(SANITIZED)SOVIET PAPERS ON ORGANIC METALLIC AND HETERO-ORGANIC COMPOUNDS(SANITIZED)

• Document Type: CREST
• Collection: General CIA Records
• Document Number (FOIA) /ESDN (CREST): CIA-RDP80T00246A010400010002-3
• Release Decision: RIPPUB
• Original Classification: U
• Document Page Count: 32
• Document Creation Date: December 22, 2016
• Document Release Date: August 4, 2009
• Sequence Number: 2
• Publication Date: April 26, 1960
• Content Type: REPORT

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Iolj(diethylsiloxane) liuids. 1. .'Iction of sulfuric r.cid on diethyldieth-
o cyshlans and its mixtures with triethylethoxysilane.
N. S. Leznov, L. A. Sebur~ and K. A. Andrianov. Zhur. Obshchei Khim. 29,
1270-5 (1959).
It vr,qs shown in z ork done in 1947 that H SO4 reacts with it23i (OEt) 2 and
itr mixt. with Et2'10 t with the formation of poly (diet hylsilosanes) which
are free of polymers cont:
f functio~,al
groups. Thus treatment of the
polymer,formed by ark. hydrolysis.of Et2Si(03't)2, with 96% 82504 1'hr. at
500 gave after aq. washing and neutralization a mixture of poly(diethyl--
s t1.xanes) with relatively greater mol* wt. through condensation of the
linear polymers at the sites of originally residual EtO groups, as shown
by high b.p. range of the polymers and essential absence.of BtO groups.
1. similar effect is produced by contacting the polymers with HCO2R (700)
or hcOH (900), Addne of coned. H,, X04 to Et21(0t) 2 with cooling gave
after stirring the mint. at 200 to 1000 a good yield of poly(diethyl-
siloxa.nes ), tithose inol. wt. and b.t. tended to' rise with the rise of temp.
of such trsatment up to about 750; at higher tem... the formation of
silanol sulfate esters and regeneration of H2504 become predominant and
the tendency to form higher polymers declines sharply. In general, elevatd4
temp. tends to favor the formation of t#aaaa polysiloxanes free of linear
polymers contg. EtO groups. Heating It2Si (OEt) 2 and Bt3Si0Bt with H2SO4
2-3 hrs.,. at 750 gave ?xz ftjE linear polymers with HO groups, formed by
the aq# treatment of the initially formed sulfate esters. Increased amt.
of It 3SiOEt tends to block the formation of sulfate esters. by blocking the
HO end-groups of the polymers.
II. Action of phosphoric and boric acids on diethyldiethoxysilane and
its mixtures with tr iethylethoxysilane. Ibid. 1276-81.
Heating St2Si'(OZt)2 with 3:2 to 1:2 molar proportion of H3B04 1-3 hrs. at
750 gave after an aq, treatment poly(diethylsiloxanes) contg. very little
residual Bt0 groups, the products being 66-8% distillable cyclic polymers.
Similar reaction with mixts. of Bt2Si(OEt)p and EtsSiO$t gave up to 924
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2
distillable poly-(diethylsiloxanes). Similar use of H3BO3 3-10 hrs. at
95O, finally at 130-400 gave aftsr an aq. treatment 35-54% distillable
p.olysiloxanes with much linear polymer. being formed. The reactions
yielded as byproducts detectable amounts of fytOPO3H2 and (BtO)3B. The
distn. curves of distillable polysiloxanes formed with the use of HPO
3 4
or l3B03 were quite similar.
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'kyntheais at polymers with inorganic molecular ah"'inns. I. i olp(orgeno-
ai.log: T,r~+,o~erbOreal~:~i.r:;'..iloAur.~8) p
'~. nc.l1 r1Cx`i, . , 1:b3. oV -Ind :.. . '.azati:ovn. .hur. C+bsbohel '%:l:::..
1,:: 1- (19 c } . ri'. Tzve t. Wit:. idr:u : Ut .e1. "biz.:. ~ I: 1 59, x6.
-low c.eatit o :.n g. ('"t3?"io)3..i *it, 2.1 Kt,aio:;(e) (crr) to 1.~4-2Q0
save , diatillatr of 0 and a re'>idue oy a poly^!or Mt.130i,o~ 1( -i.'?t3)?
Ux'(~i 4G:-i t )uJ141t, scl. In I. I1. Or. ani CFr6. i it r reaction of a
mater ratio 'of t1 react; nu la hrs. at 2200 Ave c r.:,til~ t,ta of 'z24
Conti, (it-1)0 auc, a restdue of viscous li,uid nolpn:sr r ft,, 5)0]2
(G)G `:,i!iilarly 4.. !j. (7t5:'10)%l z%uL.4 4.4 x . (.t3.iio)3110 in 21.5 hrs.
at ..OO a with a current of azoist air drawn t'hrou h the niat., ;eve some
ii20 and ( t3fsi)2?, and residua of transparent yellow rosin, aol. in org.
6olvexits and corresponding- to It zS.t7C.,1(0SJRt3)tP(O) (0811ft 3)014"9"t3.
ho producta pass into infusible insol. >ol ids on beir boated .ft i t er.
Jissilar reactions employing s..3iOP(O) (OR), or ( ewsfo).,Po prooeeded very
rapidly and directly gave insol. and infusible polymeric products. I kinetie
study showed that the visoosity of the new i.olyrara inersaaee wtth the
increaeinie amt, of distillate fcr-ed 1 the reaction. The starting w berials
were prepdo as, deeeribed previously (Toroakov, this 1. 25, 46(1953), azxi
h.ndriinov at ale this J* 23, 287 (1956) : (4t, _4.4o) 33'o, b 156-6g, n
20 11 J
1.4462; (AS
3 010)3 0* b 770, 1.1025; At3;a1O1(e) (ON)2; me343ior(O) (OFI)2, 1.
I C,
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r s z" r z. C- ?,--ice,
Poly-(organometallosiloxanes). 2. Synthesis of poly-(organoalumino-
eobaltisiloxanes) and ~ioly-(orgenoaluLiinonickelosiloxanes),
K. A. .c-,ncir1'enov !.nd . '"ld>3r_or (List. ~Ietaro-org. Gompds., _oscbw) .
Izvest?, -4-ae. Nauk . 4s.R. , Otc'el. !'him. ii ui: 19x9, 1590-4* cf. i)oklady
.Aked.. ia0- ' R 114., 1.005
Polysiloxenes were synthesized whir;ti: cc.ntain il ena. Co or Ni utor:,s in the
polymeric chain. A_ddn.. of 1.2.99 g. CoC12 in 1171 DuUh to 32.24 g.
Etbi(OH)IONa in 2,88 g. BuOF at 700 E nd h.es.tin$ hrs. gave after
filtration and avapn, a eolo-Cle ss resin which v.as free of Co, However,
the reuction of 32.14 g. 't"i (0'T) 2CI`Ta, 3.6? . 4Llt13 and. 5.25 g. Cool,
in 400 a;. BuOH et 80-100 in 2 ors. ;;ova after filtration am evapn.
20.15 g. violet polymer, scl. i-? om k. solvents and contg, 23 , Si, i .5jn
A.1 rand 5.55,. Co. Similarly Ph:3i (O;i) 2ONa g~:va s. violet soluble polymer
corltg, 5.05,E U, ?.K;. i_'o and 1o 'i.. ra ction of LtSi(0Ii)2ONa
with .,11013 and in u0H rave a greer. polymer, sol, in pry;. holy-
ants an si oont ;, 6:- "1 and l.O J i. 4 aeries of kola*~'.sra was prapd. from
Et': i (GH)2,0ila, '102.7, and. CcC1? wi.tt. differ6ut p-r-oi.ertionv of reactants,
inoreasing rr do of Cocl,4:11013 tole poly.: y a ;i r t.110 lyre senco of :n412, the reactiior rni.xt. gave
only a visco'aa L1.e 1')o11$i? o7c:3ne, evidently (O:~iMe2C:i2C6H4CA2-
C6H4CH25iL1?q)n. I huated 10 hr.3. at 120? with KOAc-xtcOH save (AcOCh2C6H4
C111 Lil~c2)20, b 268-70?, 1.0622, 1 .5110, which hydrolyzed with +;t07H-iC0II
V
in I hr. to a product which showed signs of partial reaction or decompn.
c?urirg attempted distn., leaving a residivt of apparently He Si(OSiMe2CH2-
C6114C111
01024
2
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 L 1 LL-
Approved
e
'iinyloxys ilanes.
A. Neailieyanov, I. ?. Lutsa'iko and V. A. 3rattsev (:d.V.Loao~io3ov 'tate
Univ.,ivloscow) . Doklady Akad.ilaub ..~?~.R. 128, X51-4 (1359) .
To 32 g. Hg(CH2CH)2 in 70 ml, isopentana there .vua.s added 11 g. .Me3SiCl
in 20 ;al. isopentane and after ref luxing 2 hrs. the filtere3 mixt. ;eve
72?,o -go SiOCH:CH29 b. 74-5?, n20 1.3835, d20 0.7720. irailarly ,,ere prep's.
89`o Bt,~6iOCH:CH2, b20 53-4?, 1.4275, 0,6503; i v lC`i 2 SiIc2OCH:CH2, b42
.54.50, 1.4329, 0.9796; 861,1 (C1CH2) 2 iM_e0CHi:CH,, b14 73-3.5?, 1.45469 1.1515;
6 4; a M2Si(OCH:CH2)2, b. 108.5-9?, 1.4052, O.8792; 73','; t2,. -, -::G i2)2,
b40 69-70?, 1.4246, 0.8890; 825o idePhSi(0CU:CH2)2, b1.5 65-6?, 2.4940,
0.9959; & 81 C1CH,9i a (OCH: CH2) 2, b36 72.5-30, 1.4338, 1.0457; 710,r
Lk.e (OCT-: 1CH
3, b30 50-1?, 1.4133, 0.9457; 7o,. .fit; i (QCFI: CF2)3 , b40 69-70?,
1.4225, 0.9503; 70;; 11Si(QCHaCH2) b2 79-C60?, 1.4696, 1.0385; 72,,o
Si(OCH:CH)4, b12 52-3 , 1.4146, 0.9949. To 125 g. C1HgCH2Ac in C6Hv there
,,vas added 32 g. pyridine and 17 g. SiC14 in CFH6; after 1.5 hrs. rePlLxiz
the filtered mixt* gave 49% Si(QC :Cf2)4, b5 76?, 1.4320, 0.9722.
;similarly were obtained: 58 t33i0CMe : CH2, b2o 6c? 1.4290, 1.0365(???);
63% Bt3Si0C3t : CH"' e , b3 55-6?, 1.4432, 0.8497; 45;o .ct3.3i0CPh: CTi2, b3 108-7?,
1.5089, 0.9466; 87> (ft0),,Si0CH:CH2, b30 76-7?, 1.3905, 0.9493.
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I.eaetivity of and v-chloroalkylsilane chlorides in the Friedel-Crafts
reaction.
C. A. Chernyshev and M. E. Dolgaya (Inst. Org. Chem., Acad, bci., Moscow).
Zhur. Obshchei khim. 29, 1850-3 (1959). of. 28, 2829(1958).
Detr. of the rates of HC1 evolution in a Friedel-Crafts reaction of various
chloroalkylsilane chlorides and C6HG gave the following reaction rate
constants at 30?: C13SiCH2C1 2.36X10-4 thole/min. ; C1,ISiCH2CJL,C1 4.28X10'3;
C13si(d12)3C1 5.48X10'3; McSiC12CH2C1 3.67X10'4; McSiC12(CH2)2CI 4.47X10`2;
Eti~iCi2(CH2)2C1 4.17X10'2; McSit 12(CA2)3C1 6.72X10'3; C13SiCHMeC1 2.39X10'4;
EtSiC_1.,,CHMeC1 -2.96X10'4. Reaction of C13Si(Ci12)2C1 with MCI had the rate
constant of 1.67X10'3 and with MePh 5.95XI0'3.
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S irnthf ^is vnd tranofor^ri1. ions of urgaturated, or4;enos ilicon compounds.`,
Ly. . yntre::,i.~ of ci11ooh: zracarhor~.q of vinylacatylana series.
1. -,. ;jhik 1ev, .,:. F. .k. 1 yutanko ( Inst. Or-.Chem.,
T..asc oc;1 .' Lhur. . OhsYch.e Main. 29 , 2137-9 (1959) . of . Doklady
" SR 109, 344(1950).
l`,ting 15 g. bi3-(1,1-dirlethyl-:',-P_-.?or,yne~?-ol)-ethylsilane with 13.6 6.
TIC-"
4 L. the presence of hydroauinone to 650 gave after c?1stne an Unstated
1 c i . of (CI : C 1oC':C } OiH1:t, b 76-70, LO 1.5010, d20 0.8518. Similarly
(CF_.I:C:iaCiC)0SiMs06 b4 75-5.50, 1.5000, .0.34x5; (CH2
w L+. bal J
C `C) b6 1050, 1.50270 0.8594, (CH2 : CMeC fC) 2SiMe ft I, bZ 87-80,
1.5ti06, 0.6-583; (LIT 2 : CL.IeC *C) 2Ji.,reY r, b10 .1130, 1.4990, 0.8555. These
h~rif.rn~croted to tho setd. analogs over Raney I IA in `eON'.
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0rgaiiomagnesium a.ynthasis of -tr3_i,lr;thylsil *learylie acids and
vinyl derivatives of s iliccn, ;ar-r"aiiiulii _.n(. tin.
V. V. Uircnov, A. D. L etrcv and G. : , ksi iova (N. D.2elinskii Inst.Org.
Cne~,i. , .os,^,ov). Izvast. '.kad. Nc zis .;. _.I.0. c2. , Otd$l. Ilhim. 'Vauk 1959,
1954-+60.
:The Normant method was used to p:r.?err re tii.< ?c11ming substances. RI X
from 11 1,C, anal 50 g. CIx,:CETBr, ectivFte6 by a little 'xLr, in tetrahydr-
ofuran, war treeted Frith Ft -SnCl, jtieldinig 60;: Lt,iSnC':CH.,, be 174-50
,
z1 U 1.4780, d 1.2133. Similarly was prepd. 55',~ Et2C.e (CH: CH
)
149.80
, b
2
7
745
0
1.4575, 1.0193; 22 c 3tSi?i(CH:CFI2L,, be 93-4.u , 1.4305, 0.7554; P~t2Si-
(:ri:CIIJ)., b746 133.3?, 1.4435, 0.7911; ',)ePhSi(CIH:CH2)2, b11 93.5-4.5?,
1.5185, 0.:~OE9; ~.Ie :t; i(C: i:CHj) , b7,15 111?, 1.4295, 0.7623; IISi(CH:CH2)3;L
bri47 101.4?, 1.4405, 0.769 , tSi((: i:C$2)3, b744.5 133.6?, 1./'25, 0.7930;
),, b765 168.5? 1.48609 1.2356. AG n. of Br to `.s`.iClC `:CH
2 2 2
uad3r tncanc.escent lauj: vvith ecoling gave 94 {Ie:..i Il,(I
TJE-rCH2 r, b4 101?,
1.5335, 1.9221. Similarly was prepd.. 90~, :tom iCl2CHBrC}I2jTr, h739 240?, b7
1.5320, 1.8227. I:istn. of BrCN_,,CI r11_iC13 from ~~u ir.oline or PY lBt2
65G:i2:Cr{r 3iC1~, b749 145.5?, 1.4920, 1.7151. Ji~tiilarly was prepd.
5 Cd2:CbrSi,IeC129 1735 14:5-3.5?, 1.4870, 1.5594, and CH2:CBrSiEtCl2,
,,, u3 135?, .43700 1.4458. McMgI and CHI, C3r::1013 gave 74; CH2 : CBr-
a3' 041 47-80' b745 1'24?, 1.4580, 1.1562 rRF:n1an s^etrum Ph own) , '~t;Br
..,5 ~.? at?_Ir gave 30;. Bt3SiCi3r:CH.,6 , b?,, 92?, 1.4770, 1.1273. he sting 573 .
%
r~ 1i,IJ2: iC13 with 1 g. ilC13 gave 23.7 ;?rr. : C{ i~iC1 J, be 155-6?, 1.5030,
1.'7 C?r1. 'n.I witn ae., ~1 gave 42p BrCH:CHSi"Ie3, b42 55 , 1.4375, 1.1628(Ba.-
. ectrum ::so n) . This with AIC; in tAtrahvc1rofuran 3ve she ~?'v~C,Br why. ch
-~.tr, JSiGl Lave only .is 3
"S C* :+iHSi Fs J. Carbonate !.on of - ie above Rl-Sg$r
,,E: i=e u =,Ie ic (: C T2) C02y., b13 977-105?, in. 50?. 1T*1i i r1y w&s nrepd.
23 5
46; :,.GI, AC:.: C;xiu02a: b13 1130, n
1.4500, m. 25-5.50 .
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 Reaction of tetraalkyldihyc!rosile .ee with difunctionel unsaturated
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compounds.
V. 1' . Korshak, t.. 14L. PoJ.ya.kova, V. N. Vdovln, V. F. liirouov and A. P. Petrov
(inst. Hetero-orb;. Gorapds. , ''ose..ow; . Do;fHCl, b. a5-960, which treated with H2O- :t., GJ 0 gave 08.5','o 0 ( 31Ii.: e 3 ) 2,
~
b. 125.5-60, nD 1.3980, d20 0.7935. Similarly ,vas prepd. 1.18% us 7 *x;
Ipt2SIM19b. 98.5-101.5?, nn0 1.4154, which gave 75-93~o O(3iIT t2)2, b. 172-30,
1.4160, 0.8159. EtblgBr and., Et1 i?TCl,-, gave Et . i.H and 0 (SiNIt,) after an
ar,. treattrent.irlilsrly was prepd. 0(Sie2Fi)2, b. 70-10, 1.3700, 0.7572.
Ths d'hydrosilenes above.were shaken in sealed errpuls with: Et2Ci(CF:CH2)2,
t,S4(CL,CF:CH2)2,
1h,IV'i(CH:CH2)2, t,Ge(CH:CH2)', rRe ce(C ,c :CR2):,, IrI
a e2Si(GCH2CH:CH2),, Bt2ai(0CH2CH:CH2)2 or e2s (CH,CH:CH2)2, in the presence
of 0.01 g# per 0.1, mole of H,FtCl catalyst; the reactions were then
corpleted by 6 hrs. at 120?. All the listed monomer combinations yielded
a.ppropriats polymeric products, the analyses of which are retorted.
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Synthesis of now-bis-(cyanoalkyl)-tetra-alkyldiailoxanes.
A. D. Petrov, V. M. Vdovin and R. Sultanoy (N.D.Zelinskii Inst. Org. Chem.,
Moscow), Doklady Akad. Nauk $. S. S.R, 1281, 1204-7 (1959). cf. this J. 100,
711 (1955).
Stirring 19.3 g. NC(C12)3SiMeRtC1 with 25 ml. H2O 5 hrs. gave after extn.
with Et20 10.3 g. (NC(CH2)3SiMeE't)20, b3 195-7?, b3 193? (redistd.), nD20
1.4513, d20 0.9377. This was also formed from *C(CH2)3SiEtCl2'and McMgCl,
followed by treatment with 1120. Similarly were prepd.2 NC(CH2)3SiEtCl2,
b3 99?, 1.4625, 1.1295; NC(CH2)3SiMeBtC1*, b4 121?, 1.451_5, 0.9895; NC(CH2)3-
SiBtMe2, b3 66?, 1.4363, 0.8377; NC(CH2)20(CH2)3SiMoEtC1 )b1 123?, 1.4555,
1.0098; (.NCCH2CH2SiEt2)20, b2 175?, 1.4605, 0.9470; (NCCH2CII2CH2SiNe2)20,
b2 161-2?, 1.4441, 0.9344; (NCCN2CH2CH2SiBt2)20, b1.5 193?,
1.4593, 0.9413;
(NCCH2CH2OCII2CH2CH2SiMOEt)20, undistillable, 1.4552, 0.9741.
Stirring I
with concd. HC1 finally at ('y0-90? gave (HO2CCH2CH2OCH2CH2CH2SiMeEt)20, an
oil. To 160 g. NCCH:C.H20 90 g. PhNEt2 mixt. there was added over 8 hrs.
410 g. HSiC13 at reflux, and after 32 hrs. further refluxing there was
obtained 'some C13biCH2CN2CW, bi5 96-8?, m. 26-30?, esepd, from PhNEt2 by
freezing-out.
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Addition'of hydrosilanea to dimethylvinylethynylcarbinol and the product
of its eyanoethylation.
A. D. Petrov and S. I. Sadykh-Zade (N.l).Zolinskii Inst. Org. Chem., Moscow).
Doklady Akdd. Nauk a. S. S.B. 129, 581-7 (1959). . of. this J. 112,662(1957).
Addn. of 53 g. Et3SiH to SS g. CH2:ClHCaCCMe2OH and 0.5 m1. 0.1 N H2PtC16
0 (1) o
and heating the mixt. to 170 gave 62% CH,:CHC(SiEt3):CHCMe20H, b1 85-5.5 ,.
nD0 1.4861, d20 0.8873. Similarly NCCH2CH2OCMe2CICCH:CH2 and BtSiIIC12 reacted
in iso-PrOH in the presence of H2PtC16 at 90? ( very exothermic) and gave
1% NCCH2CH2OCMe2CH:C(Si tC12)CH Ch2, b3 15O-1?, 1.4865, 1.0846. Similarly
was prepd, CH2:CHC(Si2t3):CHCMe20CH2CH2CN, 75%, b3 158?, 1.4840, 0.9196;
54% CH2-CHC(SiI,,eC12):CHCMe20CH2CH2CN, b4 146-8?; 90% 2-methyl-4-(tr. ethyl-
silyl)-1,3,5-hexatriene, b3 91?, 1.4920, 0.8759, was obtained by treating
I with KHSO4.
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Addition of trichlorositano to dialkyl(pheny?, chloro)-dially1..ilanea
in the presenne of H2PtCI6.6H20.
t . V. Xupchiov, X. S. iiamet;lcin and S. ft. furr';arlyitn? Nauk
C1. ".k. 1:30, 103-8 (1960). of. *-Sommer at al. JACS 6'a, 188(1.947).
'ihe following milanes were propel. her adcln. of HSIC13 to variouk, diallyl-
,si1anus in :ho prasenee of 1 r al. catalyst ~omnase,-I o' M S312n. of H2I'tC16
1IH20 it isc?-Pr0it with heating 10 hrs. at 500 and 2 hrn. at Soo; 23.5%
CH`:CHCH2SiMo.CH?CH.)CHI: iC1./(~, b, 115-80; 29% H,,)3SiCl ,
1)4 124- 6 0 j* 29.73; CH 2:C1'C1i,,~`.Pr2(CH2)3siC13, b9 167-g?; CIl2:CJICIi2-
Sit3u.2(("I2)13Si+:131 bc 186.?9?; 17.b% CH,,:CIiCI!,, i1~h2(CHf,) 3`ir13, 1), 22.2-4?;
1183, CIe2 :C~ICH . =iMe:"h(CI )3:icl3, h5 180-2?; 8.3 Cl'2:CIlCII2-iCl2(Clary}3Sf -
C13, b4 15:3-G0; Me2wi(C112fH2+aI13:'hOCHNC}I2N1:,, n.. 163-.5?. Ph13(OCH2I 1f1e2)2 and p-13rr6114Mp 3r rave
33% (p- e'C61i4}13PhOGI1.,C1tMu V bl 152-3?, 7_.93.99, 1.5773. 'rreatnent of 7.3' g.A
(II)
with 9.4 g. PC! S with, hooting to 50-600 gave 76.3% 1-C, 0H73PhC1, b4 1t'0-1?,
rri. 27-90?. tiiulilari ,r w.a prepO. 50%" p-McC6I'49HtC1, b8 142- ?, d20 1.5783.
Treating' I in Ht 20 with N Na(;H with ice cooling gave after evapn. and
treatment with iecpertanua at -e}0? a lots yi:3lu ).C l-C101i7'3PhOH, m. 57-9?.
aimiiariy was prepd. p-1`ioC6114a'hU;l, an oil, which on standing transformed
into 885, (PhBO)3, 212-4u. p-McC611413.PhC1 forms an equimolar adduct with
dioxane, m. 72.60. Similar adduct forned with Ph2I3C1., m. 80-5?, and with
(1-C)i7) 2;C: , t a. 9 3-ts?, and with -C10i17ii'hCI , m. 90-1?. J
10 ho .-c ..re not
statute in storage.
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 Approved For Release 2009/08/04: CIA-RDP80T00246AO10400010002-3
f.
Organohorun compounds. XXXVII. Lithium salts of diarylboronic acids
and their complex compounds with dioxane.
13. '?.1. ~`iichailov and V. A. Vaver (Inst. Org. Chem., i cad. Sri., Moscow).
l +>ir. Cf,shcei Khim. 29, 2248-53 (1959). of. preced.abstr.
1?iarylboronic acids react like protonic acids in nor.aquoous media. All
the reactions below were run under N2. Addn. of 0.018 mole BuLi soln. to
5 (1-Cit) it7)2,un In dry C6H6 gave in 10 hra. a crystn. ppto of its Li
salt. Firnilarly (p-McC6114)2130H and ?p-McC6It4Li gave the Li of the former
:grid, a crystn. Ebolid. 9Fcieeic*xgxralctoxhue#nsrx& thx66136cto nxcntExBxbicgaYee
0
Rclnpltcatof 1btre 4 (!}-McC6H,1).,BOH with 8uLi in hexane-C6H6 gave a ppt. of
mixed (o-McC61t ,~) 213BuOlf. Li and its cleavage products (o-AoC6H4) 2:3Li and
(o-'ti`eC6114) I.,.r u0Li. This rnixt. treatad with dioxane in Et20 gave on evapn.
of the. orb', layer and treatment with isopentane in the cold a ppt. of
(o-M?C61t4)28OLi.0(CH2C1H2)2O, which also formed from (o-McC6H4),;3CH and
o-McC6It 4Li.0(CH2CH2)20. Tho latter procedure. also gave froze p-HoC61t4Li.-
o(CU`C)f9)20 and (p-McC6If4),,a3Ol1 in Lt,,O-dioxane a ppt. of rulativoly mnsol.
(; -HOC 6il4).,130Li.U(CH2CHN)201 while the filtrate gave (p-MeC6li4)Iw3tMt.Li.-
0(CH?,C112),,0. (1-C10H7)y}3UH in 1 t,,O forms a dioxane adduct, n. 130-1?,
which with BuLi save (1--CleH7)28OLi.0(CH2CH2)20. Treatment of (1-C10N7)2BOLi
with Me2SO4 in C6H6 gave 12.1% (1-C10I17)2~30Me, a. 101-3?. (1-C10H7)23oLi
and MeOH in bt,,0 gave in 15 win. (.L-C10H7)2i 3(OMo)0ll.Li.Et20.
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 Approved For Release 2009/08/04: CIA-RDP80T00246A010400010002-3
Magnetic suscep&ibility of some oxalate complexes of tetravalent uranium.,
T. G. Aminov, V. V. Zeler.tsov and I. 5avieh (Phys.Tech.Inst. , Ioscow).
Dokiady Akad. Nauk '. .R. 128, 531"d,-5(1959)0
The followii av. velues of effective magnetic moment and . eiss constants
4 2 4) 4 2 2 a4] ?-
were detd. convention 1iy: K[U(C0).5H0 3.62 and 60; Ba[U(C9O
6H20 3.6C and 132; Cd2[U(C204)4].7H20 3.81.5 and 117. Variation of susoep-
tibil:Lt;,r ' 1 h terap. i,: w o'rn 1 y suitable curves and all the above salts
are found to obey tha Curie-Veiss law above 1950K. At lower temp. the
deviations are caused by formation of low -tempera-ture magnetic anomalies
and the suscertibility risen more slowly with declining temp* than expected.
The effective moments, above, idnicate the state of H4 for U, with the 2
unpaired 1uctrons being in the 5f level.
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 Approved For Release 2009/08/04: CIA-RDP80T00246AO10400010002-3
Some rules of polymerization of propylene with the catalytic system of
T iC14+.',1R3.
X. V. Topchiev, B. k. Krentsel and L. G. :.idorova. DokladyAkad. Lauk ". .
~.:~. 128, 732-5 (1959).
olymerization of C3H6 with TiC14-(iso-Bu)3A1 was examined in detail. The
chain polymerization process yields'within 17 sec. of initiation a polymer
with high viol. wt. which rem ins nearly unchanged over the continued polym-
-rization period of 1.5 hrs. Since the catalyst gradually loses its effec-
tiveness, the rate of reaction declines with time ( shown graphically ),
but if R3A1 is gradually added to the system over several hrs. the activity
of the system remains at high level and the polymer -ield is raised.
Addn. of 02 raises the yield to a max. at about 0.026 vol.% O2, after
which further addn. of 02 has a negative effect on the yield. Characteristic
viscosity of the polymer declines steadily with elevation of temp, of
polymerization ( 25-800). It is suggested that the solid-phase of the
catalyst present in the reaction zone aids the stereospecificity of the
polymerization.
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 Approved For Release 2009/08/04: CIA-RDP80T00246AO10400010002-3
cc ~~c ' h,r-rovr rrd `oc;'1-2:_^!rov (L.Y" .'~:arnov i hys.
Cr not ., .,.c; cow,. 1!oklsd~* .!.k~G'. flack 12o, 32C-2 (1y59).
ef'. 12'., ~2!l:a59).
11 ts. c r:i3 e:~ hr?_c .. re-^s rur under ir.ea.-t. ntm. To : well stirred rnixt.
of l b.;3 t ? S o l " or'cf 14.8 . dry 7-Cl ~oT.,r?sr d. under A, tberg s 5
r'5 1 1
f',i Xy1_ -'7#, by .30 i~!. ..
.~.,, ._ ~`t,.U theri?'.iC 1 and t;f!.(,, ;.ijYt.
from T.1 . t111tde
t::c 5- 5.5 hr^. ^t p '.ny: tt'? 3o.1n.. ?,Je9 ft]tered ^t 7O-E30O
Y 't. -)rLO tv--. filtrate. in part to ,r ield ,3.3 colorJ_r-.:, cry::tt' ine
rr rc J T t e 7 t
r oryt 13.ine
c `'tt c?ioxan.~ n..4 g, ,a
ryli~ , -- Sig, tlt~ rlv
tfr.r~ ass prey 7?Q (o-'`~ArCF ),,Zn, ra. E69-710; 45'~ (p-!IeC6R4)27n, rn. 16i?-700
n-,te, a col orls3c c-r str3i1ir.s sclid) ; (1-Ci, )2Zn, 49.5 :J, dec. 2000
(~ io irit3, co].orles^ solt.d) .
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 Approved For Release 2009/08/04: CIA-RDP80T00246A010400010002-3
f'f24 .z"suu_
addition of tr1.Ch1.rrerermnr i' i to " r t~T'_H7ie, Gl:1:"iI1ti &i dC3; ivatives
in the -: bsenco of. not9lyit..
etrcv, V. F. ironov erd r`. C.
Pzlurirs1:ayp. (l~;.a~.:'e] inskii Inst. Orr.
I.UkI' (:, 3.98, 70U-4 (3951)).
!3T. roc' ow
,?A :'fl 'e of `-1 _ -~ 7.d t~_ c it 50 tY. 7a-t.iC'_0_'-ited ('xe and 10 r tc . Cu at 450E 70; :IGe(17, h. 7?-30. This ! lb aided to 5.,:) g.
C? : Cliff at, 60--71 ? ( e:rothcrM e ) n ve 57 . C130GCIT2CN, h 2 135?, m. 37.7?,
i 01^rll GI' : CNCT7 C1 gave 77.4;' C13C.e (CITj 3Cl, h00 1C50, 1 1.50709 d20
1.O.bts6 . >.:eCH l e'uv-n 53.3'14 r"l3'eCJ'-T- 1IPCHZ'GJ_, bll 90-3?, 1.5000, 1.5758
Cli., :: ~'SiC13
i':o T'G aC1z
1:10-1?,
Save 33';?, Cl, 'A.CH CH2GeC13, b15 1,-:00, .7i. 350. Pa, sago of C 40 ii2
until the ,':~.trer,.ic reaction ceased, save 9C;.,? C13GeCH2CH2GeC13,
m. 36?. "irail,;r reaction ,pith C2IT4 eve 55 , Ft!teC13, b761 14:1.50
1 .4745 0 1.6001. 1-Cctsns rave 55, r-Cb I17GeCl,, bl..l 1.300, 1.4790, 1.21712.
".~. C~._c Ire C.t';,. Cl ^aCTI,,0 C7 02C?ti, bl 3.27-00 , 1.4655, 2.5',592.
_2 ,y u 2 w 2
C1~,^?C." 2"t" Cl, h 75?, 1.500 ;, 1.7637. Cl ` iCH: H( 1
15 3
Ja 5:;, G13',c I2!'113 , b13 129?, 1.5268, 1.8350. In none of the above
r~.:.:l. raa::ticn, w-- .a,, iu nec3ssary to add any, catalyst; or to heat the r~tixts.
1 ..u30cl;_v33? ' lidantly T~^st'I3 Ar:s more i:ronouncad aciditiva properties
sct td . : o 1 ? s t?^a n dJ splayed by ICiC13.
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 Approved For Release 2009/08/04: CIA-RDP80TOO246AO10400010002-3
Thermal decomposition of cr ?anic can;,~cund of rerntevf,lcnt :r;;enic.
:;? f3 Tu1 and L. i). uh.arrlok. l'skii (E .-':..Kirov Oher^. Technol? Inst., K?z!n).
Doklra,_iy .; ,Ad. :+a.u c .:'.'..R. 123, '3`99-501 (1959).
c-. Ljrn ct al. .c e l.:joc . 1949,71.
- *rolysoo .:::i the sub.itanees were y3rforrted, in distn. a.pp. at 200-
20? . i t -s (U) (0:3t) 2 ( b11 121.5-4 , ' d20 1.2435, n1.4520 ) was 4.:.7% un-
o
tahci sd and ?a a PrO,1s (OBt) 2, b10 56-9 , 1.1623 1 .,1413. Prh s (G) (OPr )2
si ,.ilarly gczva d.4 _'rOH. ~'rl.s(O) (OBu)? gave 17.1 BuOH, 5.7 PrAs(0nu)2,
1.11-13?, ? .0573, 1.4;528 - ad ~;..i;c C11H 50318, b,1 121-5?, -g-1.4496. 4,4
ep.s(0) (01?u)2 c.ive ~.. , :>101i and 1:3.5',,: ',3SAs(OBu)2b13 93-50, 1.0846, 1.45-
2
15, ?t, s(C) (0Bu)2 cave 1b.5.. 3uOH and 19.6,., ?tAs(OBu)^, b13 103-6 0 , 1.0727,
1.4534. The latter reaction also gave an unidentified carbonyl compound.
Cxi.d^t9.rn of 1i ',s0R lvith e02 Nave R Ls(O)0R. Thus were rrepd.: from
4J
t _,_^.^0?t - 1.5 c;t.: s02r, -q. 13 -7?, and 2.1;,j tt`'i.SO':~t, b. 1 ^ 0-l0, d'?0
1
1.1145, n-- 1.4020; frou' '.+_',t2 sC!r - 1E.6 IrOH, .'t2AsC2I-I, t. 135-70,
an A .:, ;t,. i Air, b13 5' .5-7o, ]..0904, 1.4621; fro"! &t AsCBu - 12.1`0
2
04 13A-30.50, 1.1922, 1.0219 11.9,, Ec2i~sO2H and 2' tAs(0Bu)2,
1.4522; fro.u Pde3u '.sC ?t - .``TeIiu:,s (O) Of , b2 110-110,
1.47`39 and 11.11,. .iea3uA-sO9H, :a. 116-80; from 4eiuAsOBu - 1.9% BuOH,
64.9... .;o:3tt,s ~U)0.'3tt, ?3 133-4 0 , 1.15079 1.4673, and 5.5;a McBuAs0~$, m. 126-
w
70. t .",.e eo xurl~lon of Rl :sCR to RgAsOR is v6:L'4 facile. The latter
e-..Yar:: ~ i e rear i_1y hyc.rol rzed v itb Ei -0 and ate.. rrio9.sture. _,tonic refraction
of ?s io tr, 3se co:epdse is es td. at 6.19. Pyrolysis of R3A.sO gave: from
r't -~-C ?.:~;; rt0'i, 51. t'is; from *-Pr AsO 5.9/, irOH and 35.8' Pr.,A8; from
3
b. 133-5?, 1.05609 1.4073 and 1.91:ieHuAs(08u), b11
0
, -, 1.4511; from reYu2 ~s0 3.9 1 rCHO, u;, iuOH, 14.9 0 McBu2As, b. 76-
6.5>?, 1.01G3, 1.41124, 2.5 , 73u3As, b10 114-60, 0.9886, 1.4716, and 0.8p
Bu,;':s(Oi.:o ), b13 86-7.,50 , -, 1.4685.
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 Approved For Release 2009/08/04: CIA-RDP80T00246AO10400010002-3
of, no., inu '1. c ~;r.tl>r;~. hee l ? '_` t~ 1C'.tn'^ `110 .
'.?:> mvftav ~?nd I. T. r.ra-3vskit. nokladv kad. n{?uk '". .R. 128, 309-11
and tj' e tr ha?_o' n ! ~r tv,~ . rzri be detd by add in.m their soln. in 0-free
"3-h to soli. of `3th_yl ri.o1_,3t in (CA,-Cl)2. 'Vii color changes from violet
c' or tresn; a0dn. of sn or . h- a r,3vsrt: t'9 color" back to violet.
t:cm-ourtc':, of tiTp.z.q R ~10R or. '9Al (U ) 2 do not prod-ce this colo-~., c i nng; ,
p,:,ssiblr C''.i r to screen to ; their 3r lsvo1 r 1eetrons by the unsh?:.,red 0
e" sctron i_rs. Titration of H.,kl and their halo sn analov . with org. oases
such 8 t:l'n c,
t Oc, ?B.;IN"r1, Tt20, r. ridine result, in a clean endpoint
;.hen ndieatcrs such as ',"ethyl violet, Crystal violet of Gentian violet
-?a^e uscd. The titration curves resemble thoss of strong-acid strong-base
r,i_tr ti on curves. Ale. N h ?e its with such i corspd.s. in 1:1 ratio. "t2A1Br
ih
;end : tA1G1N differ in P.cio strer. tt? from I'h3 1 and. Ph Zl.llir. Y.t. U.Ur behaves
1a. cc ~t C, -1 0.'1 t r~ci .. As nossihle to titrate and
..1C1., se ara-
2
;; el .-i ? .t, (;Cn the hs.'?is of ietn. of ac i,_" -trr?n?;ths by Trnntz8ch I a
r,,} ( n , ;, 975 (1999)) the following escenain w ser es of acid stren-
c'i .,s est;.~hlisheo : F,t x1, et2.-`:101, St w? 11r, t..' i;l The solns. for the
titY ;tioxi mu:.t t)s 'iil. es --o-Ins. with 30-^01,1. F.3b:l destroy the indicr-ltors.
tw'?` I -; tiT]enC; , retrolerr f'raeti.cn and heptans rrrzy be used a solventz~.
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 Approved For Release 2009/08/04: CIA-RDP80T00246A010400010002-3
Synthesis of, nolvorg;rnostannnxaties.
M. M. Koton and T. M. Y.iseleva (High Polymer Inst., Leningrad). Hok? ady
Aikad. *'auk . S. S. R. 130, 86-7 (1960).
iiei.ting a 1 sl molar mixt. of (1 t0)4an with iso-Bu25n(OAc),, (b10 140-1?)
2.8 hra. at 140? in inert atr-. gave 74.6% ! t0Ac and a residue of yerllowish
insolo solid, floes not m.. 2500, contg. 58% Nn; extn. with C6H6 five a
yu1lotd sh polymar C52H120015Sn8, w. 70.5?1, which is hydrolyzed by H.,0
to a colorless insol. and infusible solid C3,,lx,r ~0, 0Sn8. Apparently the
.}ol. polynu r was. 110(Snit2OSr0)nOH. Similarly (FtO)4Sn and 3u2Sn(4~'kc)2
( ui0 L46-70) gave an insol. solid contg~ 57: Sn and a seal. nolyraor, M.
60-70?, ltv? ose -10.. wt.was about 2000.
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