SCIENTIFIC ABSTRACT AKIMOV, G.A. - AKIMOV. K.T.

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(7 1~~-a~ffuman and Aninal Physiology - The Nervous System. V-10 V Abs Jour : Ref Zhur - Biol., No 2, 1958, 8963 Author : I.R. Petrov and G.A. Akimov Inst : - Title : Functional and Morplnol6gical Changes in the Nervous Sys- tem of Cats When the Heext is Isolated from the Circula- tion under Conditions of Artificial Hypothermy. Orig Pub : Vestn. kbirurgii, 1937) 78, Ho .1, 27-43) 156 Abstract : Nine out of twelve cats endured well the prolonged (from 18-ff' to 23 minutes) exclusion of the heart from the circu- lation while a prophylacted complex was employed: ether- o3agen anesthesia, hexone, vitamins B, and C, glucose and general chilling. Full restoration of the functions of the central nervous system occurred in the same sequence as, but more rapidly than after aphyxial. cessation of the heart. Of the animals which survived, in two focal chan- ges were observed In the hippocampus, in two others there Card 1/2 AKIMOV G.A. kandidat maditainakikh nauk (Imaningrad, 24, Nevskiy pr. Z" -P M.' kv .3 2) Changes of the nervous system following cardiac arrest (with' summary In Inglish. P-1591. Vest.kbir. 78 no-5:80-86 Ky 157. (MW 10:7) 1. In kafedr7 nervnvkh boleznay (nach. - prof. S.I.Irarchikyan) Voyenno-maditsinakoy ordena Ienina akademii im. S.K.1irova . (MYOUS SYSTIM. pathol. in cardiac arrest) WARDIAO ARREST. Pathol. nary. system changes) USSR T I, sn' ") Pt Y Human and Animal Aysiology, Tbermoregulation N,,. 218721 AA';. JOUR. RZ),Mol., N&. 5 1959 Y AUTHOR W..; Rurakovskiy, V.I.; Gubler, E.V. ITJTLE via Effect of Deep Total Hypothermia on Functional and Morphological Changes in the Central Nervous System when the Heart is Excluded from the Cir- oF.1.3. pij~q. culation. Byul. eksperim. biol. J. maditsiny, 1957, 43, No.6, A.-FiSTRACT 99--100' On the day following an op,~lration in which the heart was removed from the circulation for 4j---6j minutes, the condition of the animals was practically no different from normal, When the heart was excluded from the circulation for per- iods of 7 minutes to 7 minutes and 45 seconds, 2 out of 3 dogs died. In Tirst group during the period the heart was isolated, abrupt disturb- ances in hemodynamics were noted. Increasing inhibition in the central nervous system was Card: seen in this period. In dogs which underwent 1/2 T-20 TISSR ICA TEGOPY AIVIS. JUDUR. RZhER101, 5 1959, Not 21872 ATYINHOR T1143 . T. TI7W OIZIO. PUB.: : prolonged isolation of the heart, the changes observed were, on the Whole, reversible. The func,tional disturbances following exclusion of the heart from the circulation were in a number of-cases less pronomced than the morphological chapge5.--F.X.Mumladze Card: 2/2 AXIMOV, G.A.. Morphologic changes in the nervous system following rapture of a dissecting aortic aneurysm. Vop. paikh i nevr. no.3:121-129 158. (MIRA 12-3) 1. Iz klinilci nervrykh bolezney Voyemo-meditainakoy ordena Lenins, Fil-ademii im. S.M. Kirova. (AORTIG AWMMM) (NMVOUS SYSTAM-DISFASES) (BAW-DISFASIS) AKIMOV, G.A. Hypothermia in the prevention of neural lesions in general acute disorders of blood circulation. Vop. paikh. i nevr. no-3:148-160 158. (XIBA 12:3) 1. Iz kliniki nervnyl-h bolezuey Voyenno-meditainekoy ordena Lenina akademii im. S. M. Kirova. (UPOTHIMIA) (ANGUNIA) (IMVOUB STSUM-1EGRIMATION AND REGMWATION) AKIMOV, G.A. e--"'--Ohaogse in the nervous system in general circulatory disorders- clinical and morphological observations [with summary in Frenc~j. Zhur.uavr. i paikh. 58 no.1:3-12 158. (MIRA 11:2) 1, Kafedra nervnykh bolezney (nachallnik - prof. S.I.Korchikyan) Voyenno-maditsinskoy ordena Lenina akedemti imeni S.M.rirovs. (16WOUS SYS9NM. patholc;vp in circ. arrest & defic. of various causes (Itus)) (CARDIOVASCUIAR DISEASES, pathology, circ. arrest & defic. of various causes, NS histopathols (Rue)) AK3MOVp G.A. Nervous system in myocardial infaret. Sbor, trud, Lon* nauchn. ob-va nevr. i paikh. no.69128-141 159. (KIRA 13:12) 1. Is kafedry nervnykh bolesney (naohallnik - prof. 8.I. Kawchiluan) Voyanno-mditsinakoy ordena.Lenim akademii imeni S.M. Kirova, (NERVOUS SYSTEM) (HEART-INFARCTION) GUBLERv Ye.V.; AKIMOV, G.A.; ALISHEV, N.V.; LIKHOTA, V.N. ;. On the sequelae of deep hypothermia. Ar . pat.22 no. 12:29-36 kh 160o (MIRA 14:1) (BODY TEMPERATURE) AKIMY) (Leningrad S-24, Nevskiy prosp... d.148.kv.32); LIBOV A.S.; ~$ENINJ V.S. I State of the nervous system foUowing surgery with the use of artificial blood circulation. Grud.khir. 5 no.ls25-34 J&-FI63. OURA 1617) 1. Iz khirurgichaskoy kliniki d1ya usoversheastvovaniya vrachey no,1 (nachallnik daystvitoltnyy chlen AMN SSBR prof. P.A. Kupriya.~ov) I kafedry nervnuch bolezney (nachallnik prof. A.I. Panov) Voyanno-moditainskoy ordena Lenina akademii imeni Kirova. (BLOOD-CIRCULATIUN, ARTIFICIAL) (HRART-SLTLERY)- (BUZ-DISEASE) . A AKIMOV, G.A. (Leningrad, S-24, Nevskiy prospekt 148, kvartJra 32) "Neuromorphological studies". Reviewed by G.A. Akimov. Arkh. anat., gist. i embr. 45 no.71l2l-122 Je '63- (MIRA 17-4) A'K,1~10V G.'.'i. dohtc,,,, j,-.ed.,,,uLtkl -,C-1kov.-h -:I- , ~ , I Y, . --o". -q, - . Twiyor mcd slliz.',by Neurolclglc disorders iln acatc. , . . U- ...! -. ~~ ~ 2 3.', 165. ~ . '-~, - *30- (1-a-RA 18:10) PETROV I.R.; AKIMOV., G.A. (Leningrad) Functional and morphological changes in the central ne system of animals having had prolonged anemia of the brain under conditions of cerebral hypothermia, Arkh. pat. 27 no. 12:46-50 165. (MIRA l8tW 1. Voyenno-seditsinskaya ordena Lenina akademiya imeni Kirova.,-. Submitted Febr. 29, 1964. -j AKIMOV, G. G.,, vodite3l-motovoza *One can not do without this. Transpstroi 13 vo. 11:77 N 63. (MIRk 17:5) 1. Trost Moselaktrotyagstroy. AXIMOV, G.P. Vujrby-shev) Forming the definition of function in the 5th through 7tb grades. Mat.v shkole no.1:64 Ja-F '60. (MIRA 13:5) (Algebra--Problems, exercises, etc.) JAKI-OV, G. S. Alli.Tov, G. S. K "Basic Princinles of Breeding Br,,),,,n Latvian Cattle on the Kolkhozes Der, of the Vidzem StRte Breeding Farm." Acad Sci Estonian SSR. . ar ment of Biological, Agricultural, and Meciien! Sciences. Tallin ' 1355 (Dissertation for the degree of Candidate in Agricultural Sciences SO: Knizhnaya letopis' No. 27, 2 JuIY 1955 AKIMV) G. V. IECEASED Electrochemistry see ILC AKIMOV, I. - - . .. I . let's wAlk alOng the cit7 streets! Znan.ta pratsia,no.9:6-7 S '5 9. (MIRA 13:1) (Kiev-0ow=ication and traffic) AKIMOV., is On integralop friendship and coke pie. Znan. ta pratsia no.20:6- 7 0 116i. (MIRA 14:8) (Zaporozhlye.-Chemical industries) NOSYCINJI A.; NOVIKOV, V.; ~tMVIYEVA, N.; ZOTOV, V.;JAKI SPORISHEV, V.; J(OIOSOVA,, V.; CHESNOKOV, N.; MUZDDVA, 0.; BOGAYEVA, A.1 PIKOVSKIY,.%'X.l KAMd~MVp M.; SIYTAM, Ye.; KHODAKOVA, S.; KUSHNER, P.1 BlLYAKHKAN,, 1.1 U5SIASj, L.; KINWHEKTSEVA, A.; MZNIKGV,.N,l KALIfFLN., �.; MIIANOVA, D.; VENGERMA, R.,- AGROSKINA, M.; ATNER, B.; NARODETSKIY, B.; MMOVA.,!L.; GOLUBENKOVA,.N.; TSkKHAtSK&YA,, S.'; TERENTIYEVA, N.; NESTEROVA., S.; AKSENOV, S. D,M.Khazan-4n&eeva; obituarys Tekst.prom. 21 no.12:90 D 161. (MIPA 15:2) (Khazan-Andreevas Dora 149iseevna;, 1894-1961) AKIMOVP I. Socond birth of precious stones. Zymn. ta pratsia no.3:29 Yx t62. (NM 16:7) (Precious stones) z, -,.-k !A .- '111W. ATI , , . , ! - - AK#MOV, 1.7' , A., and PUTSEYKO, E. "Optical Sensitization of the Halides of Silver, Thallium, and Other Semi-Canductore by Dyestuffs," paper given at the International Conference on Scientific Photography, Cologne, 24-27, Sep 1956 E-3,o68,138 PI 6 V Category: USSR / Physical Chemistry - Crystals B-5 Abs Jour,. Referat 23m, -Kbimlya, No 9, 1957, 29750 Author : Aki r_t__AL_ ;t,-t VF Inst :not-given 5 Title :Photoelectric Properties of the Halides of Silver and Thallium Stained with Organic Dyestuffs Orig Pub; Zh. nauch. i prokl. fotogr. i kinomtogr., 1956, 1, No 4, 254-265 Abstract: By the method of photoconductivity under constant illumination a study was made of the photoelectric properties of iodides and bro- mides of Ag and Tl,, having adsorbed thereat organic dyestuffs (cyanines, thiazines, xanthines, triphenyl-methanes, etc). More than one bal of the investigated dyestuffs sensitize the photo- effect (PE) in Agi. These dye include photographic sensitizers as well as dessusitizers. Dyestuffs which do not affect the sensitivi- ty of photographic emulsions do not sensitize the FE in AgI. Spec- tral distribution of additional (induced by the presence of the dye- stuff) PE coincides with the absorption spectrum of the adsorbed Card 1/2 -40- .- 1 1-1- .-: L- ~ -1---l ~z '1 7-1." -.- - AUTOR: Akimov, I. SOV/20-121-2-32/53 TITLE: The Optical Sensibilization of the Photoeffect in Silver- and Thallium Bromide by Organic Dyes (Opticheskaya sensibilizatsiya fotoeffekta v bromidakh serebra i talliya organicheskimi krasitelyami) PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol- 121, Nr 2, pp. 311 314 (USSR) ABSTRACT: Various authors already reported on investigations on the optical sensibilization of the internal photoeffect in in- organic semiconductors by organic dyes, the sensibilization without impurities in the bromide, howevert is not explained yet (Refs 1-10). In this paper above all the influence of bromine vapor (at 0,1 torr) on dyed and undyed AgBr- and TlBr- layers is inyestigatedl it turns out that the adsorption of the bromine vapor has a clear influence upon the intensity as well as upon the spectral distribution of the photoeffectl e.g* TlBr dyed by malaohite green ahows an intensifioation of the photo-e.m.f. and a shift of the spectrum towards greater values Card 1/3 ofe\ after the adsorption'of bromine Yapor; (before the ad- SOV/20-121-2-32/53 -The Optioal Sensibilization of the Photoeffect in Silver- and Thallium Bromide by Organic Dyes sorption 400-450 m/j- after the adsorption 500-750 ml.4 with a maximum at 700 m~&~. If bromine partly is desorbed the value of the photo-e.m.f. is reduced to about half of it without displacing the position of the spectrum (Fig 1 - TlBr, Fig 2 - AgBr). The position of the maxima of the photoeffect coincides with the maximum of the adsorption of the dyes. A dying by methylene blue does not only change the intensity of the sensibilized photoeffect but also causes a displacement of the ipeotral distribution towards the range of the adsorption of the dye. The photoeffect aensibilized by methylene blue has a maximum at 680-700 m/:t., after the adsorption of bromine' vapor at 780-800 m/4,(Fig 3 - TlBr, Fig 4 - AgBr). The author renders his thanks to A. N. Terenin, Member, Academy of Sciences, USSR, and Ye. K. Putseyko for their interest shown in the work and for valuable suggestions. There are 4 figures and 16 references, 10 of which are Soviet. Card 2/3 . SOV/20-121-2~32/53 The Optical Sensibilization of the Photoeffect in Silver- and Thallium Bromide by Organic Dyes PRESENTED: March 24, 1958, by A. N. Terenin, Member, Academy of Sciences, USSR SUBMITTED: March 3, 1958 Card 'x'13 A.M-.O-Vl -1. $ MMNIN, A. N., and RMMUO, R. '!Energy Transfer in Systems o f Connected Organic Molecules," paper presented at a meeting of the Faraday Society in Nottingbam, England, 1449 April 1959 Angevandt Chemie, 21 June 1959. Hs o I, u 31 00 V. 611 0 a .4 o 0 IZ A 0, Wg, F30.M.~- 5-, glal 01 a E , , I I - 3 1 a. -.- 5 u -.7-C , g. a - A ; " * -.0 ! )% I T 7.0 c A .04 .,UEO~ c 14 to c v "a "C E j'. clc 4 Eat .0 u 04-: c .0 to :ZOE glino-i COU - , 1 i ~, 0 , 9 i '. " . a M V cu If s/o.58/62/ooO/oo8/o86/134 AO62/A1Ol AUTHORS: Akimov, I. A., Putseyko, Ye. K. TITLE: Sign of photocurrent carriers and photoconductivity relaxation in thallium andsilver iodidesy' sensitized by organic dyes PERIODICAL: Referativnyy zhurnal, Fizika, no. 8, 1962,-30 - 31, abstract 8E224 (In collection: "Fotoelektr. ii optich. yavleniya v poluprovodnikakh", Kiyev, AN USSR, 1959, 301 - 313) TEXT: In order to define precisely the mechanism of photoeffect sensitiza- tion, the relaxation times and the photocurrent carrier~signs were determined in non-dyed and dyed layers of TlI and AgI for different region6 of the spectrum. The a'ign of the carriers was determined by the capacitor method. The photocurrent relaxation times were measured by the method of N. A. Tolstoy and P. P. Peofilov ("Uspekhi fiz. nauk *11, 196o, 41, 44) on'a taumeter with an exponential sweep. It was found that the sign of the sensitized,photocurrent carriers does not depend on the sign of the photocurrent carriers in the dyes, but it is determined by the photoeleettic properties of the semiconductor. The role of the dye consists only Card 1/2 S/058/62/000/008/086/134 Sign of photocurrent carriers and... A062/AIOJ in light absorption and transmission of the absorbed energy to the semiconductor. The role of a sensitizer can also'be carried out by iodine molecules (RZhPiz,*1956P no. 2, 4259, and 1. A. Akimov, Ye. K. Putseyko, Dokl. AN SSSR, 1955, io2, 481; - 1. A.. Akimov, EKrKh, 1956, 30, 1007; zhNipriK, 1956, 1, 254), their absorption determines the photoelectric sensitivity in the long wavelength region of the undyed layers of TlI, AgI. The article proposes a scheme of the mechanism of the proper and sensitized photoeffect which Is confirmed by the relaxation measure- ments of the TH photoconductivity. 0. Shubtova [Abstracter's note: Complete translation] ;Card 2/2 AUTHOR: Akim SOV/77-4-1-11/22 T-ITLE: About thehiminascence of Colorants Adsorbed on Certain Semiconductors (0 lyuminestsentsii kra- siteley, adsorbiro~Wnnykh na nekotorykh polupro- vodnikakh) PERIODICAL: Zhurnal nauchnoy i prikladnoy fotografii i kine- matografii, 1959, Vol 4, Nr 1, pp 64-066 (USSR) ABSTRACT: The author investigated the luminescence of some colorants adsorbed on certain semiconductors. This work was suggested and done under the direction of Academician A.N. Terenin. Several organic colorants were tested for their ability to lumi- nescence, in the adsorbed state, on silver and thallium halogenides and the oxides of certain metals. On these semiconductors, the sensibiliza- tion of the photoeffect can be observed. Among various other colorants, fluorescein, eosin, ery- Card 1/3 throsin, rodamin B extra, chlorophyll and magnesium SOV/77-4-1-11/22 About the Luminescence of Colorants Adsorbed on Certain Semi- conductors phthalocyanin were used for investigation. The source of light for the chemical stimulation was a chromatic device of high light intensity with diffraction lattice. The investigated colorants did not luminescence in the adsorbed state of ZnO, PbO, and the silver and thallium halogenides. But the same colorants adsorbed on MgO, BaO, TiO,, paper, cotton wool, gelatin and polyvinyl la quer displayed an intensive luminescence. It does not seem to be quite impossible that such substances as PbO, AgBr, Tl&-, that have a red and orange luminescence, are energetically sensitized by the colorants. Card 2/3 SOV/77-4-1-11/22 A'bout the Luminescence of Colorants Adsorbed on Certain Semi- conductors There are 18 references, 8 of which are Soviet, 6 American, 1 English, 2 German and 1 Japanese. ASSOCIATION: Gosudarstvennyy opticheskiy institut imeni S.I. Vavilova (The State Optical Institute imeni S.I. Vavilov) SUBMITTED: October 20, 1958 Card 3/3 9(3),24(3) AUTHOR:. Akimov, I. A. SOV/20-128-4-15/65 TITLE: Effect of Illumination on the Contact Potential of Some Semiconductors PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 4, pp 691-694 (USSR) ABSTRACT: First there is mention of previous papers in this field. V. P. Bogolyubov (Ref 8) investigated the influence of illumination on the contact potential of selenium layers. 1. K. Vitol recently used a dynamic condenser for the investigation of photoelectric polarization in alkali-halide crystals. Scope of the present study is the examination of the change in the contact potential of a semiconductor under the influence of monochromatic illumination. Therefore,high requirements had to be met by the condenser cell and the amplifier device concerning sensitivity and stability of operations. The article contains a description of the measur- ing device. The condenser cell consists of a glass vacuum vessel in which a semi-translucent platinum layer on a mica sheet serves as vibrating electrode. The second electrode Card 1/3 is a platinum-coated cylinder which is subdivided by incisions Effect of Illumination on the Contact Potential of SOV/20-128-4-15/65 Some Semiconductors into four sectors. The layer of the semiconductor to be examined is put on one of these aectors by sublimation. T he author determined the difference in the contact potential between the platinum electrode and the semiconductor electrode in vacuum and in air both for inorganic semiconductors (TlJ(p), CdS(n), Zno(n)) and for several organic dyes and determined the spectral distribution of the contact-photoelectric potential. Two diagrams illustrate the spectral curves of the photoelec- tric potential for layers of ZnO and TIJ, which were sen- sitized by dyes. These curves are in accordance with the spectral distribution of the photoelectromotive force and the photoelectric conductivity of ZnO and TIJ layers (stained with identical dyes). This method permits, besides the examination of the spectra*1 distribution of the photoelectrical potential, also a judgment on the sign of the current carriers. The data obtained with the described method concerning the sign of the photoelectric current carriers are in accordance with the results obtained by other authors who used different methods. When illuminating the semiconductor layer from the opposite Card 2/3 side the photoelectric potential changes its sign as expected. Effect of Illumination on the Contact Potential of SOV120-126-4-15165 Some Semiconductors According to V. Ye. Kozhevin and V. Ye. Lashkarev (Ref 18) tile magnitude and the sign of the photoelectromotive power of the condenser investigated in 2 previous papers (Refs 10,11) depend on the character of the insulating intermediate layers. To clarify this problem the author examined the contact dif- ference of the potentials for TIJ and phtaloayanine between the platinum e.lectrode and a layer of the semiconductor, which was in vacuum, in air or in contact with various insulating media. In darkness the contact difference of the potentials can be varied within wide limits (from -0.4 to +4.5 v). But these variations were of no considerable influence on the rate and sign of the photo potential in the case of TIJ and the phtalocyanine. The excess electrons and holes developed by the light diffuse either into the depth or to the surface and re- combine subsequently. The author expresses his gratitude to Academician A. N. Terenin for suggesting the topic and for his advice, and to Ye. K. Putseyko for his counsel . There are 3 figures-,' 1 table, and 20 references, 13 of which are Soviet. PRESENTED: June 1, 1959, by A. N. Terenin, Academician SUBMITTED: flay 26, 1959 Card 3/3 69847 s/o5l/Woo8/03/035/038 E201/E191 AUTHORS: Akimov, I-.A,., and Torsunovskiy, G. TITLE: '~he E-ffect of s-o'me "Electronophylic" Compounds on the Absorption and Luminescence Spectra of Magnesium .-Phthalocyaninalsolutions PERIODICALS Optika_i spektroskopiya? 1960, Vol 8, Nr 3, PP 427 1+28 (USSR) ABSTRACTS The authors investigated the effect of hydrochloric acid and of some metal chlorides on the absorption and luminescence spectra of magnesium phthalocyanine solutions. On addition (in air) of a solution of ferric chloride (FeCli.6H20) in acetone to an acetone solution of magnesium4/ phtha ocyanine, the blue colour of the solution changes to olive green and the absorption spectrum is altered as shown in Fig 1. The absorption bands of magnesium phthalooyanine with maxima at 665 and 601 mp disappear and new absorption bands appear with maxima at 707 and 682 mp. When the solution is allowed to stand the latter two bands decrease Card in intensity. After several hours new weak bands, characteristic of phthalocy'anine without a.metal, appear at 688 and 655 mp. Simultaneously a deposit is formed 69847 a/051/60/008/03/03 5/038 B201/9191 The Effect of some "Blectronophylic" Compounds-on the Absorption and Luminescence Spectra of Magnesium Phthalocyanine Solutions which when dissolved in dioxane exhibits a spectrum of phthalocyanine without a metal. Similar behaviour is observed also on mixing of an acetone solution of magnesium phthalocyanine with an acetone solution of hydrochloric acid of lo-3 m/e concentration. These experiments indicate that the central magnesium atom is replaced by hydrogen and that this reaction proceeds via an intermediate unstable complex which has absorption-bands at 707 and 682 my. An unstable complex is formed also on addition of Sbcl~, BnC14 and SnII+ to an'acetone solution of magnesium phthalocyanine but in this case the absorption bands of phthalocyanine without & metal are not observed. Addition of bases such as pyridine, aniline or a concentrated aqueous solution of potassium hydroxide, destroys phthalocyanine complexes7las shown by the reappearance of the absorption spectrum characteristic of Card magnesium phthalocyanine. The authors.investigated also 2/1f the luminescence spectra of the mixtures described above. The spectra,were reoorded spectrophotometrically and they 69847 8/0 51/60/008/03/03 5/03 8 B201/sigi The Effect of some "Blectronophyliall Compounds on the Absorption and Luminescence Spectra of Magnesium Phthalooyanine Solutions were excited with the 365/366 mp group of lines emitted by a mercury lamp SVDSh-250. Fig 2 shows the luminescence sPectra-of the solutions of magnesium phthalooyanine (curve 1), of the intermediate complex (curve 2) and of phthalocyanine without a metal (curve 3). A. table on P 1+28 shows that the bands observed on excitation of the complex (683 and 71+5 mp) coincide with the bands of magnesium phthalocyanine, and that the bands of the complex at 720 and 780 mp are close in their positions to the bands of phthalocyanine without a metal. The 708 band$ characteristic of phthalocyanine without a metal, is not observed in the luminescence spectrum of the complex, probably because of strong absorption by the complex in this region. The complex itself does not luminesce, since all its luminescence bands are due to either magnesium phthalocyanine or due to phthalocyanine Card without a metal and at longer wavelengths no new 3A luminescence bands of the complex were observed. On addition of pyridine and aniline to the complex the 69847 S/051/60/008/03/035/038 E201/E191 The Effect of some "Electronophylic" Compounds on the Absorption and Luminescence Spectra of Magnesium Phthalocyanine Solutions luminescence bands of phthalocyanine without a natal disappear and the bands of magnesium phthalocyanine are Card intensified. Acknowledgement is made to A.V. Shablya for lending the apparatus for luminescence measurements. There are 2 figuies, 1 table and 1+ Soviet references. SUBMITTED: November 16, 1959 8h668 113o0 (/d 11.3) //Y 3'0-97) ~,qI6() (3-,ol 33/ S/020/60/135/001/021/030 41 X'A 2,0 --~Y B004/BO506 AUTHORS. Akimov, I. A., and'Terenin, A. N., Academician TITLE: Sensitization of the Photoeffect in Semiconductors by Means of Organic Dyes, Which Are Acidity Indicators \1:1 PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 135, No. 1, pp. 109-112 TEXT: The authors investigated the photoeffect in thallium iodide and zinc oxide, which had been dyed by means of organic indicators. Measurement of the photoeffect was carried out in air and in vacuo, as well as after adsorption of anhydrous HC1 and NR3 vapor. Between the resalts obtained in air and in vacuum there was no difference. Aurin, safranine T, thymolphthalein, bromothymol blue, Nile blue, and Congo-red were used, whose structural formula, reaction-pH, Amax and sensitizing effect upon TlI and ZnO are given in Table 1. Besides, experiments were made with malachite green, erythrosine, and methylene blue (Fig. 3). The spectral distribution of the photo-emf is represented in Figs. 1-3. The Card 1/2 84668 Sensitization of the Photoeffect in S/020/60/135/001/021/030 Semiconductors by Means of Organic Dyes, B004/BO56 Which Are Acidity Indicators summational photoeffect sensitized by the indicators changes in the case of TII after adsorption of HC1 only little, but the spectral. distribution changed in accordance with the absorption spectra of the dyes. After adsorption of NH 31 the sensitized photoeffect decreased or had vanished altogether. In ZnO, on the other hand, the photoeffect vanished after adsorption of HC1. After desorption of HCI, ZnO again possessed the initial sensitized photoactivity. The indicators thus sensitize in neutral form both the photoeffect of the p-type semiconductor TlI, and also that of the n-type semiconductor ZnO. In the protonized state (after adsorption of HCl), they are no longex able to sensitize ZnO, nor to sensitize TlI in the anionic state (deprotonized by NH3). These effects are explained by the change in the electron acceptor levels at the surface of the semiconductor, which, in ZnO, are formed by the adsorption of oxygen ions, and in TlI by adsorbed iodine ions. The authors mention a paper by Ye. K. Putseyko~ There are 3 figures, 1 table, and 4 references: 5 Soviet, 1 US, and 1 Prench. SUBMITTED: July 8,, 1960 AMIGV~ I.A.; TFRENIN,, A.N. Use of organic dyes for the optical sensitization of the internal photoelectric effect in silver bromide-, Zhur.nauoh.i prikl. fot. i kin. 6 no.2:108-125 Mx-AP 161. (MIM 14." 4) 1. Gosiklarstvennyy optioheskiy institut im. S.I.Vavilova. (Photoelectricity) (Photographic emiLlsions) 5/181/62/004/006/025/051 B104/B112 AUTHORSt Akimoy.L 1. A., and Putseyko# Yes Ko TITLEs Determination of the spectra of photo'electric sensitivity of semiconductors by different methods PERIODICAL: Fizika tverdogo tela, V- 4, no. 6, 1962, 1542 - 1548 TEXT: The spectral characteristics of the internal photoeffect of uncolored and colored TlI and ZnO semiconductors and of phthalo6yanine were investigated by four different methods in the region of characteristic and sensitized sensitivity; (1) The photoconductivity was determined at constant voltage and under constan~t or'intermittent illumination; (2) the longitudinal photo-emf in a capacitor with a semi-transparent electrode was determined; (3) the changes in contact potential and in the sign of the surface charge of the semiconductor were determined with a dynamic capacitor under constant illumination; (4) the photodieleotrio effect in a semiconductor layer was determined. The alternating signal of the photoeffect (150 or 600 cps) was measured with a resonance amplifier. A correlation between the absorption Card 1/ 3 S/181/62/004/006/025/051 Determination of the ... B104/B112 spectrum and the photo-emf was found for metal-free phthalocyanine in the visible and ultraviolet spectral regions. No overlap of the two spectra could be found in phthalocyanine layers of the*same kind when different forms ofo,- and $-pigments were present in them. A correlation between the absorption spectra and the spectral curves of photoconductivity could be established only for thin layers of organic and i*norganic semiconductors. Differences appear for thick layers: weakly absorbed light sets-free photoelectrons far from the surface, while strongly absorbed light sets them free near the surface. The spectral curves obtained by the four different methods for the sensitized photoeffect of ZnO, AgI, and TlI colored with different pigments agree with.one another and correspond to the absorption spectra of the'adsorbed pigments* The spectral curves of photoconductivity of AgI and TlIp obtained by various methods in the region of self-absorption of the semiconductors# do not agree with another. As in the case of phthalocyanine, the maxima of photoconductivity obtained by m*aaurement * Of the photodialeatric , effect, the photocurrent, the photo-emf, and the contact potential are shifted to the short-wave side of the spectrum. There are 6 figures. Card 2/3 S/161/62/004/006/025/051 Determination of the.. B104/B112 ASSOCIATIOV: Gosudarstvdnnyy opticheskiy institut im. S. I. Vavilova Leningrad (State Optical Institute imeni S. I. Vavilovj Leningrad) SUBMITTEDs January 27, 1962 Card 3/3 AUTHOR: TITLE: S/18 62/004/006/026/051 B104YB112 Akimov, Investigation of the spectral distribution of the internal photoeffect in photochemically sensitive semiconductors PERIODICAL: Fizika tverdogo tela, v. 4, no. 6, 1962, 1549-1558 TEXT: A high-speed apparatus (Fig.-1) was developed to study, in the region of 350-1000 mit, the change in the spectra of photoconductivity and photo-emf of microcrystalline powder of silver halides uncolored as well as colored with cyanogen pigments. The semiconductors are irradiated with about 10- 6 W/cm2 using an incandescent or xenon lamp,*the light of which is modulated by a frequen6y of 600 cps. The spectral curve of the photo-emf in the capacitor is obtained on an oscilloscope. Measurements ~were made on uncolored silver halides and also on powder which had adsorbed organic sensitizers. The change of'the photoeffect in the spectral.region of the absorption edge is attributed to the formation of electron adhesion levels by the products of photochemical decomposition of the Card 1/0- S/18 62/004/006/026/651* Investigation of the spectral... B104YB1 12 silver halide. The experiments with colored layers demonstrate the energy transfer from the pigments to the semiconductor and re,~eal the impo;rtant role of the'aciceptor levels of the semiconductor in optical sensitization. Academician 'A. N. Terenin is thanked for his interest and advice. There are 7 figures. ~LS--:'!~C:.LTION: Gosudarstvennyy opticheskiy institut im. S. I. Vavilova Leningrad (State Opti6al.Inatitute imeni S. I. Vavilov, Leningrad) SUBMITTEM 1962 January 279 Fig. 1. Experimental arrangement. Legend: (1) monochromator; (2) vac'u~m; (3) amplifier; 417-11skynchronous- detector; (5) 31HO-1 (ENO-1) oscillosco~ej (6) amplifier,for reference voltage. Oa.rd 211.-2 z I KHOIMWOROVI V.ye.~,~IMDV, I.A. Nature of a photoinduced electron paramagnetic resonance signal in silver bromide sensitized by cyamine dyes. Dokl.AN SSSR 144 no.2.-402-405 Yq 162. (MIRA 1525) 1. Predstavleno akadeinikom A.N.Tereninym. (Silver bromide-Spectra) (Gyanine dyes) BARANOV, E.V.; AKIMDV, I.A. , Photoconductivity of photographic Dokl. AN SSSR. 154 no.ltl8l+-187 layers at 1010 eyelo'frequency. Ja164. (MM 17:2) 1. Predstavleno akademikom A.N. Tereninym. ACCESSION NRs AP4041048 AUTHOR: Meshkov, A. M.; Akimov, 1. As TITLE: System for invistiRitiiig dontact potential difference, capacitive photoelectromotive Vorct, and photoconductivity of high-resistance semiconductors SOVRCEi Pribory* i tekh.alka.ekspirimenta,- no. 3, 1064, 181-185 TOPIC TXGSs aemi6onductor measureMent, high,.realstance semiconductor! 1 contact potential difference, cipacitor photoolectromotive"Y'orde', photoconductivity :I!ABSTRACT: A system is.'describ,cCl *b eans of which it is possible to measure' the photocurrent (up to '10-14m.,p) and- capacitive photo- ii: electromotive force(up to I'vv)(1a high-aresistance gemicotfductor vith an effective input resistance of l-'Gohm in a vacuum, aswell as - the contact potential difference (cpd), under condi- tions of constant, toodulated, and pulsed illumination with an-accuracy up to 0. 1 mv, An expe~rii~ental setup for measuring capacitor photo- i 4glactromotive'f orce . Oerm~tted dis iecording-of all ft processes of caps- citor photo amf takln~ pl-ace, during. a light modulation ~erlod sl~orter 1/2 ACCESSIONNRt AP4041048 Hthan 0.1 8 e*c I ncoTqbination vitha ayfichronous dete,ctor, even the t nductqr can be Isign of the photocurrent'aharge carrier ih,the semico determined. Two arrangements for measuring the cpd of'semiconductors!, Zi R c ad.pulsed illumination, and were used, one utili n ontinuous a the other modulated illumination. The zero method was used for imeasuring the stationary c~d uhder conditions of continuous illumi- nation. In pulsed illumfnatioi~ the signal proportional to the cpd i displayed on an os~illograph'or recorded. The "dulatdd illumi-". is mo nation method permitsthe.investigation,of the initial phase of the cpd variation and eliminates processes longer than a sin gle Period of light modulation, Afr'equency modulation of 10 cps'%ins used~i .1 Or.ig. art. has; 3figureae ASSOCIATIONs CoBudar.stvanny'*Ir opt'ichaskiy inatitut (State Optical institute) SUBMITTEDtt.-06JuI63 ATD PRESSt 31060 ENCL:' 00 SUB CODEt ECj EH NO REF SOVt 017 OTHERt 003 2/2 'Card--- ACCESSION NRv AP40307.'90 Si0020/64/155/004/0900/0903i kimov o' 'h AUTHORt TerenLnq A* No(Academicion); Putseykog Too Kol A Heshkovp As No TITLEs Effect of the state oi aggregation of dyes on th's photo- arrier sign current c SOURM AN SSSR, Doklady*, v. 1559 no. 49 1964, 900-903 TOPIC TAGS: dye, brilliant green, crystal violet. malachite green, auramine, organic semiconductor ABSTRACTs The spectral response of photo omf was plotted and the photocurrent and dark current carrier signs were determined for brilliant green, crystal violet, malachite green$ and auratine dyes, The spectral response of photo amf and the photocurrent carrier sign was determined by the condenser and contact potential methods, and the dark current carrier signq from the Seebeck effects, The samples used were in the following states of aggregationt amor- phoun deposits from ithonol solutions (and in some cases amorphous Card 1/3 ACCESSION NRI AP4030790 s,ublimates) having a mirror-like surface (samples I), the above deposits treated with ethanol vapors (11), or microcrystalline preci- pitates (III) prepared by repeated recrystallization from ethanol* The following results were obtained: in air or in vacuum for 1, the photocurrent and dark current carriers were electrons; in air and va- cuum for 11 and III, the carriers were holes. Evidently, contact of the mirror-like films M with water o alcohol vapors causes them to undergo rapid recrystallization to a slable form, fine crystals (II), with carriers of opposite sign. Adsorption of polar gases and vapors on the dye can lead not only to a change in the form of aggregation, but to the formation of impurity levels, both in the bulk and on the surface of the dye film. In the case of compact mirror-like films (I), the role'of the dye surfacel which interacts with the surrounding atmospherep is negligible in comparison with the role of the bulk of the sampleo Thereforej the negative photocurrent carrier sign whichim' inherent to the dye is also preserved in air* In the case of minuts- crystals (11 and 111) in which the molecules of the dye are apparently less closely packed and whose specific surface is grestarg nolissules,_ capable of trapping electrons can penetrate into the lattice, Card 2 / 3 ACCESSION. )UR-l' AP4030790 1' As 4 result,, uLcrocrystaIlLne layers exhibit holo conduction even La hLgh vacuum. OrLS., art. has# 4 figures, ASSOCIATION1 none SUBMITTEDs 06D.ec63 -DATE ACQt 3OApr64 ZVCL# 00 SUB CODE# CH#PH No REF SOVS 009 OTHIRs 008 3/3 L 6508..66 EWT(1)/T/EWA(h) IJP(c) 'AT ACCESSION 1IR: AP5013750,.,' UR/0020/65/162/002/0306/0309 AUTHOR: Akimov, I.A.: 14~shkov,. A. M. ~rc) TITLF: Determination of the sign of the photocurrent carrier charge by The crpacitor method SOURCE: Ali SSSR. Dokludy,.v. 162, no. 2, :L965, 3o6-309 TOPIC TAGS: photoconductivity, current carrier, electric polarization, charge density, conduction band, photo emf ABSTRACT: The authors refute somi! q ttIie earlier arguments, In which It was claimed that the,capacitor method,, wl, dilly used for the Investigation of photoelectric pro- perties of semi conductors-'fA4j'1'1-tbe used to determine the sign of the photocurrent canno ,carrier charge. They cite, in particular, the frequently observed "repolarization" phenomenon, wherein an additional longer-wavelength band appears in the photo-cmf spectrum, with a photo-emf of opposite sign,. and show that allowance for this phenometion explains the anomalies on the basis of which the capacitor method was deomed unsuitable. Two hypotheses are advanced to explain the "repolarization," and an experiment is described by.wbich it has been demonstrated that this pheno- menon is the result of the interaction taking place in the semiconductor betueen the carrier diffusion (Dember effect) and carrier drift in the field of the near- surface charge, producing anti-barrier bending of the bands at the illuminated surface. The photoeffect produced in the capacitor can be explained therefore by Card 1/2 0 L 65o8-66 ACCESSION NH: AP5013750 assuming the photoconductivity to be monopolar (and not due to rectifieraction, as hitherto believed), and can therefore be used to determine the photocurrent carrier charge provided an additional investigation of the photo-emf is made to determine the relative contributions of the two types of carrier motion. The conclusions are corroborated by experimental data on the photo.,;emf of AgBr, AgCl, T11, and ZnO. It is also pointed out that the capacitor method can also be used to investigate surface states of semiconductors in vhi the-surface charge can be varied. "We are grateful to Academician A. N. Terenfltior continuous interest in the work and valuable advice." This report was presented by A. N. Terenin. Orig. art. has: 3 figures. ASSOCIATION: None SUBMITTED: 270ct64 ENCL: 00 SUB CODE: RMs EE NR REF SOV: 015 BOTHER: 005 Mw. Card, 'A 4 'L 212 UR/0020/ 65/16 003/033/0556,__V' CCESSION NR, AP5024208,1 535.215.5 AUTHOR: Akimov, I. Ai m0 _~~-.~_TITLE: The influence of the.electrical field,'illumination, and lecule adsoxpt on- on the capacitive photo emf of ;ftj , AgBr, and ZnO AN SSSR. Doklady va 164-:.no. 3, 1965, 533-536 SOURCE. .OPIC TA( I;S: photo elec tromot .iveI for e, polarit .y rev .ersal, 'pace ch arg e- diffusi on.- c drift b i ABSTRACT: The capacitor. thod was, used to determine the pectral distri ut on-of, me the photoeffect and -the signs of phot ocurrent carriers in T11 , AgBr,.and ZiiO. The. ~:.__;0.001-0.01-cm-thick sublimated or powdered layers of the semiconductors were placed in the capacitor's cell between mica spacers.with two transparent electrodei. ve -,-The --spect-ra.vere, measured with a double quartz prism manochromator. The negati rsign-over~the entire. spe ct ral -range-.-of .-the -basic layer of T1.1- conformed to hole, Aal ca Howeverj~when a negative pot pacitorl dif f usion. ebtial was.applied to the f ron cover, a marked polarity reverse was, observed.:-The application:of positive ot tial increased,the photo emf, in the entire range of the spectrum, showing _i po en ao- ~ j ,Card 1/2 k 1_7 L 2128-66 --NR." 7AP502420V'-'_-_7.__"__ !inverse effect. Similar results were-.obtained with AgBr. A shortwave. continu illumination of the frontal side brought the same polarity reve rs al effect in 'TlI ~~as the application ota negative-potential. With backside illuimination, the increasi of the photo emf correspondedto that observed when the positive potenti-ol-was-.-Ii lapplied. These changes:are-explained bythe formation of a negative charge due t6 .!the diffusion of holes into the layer when the frontal or back side of the capac y a IstIron Simultaneous action of,the field itor is irradiated b gly absorbed light. iand illumination showe&a Arictly additive effect on.the capacitance photo emf.- iSimilar experiments were.madii with dye-colored-,,Tll~ and-with'., AgBr, and ZnO layers a space-charge layer produced near the surface b~.phoitqjchemical means. Origi,rart. t~j [has: 3 figures. MY CIATION: none SSO A SUBIJIT'A"D: -.263an65-- NCL D E R. 0 0 3- D-'PUS & VJ. t Card 2/;: L"12017-M ACC NRt APr EWT k(h) :op(c) AT 6 002 03 0 Ig,,, SOURCE GODS: UPT002-07 5T1 AUTHORS: Meshkov, A. M.; _Akimm 1* Ae . .......... IYYr ~