SCIENTIFIC ABSTRACT ANTIPOVA, L.A. - ANTIPOVA-KARATAYEVA, I.I.

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ANTIPOVA, L.A. Course of scarlet fever during symptomfktic treatment [with sumxm7 In Ingligh]. Pediatrita 36 no,2:12-16 Y 159. (MIRA 12:4) lo Is knfedry Inf*ktsIonnykh bolesney detay Leningradskogo pediatri- cheskogo, meditsinakogo, instItuta (dir. - prof. N.T. Shutova# nauch- nyy rukovoditell - dots. A.T. Xualmicheya) (SCAM't nTO. ther. symptomatic ther. (Bus)) ANTIPOVA, L.A. SWdy of the *oncent:ration of penicillin in biological fluids of the body following the administration of bicilline Pediatriia noe,7171-75 162* (KMP, 15112) 1, Is kafedry infektaionnykh vabolevaniy u dotay (say, - dotaent A.T. Rustmiohava) len.Ingradskogo pediatricheskogo moditainskego instituta (dire - dotwent Te.P. Somenova)t Det*oy i"fektsionnoy bolinitay Sverdlovskogo reyona, (glavnn vrach - zaaluthennyy vrach N.A. Nikitina). (PDICILLIN) (BICILLIN) XLYACHKOj N,St; ANTIMA,, L.A. spectric Prevention of armVe. Report ki. '- of clinical aml IftborAtory exardnation of children inoculated Intracutaneously with a live attenuated vacolne agaInst mops, Trudy Lpn. Innt. Ppid6 i mikrobiol. 1603-38 158. (MMA 161g) (hWWS-MVENTIVE INOCULATION) AUTIFOVA, L.A. Experience in tbo use or bicillin In scarlet fever. Sovrt* med. 27 no.6tlO7-110 Je'63 (MIRA 170) lo Ta kafedry infektotonnykh rabolevaniy u detey ( zav. - Prof. A.T.Xualmicheva) Lenin ",adskogo meditsinako ro podintrichenkogo lnstltu~;a (direktor - dotsent Ye.P.SemennvaK 4010f so, WW "I who of byb" bahmt* am 14M orocks. *does Salem almiLma UM "Irviody nvwL ANTIFOYA. I.M. (Moskva) 2doroy's ) no.1:23 Ja 157. (NUIA lOsO (TRUTISION-TRANSKITURS AND THMMISSION) ILI a, 16, 14111:11 ..Its, N fit) no 8010COM so dw nm wb*- Saftivilm mw Ismil' Ow for OsterSOMM d so &W btq m". A - A IN ukvmmwo *ad U. A. Atatipors. R"lU- fk%dww opid Lakob#&WASA lo. 4 list rainiticel" e4 t*k OvA phlbak, achis, with ghvv"4. Q)w wlr %if Catalyst (106mrs Iftak ita W I h %%% q NY twAT I CAIN! 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Ukritq)ovap N.A.] ~ It now vpeclcs of t~e geams (V,-Vatis Cron lake Kliubaugul. ar. bot. tl,.ur. 21 no#3&5)-5,91641 (HIRA 1717) 1, Riologo-geograftchook-ly nauvhbri-I Litsl rlovatell sk il inetitut pri Irkutskom gosudarntvmrom unl0rert0tele. BILYAROU, YoX.- ANTIPOVA. N.0. Automatic system for relaying gas and blow media parameter measurements to a centralised Oeint In underground coal gasification areas. Podsom. gas. ugl. no*4.-51-5.; 158. (MIRA lltl2) l.TsG6oyuzqy nauchno-loolodavat6l'okly institut Podtameas. (Coal gasification, Undergrour4-Testing) (Remote control) Fluctuations In the abundance of Melosir species in the plankton of Lake Baikal, Trudy Gidroblol, ob.-va 13t235-241 163. (MIRA 161ll) 1, Baykallskaya biologichaskays stantolya Biologo-grograficheakogo instituts pri Irkutskom universitate imeni. Udenova, pos. Listve- nichnoye. MW Dioloa - Botany Clard 1/1 Pub. 22 - 42/45 Authors Antipova, 1.1i Lo Title I Now typeo,of C~rmodinlum Stain from BaikCL lAke Perlodioal I Dok. AN M 10312o 32.5-329, Jul Up 1955 Abstract I Scientific data are presented on new "s of flora C~modiniux Stain (Oymodiniacosio) taken from the Baikal 1,akiw. Three reforencess I Gem. and 2 USSR (1935-1954). Oraphi drawing. Institution t Irkutsk State -Ahdvtrsity it-. -A.-- A. Presented by t Academician Ye. N. Pavlovskiy, Harah Up W5 A"MTA, S. L. saw Formation of auxosporee in Cyclotella 'batcalensis (C.Neyer) Skyortsov. Bot.ust.Otd4spor.rast. 1109-42 J& 156. (KLU 9:11) (Baikal,, Lake-Diatoms) - - , , ~L - ~. ~ 11 .", -.7;- ~ , - -,I L ..' ~L _ - ---~ 2'. -~ - - ANTIPOVA, N.L. Seasonal and annual changes In the phytoplankton of Lake Baikal, Trudy Lin. Inst. 2 pt. 21l2--23 163. (MIRA 17,3) - t" n, ~ ~ ~~ " 5~~L- - .~ - % i kalLl A;,AkVjVA, &'~. I.. "TI,,o Ertomofaunn ol" FicldF Used for Various flur!xres rmd Protected 17 Shelter belts, and the Regmlarity of its bintrilution Onder tic Conditions on the Let.-robortoucous YeatLer-Grare. 3tappes." Cand r1dol ai, Vorcow State PednEoCica-I Inst irvid '1. 1. Lenin, )0 Dec 54. 2;~ Lec 54) Survey of ~~civntifJc and Tecludcal Di--tertatlcmn Defended at U,61% l'iL)'Cl' MUCatiOtIO I'lStittIt'0115 0:~) ~C: SM. NO. 556, 21. jur, 55 XONOAN-10, T.Y.; MILIKA. N.I.; ANTIPOVA. N.P.; ROZFIKOVA, V.V.; VASILIT31VA. V.v. - Using now synthetic fibers in the woolen industry. Taket. prom. 18 no.8:10-14 Ag 158. (MIRA lltlO) (Textile fibers, Synthetic) (Woolen and worsted manufacture) LEYTESO L.G., kand.tekhn.naukp nauchnyy isotrudni~L-WjPQYA,_-~,~-., inzh.p nauchnyy sotrudnik; VATAROVA, L.G., inzh.0 nauchnyy sotrudnik Assortments of woolen fabrics. Tekst.prom,22 no.30-7 Mr 162., (MIRA 15:3) L TSentralInyy nauchno-isslodovatel'skly institut sherstyanoy promyshlonnosti. (Textile fabrics) ROZHKOVAS V.V., insh.1 KONONEMKOO T.V.t Imb.; PANICHFVA, A.A., kand. takhn. naukj ANTIPOVA. M.P. inzh.; KORSAP.OVA, V.B., Insh.; VASILIUVA, V . V . - -ITrin '. Technology for the protensing of atAple lavnan In woolen and worsted vAnActure, Nauoh.-iasl. trudy %N11Sherati no.171 5" 162. (MIRA 171l2) ANTInUt 0. P. k4TIPOVAp U. P.s "rho formation of schools of coniercial fish in the Ryuinsk Reservoir". Leningrad, 1955. All-~nion Sci Res In3t of lAke and River Fish EconogW* (Dissertations for -,.e Degree of Candidate of biological Sciences) SOt KnIzhnMa Istopis', No. 52, 2h Deceriber, 1955. Honcow. 00000090*6*00 0000 000000000000 90 06 goes 9*09040-0-6-141- 03 1 1 a S 4 1 1 0 to It tj 11 to is 16 It I & 10 a a frampt,m), mu me by np&41 oil mae* 6-d-1 0.04 Off -00 -00 r, et) is** 1.00 00 -06 06 -00 of hemW4 m-not 1"tedak la the U.. kite. 0. .0.0 it 2400 0 Antipove aw M. mow%*h. jty&" A:". 1W9. No. 1, Kita. AWow. ZA*I,. JON. No~ 6, 1114-11o 200 I dmrumivv as"Im "a Ow R" WAItfuls ill twever 12 rsuwd moinly by owtobic limi"ka. !0041 0: Ol NaphthkA Is lbr brst Ine. wivalive. swal In qw-lor &to slp~s taftnist. amthromiwca 0 3; awlamilim-110. goo lfvatrql Wilb VAP1111111101) Villef a 3-4.6 noMtht U40 was r.. 3.3 then Kmter than that W ibe uninated 00 W. R. lie"" 00 Ir 600 We, !800 moo I flog so too Its C1,1111110FICAT16% u if 10 of, I., it H a w e 0 0 to 0 0 0 0:6 0 0 0 0 0 4 41 0 0 6 0 000 0 o goo 0 s 0 Go 0 900090000009ot 00 .6*000000000000004*00000 AIMPOU, ?*So - Seasonal and age variations in the morphological composition of the blood in earp, Top* ikht, nooW20-122 154, (n& 815 ) lo MoRkDvokiy takhnicheski;r institut rybnoy promyshlonnosti I khosyayatra Imeat AtIsMIkoyana - MoerrbvtU2. (Blood-Awlysis and chemistri) (Car-P) GONCHLBOV, G.D,; POPOV, AXTIPOVA P.G~- B15tilY, L,.L. Diesase anong young p1he perch In the Sea of Azov In 1951-1?52. Trudy VXlRQ 31 no,2:20-258 155~ (KLRA 9,~8) (Irlehes .-Disesses and -,)oat@) AMSHTUN, A.R.; ANTIPOTA. P.S. I.-, ~ Growth OT-urevioO01=0romiess in wastc witers containing haxogens Tod, I $an. takh. no. 7t15-16 Jl 158. (MIRA 11t?) (Haxogen) (Sewage Bacteriology) S/136/61/000/011/001/007 E142/Ei65 AUTHORS3 Lurlye, Yu.Yu., and Antipova, P.S. TITLE: Extraction of bichromate ions from effluents with anion-exchange resins PERIODICAL: Tovetnyye netallyV-no,il, ig6i, 25 TEXTs During the chemic9l purification of effluents valuable substances contained in the effluents are lost. This can be avoided by Purification with ton-exchange resins. Chromates can be extracted by using highly basic anion-exchange resins, e.g. X8 -17 (AV-17). Chromic acid and chromate ions are strong acids and the satisfactory results obtained during these experiments are due to the oxidation-resistance of the anion-exchange resin. Good re8ultn were nla,.) obtained during extraction and regeneration of haxavalent chromium with the low-basic anion-exchange resin AH-18 (AN-18), which was prepared at the Institut plastmass (Plastics Institute). It was obtained by reacting o_.skox-uwvLny1ated copolymers with dimethylamine. The anion-exchange resin consists of light yellow grains of 0.3 - 1.5 mm diameter. it was subjected to swelling and then placed in a 1-cm diameter glass tube, treated Card 1/3 Extraction of .... S/136/61/000/011/001/007 E142/E365 (thus, ion-exchange witti subsequent regeneration results in a 75-to 100-fold concentration of the chromate). The regenerated solution can then be used for the extraction of the chromate, f-or recovery In industrial processes and for the preparation of chromium pigments. A regenerated solution containing a small quantity of chromium can be recycled for the regeneration of the anion-exchange resin. Three-fold recycling of tho resin did not alter its consistency. The anion-exchange resin AN-18 can be recommended for further tests in experimental and industrial plants dealing with the purification of effluents. (Abstrnctor,s licte: Abridged trnnsIntion.3 Card 3/3 LUROYN,, )'~u.Tu. . prof. I ArATLAaAj BEXnMj A.N. Purification of waste vaters from fluorides* TSvet, not. 34 no.2s 43-47 F 161, (MIRA 14 s 6) (Industrial wA~tes) (Water-Purification) ---A,NTIPOVA, NS61 HYBNIKOVAp A.I.; MILOVANOV, L,V, Purification of industrial waste waters from nickel salts, Met, meto 34 noslI66-71 J& 161, WIRA 1713) LURIYF.', Yu.Yu.; ANTIPOVA, P.S-.__-__1. Removal of chromium from plating plant waste water, using ion exchanp, Ochis, stoch. vod. no.309-49 162. (KRA 160) (Chromium) (Industrial wastes-Purification) (lon exchange) MARTUR, V.G.; KOZIDVAP V.S.; ANTIPOVAt S.A. Analysis of a mixture of halogenated hydrocarbons by the method of gas-liquid chromatography. Zav. lab. 30 no.91lO76 164. (MRX 180) KLIMC VA., V.A.; ANTIPOVA, T.A. Degradation of organic compounds in a rapid oxygen flov under cond1tions of nicroolemontary analysis. Zhur.&nal.kbim. 16 no.3043-347 Nr-Je 161, (MIM 14:6) 11 N. D. Zelinsky Institut of Organic Chemistry, Acade-.-.y of Sciences of the U.S.R.0 Moscow# Organic compounds) crochemistry) M KLFM()VA, V.A.; ANTIPOYA, T.A. Flash combustion in the microdetermination of carbon and hydrogen Irl a rapid flow of oxygena Zhur* anal, khim. 16 no. 4s465-468 Jl-Ag 161. (MIRA 140) I* N.D. Zelinekiy Institute of Organic Chemistryp Academy of Sciences U.S.S.R.p Moscow, (Carbon-Amlysis) (Hydrogen-Analysis) (Oxygen) KLIMOVA, V.A.; -ANTIP.9VAj__T,A.,- WHINA, G.E. Simultaneous determination of carbon, hydrogen, and halogens or sulfur by "flash combustion". Irv. X, SSSR Otd.k~im.nauV no.ltl9-22 ja 1(2. (MIRA 15il) 1. Institut organicheskoy khimli im. N-D.Zolinskofo ;dl SSSR. (Carbon- _Analysis) (Hydroren--Analysis) 01alogens) A F- Cultivation of sequoia In the Yalta forest station. Los. khos. 5 no. 6, 1952. SOt MLRA. August 1952. TAPSKIT, I.A;TAVININ, G. M;XHILXI)VA, V. A;ANTIPOVA, Y. T&. T'reatment of gonorrhea with penicillin and Putnh*mothor&Vy, Test. vener., 4o*kva no.205-56 Mar-Apr 1952, (CLML 2W) 1. Of Arkhangallsk Oblast Venereal Dlspensai7. T 7- XT) PH/W"E I IN ^. =WrrATION ' Wit/3031 Moscow* Toontral lnyy inatitut prognowy Voprosy aolgosro --"- vropozov (Problem in loong-Ranp Forecasting) Moscow, Gidrowteolzdat (otA.) 1958, 104 p. (Seriest Its: Trudy, "pa T3) lplOO copies printed. I Sponsoring Agenoyi USSR. Glaynoy* upravlentle gidrawtoorologichaskoy slubby, 14.t (UtIn page)t V.X, Kurganskayal Edo (inside book)t V.I. Tarukhunom; Techo 31.t 1A, Zarkh PMUX=t We Issue of the Institute's Transactions is Intended for meteorological and hydrographic specialists working In the field of long-range weather fore- casting, OOVERAGEt This collection of articles deals with aspects of extended weather forocarting. rnd1vI&ml articles dismast. "noptic conditions of wind regimes most favorable to shipping atong the Northern Bes. Bouts (Soviet Arctic Seas)j trynoptic conditions underlying a continuous lee cover In various parts Card 1/3 Problem In Iong-Range Forecasting SOV/3031 of the Sea of Azovj a method for compiling daily scha=tIc 500-mb contour maps (AT500) for 3 dare by utilizing an equation of the conservation of vortex velocity and temperature regime; a method for the advance amputation of the ba:TIc field for periods of 24,, 489 and 72 hmrs; the dateraination of definite relationships for forecasting air temperature for a natural synoptic period, The results of actual tests in a series of investigations in axtended forecasting are cited, References accompany each article, TANX OF OON1%M: jL,XI"G Synoptic Characteristics of the Wind Regime in the Southern Mj!p9p Part of the Barents and Karakoye Seas During the Navigation Period 3 Khesium, 3.0, Synoptic Conditions of Freezing in the Sea of Azov 29 Xhaywvap O.Na. and N*M, Chapysi"o Compiling Mean Prognostic 500-mb Contour Maps for :5 Days 51 Turketti, Z.L. Fort-easting pressure Fields for 2-3 rVe 57 Card 2/ 3 Problem In loong-Range Forecasting BOV13031 Turketti,, ZeL#,, and OsM. Yokusheva. Ccupating Prognostic Pressure Fields for 2-3 Days T3 D*A* Peal., and R,Me A11tvargaro The Forecasting of Air Temperature for a Natural Synoptic Period 94 Averbukh, S.K., and V.A. Pozdr,7&ava, Revults of Utilizing the Findings of Investigations In Corgiling Extended Weather Forecasts 100 AVAELAM: Library of Congress Card 313 12-19-59 charges on the Murgab u.-M T(-ri:!,,:- A lig venscri wid f-ho t, :isibIll iv iie-, ANTIPOVA, Yo.O. Synoptic processes governing wind tNirt of the BiLrente and Kara on&* Trudy TSIP no.?313-28 158. Onronts Sea,--Winds) conditions in the southern during the navigation period. (MIRA 120) (Knra, Sea--winds) I i.. .. -I , '' ,I ~ I . I I I. ~ . I . -- I-.-L - -- --..- - 1- --- - -- 53MINUIRMS16M - I~- - -7 1 - 1 -1 1 P I -~, ~ ~ ~ Lu", 'i I,i - . II. I I FM 24-9-7/33 AUTH~_.RS: Antoipovo, Ye. I., Gutermen, M. R, tknd Lozinr.3kiy, 11. G. ( _M0 I 1-c O_W_~ _' TITLL: Certain features of polymorphous P to % tran6formation of pure (iodide) titanium. (NdWDWryye osobennosti polimorfnogo 0-~a-prevrashcheniyti chistoto (iodidno6o) tittina). PERIODICAL: Izvestiya A.Kademii Houk SSSR9 Otdeleniye Ti.-kbnicheskikh Nauk, 1957, NO-9, pp.45-dtg + 6 plates (USSR) ABSTRACT: Until very recently very little informttion has been published on direct obnervctions of the polymorpliouu tron.,ifor.iation of titanium and no dotailed inforLU(tion ivi)s available on i;ho kinetics of this procesi3, the exception beinL a paper b~r Lozinskiy, M.G. (Ref.7). Such direct observations at elevated temperatures ctan only be corried out bX heotinG in vacuum with a residut..~l pressure of 10-5 to 10 6 = He (Ref.8). In this paper the experi- ments, are described which were carried out by the outhors at the'Inatituto of Mechanical EagincerinG, Ac.Sc. USSR (:[pstitu-t-ma,6iii,no'v"ea-e,n yp on itnnium containing varicus additio'ns of iron, silicon, aluuinium nnd Cord 1/3 carbon, as specified in the table, p.45. The experimeats 24-9-7/33 Certain features of polymorphous 0 to a transformation of pure (iodide) titanium. on a polished surface of a titanium apecimen, whilst Fig.7 shows a micro-photo of a zone of coexistence of the original micro-structure of the iodide titanium specimen and of the micro-relief forming as a result of 0 to a transformation. By means of hie;h temperature metallography methods, the different kinetics of growth have been elucidated of a-titanium crystals during polymorphous 0 to cL transformation. It was established that the time of formation and growth of e-titanium crystals until reaching their final dimensions may exceed 1/16 see and may also continue at a rate of 0.8-1.21/aec. In individual cases an additional growth of tte a-titanium. crystals with an average rate of 0.06 to 0.08 /sec was observed during the polymorphous transformation. The here described schemes illustrate the causes of observation of differing kin#~tics of growth on the a-titaniuja grains observed on the specimen surfaces. There are 9 figures, I table and 9 references, 6 of which are Slavic. SUBMITTED: May 24 195 AVAILABLE: Librar~ of %ngress. Card 3/3 L-6-2/1 7 AUhORZ:LozJ.nskiy, 2J. G. ~;Dr.of.Tech Sci.), Guterman, M.B. and ~Anti2a&,Ia4 I. (Enginoors5 TITLE: Micro Nonuniformity of Deformati)n of Metals during Ifigh Temperature Heating (Mikroneodnorodnoat' deformatsii motallov pri vysokotemporaturnom nagrove) PERIODICAL: Metallovedeniye i Obrabotka Metallov, 1)V'-, Nr 6, pl) 6-9 and 4 plates (USSR) ABSTRACT: Oding and Ivanova (Rof.1) have shown that in the volume of specimens subjected to tension at room temperaturo and at elevated temperature the speed of expansion differs in the in- dividual local sections of sizes of about 10 mn. In this paper information is given on the relations govern- ins the kinetics of nonuniform deformation in the micro volu;nes at temperatures above and below the equicohesion temp2rature, i.e. under regimes at which the Crain bound- arie3 are respectively weaker or stronger than the body of the grain. -The experiment3 were effected on equipment de- veloped by the Institute of Machinery$ Academy-of Sciences, USSR. A%Vajuablo.featureot tbia-equipment is the possibility of direct observation under the microscope and photographing of the micro structure of the surface of the Card 1/4 Micro Ponuni-rormity of Deformation of Metals during Hi,gh Tempera- ture Heating. studied specimens w4en heating up to 11000C during the process of deformation under tension in vacuum. For measur- in- ';he micro hardness a series of indentationo by a dia- U Mond pyramid were made in the longitudinal direction of the apecimen with spacings of about 0.05 to 0.1 mm; these indentations -we re viewed with a microscope with a mag- nification of eUU times, During the tests one and the same sect'j.on of the surface of the specimens was continuously observed and photographed and the produced aeries of micro photographs permits comparison of the nonuniformity of the def ormation and of the individual micro volumes of the speci- men. The accuracy of measurement was 0.05%. Figs.2 and 3 (plates) show two series of micro photographs made of the same section of the surface of annealed spoeimens of a single phase nickel-molybdenum alloy, with 7% 1.1o, during hea ing and tensile stressing in a vacuum of about 10-9 mm.dg col. In Fig.4 the deformation is graphed of the Card 2/4 .;C)V- 121,1- 17 Micro Nonuniformity of Deformation of Metals durin6 Hi" Tempera- ture Heating. individual micro sections and of the entire zone during the tests of the specimens, the micro photographs of which are shown in FiE;.2. In FiS.5 the deformation curvos are graphed o f raicro sections and of the entire zone durin,' testinG L; of a specimen, micro photograrhs of which are given in Pig.3. Fig.E. shows the micro structure of a specimen of a homo- Cen12ed ageing alloy of iron with 12 wt.% Mo after being subjected to tensile stresses of 40 kg/=2 at 4500C for 2 hou-rs. In Fie,7 the relative changes of the dimonsions of the &iagonals of the square indentations (shown in Fig.2), by the diamond pyramidson the specimen curface are graphed. Fig.6 shows the micro structure of the surface of a speci- men of Fe-Mo alloy (12 wt % Me) after bein" subjected to a tensile stress of 40 kg/=2 at 4500C for hours in vacuiim. The here described experimental results have enab- led for the first time the recording of the kinetics of the nonicAform.process of deformation in micro voltmea in a wide tomp-arature range by direct observation. Thereby the non- unif3rmity observed earlier in relatively larger volumes of lengths of 1 - 10 mm (Ref.1), w a a considerably more Card 3/4 pronounced in sections of dimensions from 50 V, onwards. Micro Nonuniformity of Deformation of Metals durin(- High Tempera- ture HeatinE;. Furthormoro, within a sVigle grain, the magnitude of de- formation evaluated by distortion of the indentations on the specimen and the change in the spacings of these in- dentations varies very considorably. Thero are 8 fi.,7tu-es (4 ef them plates) and 5 references, of which 4 are Soviet mid 1 Bnf,-Iish. ASSOCIATION: Institut h1ashinovedeniya AN SSSR (Institute of Machinery, Academy of Sciences US03R) 1. Metals - Deformation 2. Metals - TeVerature effects 3. Metals - Test methWa Card 4/4 ';OV/129-58-11-3/13 AUTHURS; Bokolkov, Ye. N.t Candidate of Technical Sciencev, Lozinskiy, M. G,t Doctor of Technical Science and Antlpova, Ye. L, Engineer TITLE: " Siructur-e-o-f--Gtain Boundaries and Heat Resistance of Aus~enitic Steel (Struktura granits zeren i zharoprochnost' ausVenitnoy stali) PERIODICAL: Metallovedeniye i Obrabotka Metallov, 1958, Nr 11, pp 19-25 + 4 plates (USSR) ABSTRACT: Hardening of the boundaries of austenitic grains, detected during impact bending tests and also as a result of static tensile stresses at liquid nitrogen temperature (Ref 6), leads to the assumption thattl*hxA-ning is &ccompanied by an increase in the resistance to plastic defcrmation at elevated temperatures. Therefore, it was considered advisable to investigate the influence of the structure of the grain boundaries in the austenitic steel 6OXb4G8NBX on the creep speed. After hardening from 1100-1150 C, this steel has an auotenitic structure and possesses a high impact strength, 30-40 kgm/cm . Ageing in the range of 600-8000C results in separating out of Card 1/5 a carbide phase which brings about a drop in the impact SOV/129-58-11,-3/13 Structure of Grain Boundaries and float Resistance of Austonitic Steel 2 strexxgth to 3-5 kgm/cm Tha dove ant of brittleness is ac,,ompanied by inter-crystallitucruptions. 0 It was established that rolling of steel at 9U0 to 1000 C under conditions excluding recrystallisation of austenite leads to a -eduction in the brittleness. The authors considered it of interest to compare the established influence of plastic deformation on the impact strer4_sth with the creep speed at elevated temperatures. The experiments were effected by means of the test device IlLkSh-5M which permits studying the micro-storucture during heatine and tensile teats in vacuum (Re fa.?-9). The material was prepared for the 00~nvestigatious as follows: the blanks were heated to 12 C and0allowed to cool to the rolling temperature (1000-1100 C). Rolling with a reduction of 25% was effected on a laboratory rolling stand. For preventing recryotallisation of the work hardened austenite, the metal was cooled Immediately afterwards in water, whereby the time interval between the end of the rolling and the cooling procees amounted to no more than 0.2-0.3 see. A part of the blanks which 'were ngt subjected to deformation were also Card 2/5 hardered from 1000-1100 C. Following that, the blanks were 6OV/12Q-58-11-3/13 Structure of Grain Boundaries and Heat Resistance of Austenitic Steel aged for a duration of four hours at 7500C and then specimens were cut out to a shape as shown in Fig.l. The flat surface of the specimen was ground and chemically Otched for the purpose of revealing the structure. The etched stru8ture was conserved durinS suboequent heating to 900-1000 0 in vacuum and this enabled observations of the changes in the structure during plastic deformation, For measuring the deformation during the tests a number of indentations were made on the ground surface; these wero arranged perpendicular to the axis of the specimen with spacings of 6 mm; during the tests the distance between the individual indentations were measured with an acciLracy of + 1)A. The specimen was heated by passing current direFtly through it, whereby the temperature was controlled by a thermocouple which was welded onto the specimen. All the changes in the structure observed during the tests were recorded by photographing one and the same spot of the ground surface. The micro-structures of the specimens after three heat treatment regimes are reproduced in Fig.2, wheReby the duration of ageing in all Card 3/5cases was 4 hours at 750-C. The test results graphed in SOV/129-58-11-3/13 Structure of Grain Boundaries and Heat Resistance of Augtenitic Steel Fig-3 e. the changes in the elongation of the steel 6OKh468Ni8V with various ini8ial structures as a function of the Pst duration at 900 G and an initial load of 5 kg/mm , show that the behaviour of the specimens differs greatly for differing initial structures. It can be seen from Figs.4 and 5 that in ordinary speciWens,as well as in specimens preliminarily deformed at 1000 C,cracks will appear and develop along the boundaries of the austenitic grains. The influence of partial recrystallisation at elevated temperatures on the heat resistance is graphed in Fig.3; a special experiment (curve 4) shows to what extent the creep speed can increase when crystallisation. develops. On the basis of the obtained results the following conclusions are arrived at: For the investigated alloy an increase in the heat resistance will be brought about by such changes of the structural state of the austenitie grain boundaries which result in an intensive distortion of the preliminary plastic deformation under conditions excluding development of recrystallisation; a decrease in Card 4/5 the creep, speed is linked with braking of the plastic SOV/129-58-11-3/13 Structure of Grain Boundaries and Heat Resistance of Lustenitic Steel deformation along the boundaries of the austenitic grain-, hardening of the alloy is apparently also determined by a change in the fine structure throughout the entire body of th* grain. There are 5 figures and 9 references, 8 of which are Soviet, 1 Czech. ASSOCIATIONS: Institut fiziki metallov UFAN SSSR (Institute of Metal Physics Ural Branch of the Ac.Sc., USSR) and Inatitut mashinovedeniya AN SSSR (Institute of Mechanical Engineering, Ac.Sc., USSR) 1. Steel--Structural analysis 2. Grains (Metallurgy) __Bouxid~ IVer 3. Grains (Metallurgy)--Crystal structure 4. Austenite--Metallurgical effects Card 5/5 34534 S/659~61/007/000/021/044 it. lift D217/11303 AUTHOM Sadovokly, V.D., Sokolkov, U.N., Lozinakiy, X.G., Gaydukov, M.G., amd Mirmollshteyn V* *A; TITM Influence of thermo-mochanical treatment on the high temperature strength properties of austenitic steel SOURCE1 Akademlya nauk SSSR. Institut metallureil. lonledova- n1yo. po tharoprochnym oplavanf v. 7s 1961, 202-209 TEM A complex alloy steel of the suotonitic claso, widely used In Industry for manufacturing components for high temperature ser- vice, was studied. Thiring ageing of this steel, the co=plex throni- um anti vanadium carbides responsible for Ito strengthening arc pro- clgit;lted. The material was heated to 1180 - 120006 and rolled at 10 0 - i10000 at a speed of 5.7 m/mIn. After rolling, the billets were im,modiately water quenched In order to prevent recrystalliza- tion. The croes-section of the billets obtained was 11.5 x 11.5 mm their length. 70 mm, and the reduction due to rolling, 25 - 30 Ix Card 1/4 3/65 61/007/000/021/044 Influence of thermo-mochanical D217YD303 Contrcl billets were heated simultaneoualy with thoce chosen for thermo-mechanical treatment, and were ruboequently quenched from the alloys temperaturt . All billets, whether therno-riechnniorilly treatod or only heated and quenched, were aged to a hardne9o of 510 - 320 11B. After heat treatment, specimens for two series of tests we re nods from the billets. One series woo uned for utudyinr otruc- ture (luring high temperature extension In vacuo. Thin n1no onabled the dogroo of deformation to be determineO and photographo of the some portion to be taken at various stages of testing. Tenting wan car~iod out in a IVASh-59 machine at 9000C and a strooo of 11.).5 `g /mm , using specimens of 3 x 3 mm croso-oection, heated by dire,A paucalle of current. The second series of tests, in which K.I. Tere- khov partici ated, consisted of the standard test; for long-term atr:ngth at 95000 and stre' sees of 35 and 38 kg/mn , no well as at 700 0 and a stress of 32 kg/mm2. For this purpose, opecimeno 0.0 aorkihS portion diameter of 5 mm and 50 mm length were used. The microutructure of eaoh 0psoimen was studied In conjunction with these tests, particularly any peculiarities In structure appearing after therso-cochanical trelatmont as compared with nomal quenching. Card P/4 3/6S 61/007/ON/021/044 Influence of thermo-mechanical ... D217YD303 The distribution of deformation along the length of the specimen, the inttrorystalline and crystalline plasticity and the formation and projagation of crack@ during fracture wore given particular attentIcn. It was found that high-tomperature p1notic deformation of the tteel Investigated, under conditions In which retryetallita- t1on prccessen are suppressed (thermo-mochanicnl treatment), leada to a considerable increase In long-tern strength. The beneficial ac- tion of thermo-mechanical treatment Is associated with structural charaottriotlea of the steel which arise during high temperature plastio deforustion and are fixed by cooling at a sufficiently high rate. Such characteristice are the complex geometry of grain boun- darloo, grain fragmentation and further refinement of the fine cry- stal structure. These structural characteristics of the sttcl re- tarded the development of fracture during creep, since (a) the cha- racteristic serrated grain boundar structure retards the amalgama- tion between micro- and macro-orall (b) breaking-up of the fine crystal structureq and an Increase In the density of Immobilized dislocations render plastic deformation within the grains more dif- ficult. There are 5 figures and 16 referencess 15 Soviet-bloo and Card 3/4 S/65 61/007/OCO/OZI/C44 Influerce of thermo-mechanical ... D217YV303 I non-3ovist-bloo. The reference to the Englich-language publica- tion reads as followes PA. Davies and J.P. Dennison, J. Inst. Me- %also 67, 4, 19584 Card 4/4 V129/61/0CO/010/001/012 E193/E48o AUTHORS; Oding, ].A., Corresponding Member AS USSR, Lozinshiy, W.G. Doctor of TochnienI Sciences, Ye.l. Foisiticer mid Stepanov, V.N, Engineer TITLE- A study of* the mechanism or fracture of austenitic steel in short-time service at 1100*C PERIODICALi Metallovedeniye i termichealfayn obrabotka metallov. no.10, 1961, 10-13 4 4 plates TEXT- Results are roportod of' short ticin (3 to 30 mtmutem), cont%tant-lond and timo-to-rupture tests, carried out at 1100 C on austenitic stools '3X18H9 JEKhl8N9) (0,07% C. 18% Cr, 9% Ni, 1.564~ mn, 0:31% Si) and 4XIhHI482M (Ijl'hI4Nl4V2M) (0 45', C 141- Cr, 15',- Ni, 2~3-, W, 0.61~ MI and ().VI, SI). Tho ter-I piecflyt wore prelimisiarily hent troj%trij J)y hoj%tilir fol- two litim's nt 1100% in evacuated qujirtz, apipul.ps f'o),lowecl I)y oil t1liellelling. face of each liptit trisated spocimon was polished avid etcheJ to reveal the tiic ros true ture and test pieces with an average grain- size of 30 to 60 (EhhION9) or 100 to 130 microns (liKlilliNJIM.,m) were selected. Iluring the test-; (carried out iii vacuum) the etched side of the tost pieco, marked by a serit!.q of' Card I/V lie 2-899 5/129/0 1/(4)0/010/001/012 A study or tht~ tirchaninii, E193/E411V (50 tnicrons) microhardness indentatioiis, was facing n window through which microcinephotographs were taken throughout the duration of' each test. This made it possible to study each Stage or the deformation process by measuring the increase in the dixtatice between the diamond pyramid indentations, and by following the changes in the microstructure. To overcome the difftcultier4 caused by volatilization of the test riece material and its subsequent condensation as a metallic film on the window of the vacuum chamber a special device was constructed whose detailed description is given in the paper. Some of' the typical results are reproduced in Fig.9, showing the strain (r, %) versus time (mJnutep) curves for Steel hKhl4Nl4V2M tested at 11000C under a stress of 5,5 kg/mm2j broken curve relates to the total elongation of the test piece, curves marked by numbers give the elongation of microregions bounded by the corresponding diamond indenter marks as shown in the insert in Fig,q, Other observatiotis can he summarized as follows. (1) The microstructure of the Steels Studied was revealed after one minute at 11009C; this was most likely caused by preferential volatilization of the metal in the grnin boundary regions, (2) Intergranular cracks appeared in the very early stages of Card 2/1j 09 S/129/61/000/010/001/012 A study of the mechanism ... E193/E48o deformation which indicated that, under the experimental conditions employed, creep in amsociated mainly with intercrystalline slip with very little deformation taking place within the grnins. (3) The total elongation depended upon the applied stream and varied botween 17.5ond 25% in steel EKhl8Nq and between 8 and 16% in steel 410illiN14V2M. This difference was attributed to the larger grain-size or the latter material. UO For an equal stress of 2.5 kg/mm2, the time -to-rupture was 5,5 and 24 minutes on steels EKhl8N9 and 4Khl4Nl4V2M respectively. This difference was also attributed to the difference in the grain-size, since the total length of the grain boundaries which determine the strain accumulated prior to fracture is ismaller in a coarse-grained nuiterial. There are 9 figures and 3 Soviet-bloc references. ASSOCIATION: Institut metallurgii. i Institut mashinovedeniya AN SSSH (Institute of Metallurgy and Institute of Science of Machines AS USSR) Card 3/4 BOKIRIT11-YINO S.Z. (Moskva); KISHNUN, S.T. (Moskvs); LOZINSUY, M.G. (Moskva); SOKOLKOVP Yo.N. (Moakva)l Prinimnli uclinst.1ye: PODVOYSKAYA, O.N.; ZILOVA, T.r.; SOROKINA, K.11.1 FOLYAX, E.V.; WROZ, L.R.; BULYGIN, I.P.; LASWO, N.F.; POKOESTOVA, T.N.; GORDEYEVA, T.A.; YAGLOV, ft.V.; VOLODINA, T.A.; KORABLEVA, G.N,j ANTIPOVA~U.I._ Thermomechanical treatment of chromium-nickel-mangnneso austoonitic steel. Isy. AN SM. Otd. tekh. nauk. Met. i topl. no.2tl5-21 Mr-Ap 162. WRA 1514) (Chromium-nickel steel-linrdening) S/129/62/000/011/003/007 t;073/E535 AUTHURS: Lozinmkiy, M.G., Doctor of T*chnical-aci*ncen and AnLipova, To.l., Engineer TITLE: true ture of nickel at elevated temperatures PERIODICAL: Metallovedoniye i,termichookaya obrabotka mqtallov, no.11, 1962, 18-20 TEXT: High-purity nickel specimens were heated in vacuum to 1100% for 30 mill, then cooled to 500% and subjected to the effect of' twelve successive 1 cm3 domes of air. The structural changes caused by the oxidation process were studied by observing the microstructure, particularly as regards coloration. The lowest rate or increase in the thickness of the oxide film was observed in the light yellow sections of the surface with an orientation approaching (100). The oxidation was more intensive 'in the orange coloured sections with orientaiions approaching (111). The highest rate of oxidation was in the bluo sections, the orientation of which was near to that of the dodecahedron plans (110), The change in colour was most intensive for the Card 1/2 Features or the structure of S/129/62/000/011/003/007 E073/E535 grains with the orielktation (110) which passed through the entire range or colour changes,-indicating that nickel is chemically more active in the crystallographic direction (110) than in the directions (100) and (111),. Coloured selective oxidation after high-ten,perAture vacuum heating can be usefully applied for investigating the initial stages of corrosion and for closer study or the fine crystalline structure of various materials. There are 3 figures. ASSOCIATION: Institut mashinovedeniya GKAM SM SSSR (Institute of Machine Science GKAM SM USSR) Card 2/2 WZLESKIYO 14.G.1 AN-UPOVAS YeOL-j A~~'ONOVAS le*Ao; HLITINAp I.I. Strength of nickel at room and elevated tempernturee an affected by tho specific structural state arising in hi,-h-temperature thermomechanical treatment. Dokl. All SSSR. W no.6tl289-1292 Je 162, (1-11M 150) 1. Institut mashinovedeniya Gosudarstvennogo komiteta Soveta 11inistroy SSSR po artomatizataii i mashinistroyeniyu. Predstavleno akad. A.A.Docharoym. (Metals at high temperatures) (Nickel) (Bocharoym) LOZDMY, H.G.p doktor tekhn.nauk; AYfIPOVA, Yo.I., inzh. Characteristics of nickel structure at high temperatures Motalloved. i tom. obr. met. no.11:18-20 N 162. (MIRA i5tn) (Nickel-Metallography) (Metals at high temperatures) L nilli-1)3 W(q)/tWT(m)/Br0 AFFTCASD JD/JT ACCWSION NR: AP3000491 si'0129/63/000/005/0054/0060 0 AVMOR. Jozins~ciy, M. .; Hirotvorskly, V. .; Antipova, Ye. :Z. TITIE: Effect .)f rolling conditions on-reerly tallization and heat resistance Of gcke~j Q) SOURCE: Metallovedeniye I termitheskays obrabotka inetallov, no. 5, 1963, 54-60 TOPIC TAGS*. nickel., thera=tchanical treatment., r6crystallization range, micro. haitnesso beat rtaistanot,, rdpture life, total elongation, deformation mechanixm ABSTRACT: The cffect of tbermomachanical treatment (m) on recrystallization and heat resistimce In 99.5% pure Ni has been stud-led. Round bars, 16 = In diameter and la, = long, were annealed at 1100C for I hr, cooled to 900, 800, 600, 500, 400, or 20C, rolled at these temperntures with a reduction of 25%, and water quenched. The specimens were then subjected to recrystallizatlon annealing for I hr in a Vacku= at 500-900C. Hardneon tests and microscopic examination revealed that an Increase in temperature of "k.9 increaset, the tem- perature of the beginning anA end of recrystallization. For instance, in speci- mens rolled at rDom temperature recrystallization 1~eglna at approxirately 575C Card 113 L lillh-63 ACCESSION NH.- AP3000491 and Is completeli at approximately 650C. Corresponding figures for specimens rolled at 900C iu-e L-pproximately 660 and 740C. The temperature interval between the beginning tuid end of recrystallization is not affected by the conditions of TMT and remains approximately 75C for all conditions tested. The kinetics of recryst&llizati(in were studied at 600C in a vacuum of 10'5 = Hg. At this tem- perature a sharp decrease of m1crohardnese begins after approximately I hr in all specimens rolled at 20-8000. After 50 hr recrystallization was completed and microhanines a dropped f rom the original 190-) 20 kg/= 2 to approximately 70 kg/r.M2. In specimens rolled 'at 900C the recrystalllzation prcceeded at a mucb lover rate and was not completed even after annealing 100 hr, when nicro- hardness dropped from approximately 120 kg,/=2 to &0 kg/r"2. nlie stress-rupture tests at 600C under an initial str638 of 10 kg/=2 showed that rolling at 20- 900C considerably improves beat resistance as com;ared with that of Iii annealed at 1100C. Speckseas rolled at 20, 400, 800, and 500C bad the longest rupturo life. Specimens rolled at 20 and 700-9DOC haa the lowest creep rate in the first-stage creep. The total elongation in stress-rupture tests, which does not exceed 3-4~ for Ni annealed at 1100G, varied in 7W specimens from 15% (rolled at 5000) to 42% (milled at 600 and 7000. Microscopic exanAnation re- vc&lod a considerable difference in the mechanism of deformations between fully Card 2/3 L 1111h-63 ACCESSION NRi )?3000491 annealed and theitocechecleally treated Ni. In the former, microcrackB began to forr, at the grain boundaries at the very beginning of the stress-rupture test without grain deformationp while in the latter, mlerocracke (also at grain boundaries) appeared only after' completion of recr7gtallization. Recrystalliza- tion appears to delay both the generation and pro;Agation of r-1crocracks. Orig. art. has: 4 figures and I table. ASSOCIATION: Institut mahinovedeniya GKMI pri Goaplane SSSR (Institute of the _Sgience of-Yachinev GKAY. under the Go�plan SSSR, SUMUTTED: 00 DATE ACQ: 03Jun63 EXCL 1 00 SUB COM Y1 NO REF SOVs 012 OTHER; 004' Card 3/3 S/032/63/029/002/025/028 B100166 AVrHORSs Loainskiy, M. To. I., and Nikitina, Is Is TITLEs Device for protecting the inspection glass in high -temperature studies PERIODICALs Zavodskaya laboratoriyal Y. 299 no. 2, 1963t 237 - 258 TEXTv In order to avoid misting of the field of vision caused by sublimates when studying the miorostruoture of heated samples in vaouo, driving device is suggested which causes a quartz glass diso of 105 mm diameter to rotate and simultansoualli to shift in plane-parallel direction at a rate of 3.8 mm per rotation. This ensures that a clear section of the quartz glass always appears In frontof the eyepiece, There are 2 figures. ASSOCUTIONi Inatitut mashinovedeniya (Institute of the Sciences of Machines) Card 1/1 ANTIPOVA, Ye.l.; LOZIN3KIY, M.G. Kinetics of the oxidation of metals during heating studied by means of selective coloring. 7AY.1ab. 29 no,7015-817 163, (MIRA 160) (Metals-Corrosion) (Metallography) ~ I I . " . .. . I ;I , .. I- . I , I I ~ , ~. " i , . ,, I I 1 11 1 .,%.":. %;j.~ I- I I A I rivi z-%rr Z~)Xjv- kill] I I R 000 ACC NRi AT603446o VV)' SOURCE CODE:. UR/0000/66/000/000/0231/0236 JD/JG/GD AUTHORi Lozinskiy, M. G.; Antipova, Ye. I. ORGt none 14 TIT~E: New method and IMASh-A8 unit for examining the microstructure of refractory-metal materialaNuring te-neile tests at temperatures up to 3300C In vacuim,_ argon, helium or hydrogen IM SOURCEt AN SSSR. Institut metallurgii. Svoystva i primeneniye zharoproctinykh splavov (Properties and application of heat-resistant alloys), Moscow, Izd-vo Nauka, 1966,.?31-236 TOPIC TAGS: refractory _400"o refractory microstructure inve tigation 4; 4 ~Mvk L_ J Z-7 7"09 &Lt, ABSTRACT! A new IMASh-181,Unit has been designed for the microscopic0 examination of the structure of specimens subjected to tensile testal at temperatures of up to 3300C in a vacuu of 1.10-S mm Hg or In an atmosphere of argon, helium or hydrogen* IlThe unit features three new elementes a lighting system Kor the qi~ microscopOvhich uses a uercury lamp of the (',!L-AQ_Qr2 hype (power, lOOv; brightness, about 100 keb); an HIM-13CO objective which magnifies 270 times; and a L 1,22 ACC NR AT6034460 Ablut tion, x !7ig. 1. Elongation-time curve for an AV-3 tungsten specimen tested in the IMASh-18 unit. Time min 4 P~ter vhA passes-light vaves A a 546 mu. Specimens of mon; romatic AV- 99.9%-pure tpELIten ontaining OD3%of aluminum and 0,002% of calcium e- unit for tensile streng ver tested n this th at 3000C under a c9netant -'6streas of 0e835 k 9/2P2 and vere found to have very lov ductilitVeven at high temperature (see Fig. 1)o Orig* art* hast 4 figures. SUB CODE: 43 1l/ xGUBM DATE: l0jun66/ ORIG REN oo6/ OTH REF: 001 ATD PRESS: 533 Az AUXBRIT-Vt A*A*q zaaluzhemyy vrach UkrSSR;-A~ITIPOVAp U.N. Daeryocanaliculities Vestn. oftal. 76 no.4t74-76 JI-4063 (MMA 17al) 1. Gorodskaya. bollnitea No#lp SevastopoV, K A IUYIN 91.K.; 0111'OVAP re.N. Compirfitive chdracterlatics of M.e chamical cnmF-n!!ItAon of pagmatites and enclosing rockm Jn the nima p-mAtl'ti zvno. Tzv.vy-%.ucheb.zav.; cool. A razv. 8 no.10 57-(,; C, 14~. 19.1) 1. Trkuts'Kly gosudarstvonnyy univvriltet. ANTIPOVA, YO.V, Afferent lymphatic vessels of the cervix uteri and ovaries. Akuoh. i gin. 39 no.5t82-85 S-0 163, (MIRA 170) 1. Is kafedry akusherstva, i ginekologil (sav. - doteent Ye.V. Norikova) I topograficheakoy anatonii (sav, - prof. A,N, Skobunova) pediatrichaskogo fakulltata Sverdlovskogo medi- tainskogo institutas 6)U,DRIKOV# L q brigadir roloelmotovurnoy ferinyl V.-ATOVA, T, pomoul.chnik brigadiral ahlon rabochoeo komiteta; TLrr;MD:-;Y:;VLj L., prof(.,Mporg; KAWX1NA# Ye, # doyarkal 0!'.'IIIOV, , Yu, I doyarka; F. Cl C. CV40 H, I podamennaya doyarkal Ait~HAMZ M 0--B-,t okotnil.1 IAIUIIJL,~Z%)VAPR,9 tel"taitsu. Dissord.nate, the progressive practice among all 'attte farm workers. Sov. profsoi6y 17 no. 5s12-14 Ur 161* (MM WO 1j. Sovkh6z "Washg" Kuybyshevskoy oblasti, (K4b7sh9v rrovince-Dairying) (Socialist cor-potition) SO, Tr i kA , Abs A ~ -11 P. S Pav` F-A TAt Tf "n, X T 1; IV 0 F- V -R I T~ 11 r "'C e q t, F, A 1C MD MOM -'CF, Kcrtiip. po spf-ktrosk"pi AN S."T'r. P f) Vn -Y, nl~ rorpt 1 or !-T.Pof 112 J--': Aii l;" 11 1 1 of the solvatei Into W-rates takra vlace, vht'e to &qvincPas e01-itinns of ~04 MW Cr-14 the" occiLrB a tr&ngfon %at ion of c ;o I vate m iir~~ 4~ii! I "~r - 3!- 44 odl r c 4, v r:Tt a - Ttp obnorv-~i n% 4 g n r f ', A t r fn& i i! r o r , -.q" ~ cn t) F RIF CODY OF F:W, ."d c'12 Ali? IFOYAo-KARATATVA, I,I*-, GRTJK-GRZHIKArW. S.T. Possibility of using luminescence as an analysis and control of corundum bouls components. Trudy tnet.krist.no.8:139-144 15). (XLRA 7 ' 3) (Corundum) Vaminescence) "The --olition of tliv A or of Ahu-13 f0 'tic C-111-Miun CC!lltcnlv'.ll -,and PIV~s-41',atli Sci, :11,;t 00 Acad Sci 30 Jun 54. (vcAernyaya !:oskva, 1.,oncaw, 22 Jun 15h) SO: SUIV, 318., 23 Dec 1954 PUSHKOVA, T.M.1 ANTIPOVA-KAR&TAY]ITA, I.I* Photolgi-rio ftZa~*'*"-"- lysis. Zhur, anal, khts. 12 no,5t629-636 3-0 '57. (Photometry) (MIRA 10tll) 116a -7 T 11 ~!TSIFTF %-T Fri mmulln I il- rJfT [I IV A u v A - K A 1,~ A N1 n4ell Ml W%4 Off 6 bi ell N 50) AUTHORS V~kyn -U pytj L, Ye SCV/78~4-4~13/44 Anti-nva-Kqrata TITLE: Tnventigation of the Silvation of the Cu lon in Aqueons Iring OptiQnl Absorption Spectra (Iaslodovaniye ".0ra. CU 2. q vk,Jny'Kh rastvor,%kh a pomosh--hlyu C'pttC.he61cik.'&i opektroy ycgloshcheniya) PERIODICAL: Zhurnal neorganichaskoy kbimix 1959., Vol 4. Nr 4, PP 733 1792 (USSR) ABSTRACT. The f4~r:r and the fine stru,7ture of the absorption bands of the 2 -t , CU ons in the spectra of aqueous solutions of copper chloride and -opper nitrate were inveatigated in the region 220-1 1200 m4~ The speatra. were plotted using a 3F. A spectro- photl~meter for concentrations of the copper salts from 0.008 to 9 N. A broad absorption band appears in the apottra with an absorption maximum at 800 mij, With an incroase in aon~~entration the maximum io dinplaced toward longer w%vP. lengthn. The parameters ascertained for the absorption banda in the speotra of the nolutions with tho above-mentioned con- Card 1/4 contrntions are summarized in table i, Investigation of the Solvation of the Cu 2+ Ion in SO11/716-14-4-13/44 Aqueous Solutions Using Optical Absorption Spectra A now method of analysis and evaluation of the experimental results in suggested which allows the separation of the com- pound absorption lines into their components~ This method makes possible the calculation of the parameters and the ascer- tainment of the structure of the asymmetrical absorption bands of the copper ion, The dependence of the position of the maxima of the summary absorption curves upon the distance between the maxima of the components tit various values 2 is givon in figures 2-4 absorption ratio of the D Di maxima of both components, On the basis of the parameters determined the absorption curves of the components and the summary curves were plotted and compated with the experimen- tally determined absorption spectra-. The nomogram used for establishing the absorption curves is given in figure 0. The proposed method for resolving the asymmetrical curves into the symmetrical components makes possible an analysis of 110 % accuracy. An important characteristic of the symmetry Card 2/4 of the field, which is form"d by the radioala around the Investigation of the Solvaiion of the ru 2* Ion in SOV/78 4-4 13/44 Aqueous Solutions Using Optical Absorption Spectra 2+ ii Cu ion in solution, to the ratio of the frequencies of the corresponding maxima of the single components of the observed absorption bands. In dilute solutions 01 for the V2 spectra of both the above-mentioned salts io practically the same ("C-1 for oo~per chloride solutions and 1,24 for copper nitrate oolutiots , The dependence of the configuration of the ao)vated molecules upon the concentration of the solution and upon the nature of the anions was investigated On the basis of the oalculations and the experimental data for the ratio of the f~vquenoiee of the maxima of both comronento of V, of the compound absorption bands --7- a i~24 - 1,29 It was '0'2 shown that the field formed by the radicals surroundiLg the copper ion possesses the symmetry of a tetragonal bipyramid. A table gives the parameters of both oomponents of the ab- Card 3/4 sorption bands for both the salts investigated Investigation of the Solvation of the Cu 2+ lop, In SOV/76-4-4-'3/44 Aqueous Solutions Using Optical Absorption Spectra There are 13 figures, 2 tables, and 9 references, 5 of which are Soviet., ASSOCTATION7 Inatitut geokhimii I analiticheskoy ~himii im, V, I. Vernadr- kogo Akademii nauk SSSR (Institut, of "leochemistry and Ara- lytical Chemistry imeni V~ I. Vernadakiy of the Academy of Solences, USSR) SUBMITTED: January 21. 1958 Card 4/4 5(4) AUTHOP~3: Aptipova--K~i~ ay SOV/78- 4 .4-14/44 TITLE- Investigation of the Solvation of tho Cu2+ Ton in Alcoholi,~ 3olution.i Uning Optical Absorption Spectra (Issledovaniye sollvatataii iona Cu 2+ Y spirtovykh ras%vorakh 9 pomoshchlyu opti%iheskikh spektrov pogloshcheniya) PERIODICAL: Zhurnal neorganicheekoy khimii.. 1959. Vol 4, Kr 4, pp 793-800 (113SR) ABSTRACT. The absorption spectra of solutions of Cu(NO 3)2. 3H,O and GUN 2" 2H20 in anhydrous methyl and ethyl alcohols were in.- vestigated The spectra were plotted using a SFA Apectro- photometer at wavelengths of 220 1v2OO mp, The CuCl 2' 2H 20 concentration varied betweeriCkWani3X in ethyl alcohol and 0.001 and 8.2 K in methyl alcohol. The concentration of 0U(NOj)2 3H20 varied from 0.000c, to 3,2 N in ethyl alcohol The spectra show a broad absorption band with a maximum at Card 1/3 070 m1i. The variation of the absorption bands with the naturl? Irvestigation of the Solvation of the Cu 2+ Ion in SOV/78-4-4-14/44 Alcoholic Solutions Using Optical Aboorption Spectra of the solvent and the number of solvent molecules on the sol- vated copper ion was investigatedp and the results are summa- rized in tableA 1-3. The solvated molecules formed in aqueous and alcoholic aolutions have similar structures. In the solutions of Cu(No 3)2' 3H20 the symmetry of the field of the solvated molecules is Invariable over the concentration range investigated. Nevertheless, in solutions of CuCl,. 2H 20 in water and methyl alcohol the symmetry of the field of the solvated molecule is variable over the concentration range. The cause of this is the complicated solvated molecules which form in concentrated solutions of copper chloride and which include chloride iona,. Beerle Law is followed in the range of lower concentrations in aqueous and alcoholic solutions. The absorption coefficients of Cu 2+ are nomewhat greater in ethyl alcohol than in methanol solutions. There are 5 figuren,, 3 tablee,nnd 0 references, 21 of which are Soviet. Card 2/3 60'1/51-7-2-24/34 THOR t Antipova-Karstuyeva. 1.I. TI TLE i Inv"atl6ation and Interpretation of Bands in the Absorption Gpectra of %,O,r~-stala Coloured with Chromium Ions (Issisdovaniye I interpretstolys volos v s-,)6ktralch pogloshchaniya kristallov, o1crashennykh ionsmi Ithroma) 11SMODIMLsOpt-lica I spoictrosicoplys, 1969, Vol 7, Nr 2, pp 263-265 (IISSR) AWT'.t',GTs The author studied absorption spectra of Gr3+-colourai crystals of Kcr(S04)2.l2H2O alums and artificial rubles, as well as solutions of KCr(SO4)2-l2H2O- An SP-4 spectrophotometer was used and measurements rare made In the region 200-1200 m1i. 7*o wide bands (Fig 1) with maxim at Vl a 17400 cm-1 and V2 a 243M cm-1 were observed at all concentrations of altua solutions In wat-9r. In KCr(S04)2-12H20 crystals (Fir, 2) three tends were observed at V, = 17700 cm-1, V2 = 24600 cm-1, )~ - 38730 cm-1. Three bands -..are also observed in the spectrum of artificial rub crystals .*.1203-Cr203 (Fi-- 3)1 these bands ware at Vi a 17750 cm-T, %~ - 24700 cm-1, V3 - 3G500 cm-1. The oceurrence, or three absorption bands Iii the crystal spectra to unexpected since the cryttal field ueory predicts only two bands for Cr34' tons in fields of I.~O 1/1" octahedral symaetry (ban" obtained In alums ami rubies discussed here). Ths ukithor suggests that tr.e three bands are due to configuration exchange 1i.v3-.*Ut;Ation and Interprotition of HAnds in the Actorption Spectra of Crystals zoloured with Chromium Ions interaction between levels of the same #)wuetry F, but bolon6iq to tome with different orbital quantum nimibors L, 61. levels FISOF1 and F16(4?). This leads to mutual repulsion of the ititeracting levels. as shown In Fig 4t Fig 4a shows the level scheme of a free Cr3+ ion. Fig 4d shows the ion in an octahedral symaetry field, Fir, 4% shown the ion In the soune field but with the intaraction between F, levels taken into account. The Interacting levels lose their reture of pure 4F and 41 tams , 'And the selection rule 0, tl no 'on &or holds. The following transitions are then possibles A21(4F)-#Fl ( , 4F 4p), A26(4F)-4plr(4p, 4F) "d '12 -*F26- cknowlaAgient is trride to Kof A. Ki6a of :.ungarfan Nople""s Hopublic for his advice. There are 4 fl&ureg and 7 references, I of v::ich to Soviet, I .rauslAitloij f,'mm 3neplish Into Rusr-Iq4 1 3n3lish. 3 4anaan &M I HunGarian. ~;Iji~,ITZEDs Fobrusry 16, 1059 ~--% rd VZ ~AMNMTA-UUTATVA, I.I.; VAYKSHTEYN, R.Yo. Study of ion solvation In solution by meazis of ab" orptlon spectra. Zhur,naorg.khIm. 5 no-13107-111 Ju 160. WIM 1315) 1. Inetttut gookhtmit I analiticheekoy khttali in. V.1. Vernadskogo Akadsmii Hauk SSSR, (Solvation-Spotra) -AFTIMA-KWTAYJWA, Ialst KWSIM, TUJ, Spectrophotonstria determination of arbium and holuium in solutions* Zhur* anal. Was 15 no,5081-566 8-0 160, (MIRL l3tIO) 1, Vale Verusidsky:Institute of Osochemistry and Analytical Chemistry, Academy of Solencest UeSoBaRol Moscow* (Ikbium-Azalysis) (HoWum-Analy-sis) vAT1;.';11Ti;YT;j k;.Yp.j ANTI MVA-.VJiATAYEVA,, 1.1, Spoctrophotmetrio study of the structure of eolvated ions in volutions and Lhe degree of their stability under X-irradiation, Izv. Sib. otd. AN SSSR no, 308-45 161, (MIRA 140) 1. Institut gookhimli i analiticheskoy khWi in. V.I. Vernndakogo AN SM.. 14ookva., I Institut neorganichookoy khinii Sibirskogo otdelonlya All SSSRp Novosibiroto (Solvation) (X rayo) ~,,ANTIPOVA-KARATAYEVA, I.I.; VAUSHTM, S. To. Reply to I*S. PominovIs letter "Comenta on the papaer by I.I. Attipova-Karataeva wM 9. E. Vainahtein.11 Zhur. neorg. khim, 6 no.3:759 Mr 161. (HIM 140) 1. Inatitut gookhimii i malitichoskoy khiudi imeni V. I. Vemadiskogo 4kademii nauk SSSR. (Solvation) (PODADOVO I. S.