-(Moscow. Mentrallnyi nauchno-issledovatel-le- lit-M. skii institut tekhnologii i mashinostroeniia. Trudy,, vol.103) (MIRA 15:1) (btrength o mat;;~ialis) SHCHEDROVt Mtor Sergeyevich; ARBUZOVt V.N.v kand,takhn. naukq retsen- zent; YAMINSKIY, V.V.9 kan a tekbn.-Wa-uk# red.;NIKITIN, A.G., red. izd-va; ELIKIND, V.D., tekhn. red. [Fundamentals of the mechanics of a flexible stritig] 09novy me- khaniki gibkoi niti. Moskrap Goe. nauchno-tekhn. izd-vo mashino- stroit. lit-ry, 1961. 170 p. (MIRA 14:6) (Elastic rods and wires) TARABASOV9 Vikolay Dani:Lov-iohv doktor tekhn. nauko prof.; CHERNYSBEV9 N.A.9 kand. tekhn..naukq retsenzent; -ARWq.OVI ~ 9 RancL tekhn. nank, red.; , _ff SAVHLIYEVp Ye.Ya., red. izd-va; ELIKIND9 V.D.p te-kbn. red. [Calculating wringing fits in the manufacture of machinery] Raschety napria.zhennykh posadok v mashinostroenit. Moskva, Goo. naucbno-tekhno. izd-vo mashinostroit. lit-rys 1961. 266 p. (MIRA 14,&6) (Strains and stresses) (Machinery-Design and construction) KOZHESHNIK, Yaroglav [Kozesnikp Jaroslav], prof., inzh. doktor; GOLIDENBERG, G.M.v inzh.[translatorj;_ARBUZOV,_V.N,,, kand. tekhn. nauk, red.; BYSTRITSKAYA,.Y.V., red. izd-va; MODEL', B.I.9 telft, red, [Dynamics of machinery; selected works] Dinamika mashin; iz- brannye stat'i. Moskva, Gos.nauchno-tekhn.izd-vo mashinontroit. lit-ry, 1961. 423 p. (MIRA 15:1) (Machinery) (Mechanical movements) n /n !ACCESSION NR: AT3003031 0/r.942/63/000/001/0228/0146 i AUTHOR: Arbuzovp V. N. (Candidate of technical sciences) TITLE: Calculation of wall beams based on limit conditions SOURCE: Moscow,, Aviatsionn~ty institut. Voprosy proohnosti i ustoyohivosti elemontov tonkostennykh konstruktsly~ no, 1, 1963, 128-146 TOPIC TAGS: wall beam, diagonal stress., Wagner theory., beam force,, strut force, rivet stress wall shear modulus ABSY=T; Based on the 'Wagner" theory which treats the "ideal" field of diagonal stresses in wall beams after shear instability has occurred in the wall (see Fig. 1 on the Enclosure), working equations were derived for calculating beam speoifica-, ttons for other than the "ideal" case. The 'Wagner" equations for the diagonal (see Fig. 1 on the Enclosure), the beam forces s and s .. compression stress erl, forces in the strutas stresses in the rivets, bending momen s alon P X g the beam, bangle of diagonal stresses, and equivalent shear modulus of the wall were modified Ifor the case of a real wall beam.* The complete set of equations is given below ~'(the equations for the ideal case are given on the lefto the modified equations on Card I ACGFZSION NR: AT3003031 Ithe.right, normal nomenolature oxcept as noted): Diagonal Stressj!.- 2-c (I k) + 2kz sIn 2a Forces 'M P Af TcIga SO 7 ctga n Compression forces in strats' Intl Ig a Sar Compression stresses iA struts - %a1 tg kT Ig a %t r- 7 ppr st Rivet. forc6s. Of P., P bt (I + 0. 414k)' COS CL Local bending of span C2 MMIIX -i2 %b'2 to krb[2 Ig3 a 12 AGG=ION NR: AT3003031 Amie oL too - Alga I+ - - ---- --------- x + -ILI sin 2a Equivalent shear modulus of-wall 2 T q;r- 3 2 _P C2- on Fig,- .2 10. tcr ACCESSION NRi AT3003031 102 is given in Figs 2 on the Enclosure, Orig. axt. has 1 15 figures, h3 gomdas, and 1 table. ASSOCIATIONt Moscow. Aviatsionzv*y institut (Moscow Aviation Institute) SURUTTED: 00 130 CODE: AP DATE ACQ: 27Jun63 ENCL: 02 NO REF SOV: 009 OTHERt 005 C rd A a t_8 I I & Is I ill rt" 1 U x31 Jim 36YUS of a 4i 0 ID .00 see =00 co 0 see 440 see Woo Yu. C. A 39 218V -At 67V-7801. to the Isovotoct of 2-4 Wit ~y ~t - 0l WSO, t decamm Of CUM Mo. an the bads of %YdMMbo" Posed. ribmt 20 Sid. lc buta &,Iwo towbor wkb km amta- of okfts iind N and SM QN1. If. A. Boatty I ll - S L A olTAtLWJC*L LITEWATilt CLASUPKATM saaw u A, a, al; It o 9i a oo:::Iooooo 19000090 0000000W9909000 11 U U M b Is 17 0 10 30 boo woo a T LA a 1 w 84 1 As 0 2 UD 4 1 is 000000000000400# 0*0 1 0000006000006000900044004, I It' I) It r v It H 1) A A Ps tr A A A a ~k. ~lk It 1`4 9 P-A I.- I Al It LL W It 1 '0 I - T_J ., I I I IMP (4pps A -00 00 00 00, go 00 Tbwml 4-spowd" of Weak hy~t. .00 Nl- Nlikh&Wv sud Y", A, Arbuwv. Gmpt. rtxd. aad. 00 'Jil $"- 00 dtkv"IPU. Of I-Ptutene I.bcicne In,- And 4-nttthyi.l-pcntcw (M #A WO -00 400" is an cwt~A of Vater Fiddrd 00 0- hydkowbuss. Cundejta. -00 The YkM!t d the Owl -00 00 4-VmPs' PrGd- 12-13% butmdim, 11, 1... 1 00 61tallhae aW 4G-7.9% meol". M . riNethyl- 'Ve' WE prwykw And 4J-6,87'. butacklaw; 10% p"pywM. C. W. Sudern ;; 00 "of to ii! A S 0 . S L AMtTALLVR6KAL LITFRAIURI CLaSSIMaTION t z L_ __ - ------ ..,_ - - . - ~ - - --,a - -_ :~_- - - -- -- - - _. ~ __ I I ~ - 1 1. -. _.- I . -. I . i 1 Set 0sj~j; ONV 44t 4111110.1 as I'll 0 tw 0 -1 r I An i s -3 D a (0 U 00 AT 00 M !o 0 9 0 0 0 0 of of 0 a 0 0 foe's 0 4 0 0 IN 0 0 0 0 0 0 4 0 0 e - M" 0 0 & 0 0 0 a o 0 0 0 0 Andr v4l; 04- g F~`~W 4~V4!10 o 0 I a 4 1 a I I I a to Ij is U is M 11 U it x to I n n )4 b x 17 A 29 10 it 1:131111 Nit Is 0W .1 Q At W 0&0 A 11-4-11 11 1-9 A -A-L a. x P-Q A it M 10 CC tv U j 4 4%, Apt. I.C. phyfat 00 -4# -60 0 a t l :.go 00 0 : o tk*Ws by means of aliphatic dial* com, undo, 3 A 4M " 4 7 -00 . ow. x . tAlewrhirfly oft' enuan, French anti E ligilAt litt"I urv as well &it of the works of Athumv, Favot4il unit Iti-111% j The reaction-ii, of diatomethant-s with antincs. =00 00 4,zetylen", aliphatic. aromatic. cyclaafii)hatic l k ( 1 d 06 rimirti o e% ant rhy stlh~fijuird and unsul"tituttA Rh various ypts, acids, hytitolt"utint-91, kvlo "Iefft. 111-1014. so ketrarstivor., are di-ruwA. 00 '00 00 -a 00 i- i gee 00 C;00 ago 200 t-te 0 A a - S L A .17ALtIRGICAL LITE ATURIE CLAj$Ij'KA7tOR t Z t;00 I.Vcb,) .1, O.t go .... . b U % AV 00 0 i P it Ovic Nit VC11 Iturt aft --ji j~ j7-A FA 0 a rid , ,43 (I Iit, A -,.- ~ 0000 'S' 90*06 00000000 00 0 0 18 1 000-00000000000000 0 is ; 0 6 00 0 0 0 '* 0 0 0 000 0 0 * 0 0 0000 9.0 0 10 0 00 of 00 v 9990900 0 0 0 4 f It 11 f) u It is it Iwo m v R x x 9 x Is a 41 a dy ad A B-C 15 r f A K I 00 A-V --(.P(vt,tL 'I'll 0 :.oo, :0 go r 00 .00 Cbwmiwy cd dw Astir"Wfic viumalus. imul- Lh and Ih and - the stnicuire and syn- .00 tim of vilarains; o Dj, Ds, 1). and It, citiefly " twed a* 0 thesis of vits"lix upon the wl"k ol Windmit, et al. (44 .C. A. JI, 4UP, 32, 21W4,). It, It. Rathmann 90 90 000 40 0 St. AtIALLLR(lcaL Loted'I"t C&AStwicallow tD10414 .10 Ov off u S &V to OW 0 v 9 1 If 14 t A 0 91 x :14 0,0" 't I 0 0 6 0 94 q 0 0 0 0 fooo, go 0 0 1-01 : : : : 0 0 We 0 0 9 0 0 0 0 0 0 0 0 0 * 4999006900086*000 91696600006660660*066tefooo I C 0 U 4 01 All L a 0 0 PC I S T %N I u C" x 11 !In (N 0 a IS "A- I --A A--k--A A ' - - 1-2 -,q, :&I -D W-Q W'!. F. GROUP], -Z J aM.13_1111 114 Jill IV MONA 1! 1124 111"'ST fop 040 0- '0111MAID PtM RUPOR -.Cpnp Pat"Morid %=dad pU ==I 10 S".M" P- wpnw a.. list 13,344 q.( lit -1r- I a-r-. '4. it t, ,u b 4 0 so see 0 to 0. 22 .0 LM !goal* a Ka 19- MM k 66 coo 00 1 r I 61:966600600,69: q -#M~ I I I . ~ ~ ~ L -43. MI. I R 39 w 35 a V a is a 41 a is 0 A -MILLI-a'a-CCAP U'110.k .40 jl..VPVf?t_- VOCKMIS A I Coated Cooversim ol the sli-membered ring into the it andVu.A-U1wj&_-- Ave-wImbendooe. N'.D.ZclinA, Compf. read. ared. sti. U. R. S. S. 23, -.114 SM139011 HngIijh),-%%%en qThaftexene was pasaed over curn. Allf h or over silks wrl at 4160", nirthyleyriopentene wal, (unut-4. ~Nltthytryrlohexene wits similarly movetted into dhurthyl- cyrIanwrilene. ]n each taw tile wl%atd. mAlkict wa% hy- drogertated to the corresp, ditig cycloalkanc uvrr plat - 00 InIzed charonal or silks get. Whun tile cyritlalkatir will, pawal over platinized charroal (,r silica gel at 27"', 1114. 00 -3 ago ring was broken to fom tile open-chain h)Atocarllclu. 00 Cre% at cS410 dehydrogenated Cyclollexclic and flictlay]. no* lollelene to benzene and w4ume, rcitti., utz.-tcas Cyclo.; ~Ylzsue and cyclopcittenc were menti2fly unchnnied. Ttout. It. age If lie 0 i H LAO, too ~-_S L 4 SIETALLtlAtfKAL WERATIO111 CLASWKAIIO I too 0 1411641 map Qw O&C 00 u III AT 10 It alkali 1-- 9`1 to, IT X, IN, -0, n-mr-Ig it a it of I t a (W a 11 0 ~-o : o 0 0 0 0 0 0 0 0 I I-Is a ~3. 1 00-A 060 00.4 10400, Ott 0*2 0*8 *08 00-0 004 0490 0*4 OOW 8.4 rate Ulm XV Cato 1.41 coat 1.9-9111 d-oo OAM). pentaneand 3-tudhyllvexane. a I a. S L & SITMAINIMAL UTMTWW CLASWICATION so .00 .09 Me* .0 0 alo* age no* 000 Coe Igloo fee see see see l-41TAM,&Ww, wee 1 9*0 b U is AV in I at N a a 2 1 N a 9 do a a 11 9 a& 00000 0 0 0 0 0 e 0 0 41 0.0 0 0 **is 0 0 0 0 0 0 41 0.0 0 to *see ..4 00000 00 000000 0-0-0 0-0 414:0 0 090 0 0 0 - 0 0 * * *~* 4 Lgk~ ~-D,414dy A W. Nauk S. S. S. 1 4. toe was twkv PaWAO at a - ou-cm. layer of allies, gel In a I &. ~lhtova. Themainfrution(blW-1W i 11 h=ted with a platialsed charcos, 1 to oce a satd. hydrowboo mlxt.~Mto was dehydrogenated with the ",me "t.- restid" bydrocaboo tubt. (.,; 1. b ,' ITZt. Of toluene. wbicb was removAdb Ile residual Mist. (1) (hn, 92.b- LM, d1' 0.78M) was proboMy moody 1,2- wane. Thia istratise was supported by 1. under condlitions favoring opening the i a bydrocarboo mist. (bm 83-916. xV tbought. to be moody 2.8-dimethyl. W. Perry '.16 6-W0 0 L Ax PDAL W A- ~'JL Its P ;M~ "0181, TI 0-&txtt%4,* .-K, Oxidation of cyclo1exents by saleolous acid and a ue. miatmd of StIon of 1.3-c1doltemilictoo. X4. A. r! . . 0t a. Arbititov IO~Zsllmkil. acid N. 1. Shuticin (in t Chm ISd USISR) If 11 41rad. st i. U. R.S.S t. nteflught lot thr Vtltiop set cychshcxens, air given. (I) The ryciohexcitv P- M-4') is o"filk-d with wkniow acid at WW" its AtO; two substaism me (omml. esevieste (1) (yield 48-52%), be 67 9% *V 1.461, aml the " a 0 As d s- A op ..r. it. q-1pt 7~66 00 f 0 fiacetate (11) of cyclohexenectiolp be 112-13 . nV 1.471. 6011 c 1n one of the expts. I and It with the (otlowitig mi,ts. .00 wm- obtained. 1. he 68-0', cf." 1AW. NJ.' L-RIMM. 4g 900 JAMR, AIRD a coluslem mobile liquid with 4! " zoo k 1.1225, NVV plemut froity odor. 11, be J. 1.4710, URn 49M. Ught yellow rather mobile liquid,s is al'o oxidiz ith d Th lofieXtu k t d coo o w *smu or. e t unp e Cyc " with 5--0l at W-0) in a tuixt. of AciO and glacial AcOl I wgive I 1.45R. Forth pttVn. ,o o (1111 the 3-cyclolsrietc-l-ol 4cretietr .1 for ttd with a frt*hly inrlted and fitsely pow-d. KIIS06 at 150-W'. III (W74 yield), Is. 80.5-l", 9w 0 as obtesiotil with th~ oVI.475. In one of the extitz. l " qoq , d1.1 0.8411. mi: 1.475(t. following consts.; th.v 1111.4-1 D hl R o M2. Makk suhydtide (2.94 g.). Pidded to 2 40 g. lose of III In 7.5 cc. of pure beugene, gave 5.17 g. of addu 200 ptoduct, probably 3.0-endoctil),kite-~il-tetmhytlro- hthislie anhydride, crystir. froen petroleum heptime Its C ve 0 right needless b.. 14"'.. G. Ubedeff tie 0 11tTALLURGICAL LITINATM CL&SSWKAI#CN tie 0 1 It IN 5 a 0 2 111 V &L It AV to is It it 0 0 0 0 0 go** a 0 0 *1* 0 *1* 0 0 0 0 0 0 6 6 0 0 a 0 0 0 a 0 go IST.4 mass&& at 61 a a a a a a a a a S a e a a -0 A-41 e 0 00 046 4 0 0- i oSo9q0o0*'**eOoee-be p Wil uct"all uuu l6lava g A&CD1r4TSXLfi1k Opus$ 1w 1111-1-q- 4 ~~ 9; IT (m AT u " L it, 1.6MVIO af~ 11-0.0t J;i r0'. -Ott "ITNin 1#131IM IV 84111 IT3051011 TOO 7 14 -fSV A o ji,mumpr 641mgmui."Itt! %v jua%aqoIa.(a lu!AI*Atjt liql-to J111 J01 liffuLlop all 11111tIVII.Mill u043pli .411-1A.3-VI 3-ld J.mo Aq pmoltai qllA% 110113w) 4w j0 11taulluW1 All Imirinq ma 1qtr:t.jw W .olx(3 p3luryun pum martatIotl(a lo %&ivul louriuml .0PA31AII1.1111 l1witi IV 41.111 mm, I"myll.41 'Nil IN, E y "A -p 5"j)"S 13"W03 fill.. 1111414044 -1.1 1 so of so oo Q-t d;T &it- o 00 *go 00000090 *on *a on sor 0 --.d-L- 001 0 0-0,0 0 film WD t9vive I M Afto dtk 066141 03 inlmq lump 'r47XZ 'tw 01 9 s V IL 00 - MM 1 P 09 1 91 ;qal 0 NJ %om "a P"Ut" &am " l r nee P q 4c ' P) &UlPG vt. e 1-mdaq[Aquul-g PM Anivam * UMAP3 VVIAMN atLL :: 94 191tu an P AID= 31mmoq F AM" "I so N"11003 1119111 pal 4 - law van 01 ' I u a 6 I 1 Foe j0 P --q 6u 03 99 sea a 91 oat "11 km t 4 s iMpow sql lo mW A- VVA M SNAG a &Jim 0 IV .00 IV - Fo- ,%q ow jQt6l , 1W.110.100 'mm so -wpm --n-1 -P killki tal㛜 MY *"123004 r so 7 r W. w. -2. - .01 We 7, 1 UK all T I - - o sit, 110, VI 0. W, W. wit 111 10 41; 41 -4 to JAI r-1-1 11 K-1111 -V-- 00 R ti f di i h 10 eac on o en ydrocabolis with nitro&* com. pounds. Addition of 1 3-butaillene to nilrovols , enteno. V"JilL41tiv. Poklady Mail. Nusk S.S.S.R. 60. C.A. 42. I,hNo alld 10 fort" in lullo"' alruc te 14 c0lifirlited by fornnittion of 4~mi- ; ints-2-birks-1-d (11) on reduction by Zii-Ar,011. Ph%o 1 (10.7 g.) and 10.7 g. 1,3-butadiene ki-pe. 24 htn. in a %ralctl vcsqci at 5-10* gave (11).9% 1, :it. .591-l' (froin EMU); ' th i ld 6 too 60 e e Y f m to 91.2% on 7 (lays ,tanding Willi ivv- emAing, m loP07t, if the conilxmcul, In UtOll art, allowed 10 litit"d 24 hot. With IM-MIling atilt tile PToduct then dkttl.(bj.&l07-8*). Reduction byZit-AcOll gave.M.1-P * " U :ire* . N 151- . d: LORIG. xj: LW7: trrainit-sit Aith Ar.0 at Hill' 3 Ism. gave 9301 of the di-Ac derir., It, 160-1 zo .3 d!* LIMM. x1p 11-271. Thi, (2.47 g.) in 11N) sill. hl"CO 7 i h 4 w . t , g. Khttin, its hh-,CO gave N-aertyl-N. pkewylgly% ixe. in. 194-S' (front A sticir). t Ism giving a final structure confirmation. G. M. Kcsolal.-ff zoo VIIIIIIII A STALL ?RGKAL 1.111441101 CLASSIPICA111014 ~,gq 0 _ 7 all 5 An 44: U It AT .0 It a plan Itall tv to 44 1, 14 4 IkUlft . 00000 00 * 0 0 * 0 0 0 0 * * 0 0 * .00o0 00 so* Ills Go* 40 RAW - OF it **too 0 U If 9 13 IV 141,1 J_ *0 A 04iX9011, A.6 000014141 INDIA 0044 fie C bmwbm" d Cy x. 1. eat*". and M. D. Zerlitakil. U-0-P. V 21. ildf 31. 1946. P. 124. snafus of, AbOrdds. V- ' ova Abstract row Sidi- A;W Sci. Uxw. Ct- dr, ""58* 090 , CycoMxem , was ental.tically loomorized over _d__te *" doogi, irsetionated, IIIIAM OX14C C 00 #3 tractions Identified. redistilied, and the AA2 ji 4 S V.$ L A 'PKTALLURGKAL LITIMAIUNt CLASSIFICATION smiama .10 O.V car- DU, 9 AV " , I T I I W I m U t, it 0-0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0-,* 0.0 0 0 0 0 0 0-" .0 n r C04 Nei 204 **%arm h31111 OW a". 'A An a I a [W o a a -I IF 6; 9 a Is 7 it V is, W,m 0 0 0 0 9 0 0 * 0 0 0 a 0 0 0 0 0 0 0 2j. t-t-O.-t 0 0 0 0 0 a , 0 0 0, 0 0 0 3keea on theoretical data two system wher4by 1,3- lutediane can be added to nitrosobanzine. , Deacriba ,viwjoua emparlments conducted: 1) addition-, of 1,3- butadlone to nitroadbanzina 2-PhwWl-3,6-dshy&o- orthecalne; 2) reduction of 2-phenyl-3,6-dWWdro- 67T2T USM/Chealstry 10-Batadiene (Contd) my., 1948 arthocalne by 4-phanyl-Indbutane-2-01-7.,- 3) &Ootylltatlon of 4-phaqyli=lndbutane-2-ol-l;.4) oxIdization of diacetyl produced IV In N-acevji. V-pheWlglycine. Submitted by Academiciau!A.N. Nameymov, 2T liar 3.948, 6-M7 8: ARBUZOV, YU. A. PA?6T9 ~N MIV,g 1~1 N-fw Olefins,* fie chf=istry RM ene 13~rdrocarbcns With NI i lteiictlon of Di Ltroso Ounds)" Yu. A. Arbuzov, N. L: Fedyukina, PP Ak Nauk SSM' Vol LK, No 7 ribes the addition of I 3,tutad-'ens to diene osttolu6ne, and 'the addition of 1,-3-penta 4-%axadlene to ultrosobanzane. Submitted Mai--- NO 2~ ARBUZOV$Yu. A. witty nitruNa cont- Addition ut A~) to friollicric llitrn!;O- Addifion t 1,J . 11clitildie'lto allot 1i nitr4ril ;U141 1171`7116WI, 117!1 6 60, 71. lind Oll )-. IVIIXII~1. LvIll ilk -.111 aml,%lt ~,I III-. ;it 5-10, gave tfi.7 z. Z-o-PIX-1-3 -4-JA V,11 o - 1, zine, 974-5' ill' I a j" I ,5 6; 11 -. ~ t 7 ( I INC i k: I t I was welwl 4M,6 %V.;4 ii'AA ill a w1vvIll.. I", ONCLI14Nte (INA .) will 2J g. 24 lim al, 0 51, gave of (Itv ?~km4al ,vt im,mrr, lj,.% 115- 1 V, it.' 1-0715, it' I IJAIN), sim: ill. it-.; slllvo~,llt gave .1 7 7,11k I., e-ONUMMe g;)vt (finiti McOID; the OvId %vaq ra ist-11 It, SIA% Ily ushig CHU, llu golvViti. .e I,I%NO(:Mj g.) ill 300 lilt. witil vu :Ifl;:r 21 1 11r.%. ti.~Olalvll by stealil distil.) Zk-ldiriii-I-Nar tit o- 1,2.Zt1-Ox=ille, to, A Mimilar n-ioviiii,ij ~vijjj .jvc jj I,,! AM-1:21, ill," G. ~(, 0 0 0 0 0 0 A 0 1 L 1" 1 )4 ri 14 If W I- If it 14 it to 11 11 vm.1 4) 41 " 0 l" Ill A I , LL 1~ 1 0 Itr a 41 If .11 4, 1 I 0AI '1 44 0 CIL I* u t U-40tot 00 -00 Reactionsoldlene h0tocatImms a ith nitiosocampottisda. ti n f 2 W 6 dih d 2 d 1 3 1 R o so uc o ,. e . , y At litatt v. v Akad, Aawk Ns R, 63. 1 1 1= C.A. 43, Wslr. -toxa:inr (1) KIM g.) ill IN' itti. A0111 hAvii '.99 with 2.1- C. Zn sltj~t 35 n2in., flit-if hm.&IM la 11141' 7 fu%_ civ(s, Oil licuttalit.161111 alid stv'11114161111_ 3A K. I-Phrn-vl- , 00 in. 1M-2 00 v: ill of fill. AcOll willi 25 It, Zit Ivail, ill I- w(i ... 1. aft.'f MvIl Irlimmi: I hs~ 1(m., If It ' o J flit 11 Ill I l C I Phr"I; iNvf"'Idift'. b. w. 117-18' t(mm Fi;)IM. kOltixiag 16-:4 g. MiNfl. c1l;0I.ClIciloll flill %%fill fit g' zlicl: its *of fill. 7 ji 01 fill. lwt all, AcOll 4 hm g,tvc 7:11. 11. 1 J:12.2 g.! in 6. 61011. ItvallA wilh 511 g. Na ovrf Ill mill., lwat.'f tilital tit.- N,i Ji-4ml. mul mcam di,l.l 00 .,kets-s'. tiv), 1'~ SO Nl-, 1.1" 11 061A.IA Imatull fit 67", )-wid liv mmilm s-loomn 4 Ill ill, fill, 00 C.M. Illepreftlit" I.'s7'-.S-)-. IV Klv- with ll/Cf in N..,M 00 Or Ih deriv.. tit. 90-1' iftom E1011): As dtt;r.. It. ' ' 00 PIS I,,, 1xi. 1 .41 I'm .'f t hi, t.v KNI 110 ine. sit. I'Ll.."4"). koNction ' 0 M r%vhdlv\.t11c with PI-C ove N-haYid"t. 'd IV by It 7 ille, I)$ 0-s" 1:* 11.9111, f1j" L. 0;i; ji- de"r" ill (t'"11 jwtr. 0 IwF 1. C.. M. K-1.11.41 010' All-St A Of Lillg4lkvE CIASSIFIC-740. I I it 1; %A Vt AV to is! v .4 KIt It q Pt Ct If It X IV rw0 1- W 44 -j di .3 -iI An k a114 T , go 0 0 : r0 00 00 10 0 0 0 0 09 00 0 9 9 0 0 0 * 000 0 00 00 0 0 0 e 0 0 * 0 0 0 0 0 0 0 * - 0 0 0 6 0 0 0 to 1.0 : 0 0 see* 0 0 0 0 0 0 0 0 0 0 0 9 41100 Is 0 ei ARBUZOV Yu- A. ry 'D" 48 MR/ tit' Charlitry Nitroeo, Compounds *eacticw of inene Hydrocarbons With filtrozo Cbvip6urida. Raftetion,of 2.-~hOnyl-3,'6-DihYaro- C&thoxazine," Yu.-A. ArbuzoT, Inat of Orig Chem, Aceid Sei UM, 4 PP nk)k Ak Nauk SM" Vol LXIII, No 5 We bited from a poevio-as article shake that) i4r6ducing 2~.PliOYI-3, 6-dihydroorth*2;ine by a tivim. afid a*6hol, 4-'phenyl-amdhobuteEe-2-ol-1 le,formed. Thin is fu-Aher reducett to &6tylanj+ lene. gi~bmitted by Acad A. N. Nesmayanov VNIMN 55142T14 Structwill formula of diams-nitroito compound addition ducts. A 11hilarl'ahlivin, It'll, A. ArNiFow. and 1'. 1'. I rt-twy In fis, f, Aloc 14, 413 IIIIJUNI). lite .4 414-kit's tit llitl~ 14 1.1%. 1.4 ~.tllltvs '1111% , .4 3,1% aillytilt.nillowille (1), e.g.. Initudiclic Ph%O - I CILL111'. The conibiwition disi-crsion -IxAint I)( C:C tit N. I ~;tnd 6-nivinIvred liciefocycles "ere dc(d. The intest,ily t,1 "llic Put) rill. I hind vibmiltmi of the Villa ring "lily Iw itwil ws lilt inifiemor tit lite v;ilrner swir tit the N aloin rt-tinert"I I., thk lilic. ]'Ill. k.111. A Ow bllvll~ilv 4.1 lilt C-C ImIl't Illdie.'I'd thal it, III IIWi'A Owl'. III 111, 1,41. 11"Ir 1.01". .. ......... ... I oj%~l 11. Vmd W. "Addition of cvclohexadi ell e-1) 3 to 01-,roben~zenp." Vel-i. 2ap. Mos!-. un. po. 132, 1950. -K: IMLRA, October) 1950" ARWZOV-Yu~Aj FEDYUXINA, N.L.; SHAVYRINA, V.V.- Dienes InteractLon of di-(cycloh-qx6ne-1-yi-1). 2, 3-dimethyl-butadiene-1, 3 and 1-phenyl-butadiene- lt 3 with nitroso compounis. Uch, zap. Mosk. un.,*No. 132, 1950. Monthly List of Rassian Accessions. Library of Congress, October 1952. UNCLASSIFUD. Reaction of Mohr hydrWarbms with nitrotic, com ounds' and J-m-tolyl,11,01hydro. 2,oassins. Vu. A.-Alibutoy 01. V. Slate. Vitiv., Abad. Ximit S S S. R , Odd, Nk"Ps. Namk JOS;. 013 01-11111"dirlie (11%, 1.) saild 72 -, 1. III ClICI, after 2.1ave III 11rAl 1) 0"% r 141 a I. W6 0,11'. .1.0, 1 07:111. at? NU15. Which will% Zit duut and Acoll save X2.5% (111, th 181-;1*, all- LOUIS, III,- 1 .57,113, yirlding wills Ar,O altrt 3 hm at Hill' 04",' di-Ac .fr,lr . 14 1-,* IAW, aV 1,5243. %hicli wilb Nfr,ct ),-K %trio, rr4.111V gave NX.Al" N-Oerjyj-.V~-44114- .C1.11me (111). tit. '--11-13* (imm 11,0):o It the 1"lucli'm if the ousine nlt,%c is alone at reflux, 47" dihydrepyrrale. Lot-* 904-1,5% all." 1.032N). ml,* I.&R42, bt a'blahird. 11 In rrallithis nits. I"1011 with Na uirtal gilve -.5"t, I-t-t,4yhm4x*-:-bu1rme. 14 ISO-1)0% d" 0.9314, mj~* which with hot Ar.0 ravr the A( dcrir.. C.,II,,0N. 1" 11.1 - 14.46% JAXIIII, xf.* LAL'97. 3-ichling with NXICtO. It, slycitar dmiv. Similarly but-lient, with 1 111INC., I.Nle lrave 86.37, 1"401yi iseta" (If 1, 1., I(M.6 5.0'. 1.071.1. at* IZA178. which tit rtwin temp. will% Zia olim ill ArOll vIVI,I% A2.:r" M-14yhlmiae i,,,mrr tit If. 1'. 1 $7 ,;,. ,I:* 1 0:46. at' who,r di,4c I., M W. I-. I IWWI. -it.' I with KNIIA1. lit "le'CO givvx W."', I's. Ad Ill. lit. 145-0, (trallit dil. VIM), 0. M, Koscil.11,011' Reaction W these sydrocautwas with nitroso coinpounds. C reducdw of 21ski yi-36-dib dra-1.2011,~oxa- M"-' A, Ariniurl dbo! PPkw ". .14*' 79, &k S.S.S.R T6, 491 NT _--i I--r7r- 4.1. ILVI Alksolls III) C ICIUCII'l, i"lls 111'.1 r 11.11c,l I,h%*I) In I I VIICI., 1,,Iliilx .1,410 .,%villight, .410 411.1c Jbi 1. 11, Im W, N) I 110ti, tutlAIM ill Oliv, 1 .1 it. Pt-C it 1-111 truill Ishii, 111),14,011111, It, Acid 4 K-IfINAIWIP"'PIN-Ji- till -''*. ,41 1 WAKI. all 1 .54,61). Till- I MA x'. I till. A0111 trrAl"I its 4 lxxlkmtx with 4,1 it. Zn, iluA % ith till ~ttnsll-fii,ld '.11.1 'Allitc.11.; lite ec,t. 4-phrOY&S tug I-0- I-buldstal (1 1* 11' 154 %'. it'* 1(411- foil LAWO, drid MV141r. deo"Ill). 1.24,5-5.0" (It"Ill Mt-Off I Ilydroxenation of I'liXIM1,4011:0101,011 Ili Viso at sticull tritill. O%vt PI-C virl'ItA 11111,011, Ph.N11,, /,A. 114 1 W% 11'. Il'l* 11.0391. mi., I "3M i /is dent.. tit 41, "'t told I7.1r., 1, lilroil6-al %Ilh till- Mitwv. 1,,.. 147, A', ii,,, 1 114111, mi,* LbMb~ C. M. Kowl.11hill OA It"Waimii,s d time by*--b- -ft 2 -T 64 W 2 R. 71. ~*'~MVA 6d -are bli I V-HS ~~ SW 723 1. p.MtC,)I.NO, 78 1. butildW., Mi. ClIcAl 'mnight at o' ga- 94-2 g- Y"."A stand 4 Eloll 1.2(111).ozatime (1). bs 112-13'. m. 47-8 (from Aken 0.5 hr. with AcOH-Zn dust. ninittaUted, and ateam- Sh - .4 (U). b. 139-0'. td.. pvc 78 SAO.""Me I 0 I.M53, a %7 1. i.Bxd&riv.. in. 130-11 (from MIT); s J",.t 167- & d - I.Orm. MV 1,3m. The tattft .61 Jr.) in IOD nollMo tmated with 4.7 9. Oftl()o In ~2-.A co 2J5 kn. 55.6% N-"#I*N-P"vt- 0 (fmm (ciude (ITm) 175.b-7.0' _qj4j, a ust I..,AtH 30M _j!j it . j Ut b Z"Cl, mid AeOll 6 hn. U with Kmnth py-ok. in. is or HCI-FeClo 9&vc I 1 33 L) in =1. abs. RtOH led with 60 C. t t 69% %,& ortr coal 1-0 '94m; Is, 7'. mV I. I "0 Ac dorip.. t% 1.5 IW70 dl* 1 1. . S. 12f)-io.3 . dl- I. I. a 1. . 0. . K Doff ---- MMIMI A-A-43-OG-7-0 VJ-YIA Chemical Abst. The reactions of dlenic hydrocarbons with n1trosoNom Vol. 48 No. 9 pounds, Addition of I 3-butadlene to n1trosobewens. \11. Vu. A. WrbuVv, BJ. Icad. 3d. U.S.S.R., Die . 47* C"! May 10t 1954 translation).--See CA * 4874 Organic Chemistry H. L. ff. "a-, ~' M*- 9 A M M~MZFQM Awl ~ ~t Its reatims of diente h n1trow com- y Ghemical Abst. Vol. 48 No. 9 .fS-I-I 3- fliene, I-phen* pmds. Addiflonaf 2-A-d. 1,3-~ =adle 0, AndX-IW-C0heM-I- aronutle n1troso COM me *K- Vi - YU.A. 'zov kina V. N. L. Fed3 Hay 10, 1954 , , . W Sbawrwa,aUdR.-Usbede va. ffuU.Acad.,Yd.U..Y..Y.R.i - -1 Ch S Organic Chemistry My. em. C S 952, 2(Engi. tmndation).-See C-4.47,43421._ H. L'. H, 7~v --R-ROuzo-v yu.-tq. VC/ R6actlons of diene hydrocArbons with tdtrosa compounh A dditio f 13 1 h dl I iobenzene. ~ j-cyc o exa ~q~"o n troi ~7,nA: --Fu C cl.,~ rh Div tion). y e C.A. 47,R-6. iiABLID)v Yu. A. Chemical Abst. -3-i~y'd to 0 I-ELryl r0 Vol. 48 No. 9 TMOO &nmCl T1115W, B3111. Acad. rtu. Sci. 1952, 09.5-0(Engi. trasi%=1011).-Spe C.A. .May 101 1954 47, 5927c. Organic Chemistry ARBUZOV, IU. A.: KfUZELINITZ)KIY, L.I. Fyrrolldines S.~nthesis of 1-aryl-3-hydroxypyrrolidines. Iav. AN SSSR. Ot,-I. Khin. nauk, 1110-4, 1952. Monthly List of Russian Accessions Library of Con,gress, T)ecember 1952. Unclassified. UM/Chemistry - Diene,Synthi4es'', M&y1J= 52. Witroso Compounds ReaLation.Between Diene Aydrocarbons arA Nitroso, Compounds. Addition of Butadii"w~~J,3'to ,:,Ikt~rosobenzene. Part 2; Yu.A. Arbuzov; Inst of Oig Chem, Acad Sci USSR ."It Ak Nauk, Otdel Xhim Nauk" No 3., pp 547-555 In,energetic reduction of ?--phenyl-3, 6-dibydro-, orthoxazine with zinc powder and acetic acid I- phinyl-2,0-dihydropyrrol is formed. The reduction ,of:2-phenyl-3,6-dibydroorthoxazine with sodium 220r2l 4m4 alc results in formation of N crotylaniline. The intermediate product in these reactions is )+,pbenylamindbutene-2-ol-l. 22OT21 UNR/Chemistry - Pyrrole Derivatives Vliy/Jvn~~52 "Reduction of I-Phenylpyrrole," Yu.A. Arbuzov, N.M. Garburg., Inst of Org Chem, Acad Sci USSR; lbscov State U imeni M.V. Lomonosov ""Iz Ak Vauk, Otdel Xhim Nauk" No 3, pp 556-563 Reduction of 1-phenylpyrrole was studied, using zinc powder and hydrochloric acid at 60-750, zinc powder, hydrochloric acid and acetic acid at 40- 50 and at 50-650. Under those conditions, 4 hydro- gen atoms are added, resulting in the formation 22=2 0.f 1-phenylpy.Lxolidine and N-crotylaniline. The reduction mechanism is explained by the intler- mediate formation of 1-phenyl-2,3-dihydropyrrole. MR/Chemiatry Dieiie: 87nthes6s May/Jua. 5,R Nitroso Compounds "the Reaction Between Diene Hydrocarbons and Ni- tr6so Compounds. Addition of 2,3-Dimethylbutediene- 1,3, I-Phenylbutadiene-1,3, and Di-(Cyclohexiene-l- ,yl-l) to Aromatic Nitroso Compounds," Yu.A. Arbuzov N.L,. Fedyukina, V.V. Shavyrina, R.I. Shepeleve, Inst pf Org Chem, Acad Sci USSR; Moscow State U imeni .M.V. lAmonosov "Iz Ak Nauk, Otdel Khi-m Nauk" No 3, 'PP 566-569 Studied the reactions of 2,3-dimethylbutadiene-1,3, trans-l-pbenylbutadiene-1,3 and di-(cyclohexene'-l- 71-11 v-itb aromatic nitroso compds. Obtained 220T21A the adft products of 203-dimethylbutadlene-1,3 with nitrosobenzene and p-altrosotoluene,lof trans-1- phenylbutadiene-1,3 with nitrosobenzene, o-nitro- ~sotoluene and p-nitrosotoluene, and of di-(cyclo- ~hexene-l-yl-l) with nitrosobenzene and p-nitro- totoluene. ARBUZOV, Tu.A. Reaction of diene hydrocarbons with nitroso compounds. Addition of 1,3-- b~~&dlene to p-nitroGotolusne. Isvest. Akad. Nauk S.S.S.R~, Otdel,Xhim-o~ Ni~k 152, 658-64. 5:9) (CA-47 no.20:1049) 153) 1. M.Y.Lomonoso* State Univ., Moscow* WTRYUKOV , T.A. Ae ]j! A .R&qyoj Reactions of dionshydrocarboas with nitroso cyclobexidiene t6, 'nitrosobenzens.' Izvest. Nduk '52, 665-7o. (CA 47 no.2o:Ao493 '53) compounds. Addition Of 1,3- Akad. Vauk S.S.S.R.. ~Otdsl. I[him. (MMA 5: 9) 1. M.Y.10monosov State Univ., Moscow. 1 1 'A (~ ~ ti 6i , f . . . %;- T. ~ ", : . , - , - . . . . . - --- -1- , , ': , , . I" :7 , , - , ; "; i~ ! q44~, MTJZOV. Yu. A.;DYATKIN, B.L.;SIMVBLNV, S.A. II .~Z- Some reactlons of 1, 4-dichlorobutanone-2. Dokl. AN SM 112 no.2: 261-263 Ja 157. (XLRA 10:4) L, Moskovskly goandaretyanVy univernit*t im. N.V. Lomonosova. Predstavleno akademikon A. N. Nesmayanovym. (Butanone) C) v I/ &THORS: Arbuzov, Yu and Pisha, T. A& 2o-1-19/44 A ~- TITLE: Reactions of Diene Hydrocarbons With Nitroso Compounds. The Addio tion of Pentadiene-10 to Nitrosobenzene (Reaktsii diyenovykh uglevodorodov a nitrozosoyedineniyami. Prisoyedineniye pentadiyena-I., 3 k nitrozobenzolu). FERIODICAL: Doklady AN SSSR) 1957, Vol. U6, Nr 1, PP- 71-73 (USSR). ABSTRACT: It was already proved earlier that conjugate diene-hydrocarbons react with aromatic nitroso-compounds according to the dione-aynthe- ais-scheme under formation of derivatives of 3,6-deh_vdro-1,2-oxazine. It is the purpose of this paper to clear up the structure of the reaction products,, as mentioned in the sub-title. The reaction of the diene synthesis,, in which conjugate unsymmetrically built dienes participate, was already earlier studied in a number of examples* In 30MO cases either o-isomers or their mixtures with m-isomers respectively develop,in which the former are strongly predominant. In other cases p-iaomers develop. These data are in good agreement with the ionic mechanism of the diene-synthesia-reaction in which the transfer of an electron from diene to the dienophile takes place under formation of a ion complex. The second stage is the regrouping Gard 1/3 of this comp3Lex under formation of a stable adduct. In a number of Reactions of Diene Hydrocarbons With Nitroso Compounds. 20;~9/44 The Addition of Pentadiene-1,3 to Nitrosobenzene. papers, however, data were obtained which contradict the above- mentioned mechanism: o-isomers were predominantly or exclusively obtained. The problem of the reaction mechanism, as mentioned in the title, was hitherto never discussed. In case that the reaction mentioned in the sub-title took place according to the ion-mechanism., a 6-substituted polymer Ia, possibly with an admixture of the 3-aub- stituted po]~7mer 1b, should develop. Transpentadiene-1.0 was pro- duced from croton aldehyde and bromo-nethylmagnesium pentane 2-01-4 and dehydrated over magnesium sulfate at 3oooC. Further the authors produced the above-,mentioned addition product from a mixture of ni- trosobenzene. and pentadiene-1,3. The production speci- fications ana the constants of the substances produced in this con- nection are given. The yield of the latter addition product amounted to 72% of the the6ratically possib '1e yield. By its reduction with zinc dust and glacial acetic acid, amino alcoho1LCIH,50N was proo duced with a 71 O/o yield as compared to theory. This alcohol. was ace- tylated with acetic anhydride and finally N-acetyl.44-phenylglyetine IVa was obtained. From the above-4nentioned data follows that the addition product under review consists of a mixture of 2-phenyl-6--. Card 2/3 methyl-3'j,6-dahydro-lp2-oxazine la and of 2_pheny1_3methy1_3.,6_d*hydro Reactions of Diene Hydrocarbons With Nitroso Compounds. 2D -L,19/44 The Addition of Pentadione-1,3 to Nitrosobenzene. -IL,2-oxazine lb with a predominance of the latter isomer. This result contradicts the conception on the ionic reaction-mechanism of the diene synthesis and is' in agreement with the assumption of a radical mechanism of this reaction. There are 26 references, 14 of which are Slavic. ASSOCIATION: Moscow., State University imeni M. V. Lomonosov (Moskovskiy gosudarsts vennyy'universitet imeni M. V& Lomonosova)* FRESEw?TED: By A. N. Nesmayanov, Academician. SUBMITTED: April. 12, 1957. - AVAILABLE: Library of Congress. Card 313 AUTHOR: Arbuzovo Yu. A. and Ovchinnikov, Yu. A. 20-117-5 24/54 TITLE: The Synthesis of 3-Oxypyrrolidine and 3-Ox thiophane (Sintez 3-okbipirrolidinov i 3-oksitiofana~ PERIODICAL: Doklady AN SSSRO' 19579 Vol,-117, Nr 5, PP- 813-816 (USSR) ABSTRACT: At present many compounds are known which contain a pyrrolidine -iinge The series of the functional derivatives of the pyrrolidine remains, howeverp only to a small extent known*up'to now* After a short reference review and a criticism of,the known methods of the mentioned synthesis the authors have decided to use for this 'purpose 1,4-dichlorine butanol whi6h.can be produced easily and with high yields. In the heating of butanol with okuimolecular quantities of primary amines in a medium of absolute alcohol in prose.nce*of potash N-substituted 3-oxypyrrolidine are formed 'with high yields. Thus 1-phenyl-, I-p-tolyl-, 1-p- anisyl-, 1-n-butyl-, and 1-benzyl-41-oxypyrrolidine were produced. By catalytic debenzylation of the 1-benzyl-3-oxy- pyrrolidine in presence of palladiumoxide the authors obtained 3-oxypyrrolidine with a high yield which up to 1957 was not Car4 1/2 known. By condensation of 1,4-dichlorine butanol with 3odium AUTHORS: Shemyakin, M. M., Kolosov, M. N., SOV/62-58-6-34/37 Arbuzo .,.W,.Onopriyenko,' V. V., a enshteyn, G. A. TITLE: The Course Taken by the Synthesis of Ring A of Tetraoyclic Compounds (Putl,sinteza kolltsa A tetratsiklinov) PERIODICALs Izvestiya Akademii nauk SSSR, Otdeleniye khimicheskikh nauk,1958, Nr 6, pp- 794-795 (USSR) ABSTRACT: Already in 1957 the authors of this report described the synthesis of tricyclic compounds in which 2 rings, with respect to thdir structure, resemble rings D and C of tetraoyclinic compounds. The third ring, which corresponds to ring B, contains a binary compound or a potential carbonyl group. At present the authors are studying the possibility of synthetizing ring A and describe this synthesis. The group CRX . CO 2 is introduced into the initial ketone, ketone ester is ethylated, ethynyl carbinol (formula III) Y-C~CH is hydrated in the neutral medium and oxy-ketoester (formula II;Yzr-Ac) is cyclized into an ox diketone (formula III; Z=:H). Card 1 (Formula III; Z=CONHZ. The scheme has the following forms The Course Taken by the Synthesis of Ring A SOV/62-58-6-34/37 of Tetracyclic Compounds x I\C02Et \\0 (I) x x 1\ CO2Et / OH Y ~-~ "-\( -1z HO HO (II) (III) There are 2 references, 1 of which is Soviet. ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk SSSR i Institut biologicheskoy i meditsinskoy khimii Akademii meditsinskikh nauk SSSE.(Institute of Organic Chemistry imeni N. D. Zelinakiy, AS USSR and Institute of Biological and Medico-shemistry of the Academy of Medical Card 21,~- Sciences of the USSR) 5 ~W AUTHORS. Shemyakin,, M. M., Kolosov, M. N., SOY/7-1-29-6-13/72 Arburov, Yu, A., Karapetyan, M. G., Chamanp Te. 3..q Onishchenko, A. A. TITLE,- Investigations in the Field of Tetra-,yelines (Issiedovanlya Y oblasti. tetrateiklinov). IV. Investigation of Different Syn- theses of the Tricyclic System DCB of the Tetracyolines (IV. Izucheniye putey sinteza tritsiklioheskoy sistemy DCB tetra- tsiklinov) PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 6, pp 183! - 1842 ABSTRACT: The structure of the well-known tetraoyclines (I) has a speci- fic characteristic which indicatesthe ways and methods neces- sary for carrying out the complete synthesis of compounds of this type. On the basis of certain theoretical considerations the authors tried to synthesize such ketols of the hydroanthra- cone series of type (III) and (IV) in which two rings had to be similar with respect to structure and spatial arrangement to the rings D and 0 of the tetracyclines. The third ring had to offer the structural conditions for the subsequent building-up Card 1/3 of the ring A and for the introduction of the necessary func- Investigations in the Field of Tetracyclines. 50V/79-29-6-13/72 IV. Investigation of Different Syntheses of the Tricyclic System DCB of the Tetracyclines tional. groups of the ring B of the tetracyclines. The adopted method of synthesizing these compounds consisted in the con- densation of the 194-naphthoquinones with butadiene or its derivatives and the transformation of the resultant adducts (II) into the ketols (M) which, on their part, can easily be hydrolyzed to give the oxy-diketones (IV). The first step, the diene synthesiag takes place readily by heating naphthoquinone with-the diene. By condensation of the 5-methoxy-naphtho-qui- none with 2-methoxy-butadiene two isomeric adducts - (II d) and (II e) in the ratio 4 ; I - are formed. The second step, the selective transformation of the Cq-keto group of the ad- ducts (!I) into the tertiary methyl carbinol grouping meets with some difficulties, it was howaver possible to carry out the reaction by means of magnesium methyl halide. The third stop of the synthesis of the compounds kIV), the hydrolysis of the enol-methoxyl up to the keto group is only possible when using dilute acids. The synthesis of the tricyclines (XV) was thus performed on the basis of naphthoquinones, in which two Card 2/3 rings are analogous with the rings D and C of the natural tet- Investigations in the Field of Tetracyclines. SOV/79-29-6-13/72 IV- Investigation of Different Syntheses of the Tricyclic System DCB of the Tetracyclines racyclines with respect to structure and spatial arrangement. The presence of the reactive double bond, the enol grouping or the carbonyl group in the third ring of the compounds (XV) Of- fers further possibilities for the introduction of substituents and for the building i,.p of the fourth ring of the tetracyclines. There are 12 references, 4 of which are Soviet. I ASSOCIATION: Institut biologicheekoy i maditainakoy khimii Akademii medi- tsinskikh nauk SSSR i Institut organichaskoy khimii Akademii nauk SSSR (Institute of Biological and Medical Chemistry of the Academy,of Medical Soien-7es,USSR9 and Institute of Organic Chemistry of the Academy of Sciences; USSR) SUBMITTED: June 99 1958 Gard 3/3 50) SOV/79-29-9-11/76 AUTHORS: Arbuzov, Yu. A., Vatsuro, K. V., Volkov, Yu. P. TITLE: Synthesis of 1-Methoxy Pent.'07A_ on-3 and Diene Synthesis With It PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 9, pp 2857 - 286o (USSR) ABSTRACT: I. N. Nazarov and I. V. Torgov (Ref 1) obtained 1-methoxy penten-4-on-3 on heating 1,5-dimethoxy pentanone-3 in va- cuum in the presence of p-toluene sulfonic acid. In the in- vestigation under review, the synthesis was made in a differ- ent way: by addition of chloro methyl ether to butadiene-1,3 under the action of ZnCl 2 (Ref 2), the authors obtained a mixture of isomeric methoxy chloropentenes (I)'and (II). The catalytic isomerization of the primary chloride (I) under the action of ZnCl 2 (Ref 3) resulted in the separation of 0 the secondary chloride (II) (6oal yield); its saponification with sodium-carbonate solution (Ref 4) yielded a mixture of isomeric methoxy pentenols (III) and (IV), from which If Card 1A pure alcohols were obtained on fractionation. 1-methoxy pen- Synthesis of 1-1,lethoxy Penten-4-on-3 and Diene Synthesis SOV/79-29-AVAi'll,'T-6~ L with it ten-4-0n-3 (V) resulted from the oxidation of compound (IV). The manganese dioxide first used as oxidation agent gave a 67~'o yield of ketone (V) which was still mixed with the initial alcohol. When using chromic anhydrides the yields amounted to 35-50~44 only, but the ketone was obtained in pure state, with a glass-like residue always remaining in the distillation flask, which is safely to be regarded as a polymer of the ketone. To prevent this, and to increase the pure product yield, the ketone was extracted with chloroform, and hydroquinone was added when drying the chloroform solution and when distilling the ketone. The yield of pure ketone amounted to 6el~.. A higher yield (94%) was obtained by oxidizing the alcohol with the pyridine complex of CrO . The condensation of the ketone (V) with cyclopentadiene reLlted in compound (VI) (yield 76%); the reaction of the same ketone (V) with cyclohexadiLne-1,3 yielded compound (VII) (yield.72%). There are 8 references, 3 of which are Soviet. ASSOCIATION: Moskovskiy gosudarutvennyy universitet (Moscow State Univer- sity) bUB?-fj September 15, 1958 arl 50) SOII/20-128-1-30/58 AUTHORS: Shemyakin, M. M., Academician, Kolosov, M. N 4rbuzov,_Yut 1, 1 ~ -A... 9 Hsieh Yu-yYan, Sheng IluaiL.3ft"., Sklobovskiy, K:'A., Karapetyan, M. Q., Gurevich~ A. I. TITLE: Intermediate Stages in the Synthesis of Tetracyclines PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 1, PP 113-116 (USSR) ABSTRACT: In 1956 the authors Wntbesized tricyclic ketols of kind (1) (Ref 1). They are similar to tetracyclines (III) as far as the structure of two rings is concerned. In the third ring they have a reactive double linkages in position 2,3. The present paper investigates the addition of heterogeneous re- agents to the 2,3-double linkage of compounds (1) for intro- ducing active groups into their molecules. The active groups are necessary for establishing a 1-grouping (II) in the B-ring. and for a further extension of the A-ring of tetracyclines by a method previously elaborated. Investigations have shown that compounds (I) with typical electrophilic reagents such as Hal 21 RC03 H and HOHal react readily. Thus, corresponding _qard 1/2 halogen derivatives, epoxides, hydrine halides, and halogen SOV/20:-'128-1-30/58 Intermediate Stages in the Synthesis of Tetracyclines ketones with good yields are formed. Constants and analytical results of synthesized compounds are given in table 1. The Synthesis of tricyclic ketols with active groups in the B-ring made by the authors provides the possibility of building up the A-ring of tetracyclines. There are I table and 3 references, 2 of which are Soviet. ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinakogo AN SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy, AS USSR). Institut biologicheskoy i meditainskoy khimii AMN SSSR (Institute of Biological and Medical Chemistry, AMIT USSR) SUBMITTED: June 4, 1958 Card 2/2 5 (3) AUTHORS: Shemyakin, M. M., Academician, SOV120-128-4-30165 Kolosov, M. N., Arbuzov, Yu. A., Berlin, Yu. A. TITLE: Investigation of the Methods of Ring Synthesis of A-.Tetra- cyclines - Method of Introducing the N,N-Dimethylglycine Residue Into the Cyclohexanone Ring PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 4, PP 744 - 74.7 (USSR) ABSTRACT: For a further utilization of the tricyolio oxydiketones of type (I), described by them, in the synthesis of tetracyclines (11)2 the authors developed a general method of transformation of cyclohexanones (III) via keto-ester (IVa) into compounds (V). The (Va) have a characteristic oxydiketone-carboxamide system of the A-ring of tetracyclines (Ref 2). To build up the A-ring itnelf in a similar way (this ring having a Me 2N-group in posi- tion 4 (Vb)), the method of introducing the N,N-dimethylglycine residue into the cyclohexanone ring (III) had first to be de.- veloped, and the reactivity of dimethyl-amino-keto esters of Card 1/3 type (IVb) had to be investigated. The present paper deals with