REVIEW OF ZHURNAL ANALITICHESKOY KHIMII (JOURNAL OF ANALYTICAL CHEMISTRY)

• Document Type: CREST
• Collection: General CIA Records
• Document Number (FOIA) /ESDN (CREST): CIA-RDP82-00039R000100030051-2
• Release Decision: RIPPUB
• Original Classification: C
• Document Page Count: 5
• Document Creation Date: December 22, 2016
• Document Release Date: June 1, 2012
• Sequence Number: 51
• Publication Date: February 1, 1948
• Content Type: REPORT

Declassified in Part - Sanitized Copy Approved for Release 2012/06/01 : CIA-RDP82-00039R000100030051-2
R14VIEVt OF ZHURNAD ANALITIC1U SKOY KHIh1II (Journal oL Analytioal Chemietry),
Vol,. III, No. 1, January-February 1-94E3
A. r'. V1inoplti~dav, Iator
l ditorii l Gallo ,o I. P. iimarin, A. ,,Dymov, G. S. annd 3bor,
, ,
A
t'. B. tfayman, Ya. 0. Parnaa, V. . ! od nu-vfi~2
(Aetintj editor),
.
f,
V. fir. Kli.opin
AU but ono of tho twolve rirtioies in thin 71-page iscue care devot
to qualitativo rind quantitative e,nal.ysia, wLth omphaaie on the~i Te
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side. !T-1 The majority deal w!th specific substanoas, r~nd~oniy throe
of tho cloven tiro of n ronorrtl nature. The twelfth is concerned with
structural, analysis. Each article i.s followed by a bibliogr iphi.
Among tlu croup reporting on dotoctinn o " specific substances,
"Now Reactions on Rhodani'dos" by A. P. Kreslikov arid S. S. Vyborg of the
i'oscow Order of I onin C1~emioe~Toclmolonical, Im tituto imoni D. I.
r:ondo1oyev, ogxnninr; on 1)C O U, r1avol..ops two now mothods for dotoct"-
ion. Ono is braced on the formation of carnarinic, psoudothiocyanic,
hydroporthiocyani.e, and isoperthiocya,nie acids during the evaporation
of a rhorlanide solution with a surniw of m pots,ssium chlorate and
subsequently hor,ting the roeidue. In the other, a moiybclonumrhodanide
complex is obtained during the interactiv r of a rhodanide solution
with a i surplus of a saturated souti.on of ammonium molybdate
in nitric acid (1s5) in the presence of ema11 quantities of reducing
agonts. The compound thus formed has an orange'yei1.ow color. end
is separated with ethor or amyl alcohol. Both of these reactiona are
50X1 -HUM
50X1 -HUM
 D
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CONFIDENTIAL
cuffioiantiy nonnitive, clo not roquiro trovtbthnomo ronr~onta nn~1 appnratun,
rtrnd the rletoottcn in not hinc1orod by t.4clidon, rncotrtton, nnrl other cub-
a
which do not Pormit tho neo of/forrio ari1.tn r r q' ronr!ent. Apl)onciocl
to thin rtirtioio, ubmitted April 24, 1947, t,n a btbl for a~' y of 1,9
rotoronoc:n, tviB-thirc3,~ of tlifilm form.
"Phy ii.cc-Ca ~nmicn7 Artnlynin of Cyntom,n Tmportnnt to Aria'I,ytcai
Chemistry. XIII. Tha Syntom 1TIIO1Jt-_1 'Cn'.O4 - E4Fo(Cf)(, - f20"
The authors,
is conoorned With tho dotootion of cobnit. /I. V. Tnrcrayov and )~i. I.
Loving of tho Ltiborr~tory of Anc Lyttai Chomi.~try r f tho Inntituto
of Gonoral. rind Inort;.nnic Chomictry imoni N. i urnnkov of tho Acrtd?my
of his Scioncow of tho UyS'R, studi?d tho coLubility (rtt 25?C) rrcl
ova
l.iglxt n,bsorption of this syatom, and shower/ tlir?t t1;c, ntorrt,ctiro r
botweon tklo 1.ons of cobalt amul ' ohnaium rorroc;ir nido ~rncoock through
three ~hgo r with tho f ormr~tt.an of two hini,ry cn.ltn ~I.
S wGl~
5Co o (CN) .,..1: Pe (Ci") and 4Co2Fo (CI1) 6.3K4x a (ON) 6) solutions ?f
of varying composition. The cobalt was detected by 1 '-s
(per"I
phototurbidimetrio and ordinary titration methods, And the mid- otiui 2 IJ%
~t it r of tho two raltq was confirmed ~ . roentgenographioally.
Eight reforoncos, the majority Russian, are listed. This wort; was
submitted lTarch 3 , 147.
A third study of specific qualitAtivo anal r is, ~cr; ethod
acL for termination of Water Vapory and Oxygen in Ga.Ses not Containing
Oxygen Compounds" by N. Shurmovrikaya rand L. Kupriyanova of tho Strtte
i_Td Sc1entfic-fosearch and Pjanning Instituto of the 1litrogen Industry,
ti
JL re1atos to the detor. riination of the amount of 02 or 1120 in 002 tN'~ tJt
EcA o w'' iA
1 4"
or'~ W w 1 "~/1 v M v 7 p~ o-wi.dvvh
1 ~ 1~ 1 r_ . r
'1 n~v+ G ,
A
N
f i' +~ti JI ~GJr3e ~~e +` SCE,;
 Declassified in Part - Sanitized Copy Approved for Release 2012/06/01 : CIA-RDP82-00039R000100030051-2
!- ' #to tic I " r~'A ?vG r
o~
y- w ' e
t c
4'A /L##we
x
1.
If ? ; v4A '1, 4 I ''v% Vt ir - , ,1 ,$ L t7t
L' WVA /L4 v(f _t
by
nrnl.t -iy't. Tito
ri*-,c : rir+ ti'11 t.l?~ '1 t~di,nQ x e i J This t! ctl~orl 7L if1 'in' hflfl
'-?: vnl)ar
an nvrarno mar .n ~f ortor I'or~ p.2 a concf:~ntr ti.on of p
'a w
rir c1 osn than that or f 1e,econoent1r~tions oC 02.
o t of t- Q ton rof or n c o,oo m;ian tg tho ctrti:o1 o,/m,ibr t! ttt~c1 y
1=0, 1947, rlro f or i i ` .
Fiv? additto r~rticlos der~1, with clotorminfl.tinn 'f spoci:fio cub-
strtrncos ? They Tire s ItDotorm:~nntion nF c'oloniUm i:n ` tool." by
N ? fl. hnctnayov and V ? I. r.M~rahitnvr. of t1 o Ln1x~r,ntory of Annlytioal
Cllonlistry of 1 the Uri Industrial Institute at Sverdlovsk, on
.i;Vo1umotrio Detornri.ntiation of Trivaiont Iron with tho Aicl of
T1rt.tes" by A. V. PavUnova of t11o Chrr of '~nr~lytioal Chemitry of
Chernovit,iiy State Univornity, page 7, nubmitted ?ay 15, 1947;
ItPo1arorraphic Dete 'mi:nation of Sma1.1 uantities of Arsoni&' by N. Ya.
Khlopin N. A ? faf nlovioh, and G ? P ? Aksonovc of tblotov Pharmaceutiical
Instituto rand the Oblast SanitaIly ianio Laboratory, pag? 16,
submitted Feb. 1., 1947; "Indio,iti.on of Small Quantities of
th logon Derivp,tives of 'Iiyc~rocarbons" by A. V. Pyleyev of the A1.1-Union
Sci.entifie-ResecUrch Institute of Lsbor Promotion at Moscow, page 6,
submitted_TT Feb. i6, 1947; and 14u1ck 1u;Jethod for Determining Sugars
i
ng
Tann
in --/rlu,r~sri~ S. Pitel.~ms,n of Kiev
? ?ias_el-is ya~. r~ 1 it r . . ~+&...~~ L
p" J,~ . .
Teohnologioal Instituto of Light Industry", page 66, submitted Mar. 15,
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1947.
4 (prt"o 4)
 OFPENTI
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1' i
r4'.
ivN~O~N~gl
oonsccutivo roports (pagos 21. and hf~) by F? T.
Two
m!ttod P'aroh 2, 1:947, cuont a now tj?tht)d for aimultaneous
c~tk~ in ninp1y a
In the now mcthorl nugt~aitad 'fin this worl~, f '~~:r~,~ a moasure o
tho aubAtnnce under inv~stj.gati0n. Tho inoro^ao in
the girnntity of
i t an inclic r~tnr of tlio bo fpnning and onri of tl to inn
ti-IC) pot-ntiaa
1ibc~rcan and also detormi.np^ ita chemioal nature ? The
iutomatio&.' Y
apr~aratus/o f fact tho stabi1izs.tion of the s,mperage and also
~
autrmtic rocordng of tl~o volt~g? of tlro Qleotrolyzer,
9 ~
pormit,~ the
under e g1.ven cc.nd?ti?ns, a functin f
vrhich i.,
The 1l1'al.ectolyzer,
tha l)otantial of the ion Liberation.
is oarriea out
in which the ion Liborc~tion/on a morc w thode 1.n the form of an
structod for this purpos? ? The foUowin(; conditions
ari9lgam, was aon
e sta lisheds ].) 0lectromagnetio ' vibratbon of the
for the analysis wer?
" . trot ronomotrio l.Tet od of An1%11si9 . 1st f?port".
. , :-vo ~~ -:, ~ ~.,~a.?, ~hn1tir~r~ % . ~'1~ 1,attor/~ nD?gOri~l~~On
qunntcit,u ~~- ~~.~ v ~~. -r N
of tlio Dirrm of the Ftop :strirC Automatio Apparritua for Quantitative
and Ql,inlit~ntiv? Ana~.yais of I ono Aooorciin( to Potontir'l. rind Tame of
tha it Libor !ttion with a ^tortriy Amporage" , c~1indoci to ;tn the fir t,
tend the electrolyte to increase diffusion and decrease
cathorle
polarization,) use of a high concentration of the electrolyte to
e beration of more than one type of ion at one time,
eiminate the :li ,
1
constant eieotro~onauetivity of the electrolyte
:3) ~ n ntj~+f14of a
1
WvJ
G' ^ he ecentx"d polarization of the anolyte by
and elr~m~ation of t
tions
l
l
`'
'
a
cu
Ca
(potassium chloride).
uantity
. q
tance will be
b
s
e stablished the amperage iuMatg which a unit/o u
n The results, satisfaotorily duplicable,
'liberated in a unit of time
 tONFIDENIIAL
r,;l4ti,on
aro rooordod on rs hpo ourves ivinr the
of +pET
of tho potontial of 1 iboration to tho time/sue
clootrolYrain and the titclo obn'umod in tlae ion iiborrttion. AU but
ono of the f ivo roforonoes in tho biblio rOp) T oro to other
d air
wor1c by tho,author.
Ti~? tyro rcamai nl nr~ rirtol~o of th;l, poriodidal are "The Theory
` (' ` bor of i~iev `oolu~o].oCical
of Speotfio by L. r... K~
Institute of Light Tncluctry, paso 45, aubmittod rob. lj, 1947, and
"The Theory of Organic Rory or Al III, Roeoaroh on tho piuret R?aotion"
'
I. r:I. Korenr n~ of tha Laboratory of Microal*?7Sie of the Inetitu~o
by
of Chomistry and t,Le Chair of Analytical C. omistry of Gorki 5tnte
Univerd?ty, page 52, subrlitted Nov. 1, 1946.
END
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